SE452012B - Stabil polymerdispersion av en ymppolymer av vinylmonomer och sterkelse samt forfarande for dess framstellning - Google Patents
Stabil polymerdispersion av en ymppolymer av vinylmonomer och sterkelse samt forfarande for dess framstellningInfo
- Publication number
- SE452012B SE452012B SE8102663A SE8102663A SE452012B SE 452012 B SE452012 B SE 452012B SE 8102663 A SE8102663 A SE 8102663A SE 8102663 A SE8102663 A SE 8102663A SE 452012 B SE452012 B SE 452012B
- Authority
- SE
- Sweden
- Prior art keywords
- starch
- viscosity
- diluted
- derivatized
- dispersion according
- Prior art date
Links
- 239000000178 monomer Substances 0.000 title claims description 65
- 238000000034 method Methods 0.000 title claims description 22
- 229920002554 vinyl polymer Polymers 0.000 title claims description 21
- 238000002360 preparation method Methods 0.000 title description 20
- 229920000642 polymer Polymers 0.000 title description 6
- 238000009826 distribution Methods 0.000 title description 2
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical class C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 title 1
- 229920002472 Starch Polymers 0.000 claims description 163
- 235000019698 starch Nutrition 0.000 claims description 162
- 239000008107 starch Substances 0.000 claims description 147
- 239000006185 dispersion Substances 0.000 claims description 56
- 229920000578 graft copolymer Polymers 0.000 claims description 45
- 239000007787 solid Substances 0.000 claims description 38
- 238000006467 substitution reaction Methods 0.000 claims description 36
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 20
- 125000001424 substituent group Chemical group 0.000 claims description 16
- 125000001731 2-cyanoethyl group Chemical group [H]C([H])(*)C([H])([H])C#N 0.000 claims description 14
- 239000003999 initiator Substances 0.000 claims description 14
- 238000010559 graft polymerization reaction Methods 0.000 claims description 12
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 11
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 11
- 125000000218 acetic acid group Chemical group C(C)(=O)* 0.000 claims description 11
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 11
- 238000001212 derivatisation Methods 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 6
- MZVQCMJNVPIDEA-UHFFFAOYSA-N [CH2]CN(CC)CC Chemical group [CH2]CN(CC)CC MZVQCMJNVPIDEA-UHFFFAOYSA-N 0.000 claims description 6
- 238000007334 copolymerization reaction Methods 0.000 claims description 6
- 239000004815 dispersion polymer Substances 0.000 claims description 6
- 230000007717 exclusion Effects 0.000 claims description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 42
- 239000000203 mixture Substances 0.000 description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 239000000047 product Substances 0.000 description 23
- 239000002002 slurry Substances 0.000 description 23
- 229910052757 nitrogen Inorganic materials 0.000 description 22
- 238000006116 polymerization reaction Methods 0.000 description 19
- 238000000576 coating method Methods 0.000 description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 17
- 229920000881 Modified starch Polymers 0.000 description 16
- 229920001577 copolymer Polymers 0.000 description 16
- 235000019426 modified starch Nutrition 0.000 description 16
- 229920002261 Corn starch Polymers 0.000 description 15
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 14
- -1 acrylic ester Chemical class 0.000 description 14
- 239000000853 adhesive Substances 0.000 description 14
- 230000001070 adhesive effect Effects 0.000 description 14
- 239000011541 reaction mixture Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000008120 corn starch Substances 0.000 description 11
- 102000004190 Enzymes Human genes 0.000 description 10
