NO752185L - - Google Patents
Info
- Publication number
- NO752185L NO752185L NO752185A NO752185A NO752185L NO 752185 L NO752185 L NO 752185L NO 752185 A NO752185 A NO 752185A NO 752185 A NO752185 A NO 752185A NO 752185 L NO752185 L NO 752185L
- Authority
- NO
- Norway
- Prior art keywords
- monomer
- weight
- acrylic acid
- cross
- acid
- Prior art date
Links
- 239000000178 monomer Substances 0.000 claims description 63
- 229920001577 copolymer Polymers 0.000 claims description 24
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 21
- 238000004132 cross linking Methods 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 14
- -1 acrylic ester Chemical class 0.000 claims description 13
- 229920000570 polyether Polymers 0.000 claims description 11
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 10
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 claims description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 7
- 125000001033 ether group Chemical group 0.000 claims description 6
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 claims description 6
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 3
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 3
- 239000011976 maleic acid Substances 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 2
- 229920001542 oligosaccharide Polymers 0.000 claims 2
- 150000002482 oligosaccharides Chemical class 0.000 claims 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- 239000000243 solution Substances 0.000 description 35
- 229920000642 polymer Polymers 0.000 description 27
- 150000003839 salts Chemical class 0.000 description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- 239000002562 thickening agent Substances 0.000 description 16
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
- 239000000463 material Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000003431 cross linking reagent Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 229920001897 terpolymer Polymers 0.000 description 6
- 229920000715 Mucilage Polymers 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 5
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 230000008719 thickening Effects 0.000 description 5
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 4
- 229930006000 Sucrose Natural products 0.000 description 4
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- PBOSTUDLECTMNL-UHFFFAOYSA-N lauryl acrylate Chemical compound CCCCCCCCCCCCOC(=O)C=C PBOSTUDLECTMNL-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000005720 sucrose Substances 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- 150000001253 acrylic acids Chemical class 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000005553 drilling Methods 0.000 description 3
- 239000011953 free-radical catalyst Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000006072 paste Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 241000416162 Astragalus gummifer Species 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920001615 Tragacanth Polymers 0.000 description 2
- 150000008065 acid anhydrides Chemical class 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 150000008064 anhydrides Chemical group 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 229910001867 inorganic solvent Inorganic materials 0.000 description 2
- 239000003049 inorganic solvent Substances 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 2
- 239000002674 ointment Substances 0.000 description 2
- 229920000867 polyelectrolyte Polymers 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000000518 rheometry Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000004334 sorbic acid Substances 0.000 description 2
- 229940075582 sorbic acid Drugs 0.000 description 2
- 239000000375 suspending agent Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 239000000606 toothpaste Substances 0.000 description 2
- XVOUMQNXTGKGMA-OWOJBTEDSA-N (E)-glutaconic acid Chemical compound OC(=O)C\C=C\C(O)=O XVOUMQNXTGKGMA-OWOJBTEDSA-N 0.000 description 1
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 1
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- PUGOMSLRUSTQGV-UHFFFAOYSA-N 2,3-di(prop-2-enoyloxy)propyl prop-2-enoate Chemical compound C=CC(=O)OCC(OC(=O)C=C)COC(=O)C=C PUGOMSLRUSTQGV-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- WROUWQQRXUBECT-UHFFFAOYSA-N 2-ethylacrylic acid Chemical compound CCC(=C)C(O)=O WROUWQQRXUBECT-UHFFFAOYSA-N 0.000 description 1
- ONPJWQSDZCGSQM-UHFFFAOYSA-N 2-phenylprop-2-enoic acid Chemical compound OC(=O)C(=C)C1=CC=CC=C1 ONPJWQSDZCGSQM-UHFFFAOYSA-N 0.000 description 1
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 1
- GXLIFJYFGMHYDY-ZZXKWVIFSA-N 4-chlorocinnamic acid Chemical compound OC(=O)\C=C\C1=CC=C(Cl)C=C1 GXLIFJYFGMHYDY-ZZXKWVIFSA-N 0.000 description 1
- FEIQOMCWGDNMHM-UHFFFAOYSA-N 5-phenylpenta-2,4-dienoic acid Chemical compound OC(=O)C=CC=CC1=CC=CC=C1 FEIQOMCWGDNMHM-UHFFFAOYSA-N 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical compound ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 239000004160 Ammonium persulphate Substances 0.000 description 1
- 244000061520 Angelica archangelica Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- 235000001287 Guettarda speciosa Nutrition 0.000 description 1
- 229920000569 Gum karaya Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000004159 Potassium persulphate Substances 0.000 description 1
- 241000934878 Sterculia Species 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229940091181 aconitic acid Drugs 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- BHELZAPQIKSEDF-UHFFFAOYSA-N allyl bromide Chemical compound BrCC=C BHELZAPQIKSEDF-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- 235000019395 ammonium persulphate Nutrition 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- AOESAXAWXYJFNC-UHFFFAOYSA-N bis(prop-2-enyl) propanedioate Chemical compound C=CCOC(=O)CC(=O)OCC=C AOESAXAWXYJFNC-UHFFFAOYSA-N 0.000 description 1
- XNNQFQFUQLJSQT-UHFFFAOYSA-N bromo(trichloro)methane Chemical compound ClC(Cl)(Cl)Br XNNQFQFUQLJSQT-UHFFFAOYSA-N 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- RLYNGYDVXRKEOO-SQQVDAMQSA-N but-2-enoic acid;(e)-but-2-enoic acid Chemical compound CC=CC(O)=O.C\C=C\C(O)=O RLYNGYDVXRKEOO-SQQVDAMQSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 229950005499 carbon tetrachloride Drugs 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 230000009918 complex formation Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- MRIZMKJLUDDMHF-UHFFFAOYSA-N cumene;hydrogen peroxide Chemical class OO.CC(C)C1=CC=CC=C1 MRIZMKJLUDDMHF-UHFFFAOYSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 239000000850 decongestant Substances 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- FWLDHHJLVGRRHD-UHFFFAOYSA-N decyl prop-2-enoate Chemical compound CCCCCCCCCCOC(=O)C=C FWLDHHJLVGRRHD-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- KHAYCTOSKLIHEP-UHFFFAOYSA-N docosyl prop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCCCCCOC(=O)C=C KHAYCTOSKLIHEP-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 description 1
- 238000006266 etherification reaction Methods 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004872 foam stabilizing agent Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 125000000686 lactone group Chemical group 0.000 description 1
- 150000002596 lactones Chemical group 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Substances [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- FEZFGASTIQVZSC-UHFFFAOYSA-N nonanoyl nonaneperoxoate Chemical compound CCCCCCCCC(=O)OOC(=O)CCCCCCCC FEZFGASTIQVZSC-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Substances [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 235000019394 potassium persulphate Nutrition 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Substances [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- SPDUKHLMYVCLOA-UHFFFAOYSA-M sodium;ethaneperoxoate Chemical compound [Na+].CC(=O)O[O-] SPDUKHLMYVCLOA-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 235000010199 sorbic acid Nutrition 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- UBLMWQYLVOVZMT-UHFFFAOYSA-N tert-butyl n-(3-acetylphenyl)carbamate Chemical compound CC(=O)C1=CC=CC(NC(=O)OC(C)(C)C)=C1 UBLMWQYLVOVZMT-UHFFFAOYSA-N 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
- 229960000834 vinyl ether Drugs 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K47/00—Medicinal preparations characterised by the non-active ingredients used, e.g. carriers or inert additives; Targeting or modifying agents chemically bound to the active ingredient
- A61K47/30—Macromolecular organic or inorganic compounds, e.g. inorganic polyphosphates
- A61K47/32—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. carbomers, poly(meth)acrylates, or polyvinyl pyrrolidone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/08—Homopolymers or copolymers of acrylic acid esters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/916—Hydrogel compositions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/93—Water swellable or hydrophilic
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/932—Thickener or dispersant for aqueous system
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Cosmetics (AREA)
Description
Vannfortykningsmiddel og emulgeringsmiddel.
Foreliggende oppfinnelse vedrører sampolymerisat av en karboksylsyremonomer og en eller flere høyere, d.v.s. med 10 - 30 karbonatomer, alkylakrylatestere som overraskende har vist seg å virke som effektive fortykningsmidler for vannholdige oppløsninger•til og med i nærvær av betydelige mengder uorganiske salter slik som natriumklorid.
