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RU2018138738A - Модификатор индекса текучести полимера - Google Patents

Модификатор индекса текучести полимера Download PDF

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RU2018138738A
RU2018138738A RU2018138738A RU2018138738A RU2018138738A RU 2018138738 A RU2018138738 A RU 2018138738A RU 2018138738 A RU2018138738 A RU 2018138738A RU 2018138738 A RU2018138738 A RU 2018138738A RU 2018138738 A RU2018138738 A RU 2018138738A
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polymer
yield index
modifier
index modifier
yield
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RU2018138738A
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RU2018138738A3 (ru
RU2736067C2 (ru
Inventor
Чарльз Д. ЛЕСТЕР
Марк Дж. ГУДИ
Тимоти Р. ЛИНН
Кевин Дж. КАНН
Джон Х. МУРХАУЗ
Уильям А. МЭТЬЮЗ
Кефу САН
Франсуа АЛЕКСАНДР
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ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/06Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C08F4/22Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of chromium, molybdenum or tungsten
    • C08F4/24Oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/69Chromium, molybdenum, tungsten or compounds thereof
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/01Hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/06Catalyst characterized by its size
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/24Polymer with special particle form or size

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polyethers (AREA)
  • Polymerization Catalysts (AREA)
  • Polyesters Or Polycarbonates (AREA)

Claims (13)

1. Способ модификации индекса текучести полимера, включающий:
обеспечение мономеров в реакторе-полимеризаторе;
обеспечение хромового катализатора в реакторе-полимеризаторе; и
обеспечение активного количества модификатора индекса текучести в реакторе-полимеризаторе, при этом указанный модификатор индекса текучести выбран из диоксида углерода, монооксида углерода, 2,4-гексадиена и их комбинаций.
2. Способ по п. 1, отличающийся тем, что указанный модификатор индекса текучести представляет собой диоксид углерода и составляет от 0,50 частей на миллион до 50,00 частей на миллион в расчете на указанные мономеры.
3. Способ по п. 2, отличающийся тем, что обеспечение активного количества модификатора индекса текучести в реакторе-полимеризаторе позволяет получить полимер с индексом текучести, пониженным по сравнению со вторым полимером, имеющим другой индекс текучести, где указанный второй полимер получен посредством того же способа полимеризации, но без применения активного количества модификатора индекса текучести.
4. Способ по п. 3, отличающийся тем, что указанный индекс текучести полимера понижен на от примерно 5% до примерно 50% по сравнению со вторым полимером.
5. Способ по п. 1, отличающийся тем, что указанный модификатор индекса текучести представляет собой монооксид углерода и составляет от 0,010 частей на миллион до 2,000 частей на миллион в расчете на указанные мономеры.
6. Способ по п. 5, отличающийся тем, что обеспечение активного количества модификатора индекса текучести в реакторе-полимеризаторе позволяет получить полимер с индексом текучести, пониженным по сравнению со вторым полимером, имеющим другой индекс текучести, где указанный второй полимер получен посредством того же способа полимеризации, но без применения активного количества модификатора индекса текучести.
7. Способ по п. 6, отличающийся тем, что указанный индекс текучести полимера понижен на от примерно 5% до примерно 50% по сравнению со вторым полимером.
8. Способ по п. 1, отличающийся тем, что указанный модификатор индекса текучести представляет собой 2,4-гексадиен и составляет от 0,05 частей на миллион до 5,00 частей на миллион в расчете на указанные мономеры.
9. Способ по п. 8, отличающийся тем, что обеспечение активного количества модификатора индекса текучести в реакторе-полимеризаторе позволяет получить полимер с индексом текучести полимера, повышенным по сравнению со вторым полимером, имеющим другой индекс текучести, где указанный второй полимер получен посредством того же процесса полимеризации, но без применения активного количества модификатора индекса текучести.
10. Способ по п. 9, отличающийся тем, что указанный индекс текучести полимера повышен на от примерно 50% до примерно 250% по сравнению со вторым полимером.
RU2018138738A 2016-04-20 2017-04-17 Модификатор индекса текучести полимера RU2736067C2 (ru)

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US201662325175P 2016-04-20 2016-04-20
US62/325,175 2016-04-20
PCT/US2017/027872 WO2017184483A1 (en) 2016-04-20 2017-04-17 Polymer flow index modifier

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RU2018138738A3 RU2018138738A3 (ru) 2020-05-28
RU2736067C2 RU2736067C2 (ru) 2020-11-11

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EP (2) EP3445790B1 (ru)
JP (1) JP6971252B2 (ru)
KR (2) KR102490005B1 (ru)
CN (2) CN113912760B (ru)
BR (1) BR112018069517B1 (ru)
CA (1) CA3021386A1 (ru)
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CN108884179A (zh) 2018-11-23
US20210102016A1 (en) 2021-04-08
EP3445790B1 (en) 2023-07-12
KR20220016277A (ko) 2022-02-08
CA3021386A1 (en) 2017-10-26
CN113912760A (zh) 2022-01-11
US11655316B2 (en) 2023-05-23
BR112018069517A2 (pt) 2019-01-22
KR102354621B1 (ko) 2022-01-25
RU2018138738A3 (ru) 2020-05-28
JP2019515058A (ja) 2019-06-06
BR112018069517B1 (pt) 2022-12-20
EP3445790A1 (en) 2019-02-27
WO2017184483A1 (en) 2017-10-26
RU2736067C2 (ru) 2020-11-11
CN113912760B (zh) 2023-08-08
CN108884179B (zh) 2021-09-21
EP4234589A2 (en) 2023-08-30
KR102490005B1 (ko) 2023-01-19
EP4234589A3 (en) 2023-09-13
KR20180136463A (ko) 2018-12-24
SG11201808889RA (en) 2018-11-29
US10870719B2 (en) 2020-12-22
US20190119416A1 (en) 2019-04-25

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