- 108090000790 Enzymes Proteins 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 10
- 229940088598 enzyme Drugs 0.000 description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 102000004139 alpha-Amylases Human genes 0.000 description 8
- 108090000637 alpha-Amylases Proteins 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 229940024171 alpha-amylase Drugs 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 239000011780 sodium chloride Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 6
- 238000005299 abrasion Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000010926 purge Methods 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000003518 caustics Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 4
- 235000019759 Maize starch Nutrition 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 4
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 description 4
- 239000013256 coordination polymer Substances 0.000 description 4
- 230000000977 initiatory effect Effects 0.000 description 4
- 238000010992 reflux Methods 0.000 description 4
- FCZYGJBVLGLYQU-UHFFFAOYSA-M sodium;2-[2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethoxy]ethanesulfonate Chemical compound [Na+].CC(C)(C)CC(C)(C)C1=CC=C(OCCOCCOCCS([O-])(=O)=O)C=C1 FCZYGJBVLGLYQU-UHFFFAOYSA-M 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 235000014469 Bacillus subtilis Nutrition 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
- 239000000908 ammonium hydroxide Substances 0.000 description 3
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 3
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
- 229920001400 block copolymer Polymers 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- ITZXULOAYIAYNU-UHFFFAOYSA-N cerium(4+) Chemical compound [Ce+4] ITZXULOAYIAYNU-UHFFFAOYSA-N 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 235000005822 corn Nutrition 0.000 description 3
- 239000012362 glacial acetic acid Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 3
- 229940001584 sodium metabisulfite Drugs 0.000 description 3
- 235000010262 sodium metabisulphite Nutrition 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- YMDNODNLFSHHCV-UHFFFAOYSA-N 2-chloro-n,n-diethylethanamine Chemical compound CCN(CC)CCCl YMDNODNLFSHHCV-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- MKRNVBXERAPZOP-UHFFFAOYSA-N Starch acetate Chemical class O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OC(C)=O)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 MKRNVBXERAPZOP-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000005903 acid hydrolysis reaction Methods 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000004026 adhesive bonding Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 230000001580 bacterial effect Effects 0.000 description 2
- 238000010923 batch production Methods 0.000 description 2
- 239000007853 buffer solution Substances 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 230000002255 enzymatic effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- JKNCOURZONDCGV-UHFFFAOYSA-N 2-(dimethylamino)ethyl 2-methylprop-2-enoate Chemical compound CN(C)CCOC(=O)C(C)=C JKNCOURZONDCGV-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000937119 Ceresa Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 101100298295 Drosophila melanogaster flfl gene Proteins 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 238000007696 Kjeldahl method Methods 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000005041 Mylar™ Substances 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920001218 Pullulan Polymers 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 229920004896 Triton X-405 Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000006177 alkyl benzyl group Chemical group 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 