Det er kjent (kfr. US patent 2.798.053) at sampolymerisater av karboksylsyremonomere slik som akrylsyre, og ca. 0,1 - 1,0 vekt-% av et polyalkenylpolyeter-kryssbindemiddel, slik som polyallylsakkarose, er gellignende polymere som er uoppløselige i vann og uorganiske oppløsningsmidler og. som, spesielt i form av sine salter, absorberer store mengder vann eller oppløsningsmiddel med derav følgende mangfoldig økning i volum. Andre monomere som ifølge nevnte patent er kombinerbare med 40 - 95 vekt-% akrylsyre og 0,2 - 2,5 vekt-% polyalkenylpolyeter, er 4 - 59 vekt-% metylakrylat og 2-etylheksylakrylat. Disse polyelektrolyttpolymere er anvendbare som fortyknings- og suspenderingsmiddel i forskjellige slamlignende og kolloidale,, gellignende anvendelsesområder, slik som tannpastaer, medisinske geler, kremer og salver, trykkpastafortykningsmiddel og lignende. Et fremdeles uløst problem er at de fleste polyelektrolyttopp-løsninger minsker sin viskositet drastisk ved tilsetning av elektrolytter slik som natriumklorid. Kjente fortykningsmidler er ionefølsomme og kan ikke effektivt opprettholde eller øke viskositetene hos vann eller oppløsninger,i uorganiske oppløs-ningsmidler som inneholder uorganiske salter, slik som natriumklorid, også når en tredje monomer slik som 2-etylheksylakrylat befinner seg i polymeren, som foreslått i nevnte patent. Denne egenskap ville være av stor verdi, f.eks. ved fortykning . av • visse latekser, boreslam for oljeboring, næringsmiddelpreparater, ioniske vaskemidler, fargestoffpastaer, kosmetiske preparater og farmasøytika. I visse tilfeller er problemet å fortykke en oppløsning som inneholder en gitt mengde salt, f.eks. i en spesiell farmasøytisk resept. I andre tilfeller kan det være ønskelig å opprettholde et konstant viskositetsnivå i en oppløs-ning, i hvilken mengden av tilstedeværende salt øker, f.eks..i et bilbatteri.
Polymere av karboksylsyremonomer og en eller flere akrylsyreestere med en lengde på den alifatiske kjede på 10 - 30 karbonatomer, har vist seg å være effektive vannfortykningsmidler, som når de er nøytraliserte med et basisk materiale, danner vannmucilago, som har meget større bestandighet mot kraf-' tig fall i viskositet når et salt, slik som natriumklorid,
enten tilsettes dertil eller allerede befinner seg i vannsys-temet, enn mucilago som er fremstilt med kjente fortykningsmidler .
Avhengig av den benyttede andel alifatiske akrylater med kritisk lang kjede, varierer polymerene betydelig i egenskaper. Variasjon av andelen akrylatmonomer tjener til å regulere vannoppløsnings-viskositeten hos sampolymerisatoppløsninger, regulere reologien eller,strømningsegenskapene' hos kombinasjoner av polymer og et oppløsningsmiddel, slik som vann, og å tilveiebringe evne til å fortykke ionholdige vannoppløsninger med en effektivitet som hittil ikke har vært mulig med kjente fortykningsmidler.
Foreliggende nye sampolymerisat kan eventuelt kryss-bindes ved inneslutning i polymersystemet av en kryssbindande monomer som utgjøres av polymeriserbare forbindelser inneholdende en polymeriserbar gruppe CH2=Cd og minst en annen polymeriserbar gruppe, hvorved de umettede bindinger i den polymeriserbare gruppe er ikke-konjugerte med hensyn til hverandre.
Når en eventuell kryssbindende monomer er tilstede, tjener den til å tilveiebringe spesiell regulering av reologien hos mucilago. Uten noe tilstedeværende kryssbindemiddel danner fortykningsmidlet som inneholder mindre enn 20-30 vekt-% akryl-ester, ofte oppløsningen som er trådlignende i konsistens, før et salt tilsettes, men som blir jevne og smørlignende i utseende etter tilsetning av et salt. En oppløsning eller mucilago av et kryssbundet.fortykningsmiddel ifølge oppfinnelsen, som omfatter et egnet innhold alkylakrylat eller -metakrylat- med lang kjede, er vanligvis smørlignende i sin begynnelsesfase og bibeholder mer konstant oppløsningsviskositet i de tilfeller når salt tilsettes til oppløsningen i økende mengder, enn kjente materialer.
Høyverdige anvendbare karboksylsyrepolymere oppnås når en slik karboksylsy-remonomer som akrylsyre, maleinsyre eller maleinsyreanhydrid og lignende sampolymeriseres med visse ande-ler akrylsyreestere med alifatiske grupper med lang kjede (10 - 30 karbonatomer) og eventuelt et kryssbindemiddel (brodanner) sem utgjøres av en polymeriserbar forbindelse inneholdende en .poly-. meriserbar gruppe C^^CZ og minst en annen polymeriserbar gruppe, hvorved gruppene er ikke —konjugerte med hensyn til hverandre.. Disse kryssbindemidler eksemplifiseres av allyl-akrylat, metallylmetakrylat, diallylmalonat, divinyleter, glykol-diakrylat (etylendiakrylat), glyceryltriakrylat og divinylbensen.
Et anvendbart kryssbindende materiale er en polyalkenylpolyeter av en flervérdig alkohol inneholdende mer enn en alkenyletergruppe pr. molekyl, hvorved den flerverdige moderalkoholen inneholder minst 4 karbonatomer og minst tre hydroksy-grupper, f.eks. polyallylsakkarose.
I vannholdige systemer der en relativt konstant viskositet skal opprettholdes, når mengden av et til systemet tilsatt uorganisk salt økes fra ca. 0,05 til ca. 330 vekt-%, er tilstedeværelsen av en kryssbindende monomer i alminnelighet fordel-aktig. Tilstedeværelsen av kryssbindende materiale i disse oppløsninger bibeholder oppløsningens tekstur. Dette er spesielt betydningsfullt ved farmasøytiske og kosmetiske anvendelser. Visse fortykkende vannholdige oppløsninger er trådaktige i sin natur, utseende og "grep".. Denne tekstur kan forandres til en mer ønsket, smørlignende eller jevn konsistens når salt tilsettes. Den jevne tekstur kan vanligvis oppnås fra begynnelsen og kan best opprettholdes ved tilsetning av salt, dersom en kryssbindende monomer er tilstede.
Kryssbindende monomére i foreliggende fortyknings-sammensetninger er ikke nødvendige eller egnede dersom det nøy-traliserte sampolymerisat skal anvendes for fortykning av et vannholdig system som fra begynnelsen av inneholder saltioner (hvorved saltet er tilstede i et innhold av 0,5 - 5 vekt-% i oppløsningen). Saltoppløsninger som forefinnes ved oljehull-boring er eksempler på denne situasjon.
Mange av de foreliggende sammensetninger er overlegne
i forhold til gummi-tragant, karayagummi og andre naturlig forekommende, mer eller mindre uoppløselige, gummilignende stoffer, som konvensjonelt anvendes som midler for tilveiebringelse av fyldighet og suspenderingsmidler.. Foreliggende høysvellende polymere er anvendbare ved fremstilling av forskjellige slimaktige eller kolloidale, gellignende materialer, slik som tannpasta, medisinske geler, kremer og salver, og trykkpasta-fortykningsmidler. De viser seg å være lovende som skumoppbygningsmidler og skumståbiliseringsmidler og som emulge-ringsmidler for sammensetninger av vann-oppløsningsmiddelkombi-nasjoner. De finner også anvendelse i lave konsentrasjoner (vektkonsentrasjoner) som behandlingsmidler for avløpsvann, kjølevann og kjelevann. I flytende vaskemiddeloppløsninger tjener sampolymerisatene som klaringsmidler eller oppløselig-gjørende midler samt som fortykningsmidler.
Ved fremstilling av foreliggende polymere anvendes en monomerblanding som inneholder to vesentlige monomerbestanddeler hver i visse mengdeforhold, og hvorved.en er en monomer, olefinisk umettet karboksylsyre og den andre er en akrylsyreester med en alifatisk gruppe med lang kjede. Eventuelt er det i monomerblandingen en kryssbindende monomer, f.eks. allylsakka-rose.
