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RU2003110601A - METHOD FOR PRODUCING 1- (DIALCOXYMETHYL) -2-HYDRO [60] FULLERENES - Google Patents

METHOD FOR PRODUCING 1- (DIALCOXYMETHYL) -2-HYDRO [60] FULLERENES

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Publication number
RU2003110601A
RU2003110601A RU2003110601/04A RU2003110601A RU2003110601A RU 2003110601 A RU2003110601 A RU 2003110601A RU 2003110601/04 A RU2003110601/04 A RU 2003110601/04A RU 2003110601 A RU2003110601 A RU 2003110601A RU 2003110601 A RU2003110601 A RU 2003110601A
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RU
Russia
Prior art keywords
etalcl
amount
fullerenes
hydro
mmol
Prior art date
Application number
RU2003110601/04A
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Russian (ru)
Other versions
RU2240302C1 (en
Inventor
Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Евгений Федорович Дехтярь
Ренат Фаритович Туктаров
Ренат Рафикович Абзалимов
Леонард Мухибович Халилов
Original Assignee
ГУ Институт нефтехимии и катализа Академии наук Республики Башкортостан и УНЦ РАН
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Priority to RU2003110601/04A priority Critical patent/RU2240302C1/en
Priority claimed from RU2003110601/04A external-priority patent/RU2240302C1/en
Application granted granted Critical
Publication of RU2003110601A publication Critical patent/RU2003110601A/en
Publication of RU2240302C1 publication Critical patent/RU2240302C1/en

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Claims (1)

Способ получения 1-(диалкоксиметил)-2-гидро[60]фуллеренов общей формулы (I)The method of obtaining 1- (dialkoxymethyl) -2-hydro [60] fullerenes of the General formula (I)
Figure 00000001
Figure 00000001
 где R=Et, n-Pr, n-Bu; m=1-3,where R = Et, n-Pr, n-Bu; m = 1-3, характеризующийся тем, что фуллерен С60 подвергают взаимодействию с этилалюминийдихлоридом EtAlCl2 и магнием при мольном соотношении C60:EtAlCl2:Mg=0,04:(1,0-1,4):(1,0-1,4) ммолей в присутствии катализатора титанацендихлорида (Cp2TiCl2), взятого в количестве 0,006-0,010 ммолей по отношению к С60, в атмосфере аргона при комнатной температуре (20-21°С) и атмосферном давлении в среде толуола в течение 8 ч с последующим добавлением к реакционной массе при температуре -15°С катализатора хлорида меди (CuCl) в количестве 0,006-0,010 ммолей и триалкилортоформиата (СН(OR)3) в эквимольном по отношению к EtAlCl2 количестве, после чего реакционную массу перемешивают при комнатной температуре в течение 6-10 ч.characterized in that the fullerene C 60 is reacted with ethyl aluminum dichloride EtAlCl 2 and magnesium in a molar ratio of C 60 : EtAlCl 2 : Mg = 0.04: (1.0-1.4) :( 1.0-1.4) mmoles in the presence of a titanacene dichloride catalyst (Cp 2 TiCl 2 ), taken in an amount of 0.006-0.010 mmol with respect to C 60 , in an argon atmosphere at room temperature (20-21 ° C) and atmospheric pressure in toluene for 8 hours, followed by addition to the reaction mass at a temperature of -15 ° C of a catalyst of copper chloride (CuCl) in an amount of 0.006-0.010 mmol and trialkyl orthoformate (CH (OR) 3 ) in equimole nom in relation to EtAlCl 2 amount, after which the reaction mass is stirred at room temperature for 6-10 hours
RU2003110601/04A 2003-04-14 2003-04-14 Method for preparing 1-(dialkoxymethyl)-2-hydro[60]fullerenes RU2240302C1 (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2384561C2 (en) * 2008-01-28 2010-03-20 ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук Method of producing 1-alkoxy- or 1-cycloalkoxy-1,2-dihydro[60]fullerene
RU2385859C2 (en) * 2008-01-28 2010-04-10 ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук Method of producing 1-phenoxy-1,2-dihydro[60]fullerene
RU2375343C2 (en) * 2008-01-28 2009-12-10 Институт Нефтехимии И Катализа Российская Академия Наук Method of producing 1-(2-propenyloxy)- or 1-(phenylmethoxy)-1,2-dihydro[60]fullerene
RU2540082C2 (en) * 2012-10-25 2015-01-27 Федеральное Государственное Бюджетное Учреждение Науки Институт Нефтехимии И Катализа Ран Method of obtaining aryl(c60-ih)[5,6]fullerene-(9h)-yl ketones

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RU2160270C1 (en) * 1999-07-12 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of preparing di(1-ethyl-1-alkoxyaluminium) [60] fullerenes
RU2160274C1 (en) * 1999-07-14 2000-12-10 Институт нефтехимии и катализа АН РБ и УНЦ РАН Method of preparing 1-alkoxy-2,3-fullerene [60] alumacyclopropanes

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