125000004966 cyanoalkyl group Chemical group 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- IVJISJACKSSFGE-UHFFFAOYSA-N formaldehyde;1,3,5-triazine-2,4,6-triamine Chemical compound O=C.NC1=NC(N)=NC(N)=N1 IVJISJACKSSFGE-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- KKFHAJHLJHVUDM-UHFFFAOYSA-N n-vinylcarbazole Chemical compound C1=CC=C2N(C=C)C3=CC=CC=C3C2=C1 KKFHAJHLJHVUDM-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- YFQOMWCXASCIMB-UHFFFAOYSA-N nonylperoxybenzene Chemical compound CCCCCCCCCOOC1=CC=CC=C1 YFQOMWCXASCIMB-UHFFFAOYSA-N 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000015927 pasta Nutrition 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920001592 potato starch Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000012898 sample dilution Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 238000012289 standard assay Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- FBWNMEQMRUMQSO-UHFFFAOYSA-N tergitol NP-9 Chemical compound CCCCCCCCCC1=CC=C(OCCOCCOCCOCCOCCOCCOCCOCCOCCO)C=C1 FBWNMEQMRUMQSO-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paper (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/144,009 US4301017A (en) | 1980-04-28 | 1980-04-28 | Stable, liquid starch graft copolymer composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8102663L SE8102663L (sv) | 1981-10-29 |
| SE452012B true SE452012B (sv) | 1987-11-09 |
Family
ID=22506671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE8102663A SE452012B (sv) | 1980-04-28 | 1981-04-27 | Stabil polymerdispersion av en ymppolymer av vinylmonomer och sterkelse samt forfarande for dess framstellning |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US4301017A (hu) |
| JP (1) | JPS5718714A (hu) |
| AR (1) | AR227423A1 (hu) |
| AU (1) | AU543579B2 (hu) |
| BE (1) | BE888604A (hu) |
| BG (1) | BG36788A3 (hu) |
| BR (1) | BR8102550A (hu) |
| CA (1) | CA1184688A (hu) |
| DE (1) | DE3116797A1 (hu) |
| ES (1) | ES502297A0 (hu) |
| FI (1) | FI68633C (hu) |
| FR (1) | FR2481297A1 (hu) |
| GB (1) | GB2075525B (hu) |
| HU (1) | HU190674B (hu) |
| IT (1) | IT1136585B (hu) |
| MX (1) | MX158448A (hu) |
| NL (1) | NL191464C (hu) |
| NZ (1) | NZ196942A (hu) |
| PT (1) | PT72928B (hu) |
| SE (1) | SE452012B (hu) |
| SU (1) | SU1508965A3 (hu) |
| YU (1) | YU42566B (hu) |
Families Citing this family (33)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4375535A (en) * | 1980-04-28 | 1983-03-01 | Standard Brands Incorporated | Stable liquid, amylopectin starch graft copolymer compositions |
| DE3627594A1 (de) | 1986-08-14 | 1988-02-18 | Basf Ag | Leimungsmittel fuer papier auf basis feinteiliger waessriger dispersionen |
| DE3702712A1 (de) * | 1987-01-30 | 1988-08-11 | Basf Ag | Leimungsmittel fuer papier auf basis feinteiliger waessriger dispersionen |
| US5416181A (en) * | 1989-02-10 | 1995-05-16 | Penford Products Company | Reinforced films made from water soluble polymers |
| US5003022A (en) * | 1989-02-10 | 1991-03-26 | Penford Products Company | Starch graft polymers |
| DE4133193A1 (de) * | 1991-10-07 | 1993-04-08 | Basf Ag | Waessrige polymerisatdispersionen |
| FI90793C (fi) * | 1991-11-25 | 1994-03-25 | Raision Tehtaat Oy Ab | Menetelmä paperin tai kartongin läpäisevyyden vähentämiseksi sekä menetelmässä käytettävä aine |
| DE69313255T2 (de) * | 1992-06-19 | 1997-12-18 | Penford Products Co., Cedar Rapids, Ia. | Bindemittel aus kationischer staerke/vinylacetat zum beschichten von pappe |
| US5851684A (en) * | 1992-06-22 | 1998-12-22 | Arjo Wiggins Deutschland Gmbh | Decorative sheets used in the production of laminated panels |
| DE4233497A1 (de) * | 1992-10-06 | 1994-04-07 | Basf Ag | Verwendung von wäßrigen Polymerisatdispersionen als Textilhilfsmittel zur pflegeleichten Veredlung von Textilien |