Karboksylsyremonomere som er egnet ved fremstilling av de foreliggende polymere er olefinisk umettede karboksylsyrer som inneholder minst en aktivert, olefinisk karbon-karbon-dobbeltbinding og minst en karboksygruppe, d.v.s. en syre med en olefinisk dobbeltbinding, som lett fungerer ved polymerisering på grunn av dens tilstedeværelse i monomermolekylet enten i
t i a,$-stilling med hensyn til en karboksygruppe, således -C=C-COOH, eller som en del av en metylgruppe i endestilling, nemlig CH2=CC. I a,$-s^rene har den sterkt polare karboksygruppens store nærhet til de dobbeltbundne karbonatomene en sterkt aktiverende innvirk-ning, hvilket gjør stoffene, som inneholder denne struktur,
meget lett polymeriserbare. Tilstedeværelsen av en metylengruppe i endestilling i en karboksylsyremonomer gjør denne type forbindelse meget lettere polymeriserbar enn om dobbeltbindingen
er mellomliggende i karbonstrukturen. Olefinisk umettede syrer av denne klasse omfatter slike forskjellige materialer som akrylsyrer, f.eks. akrylsyre selv, metakrylsyre, etakrylsyre, a-klorakrylsyre, a-cyanakrylsyre,. 3-metylakrylsyre (krotonsyre) , a-fenylakrylsyre, g-akryloksypropionsyre, sorbinsyre, a-klor-sorbinsyre, angelikasyre, kanelsyre, p-klorkanelsyre, g-styryl-akrylsyre (1-karboksy—4-fenylbuta-l,3-dien), itakonsyre, citra-konsyre, mesakonsyre, glutakonsyre, akonitinsyre, maleinsyre, fumarsyre og trikarboksyetylen/ Betegnelsen "karboksylsyre" omfatter her polykarboksyIsyrer og slike syreanhydrider som maleinsyreanhydrid hvor anhydridgruppen er dannet ved fjerning av et molekyl vann fra to karboksygrupper som er bundet ved samme polykarboksylsyremolekyl. Anhydrider av typer dannet ved fjerning av vann fra to eller flere molekyler av samme eller forskjellige umettede syrer, slik som akrylsyreanhydrid, omfat-tes ikke på grunn av den sterke tendensen hos deres polymere til å hydrolyseres i vann og alkali. Maleinsyreanhydrid og andre syreanhydrider som her er anvendbare, har den generelle formel:
hvor R og R' er hydrogen, halogen, cyanogen (-C=N), hydroksy, laktam- eller laktongrupper eller alkyl, aryl, alkaryl, aralkyl eller cykloalkyl, f.eks. metyl, etyl, propyl, oktyl, decyl, fenyl, tolyl, xylyl, bensyl, cykloheksyl og lignende.
Egnede karboksylsyremonomere for anvendelse ifølge oppfinnelsen er monoolefiniske akrylsyrer med generell formel: .
hvor R er hydrogen, halogen, hydroksy, lakton, laktam eller
cyanogen (-C=N) , enverdige alkylgrupper, enverdige arylgrupper, enverdige aralkylgrupper, enverdige alkarylgrupper eller enverdige cykloalifatiske grupper. I denne klasse er akrylsyre selv den mest egnede på grunn av dens generelt lave pris, lett. til-gjengelighet og evne til å danne overlegne polymere. Andre spesielt egnede karboksylsyremonomere er maleinsyreanhydrid.
Egnede akrylsyreestermonomere med alifatiske grupper med lang kjede er derivater av akrylsyre, som illustreres av formelen:
hvor R er alkyl med 10 - 30 karbonatomer, fortrinnsvis 12 - 22 karbonatomer, og R' er hydrogen eller en metylgruppe. ' Typiske høyere alkylakrylsyreestere er decylakrylat, laurylakrylat, stearylakrylat, behenylakrylat og melissylakrylat og tilsvarende metakrylater. Blandinger av to eller tre eller flere akrylsyreestere med lang kjede kan med fordel polymeriseres med en av karboksylsyremonomeréne for tilveiebringelse av foreliggende verdifulle fortykningsharpikser.
Den foretrukne kryssbindende'monomer, dersom en slik anvendes, er en polyalkenylpolyeter med mer enn en alkenyletergruppe pr. molekyl. De mest anvendbare har alkenylgrupper, i hvilke en olefinisk dobbeltbinding er bundet ved en metylengruppe i endestilling, CH2 = C<.. De fremstilles ved foretring av en flerverdig alkohol med minst 4 karbonatomer og minst 3 hydroksy-grupper. Forbindelser i denne klasse kan fremstilles ved omsetning av et alkenylhalogenid, slik som allylklorid eller allylbromid, med en sterkt alkalisk, vannholdig oppløsning av en eller flere flerverdige alkoholer. Produktet fra en slik reaksjon er. vanligvis en kompleks danning av polyetere med varierende
■ antall etergrupper på hvert molekyl. Analyse av slike materialer viser derfor bare middelantallet av etergrupper pr. molekyl. Effektiviteten til det tverrbihdende polyetermiddel øker med antall potensielt polymeriserbare grupper i molekylet. Det er egnet å anvende polyetere med et middeltall av to eller flere alkenyletergrupper pr. molekyl.
I monomerblandingen bør dé to vesentlige monomermate-rialene være tilstede i visse mengdeforhold, skjønt de eksakte mengder vil variere betydelig avhengig av de ønskede egenskaper hos polymeren. Monomere to-komponentblandinger av karboksylsyremonomer og akrylsyreestermonomer med lang kjede inneholder fortrinnsvis 95-50 vekt-% karboksylsyremonomer og 5~50 vekt-% akrylsyreestermonomer.
Når det eventuelle kryssbindende middel er tilstede, anvendes polymerblandinger inneholdende ca. 0,1 - ca. 4 vekt-% kryssbindende monomer, beregnet på totalmengden av karboksylsyremonomer pluss alkylakrylatestermonomer med lang kjede, fortrinnsvis 0,2 - 1,0 vekt-%, beregnet på totalblandingen. Polymere som inneholder mindre enn 5-10 vekt-% materiale,'som er ekstraherbart med vann, fremstilles med så lite som 0,2 - 0,5 vekt-% av det kryssbindende middel. Når 0,1 - 4,0 vekt-%,. fortrinnsvis 0,2 - 1,0"vekt-% av den kryssbindende monomer anvendes, oppnås vannuoppløselige.polymere, spesielt med akrylsyrer som er ytterst vannfølsomme, spesielt i form av deres enverdige salter, og sveller meget under absorbsjon av flere hundre ganger deres egen vekt av vann når de er nøytralisert med en base. Når 0,1 - 6,0 .%, fortrinnsvis 0,2 — 2,5 % av den kryssbindende monomer sampolymeriseres med maleinsyreanhydrid, oppnås også høytsvellende polymere. I disse sampolymere bør karboksylsyremonomeren eller -monomerene ikke utgjøre mindre enn 50 % av den totale monomerblanding. Trekomponent-sampolymerisater kan fremstilles av monomerblandinger omfattende 60 - 95 % av en karboksylsyremonomer, slik som akrylsyre, 39,9 - 4 vekt-% av en akrylsyreester med lang kjede, slik som laurylakrylat, og 0,1 - 6 % kryssbindende monomer slik som polyallylsakkarose,
hvorved totalmengden i vektdeler er.lik 100.
Foretrukket for bruk som kryssbundne, i vann svellbare kunstgummier, er tripolymere som resulterer fra polymerisering av monomerblandinger inneholdende 70 - 95 vekt-% akrylsyre, 4 - 29,5 vekt-% av en annen monomer, slik som laurylakrylat eller stearylakrylat, og 0,5 - 1,0 vekt-% av et kryssbindende stoff slik som en polyallylpolyeter. Det er tydelig at dersom man i de angitte mengdeforhold anvender en maksimal mengde av to av monomerene, må en noe mindre enn maksimalmengden av den tredje monomer benyttes.
Foreliggende polymere fremstilles fortrinnsvis ved polymerisering i et inert fortynningsmiddel med en viss oppløse-liggjørende virkning på en eller flere av monomerbestanddelene, men vesentlig uten en slik virkning på den oppnådde polymer. Polymerisering i masse kan anvendes, men er ikke egnet på grunn av vanskeligheten med å opparbeide de oppnådde faste polymer-massene. Polymerisering i et-vannholdig medium som inneholder en vannoppløselig fri radikalkatalysator er egnet, hvorved produktet oppnås enten som en kornformig utfelling eller som en meget svellet gel, idet begge produktene kan anvendes direkte eller ytterligere lett findeles og tørkes. Polymerisering i en organisk væske som er et oppløsningsmiddel for monomerene, men et ikke-oppløsningsmiddel for polymeren, eller i en blanding av slike oppløsningsmidler i nærvær av en katalysator som er opp-løselig i oppløsningsmidlet, er mest egnet fordi produktet vanligvis oppnås som en meget fin, oppsmulbar og ofte fnugget utfelling som etter fjerning av oppløsningsmidlet sjelden krever maling eller annen ytterligere behandling før anvendelse.
Egnede oppløsningsmidler for den sistnevnte metode omfatter bensen, xylen, tetralin, heksan, heptan, karbontetraklorid, me-tylklorid, etylklorid, bromtriklormetan, dimetylkarbonat, dietylkarbonat, etylendiklorid og blandinger derav og andre oppløsningsmidler.
Polymerisering i det fortynnende medium utføres i nærvær av en friradikalkatalysator i en lukket beholder i en inert atmosfære og under autogent trykk eller kunstig indusert trykk eller i en åpen beholder under tilbakeløpskoking ved atmosfæretrykk. Polymeriseringstemperaturen kan variere fra 0
- 100°C i høy grad avhengig av den til polymeren ønskede molekyl-vekt. Polymerisering under tilbakeløpskoking ved 50 - 90°C ved atmosfæretrykk under anvendelse av en fri radikalkatalysator er vanligvis effektiv for tilveiebringelse av et polymerutbytte på 75 - 100 % på mindre enn 10 timer. Egnede katalysatorer er per-oksygenforbindelser slik som natrium-, kalium- og ammoniumper-sulfat, kaprylperoksyd, bensoylperoksyd, hydrogenperoksyd, pelargonylperoksyd, kumenhydroperoksyder, t-butyldiperftalat, t-butylperbensoat, natriumperacetat, natriumperkarbonat og lignende samt azodiisobutyrylnitril, i det følgende betegnet som azoisobutyronitril. Andre anvendbare katalysatorer er såkalte katalysatorer av "redox"-typen og tungmetallaktivert katalysa-torsystem. Disse katalysatorer oppnår vanligvis ikke sine maksimale egenskaper i vann, før de er overført til et partielt alkali-, ammonium- eller aminsalt. Det nøytraliserende midlet er fortrinnsvis et enverdig alkali slik som natrium-, kalium-, litium- eller ammoniumhydroksyd eller karbonat og bikarbonat derav eller blandinger av dem og også aminbaser med ikke mer enn en primær eller sekundær aminogruppe. Flerverdige baser slik som kalsiumhydroksyd, har vanligvis en avsvellende virkning på
vannsvellede polymere og deres salter, skjønt deres absolutte svelling til tross for tilstedeværelsen av disse flerverdige metallioner er høyere enn svellingen hos naturlig forekommende, gummilignende materialer slik som tragantgummi og lignende, i nærvær av samme avsvellende midler.
Sampolymerisater vurderes som fortykningsmidler eller viskositetsforbedrende midler ved blanding av sampolymerisatet med en base (vanligvis trietylamin). Det nøytraliserte sampolymerisat oppløses i vann. Oppløsningsviskositetene måles deretter med et Brookfield-viskosimeter av modell RVT. Innvirk-ningen av salter slik som natriumklorid, .på viskositetene til disse oppløsninger iakttas ved måling av viskositeten ved tilsetning av økende mengder salt til oppløsningene.
Oppfinnelsen beskrives nærmere i følgende eksempler som angår fremstilling av flere typer av polymere under anvendelse av forskjellige mengder monomere, polymerisasjonsmedier, temperatur, osv., og virkningen av disse polymere på viskositetene til vannholdige oppløsninger.
Eksempel 1
En rekke polymeriseringer av akrylsyre og stearylakrylat ble utført satsvis i bensen ved 65°C under anvendelse av kaprylylperoksyd som initiator. Reaksjonene ble gjennomført i 3^0 ml lukkede glassflasker under tørr nitrogengass. Polymerene, som var uoppløselige i bensen, ble separert ved sentri-fugering og tørket i en vakuumovn ved 55°C.
Stearylakrylatinnholdet (vekt-%) i sampolymerisatene og utseendet til oppløsninger av 0,5 g sampolymerisat, 1 ml trietylamin og 100 ml destillert vann, var følgende:
Verdiene viser at viskositeten til sampolymerisat-oppløsningen øker gjennom et maksimum når stearylakrylatinnholdet i sampolymerisatet øker. Oppløsningenes reaksjon med hensyn til viskositetstap eller -økning når salt tilsettes, avhenger av det benyttede sampolymerisatets stearylakrylatinnhold. Kjente vannfortykningsmidler benyttet som kontrollprøver oppviser fra begynnelsen av større viskositet i oppløsning, men denne viskositet faller drastisk når saltporsjoner tilsettes.
En kontrolloppløsning med bare 0,2 deler salt tilstede oppviser en helt utilfredsstillende viskositet på 2950 cP, mens foreliggende sampolymerisat bibeholder viskositeter opp til 1^500 cP med samme saltinnhold tilstede. Noen av oppløsningene som er trådaktige i sin' natur før tilsetningen av salt, blir mer gellignende eller smørlignende når økende mengder salt tilsettes. Denne forandring viser at salt kan anvendes sammen med foreliggende polymer, ikke bare for å regulere oppløsningens viskositet som sådan, men også for å regulere det vannholdige systems konsistens.
Eksempel 2
Under anvendelse av fremgangsmåten i eksempel 1 ble det fremstilt en rekke sampolymerisater av akrylsyre og stearylmetakrylat og.de i tabell 2 angitte resultater ble oppnådd.
Verdiene viser at oppløsningsviskositeten øker til et maksimum og deretter minsker når vektprosent innholdet av stearylmetakrylat øker. Motstanden mot viskositetsfall' når mengden av salt øker, øker også til et maksimum og synker deretter når vekt-%-innholdet av stearylmetakrylat øker. Optimalt vekt-%-innhold stearylmetakrylat bestemmes av konsentrasjonen til saltoppløsningene som skal fortykkes.
Kontrolloppløsningene har igjen falt til utilfredsstillende viskositetsnivåer (under ca. 3000. cP), når 0,2 deler
salt tilsettes. Lignende oppløsninger ifølge oppfinnelsen viser
■viskositeter opp til 17.900 cP.
De nøytraliserte akrylsyre-stearylmetakrylatsampoly-merisater danner, meget viskøse oppløsninger også når de er tilstede i .lav vektkonsentrasjon.
Det er uventet å finne oppløsninger av denne type som
øker i viskositet når natriumklorid tilsettes.
Lignende resultat er•ble oppnådd når en rekke sampolymerisater og forsøksoppløsninger ble fremstilt som. i eksempel 1, med unntagelse av at laurylakrylat ble benyttet i stedet for stearylakrylat.
Eksempel 3
Under- anvendelse av fremgangsmåten i eksempel 1 ble det fremstilt to serier terpolymere av akrylsyre, stearylmetakrylat og polyallylsakkarose og man oppnådde resultatene som an-gitt i tabell 3. Forsøksoppløsningene besto av 1 g polymer,
2 ml trietylamin og 100 ml vann. Den første serie terpolymer
inneholdt 0,5 vekt-% kryssbindemiddel. Den andre serien inneholdt 1,0 vekt-% kryssbindemiddel.
Kryssbundne terpolymere viser høyere oppløsnings-viskositeter ved saltinnhold enn slike oppløsninger som inneholder kontrollfortykningsmidler av kryssbundet karboksylsyre. Terpolymere inneholdende 1 % kryssbindemiddel gir oppløsninger med høyere viskositeter enn ekvivalente oppløsninger inneholdende bare 0,5 % kryssbindemiddel i fortykningsmidlet. Oppløsninger oppviser høyere viskositeter når vekt-prosentinnholdet av alkylakrylatester øker.
Reaksjonen til fremstilt oppløsning eller mucilago med hensyn til viskositetsøkning eller -tapet når salt tilsettes i økende mengder, avhenger av innholdet av langkjedet akrylat-éster i terpolymere og også på terpolymerens innhold av kryssbindemiddel.
Eksempel 4
Fremgangsmåten i eksempel 1 ble fulgt ved utførelse, av en rekke polymeriseringer ved hvilke 95 mol-% akrylsyre ble sampolymerisert med 5 mol-% av et antall langkjedede alkylakrylatestere i hvilke alkylesterens kjedelengde var 8 karbonatomer (eksempel på teknikkens stand) opp' til 18 karbonatomer. Oppløs-ninger av 1 g sampolymerisat, 2 ml trietylamin og 100 ml destillert vann oppviste viskositeter ifølge tabell 4.
Økende lengde av alkylesterkjeden leder til økende viskositeter. Et uventet skarpt brytningspunkt i viskositets-økningen inntrer mellom kjedene med 8 og 10 karbonatomer.