| US5707720A (en) * | 1993-02-24 | 1998-01-13 | Penford Products Co. | Methods and materials for coating textile compositions |
| US5525414A (en) * | 1994-02-03 | 1996-06-11 | Penford Products Co. | Method and materials for coating synthetic textile compositions |
| JP2997995B2 (ja) * | 1995-09-13 | 2000-01-11 | 日本コーンスターチ株式会社 | 生分解性樹脂組成物の水系分散液 |
| ES2112192B1 (es) * | 1995-11-29 | 1999-09-16 | Univ Pais Vasco | Mezclas de almidon y copolimero de etileno y acetato de vinilo y adhesivos termofusibles que las contienen. |
| EP0865535A1 (en) * | 1995-12-05 | 1998-09-23 | The Dow Chemical Company | Method for externally sizing fibrous materials |
| WO1999009251A1 (en) * | 1997-08-15 | 1999-02-25 | Penford Corporation | Starch copolymer products and process |
| GB9807426D0 (en) | 1998-04-08 | 1998-06-03 | Ici Plc | Environmentally friendly aqueous architectural coating compositions |
| US5886124A (en) * | 1998-05-05 | 1999-03-23 | Grain Processing Corporation | Liquid-absorbent polymer and gelatinoid product |
| US6090884A (en) * | 1998-05-07 | 2000-07-18 | S. C. Johnson Commercial Markets, Inc. | Starch degradation/graft polymerization composition, process, and uses thereof |
| JP2002523108A (ja) * | 1998-08-31 | 2002-07-30 | ペンフォード コーポレイション | 改善された酵素希釈澱粉 |
| DE19903979C2 (de) * | 1999-01-25 | 2000-12-21 | Worlee Chemie G M B H | Pfropfpolymerisat auf Stärkebasis, Verfahren zu seiner Herstellung und seine Verwendung in Druckfarben über Überdrucklacken |
| FI105565B (fi) * | 1999-02-05 | 2000-09-15 | Raisio Chem Oy | Polymeeridispersio ja menetelmä sen valmistamiseksi |
| FI117716B (fi) * | 2000-04-18 | 2007-01-31 | Ciba Sc Holding Ag | Menetelmä täyteaineen esikäsittelemiseksi, modifioitu täyteaine ja sen käyttö |
| US6414055B1 (en) | 2000-04-25 | 2002-07-02 | Hercules Incorporated | Method for preparing aqueous size composition |
| US6593414B2 (en) * | 2000-08-09 | 2003-07-15 | Penford Corporation | Pressure sensitive adhesives |
| FI116536B (fi) * | 2001-04-12 | 2005-12-15 | Ciba Sc Holding Ag | Uusi päällystyspastakoostumus |
| EP2297283A1 (en) * | 2008-06-23 | 2011-03-23 | CSL Carbon Solutions Ltd | Process for the preparation of hydrothermal hybrid material from biomass, and hydrothermal hybrid material obtainable by the process |
| CN101906190B (zh) * | 2010-08-23 | 2011-12-14 | 成都海旺科技有限责任公司 | 丙烯酸与丙烯酰胺接枝氰乙基淀粉的制备方法 |
| EP2514777A1 (en) | 2011-04-20 | 2012-10-24 | Basf Se | Polysaccharide macromonomer based co-polymer |
| EP2532682A1 (en) | 2011-04-20 | 2012-12-12 | Basf Se | A process for the preparation of co-polymerizable polysaccharide derivatives |
| WO2020249706A1 (en) * | 2019-06-14 | 2020-12-17 | Basf Se | Aqueous polymer dispersions suitable as opacifiers in liquid formulations |
| EP4323416A1 (de) | 2021-04-16 | 2024-02-21 | Wacker Chemie AG | Stärke-hybridcopolymere |
| WO2024183924A1 (en) | 2023-03-09 | 2024-09-12 | Wacker Chemie Ag | Starch hybrid copolymers |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1162342B (de) * | 1955-09-21 | 1964-02-06 | Polymer Corp | Verfahren zum Aufpfropfen von Monomeren auf Polysaccharide und Proteine oder deren Derivate |
| US2922768A (en) * | 1956-04-12 | 1960-01-26 | Mino Guido | Process for polymerization of a vinylidene monomer in the presence of a ceric salt and an organic reducing agent |
| NL114122C (hu) * | 1959-03-13 | |||
| US3061471A (en) * | 1959-04-23 | 1962-10-30 | Staley Mfg Co A E | Sizing hydrophobic fibers with graft copolymers of gelatinized starch and acrylates |
| NL261869A (hu) * | 1959-04-23 | 1900-01-01 | ||
| US3377302A (en) * | 1966-01-18 | 1968-04-09 | Agriculture Usa | Saponified starch acrylate grafts |
| US3669915A (en) * | 1970-09-08 | 1972-06-13 | Us Agriculture | Flocculants from starch graft copolymers |