Claims (7)
1. Sampolymerisat av en monomerblanding, karakterisert ved at det omfatter 95 - 50 vekt-% av en
karboksylsyremonomer og 5 - 50 vekt-% av en akrylestermonomér med formelen:
hvor R er alkyl med 10 - 30 karbonatomer og R' er.hydrogen eller metyl.
2. Sampolymerisat ifølge krav 1, karakterisert ved at karboksylsyremonomeren utgjøres av akrylsyre, metakrylsyre, maleinsyreanhydrid eller maleinsyre.
3. Tripolymer av en monomerblanding, karakterisert ved at den omfatter 60-95 vekt-% av en karboksylsyremonomer, 4 - 39,9 vekt-% av en akrylsyreestermonomer med formelen:
hvor R er alkyl med 10 - 30 karbonatomer og R' er hydrogen eller metyl, og 0,1 - 6,0 vekt-% av en polymeriserbar, kryssbindende monomer inneholdende en gruppe CH2 =Cc^ og minst en annen polymeriserbar gruppe, hvorved de umettede bindinger i de polymeriserbare grupper er ikke-konjugerte med hensyn til hverandre.
4. Tripolymer ifølge krav 3, karakterisert ved at den kryssbindende monomer er en polyalkenylpolyeter av en flerverdig alkohol inneholdende mer enn en alkenyletergruppe-ring pr. molekyl, hvorved den flerverdige moderalkoholen inneholder minst 4 karbonatomer og minst tre hydroksygr.upper.
5. Tripolymer av en monomerblanding, karakterisert ved at den omfatter, akrylsyre, minst en av for-, bindelsene laurylakrylat, stearylakrylat og stearylmetakrylat og ca. 0,5 - 1,0 vekt-% av monomerene av en kryssbindende monomer inneholdende gruppen CH2 = C\.og minst en annen polymeriserbar gruppe, hvorved de umettede bindingene i de polymeriserbare grupper er ikke-konjugerte med hensyn til hverandre.
6. Tripolymer ifølge krav 5, karakterisert ved at den kryssbindende monomer er en monomer polyeter av et oligosakkarid, i hvilket hydroksylgruppene, som er modifiserte, er foretrede med allylgrupper, hvorved polyeterne inneholder minst to allylgrupper pr. oligosakkaridmolekyl.
7. Sampolymerisat, karakterisert ved" at det er avledet av■en monomer, monoolefinisk akrylsyre med formelen:
hvor R er en substituent som utgjøres av hydrogen, brom, klor, hydroksy eller cyanogen (-C=N) eller enverdig alkyl, aryl, aralkyl, alkaryl eller en cykloalifatisk hydrokarbongruppe, og ca.5,0 - ca. 50 vekt-%, beregnet på totalmengden monomer, av en monomer akrylsyreester med formelen:
hvor R er alkyl med 10 - 30 karbonatomer og R' er hydrogen eller metyl.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US485125A US3915921A (en) | 1974-07-02 | 1974-07-02 | Unsaturated carboxylic acid-long chain alkyl ester copolymers and tri-polymers water thickening agents and emulsifiers |
Publications (1)
Publication Number | Publication Date |
---|---|
NO752185L true NO752185L (no) | 1976-01-05 |
Family
ID=23926998
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
NO752185A NO752185L (no) | 1974-07-02 | 1975-06-19 |
Country Status (17)
Country | Link |
---|---|
US (1) | US3915921A (no) |
JP (1) | JPS6012361B2 (no) |
AT (1) | AT342007B (no) |
BE (1) | BE830668A (no) |
BR (1) | BR7504140A (no) |
CA (1) | CA1037643A (no) |
CH (1) | CH606154A5 (no) |
DE (1) | DE2528202A1 (no) |
DK (1) | DK298375A (no) |
ES (1) | ES437098A1 (no) |
FR (1) | FR2277109A1 (no) |
GB (1) | GB1514494A (no) |
IT (1) | IT1036409B (no) |
NL (1) | NL180675C (no) |
NO (1) | NO752185L (no) |
SE (1) | SE413773B (no) |
ZA (1) | ZA752489B (no) |
Families Citing this family (494)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5387870A (en) * | 1977-01-10 | 1978-08-02 | Yoshizaki Kozo | Laminated bag for packaging food |
DE2706135C2 (de) * | 1977-02-14 | 1982-10-28 | Chemische Fabrik Stockhausen GmbH, 4150 Krefeld | Verdickungsmittel für ausgeschiedenen Darminhalt und Harn |
US4138380A (en) * | 1977-02-18 | 1979-02-06 | Gaf Corporation | Preparation of copolymer emulsions of an α,β-unsaturated carboxylic acid and methyl acrylate |
US4190562A (en) * | 1977-04-04 | 1980-02-26 | The B. F. Goodrich Company | Improved water absorbent copolymers of copolymerizable carboxylic acids and acrylic or methacrylic esters |
US4062817A (en) * | 1977-04-04 | 1977-12-13 | The B.F. Goodrich Company | Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms |
US4172122A (en) * | 1977-07-29 | 1979-10-23 | Minnesota Mining And Manufacturing Company | Substantive sunscreening compositions |
US4167464A (en) * | 1978-10-16 | 1979-09-11 | The B. F. Goodrich Company | Photopolymerized hydrophilic interpolymers of unsaturated carboxylic acid and esters |
BR8008821A (pt) * | 1979-09-11 | 1981-06-23 | Goodrich Co B F | Interpolimeros hidrofilos fotopolimerizados de acidos e esteres carboxilicos insaturados |
EP0055728A4 (en) * | 1980-07-08 | 1982-08-11 | Goodrich Co B F | HYDROPHILIC INTERPOLYMERS OF ACRYLIC ACIDS AND AN ACRYLATE. |
US4338239A (en) * | 1980-10-10 | 1982-07-06 | Celanese Corporation | Polyacrylate thickening agents |
JPS5920340B2 (ja) * | 1981-03-16 | 1984-05-12 | フワ,ステイ−ブン シ−.ピ−. | 新規な蛋白質カ−ド製品および製造方法 |
US4740325A (en) * | 1982-02-23 | 1988-04-26 | Allied Colloids Limited | Thermal energy storage compositions |
US4673520A (en) * | 1982-02-23 | 1987-06-16 | Allied Colloids Ltd. | Thermal energy storage compositions |
US4426485A (en) * | 1982-06-14 | 1984-01-17 | Union Carbide Corporation | Polymers with hydrophobe bunches |
US4604216A (en) * | 1982-10-19 | 1986-08-05 | Phillips Petroleum Company | Drilling fluids |
US4509949A (en) * | 1983-06-13 | 1985-04-09 | The B. F. Goodrich Company | Water thickening agents consisting of copolymers of crosslinked acrylic acids and esters |
ATE46178T1 (de) * | 1984-04-04 | 1989-09-15 | Hoechst Ag | Umsetzungsprodukt von olefinisch ungesaettigten verbindungen mit wasserstoffaktiven verbindungen, verfahren zu dessen herstellung und darauf basierende 2-komponentenlacke. |
US4911736A (en) * | 1985-09-18 | 1990-03-27 | The Standard Oil Company | Emulsifier and stabilizer for water base emulsions and dispersions of hydrocarbonaceous materials |
US4709767A (en) * | 1986-01-06 | 1987-12-01 | American Colloid Company | Production process for manufacturing low molecular weight water soluble acrylic polymers as drilling fluid additives |
JPH062826B2 (ja) * | 1986-04-30 | 1994-01-12 | 出光石油化学株式会社 | ポリプロピレン樹脂成形体の製造方法 |
JPH0643462B2 (ja) * | 1986-04-30 | 1994-06-08 | 出光石油化学株式会社 | プロピレン単独重合体およびその製造方法 |
KR880005918A (ko) * | 1986-11-10 | 1988-07-21 | 원본미기재 | 안정하며 빨리 분해되는 국소피부조성물 |
US4758641A (en) * | 1987-02-24 | 1988-07-19 | The B F Goodrich Company | Polycarboxylic acids with small amount of residual monomer |
EP0343233B1 (en) * | 1987-11-27 | 1994-02-02 | Battelle Memorial Institute | Supercritical fluid reverse micelle separation |
US4933404A (en) * | 1987-11-27 | 1990-06-12 | Battelle Memorial Institute | Processes for microemulsion polymerization employing novel microemulsion systems |
US4888367A (en) * | 1987-12-01 | 1989-12-19 | The Standard Oil Company | Process for neutralizing crosslinked poly (acrylic acid) |
US4996274A (en) * | 1988-02-19 | 1991-02-26 | The B. F. Goodrich Company | Polycarboxylic acids with higher thickening capacity and better clarity |
GB8813966D0 (en) * | 1988-06-13 | 1988-07-20 | Nat Starch Chem Corp | Process for manufacture of polymers |
CA1339231C (en) * | 1989-03-30 | 1997-08-05 | Ratana Kanluen | Polyfunctional polymers as deinking agents |
US5053448A (en) * | 1989-07-21 | 1991-10-01 | S. C. Johnson & Son, Inc. | Polymeric thickener and methods of producing the same |
US5011681A (en) * | 1989-10-11 | 1991-04-30 | Richardson-Vicks, Inc. | Facial cleansing compositions |
DK0427411T3 (da) * | 1989-10-27 | 1995-03-20 | Richardson Vicks Inc | Lysbeskyttelsesmiddel med forbedret bestandighed |
ES2059982T3 (es) * | 1990-01-11 | 1994-11-16 | Rheox Int | Formulaciones cosmeticas y farmaceuticas que comprenden copolimeros carboxilicos reticulados utiles como espesantes. |
US5066749A (en) * | 1990-09-11 | 1991-11-19 | National Starch And Chemical Investment Holding Corporation | Hydrophobically-modified polycarboxylates and process for their preparation |
EP0482417A1 (en) * | 1990-10-22 | 1992-04-29 | The B.F. Goodrich Company | Emulsion composition comprising a high molecular weight anionic emulsifying agent and a low molecular weight cationic surfactant, and methods relating thereto |
US5308530A (en) * | 1990-11-21 | 1994-05-03 | Lever Brothers Company, Division Of Conopco, Inc. | Detergent compositions containing polycarboxylates and calcium-sensitive enzymes |
US5470931A (en) * | 1990-12-07 | 1995-11-28 | Hawaiian Sugar Planters' Association | Thermostable polymers from 1',2',3,3',4,4',6,6'-octa-O-allylsucrose |
US5789469A (en) * | 1990-12-07 | 1998-08-04 | Hawaii Agriculture Research Center | Polymers having enhanced thermal stabilities and methods for their preparation using stabilization agents 1,6,6,-trimethacryloyl 2,3,3,4,4,-penta-o-methylsucrose 1,2,3,3,4,4,6,6,-octa-o-allylsucrose 1,2,3,3,4,4,6,6,-octo-o-crotylsucrose |
US5571907A (en) * | 1990-12-07 | 1996-11-05 | Hawaiian Sugar Planters' Association | Epoxy monomers from sucrose |
GB9114095D0 (en) | 1991-06-29 | 1991-08-14 | Allstate Limited | Improvements in water-soluble polymers |
US5391624A (en) * | 1992-02-10 | 1995-02-21 | S. C. Johnson & Son, Inc. | Thermosettable compositions |
US5739378A (en) * | 1992-05-29 | 1998-04-14 | Union Carbide Chemicals & Plastics Technology Corporation | Complex hydrophobe-containing oligomers |
US5426182A (en) * | 1992-05-29 | 1995-06-20 | Union Carbide Chemical & Plastics Technology Corporation | Polysaccharides containing complex hydrophobic groups |
US5292828A (en) * | 1992-05-29 | 1994-03-08 | Union Carbide Chemicals & Plastics Technology Corporation | Polymers containing complex hydrophobic groups |
EP0642541A1 (en) * | 1992-05-29 | 1995-03-15 | Union Carbide Chemicals & Plastics Technology Corporation | Aqueous latexes containing macromonomeres |
US5488180A (en) * | 1992-05-29 | 1996-01-30 | Union Carbide Chemicals & Plastics Technology Corporation | Complex hydrophobe compounds |
US5292843A (en) * | 1992-05-29 | 1994-03-08 | Union Carbide Chemicals & Plastics Technology Corporation | Polymers containing macromonomers |
US5461100A (en) * | 1992-05-29 | 1995-10-24 | Union Carbide Chemicals & Plastics Technology Corporation | Aircraft anti-icing fluids |
US5663123A (en) * | 1992-07-15 | 1997-09-02 | Kb Technologies Ltd. | Polymeric earth support fluid compositions and method for their use |
WO1994005769A1 (en) * | 1992-09-01 | 1994-03-17 | The Procter & Gamble Company | Liquid or gel dishwashing detergent containing alkyl ethoxy carboxylate, divalent ions and alkylpolyethoxypolycarboxylate |
US5393452A (en) * | 1992-11-09 | 1995-02-28 | General Electric Company | 2 in 1 shampoo system and conditioner comprising a silicon-polyether copolymer |
US5364894A (en) * | 1993-03-31 | 1994-11-15 | Tremco, Inc. | Emulsification of asphalt and modified asphalt with primary emulsifier polymers comprised of acrylic acid type monomers |
US5338345A (en) * | 1993-05-05 | 1994-08-16 | Eastman Kodak Company | Water-based water repellent coating compositions |
US5399618A (en) * | 1993-06-28 | 1995-03-21 | Union Carbide Chemical & Plastics Technology Corporation | Processes for preparing aqueous polymer emulsions |
US5362789A (en) * | 1993-12-21 | 1994-11-08 | Isp Investments Inc. | Crosslinked terpolymers of high salt tolerance |
US5425939A (en) * | 1994-05-27 | 1995-06-20 | Elizabeth Arden Company, Division Of Conopco, Inc. | Thickened cosmetic compositions |
US5830967A (en) * | 1994-10-24 | 1998-11-03 | Amcol International Corporation | Process for producing an oil and water adsorbent polymer capable of entrapping solid particles and liquids and the product thereof |
US5618877A (en) | 1994-10-24 | 1997-04-08 | Amcol International Corporation | Process for polymerization of water-soluble and water-insoluble carboxylic acid polymers and copolymers in a silicone oil solvent |
US5837790A (en) * | 1994-10-24 | 1998-11-17 | Amcol International Corporation | Precipitation polymerization process for producing an oil adsorbent polymer capable of entrapping solid particles and liquids and the product thereof |
US5608005A (en) * | 1994-10-24 | 1997-03-04 | Amcol International Corporation | Process for viscosifying water with carboxylic acid monomers polymerized in silicone solvents |
US6107429A (en) * | 1994-10-24 | 2000-08-22 | Amcol International Corporation | Process for producing an oil and water adsorbent polymer capable of entrapping solid particles and liquids and the product thereof |
US5708068A (en) * | 1995-01-16 | 1998-01-13 | Union Carbide Chemicals & Plastics Technology Corporation | Aircraft deicing/anti-icing fluids thickened by associative polymers |
US5516865A (en) * | 1995-02-03 | 1996-05-14 | Minnesota Mining And Manufacturing Company | Waterborne (meth) acrylic latex polymers for release |
US5648083A (en) * | 1995-02-10 | 1997-07-15 | The Procter & Gamble Company | Personal care compositions and wipe products containing the compositions |
US5712358A (en) * | 1995-06-07 | 1998-01-27 | Amcol International Corporation | Process for producing an oil sorbent copolymer and the product thereof |
DE19600324A1 (de) | 1996-01-08 | 1997-07-10 | Basf Ag | Granulate für kosmetische und pharmazeutische Zubereitungen |
FR2748932B1 (fr) * | 1996-05-23 | 1998-07-03 | Oreal | Composition de teinture directe capillaire comprenant un polymere reticule a motifs acryliques et acrylates d'akyles en c10-c30 |
US7056346B1 (en) | 1996-05-23 | 2006-06-06 | L'oreal S.A. | Direct dye composition for the hair, comprising a crosslinked polymer containing acrylic units and C10-C30 alkyl acrylate units |
FR2753094B1 (fr) * | 1996-09-06 | 1998-10-16 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere amphiphile anionique |
US5849273A (en) * | 1996-11-21 | 1998-12-15 | The C. P. Hall Company | Skin care and sunscreen composition containing dibenzoylmethane derivative, e.g., parsol® 1789, and C12, C16, C18 branched chain hydroxybenzoate and/or C12, C16 branched chain benzoate stabilizers/solubilizers |
US6248697B1 (en) | 1997-02-12 | 2001-06-19 | Kb Technologies, Ltd. | Composition and method for a dual-function soil-grouting excavating or boring fluid |
US6897186B2 (en) * | 1997-02-12 | 2005-05-24 | Kg International, Llc | Composition and method for dual function soil grouting excavating or boring fluid |
US5804624A (en) * | 1997-04-30 | 1998-09-08 | Wang; Jianming | Water-based silicone resin compositions |
EP0885906B1 (en) | 1997-06-20 | 2003-02-12 | Rohm And Haas Company | Polymer compositions |
US5997764A (en) * | 1997-12-04 | 1999-12-07 | The B.F. Goodrich Company | Thickened bleach compositions |
DE19811919A1 (de) * | 1998-03-18 | 1999-09-23 | Basf Ag | Verwendung von Copolymerisaten monoethylenisch ungesättigter Carbonsäuren als Solubilisatoren |
FR2780880B1 (fr) | 1998-07-09 | 2001-08-10 | Oreal | Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un polymere epaississant |
FR2780881B1 (fr) * | 1998-07-09 | 2001-08-10 | Oreal | Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un polymere epaississant |