| US3661819A (en) * | 1970-09-21 | 1972-05-09 | American Cyanamid Co | Aqueous coating for use in electrodepositions containing fully etherified polymethylol aminotriazine crosslinking agents |
| US3770672A (en) * | 1971-02-10 | 1973-11-06 | Nihon Rika Seishi K K | Paste for gummed tape and process for producing the same from hydrolyzed starch |
| JPS5341199B2 (hu) * | 1972-03-06 | 1978-10-31 | ||
| NL7404110A (hu) * | 1973-02-22 | 1974-09-30 | ||
| US3809664A (en) * | 1973-08-16 | 1974-05-07 | Us Agriculture | Method of preparing starch graft polymers |
| JPS5411358B2 (hu) * | 1974-02-01 | 1979-05-14 | ||
| US3984361A (en) * | 1975-05-30 | 1976-10-05 | The United States Of America As Represented By The Secretary Of Agriculture | Preparation of graft polymer latexes by sonification |
| US4079025A (en) * | 1976-04-27 | 1978-03-14 | A. E. Staley Manufacturing Company | Copolymerized starch composition |
| US4159260A (en) * | 1977-11-23 | 1979-06-26 | Henkel Corporation | Dispersible starch graft copolymer blend |
| US4204983A (en) * | 1979-05-07 | 1980-05-27 | Illinois Cereal Mills | Absorbent polymeric compositions derived from amylaceous material-formaldehyde substrates |
-
1980
- 1980-04-28 US US06/144,009 patent/US4301017A/en not_active Expired - Lifetime
-
1981
- 1981-04-23 GB GB8112642A patent/GB2075525B/en not_active Expired
- 1981-04-27 HU HU811089A patent/HU190674B/hu not_active IP Right Cessation
- 1981-04-27 PT PT72928A patent/PT72928B/pt unknown
- 1981-04-27 NZ NZ196942A patent/NZ196942A/xx unknown
- 1981-04-27 AU AU69887/81A patent/AU543579B2/en not_active Expired
- 1981-04-27 BR BR8102550A patent/BR8102550A/pt not_active IP Right Cessation
- 1981-04-27 SE SE8102663A patent/SE452012B/sv not_active IP Right Cessation
- 1981-04-27 FI FI811300A patent/FI68633C/fi not_active IP Right Cessation
- 1981-04-27 SU SU813277450A patent/SU1508965A3/ru active
- 1981-04-28 BE BE0/204633A patent/BE888604A/fr not_active IP Right Cessation
- 1981-04-28 NL NL8102092A patent/NL191464C/xx not_active IP Right Cessation
- 1981-04-28 MX MX187044A patent/MX158448A/es unknown
- 1981-04-28 YU YU1107/81A patent/YU42566B/xx unknown
- 1981-04-28 AR AR285110A patent/AR227423A1/es active
- 1981-04-28 DE DE19813116797 patent/DE3116797A1/de active Granted
- 1981-04-28 FR FR8108465A patent/FR2481297A1/fr active Granted
- 1981-04-28 ES ES502297A patent/ES502297A0/es active Granted
- 1981-04-28 JP JP6349981A patent/JPS5718714A/ja active Granted
- 1981-04-28 CA CA000376374A patent/CA1184688A/en not_active Expired
- 1981-04-28 BG BG051869A patent/BG36788A3/xx unknown
- 1981-04-28 IT IT21422/81A patent/IT1136585B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| BE888604A (fr) | 1981-10-28 |
| HU190674B (en) | 1986-10-28 |
| YU42566B (en) | 1988-10-31 |
| AU543579B2 (en) | 1985-04-26 |
| US4301017A (en) | 1981-11-17 |
| ES8203397A1 (es) | 1982-04-01 |
| FI811300L (fi) | 1981-10-29 |
| MX158448A (es) | 1989-02-02 |
| FI68633C (fi) | 1985-10-10 |
| IT8121422A0 (it) | 1981-04-28 |
| JPS5718714A (en) | 1982-01-30 |
| FI68633B (fi) | 1985-06-28 |
| BR8102550A (pt) | 1982-01-05 |
| AR227423A1 (es) | 1982-10-29 |
| PT72928B (en) | 1982-04-12 |
| SE8102663L (sv) | 1981-10-29 |
| AU6988781A (en) | 1981-11-05 |
| GB2075525B (en) | 1984-06-20 |
| NZ196942A (en) | 1983-11-18 |
| FR2481297A1 (fr) | 1981-10-30 |
| NL191464B (nl) | 1995-03-16 |
| IT1136585B (it) | 1986-09-03 |
| NL191464C (nl) | 1995-07-18 |
| DE3116797C2 (hu) | 1990-11-22 |
| NL8102092A (nl) | 1981-11-16 |
| ES502297A0 (es) | 1982-04-01 |
| SU1508965A3 (ru) | 1989-09-15 |
| PT72928A (en) | 1981-05-01 |
| YU110781A (en) | 1983-10-31 |
| FR2481297B1 (hu) | 1985-01-25 |
| CA1184688A (en) | 1985-03-26 |
| GB2075525A (en) | 1981-11-18 |
| BG36788A3 (en) | 1985-01-15 |
| DE3116797A1 (de) | 1982-03-18 |
| JPH0212247B2 (hu) | 1990-03-19 |
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