FR2780883B1 (fr) * | 1998-07-09 | 2001-04-06 | Oreal | Composition de teinture pour fibres keratiniques avec un colorant direct cationique et un polymere epaississant |
US6492488B1 (en) | 1998-08-02 | 2002-12-10 | Pmd Holdings Corp. | Controlled release polyacrylic acid granules and a process for preparing the same |
DE19836808A1 (de) | 1998-08-14 | 2000-02-24 | Basf Ag | Verdickungsmittel für tensidhaltige Zusammensetzungen |
US6211296B1 (en) | 1998-11-05 | 2001-04-03 | The B. F. Goodrich Company | Hydrogels containing substances |
FR2788974B1 (fr) | 1999-01-29 | 2001-03-30 | Oreal | Composition anhydre de decoloration des fibres keratiniques comprenant l'association de polymeres amphiphiles anioniques et/ou non ioniques comportant au moins une chaine grasse et de polymeres substantifs cationiques ou amphoteres |
FR2788976B1 (fr) | 1999-01-29 | 2003-05-30 | Oreal | Composition anhydre de decoloration de fibres keratiniques comprenant l'association d'un polymere epaississant hydrosoluble et d'un polymere amphiphile non ionique comportant au moins une chaine grasse |
FR2788975B1 (fr) | 1999-01-29 | 2002-08-09 | Oreal | Composition aqueuse de decoloration de fibres keratiniques prete a l'emploi comprenant l'association d'un solvant hydrosoluble et d'un polymere amphiphile non ionique ou anionique comportant au moins une chaine grasse |
GB9903140D0 (en) | 1999-02-12 | 1999-04-07 | Basf Ag | Interpolymers |
US6297337B1 (en) | 1999-05-19 | 2001-10-02 | Pmd Holdings Corp. | Bioadhesive polymer compositions |
FR2799956B1 (fr) * | 1999-10-20 | 2001-12-07 | Oreal | Compositions cosmetiques contenant un copolymere vintldimethicone/dimethicone en emulsion aqueuse et un epaississant associatif et leurs utilisations |
FR2803197B1 (fr) | 1999-12-30 | 2002-03-15 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un polymere epaississant comportant au moins une chaine grasse et un alcool gras ayant plus de vingt atomes de carbone |
FR2803196B1 (fr) | 1999-12-30 | 2002-03-15 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un alcool gras ayant plus de vingt atomes de carbone et un tensioactif non-ionique oxyalkylene de hlb superieure a 5 |
FR2803198B1 (fr) | 1999-12-30 | 2003-09-26 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant deux polyammonium quaternaires particuliers |
FR2803195B1 (fr) | 1999-12-30 | 2002-03-15 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un polymere epaississant comportant au moins une chaine grasse et un alcool gras mono-ou poly-glycerole |
FR2806299B1 (fr) | 2000-03-14 | 2002-12-20 | Oreal | Compositions pour la teinture des fibres keratiniques contenant des derives de paraphenylenediamine a groupement pyrrolidinyle |
FR2807648B1 (fr) | 2000-04-12 | 2005-06-10 | Oreal | Composition de teinture d'oxydation des fibres keratiniques et procede de teinture mettant en oeuvre cette composition |
US6623756B1 (en) * | 2000-04-27 | 2003-09-23 | Noveon Ip Holdings Corp. | Directly compressed solid dosage articles |
PT1309635E (pt) * | 2000-08-03 | 2005-09-30 | Ici Plc | Composicoes aquosas de agente espessante de copolimero |
FR2813016B1 (fr) * | 2000-08-21 | 2002-10-11 | Oreal | Composition de decoloration des fibres keratiniques teintes |
US6433061B1 (en) * | 2000-10-24 | 2002-08-13 | Noveon Ip Holdings Corp. | Rheology modifying copolymer composition |
FR2817466B1 (fr) * | 2000-12-04 | 2004-12-24 | Oreal | Composition de teinture d'oxydation pour fibres keratiniques comprenant un polymere associatif et un agent nacrant |
FR2817467B1 (fr) * | 2000-12-04 | 2003-01-10 | Oreal | Composition de teinture pour fibres keratiniques comprenant un polymere associatif et un polymere a motifs acrylamide, halogenure de dialkyldiallylammonium et acide carboxylique vinylique |
FR2817474B1 (fr) * | 2000-12-06 | 2003-01-03 | Oreal | Composition de teinture d'oxydation a base de 1-(4-aminophenyl) pyrrolidines substituee en position 2 et procede de teinture de mise en oeuvre |
FR2817471B1 (fr) * | 2000-12-06 | 2005-06-10 | Oreal | Composition de teinture d'oxydation a base de 1-(4-aminophenyl) pyrrolidines substituees en position 3 et 4 et procede de teinture de mise en oeuvre |
FR2817470B1 (fr) * | 2000-12-06 | 2003-01-03 | Oreal | Composition de teinture d'oxydation a base de 1-(aminophenyl)pyrrolidines substituees en position 2 et 5 et procede de teinture de mise en oeuvre |
FR2817472B1 (fr) * | 2000-12-06 | 2003-01-03 | Oreal | Composition de teinture d'oxydation a base de 1-(4-aminophenyl)pyrrolidines substituees au moins en position 2 et 3 et procede de teinture de mise en oeuvre |
FR2820312B1 (fr) * | 2001-02-02 | 2003-05-02 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
US6562770B2 (en) | 2001-03-27 | 2003-05-13 | Colgate-Palmolive Co. | Fragrance-containing gel for delivering fragrance from structured liquid detergent compositions |
FR2822697B1 (fr) * | 2001-04-02 | 2003-07-25 | Oreal | Nouvelle composition tinctoriale pour la teinture des fibres keratiniques comprenant un colorant azoique cationique particulier |
FR2824734B1 (fr) | 2001-05-16 | 2003-06-27 | Oreal | Composition pulverulente pour la decoloration des fibres keratiniques humaines |
US6623754B2 (en) * | 2001-05-21 | 2003-09-23 | Noveon Ip Holdings Corp. | Dosage form of N-acetyl cysteine |
FR2825624B1 (fr) * | 2001-06-12 | 2005-06-03 | Oreal | Composition de teinture des fibres keratiniques humaines avec des colorants directs et des composes dicationiques |
US7244703B2 (en) | 2001-06-22 | 2007-07-17 | Bentley Pharmaceuticals, Inc. | Pharmaceutical compositions and methods for peptide treatment |
US8481043B2 (en) * | 2001-06-22 | 2013-07-09 | Cpex Pharmaceuticals, Inc. | Nasal immunization |
CA2451839C (en) * | 2001-06-22 | 2013-08-06 | Bentley Pharmaceuticals, Inc. | Pharmaceutical compositions comprising peptides and permeation enhancers |
MXPA04000760A (es) | 2001-07-25 | 2004-04-20 | Sherwin Williams Co | Composiciones para recubrimiento, con base de agua, formadoras de pelicula y repelentes al agua. |
FR2827761B1 (fr) * | 2001-07-27 | 2005-09-02 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un alcool gras mono- ou poly-glycerole et un polyol particulier |
FR2830189B1 (fr) | 2001-09-28 | 2004-10-01 | Oreal | Composition de teinture a effet eclaircissant pour fibres keratiniques humaines |
FR2831817B1 (fr) * | 2001-11-08 | 2003-12-19 | Oreal | Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831814B1 (fr) * | 2001-11-08 | 2004-09-10 | Oreal | Utilisations de silicones aminees particulieres en pre- ou post-traitement de decolorations de fibres keratiniques |
AU2002301801B2 (en) * | 2001-11-08 | 2004-09-30 | L'oreal | Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof |
FR2831813B1 (fr) * | 2001-11-08 | 2004-10-01 | Oreal | Utilisation de silicones aminees particulieres en pre-traitement de colorations directes ou d'oxydation de fibres keratiniques |
FR2831809B1 (fr) * | 2001-11-08 | 2004-07-23 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831818B1 (fr) * | 2001-11-08 | 2004-07-16 | Oreal | Composition oxydante pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
AU2002301803B2 (en) * | 2001-11-08 | 2004-09-09 | L'oreal | Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof |
FR2831803B1 (fr) * | 2001-11-08 | 2004-07-30 | Oreal | Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations |
FR2831802B1 (fr) * | 2001-11-08 | 2004-10-15 | Oreal | Compositions cosmetiques contenant une silicone aminee et un agent epaississant et leurs utilisations |
FR2831805B1 (fr) * | 2001-11-08 | 2004-08-06 | Oreal | Procede de deformation permanente des cheveux mettant en oeuvres des silicones aminees particulieres |
FR2831815B1 (fr) * | 2001-11-08 | 2004-08-06 | Oreal | Composition reductrice pour le traitement des fibres keratiniques comprenant une silicone aminee particuliere |
FR2831804B1 (fr) * | 2001-11-08 | 2004-07-30 | Oreal | Procede de deformation permanente des cheveux mettant en oeuvre des silicones aminees particulieres |
FR2833837B1 (fr) * | 2001-12-21 | 2005-08-05 | Oreal | Composition pour la teinture d'oxydation des fibres keratiniques comprenant un amide d'acide gras de colza oxyethylene |
US6964836B2 (en) | 2002-03-15 | 2005-11-15 | Eastman Kodak Company | Photosensitive microcapsules containing a synthetic viscosity modifier in the continuous phase |
JP3940009B2 (ja) | 2002-03-18 | 2007-07-04 | 住友精化株式会社 | カルボキシル基含有水溶性重合体の製造方法 |
US6946005B2 (en) | 2002-03-27 | 2005-09-20 | L'oreal S.A. | Pyrrolidinyl-substituted para-phenylenediamine derivatives substituted with a cationic radical, and use of these derivatives for dyeing keratin fibers |
US7132534B2 (en) * | 2002-07-05 | 2006-11-07 | L'oreal | Para-phenylenediamine derivatives containing a pyrrolidyl group, and use of these derivatives for coloring keratin fibers |
US6923835B2 (en) * | 2002-09-09 | 2005-08-02 | L'oreal S.A. | Bis-para-phenylenediamine derivatives comprising a pyrrolidyl group and use of these derivatives for dyeing keratin fibres |
JP3981129B2 (ja) | 2002-09-26 | 2007-09-26 | ロレアル | 順列を含むポリマーを含む口紅 |
MXPA03008714A (es) * | 2002-09-26 | 2004-09-10 | Oreal | Polimeros secuenciados y composiciones cosmeticas que comprenden tales polimeros. |
GB2393908A (en) * | 2002-10-12 | 2004-04-14 | Reckitt Benckiser Inc | Thickened, abrasive containing, liquid disinfectant |
AU2003276212A1 (en) * | 2002-11-07 | 2004-06-07 | Ciba Specialty Chemicals Holding Inc. | Thickening agents comprising a crosslinked polymer powder |
US7326256B2 (en) * | 2002-12-06 | 2008-02-05 | L'ORéAL S.A. | Composition for the oxidation dyeing of keratin fibers, comprising at least one non-oxyalkenylated fatty alcohol, at least one oxidation dye, at least one associative polymer, and at least one amide of an alkanolamine and a C14-C30 fatty acid |
US7329287B2 (en) * | 2002-12-06 | 2008-02-12 | L'oreal S.A. | Oxidation dye composition for keratin fibers, comprising at least one oxidation dye, at least one associative polymer, at least one nonionic cellulose-based compound not comprising a C8-C30 fatty chain, and at least one cationic polymer with a charge density of greater than 1 meq/g and not comprising a C8-C30 fatty chain |
FR2848102B1 (fr) | 2002-12-06 | 2007-08-03 | Oreal | Composition de teinture d'oxydation comprenant un colorant d'oxydation, un polymere associatif, un compose cellulosique non ionique et un polymere cationique |
US7993632B2 (en) * | 2002-12-20 | 2011-08-09 | L'oreal S.A. | Composition for coating keratin fibres having a threading nature |
US7186276B2 (en) * | 2002-12-23 | 2007-03-06 | L'oreal | Dye composition comprising at least one direct dye, dyeing processes, uses and multi-compartment devices |
US7169194B2 (en) * | 2002-12-23 | 2007-01-30 | L'oreal S.A. | Dye composition comprising at least one particular tricationic direct dye, dyeing process, use and multi-compartment devices |
US7261744B2 (en) | 2002-12-24 | 2007-08-28 | L'oreal S.A. | Method for dyeing or coloring human keratin materials with lightening effect using a composition comprising at least one fluorescent compound and at least one optical brightener |
US7226486B2 (en) * | 2003-01-16 | 2007-06-05 | L'oreal S.A | Ready-to-use bleaching compositions, preparation process and bleaching process |
US7217298B2 (en) * | 2003-01-16 | 2007-05-15 | L'oreal S.A. | Ready-to-use bleaching compositions, preparation process and bleaching process |
US7303588B2 (en) * | 2003-03-25 | 2007-12-04 | L'oreal S.A. | Composition for dyeing keratinous fibers, comprising at least one polycarboxylic acid or a salt, ready-to-use composition comprising it, implementation process and device |
FR2852832B1 (fr) * | 2003-03-25 | 2008-06-27 | Oreal | Composition de coloration pour fibres keratiniques comprenant un acide hydroxycarboxilique ou un sel, composition prete a l'emploi la comprenant, procede de mise en oeuvre et dispositif |
US20050039270A1 (en) * | 2003-03-25 | 2005-02-24 | L'oreal S.A. | Use of polycarboxylic acids and salts thereof as complexing agents in oxidizing compositions for dyeing, bleaching or permanently reshaping keratin fibres |
US20050011017A1 (en) * | 2003-03-25 | 2005-01-20 | L'oreal S.A. | Oxidizing composition comprising hydroxycarboxylic acids and salts thereof as complexing agents for dyeing, bleaching or permanently reshaping keratin fibres |
US7204860B2 (en) | 2003-04-01 | 2007-04-17 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one polyol, process therefor and use thereof |
US7198650B2 (en) | 2003-04-01 | 2007-04-03 | L'oreal S.A. | Method of dyeing human keratin materials with a lightening effect with compositions comprising at least one fluorescent dye and at least one amphoteric or nonionic surfactant, composition thereof, process thereof, and device therefor |
US7192454B2 (en) | 2003-04-01 | 2007-03-20 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising a fluorescent dye and a particular sequestering agent, process therefor and use thereof |
US7736631B2 (en) | 2003-04-01 | 2010-06-15 | L'oreal S.A. | Cosmetic dye composition with a lightening effect for human keratin materials, comprising at least one fluorescent dye and at least one aminosilicone, and process of dyeing |
US7195651B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Cosmetic composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one cationic polymer, and a dyeing process therefor |
US7186278B2 (en) | 2003-04-01 | 2007-03-06 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one compound comprising an acid functional group and processes therefor |
US7208018B2 (en) | 2003-04-01 | 2007-04-24 | L'oreal | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one associative polymer, process therefor and use thereof |
US7250064B2 (en) | 2003-04-01 | 2007-07-31 | L'oreal S.A. | Dye composition comprising at least one fluorescent dye and a non-associative thickening polymer for human keratin materials, process therefor, and method thereof |
US7150764B2 (en) | 2003-04-01 | 2006-12-19 | L'oreal S.A. | Composition for dyeing a human keratin material, comprising at least one fluorescent dye and at least one insoluble conditioning agent, process thereof, use thereof, and devices thereof |
US7147673B2 (en) | 2003-04-01 | 2006-12-12 | L'oreal S.A. | Composition for dyeing human keratin materials, comprising at least one fluorescent dye and at least one insoluble polyorganosiloxane conditioning polymer, process therefor and use thereof |
US7195650B2 (en) | 2003-04-01 | 2007-03-27 | L'oreal S.A. | Process for dyeing, with a lightening effect, human keratin fibers that have been permanently reshaped, using at least one composition comprising at least one fluorescent dye |
US7303589B2 (en) | 2003-04-01 | 2007-12-04 | L'oreal S.A. | Process for dyeing human keratin fibers, having a lightening effect, comprising at least one fluorescent compound and compositions of the same |
US7306630B2 (en) * | 2003-04-29 | 2007-12-11 | L'oreal S.A. | Composition comprising at least one coupler chosen from 2-chloro-6-methyl-3-aminophenol and addition salts thereof, at least one oxidation base, and at least one associative polymer comprising at least one C8-C30 fatty chain |
US7300470B2 (en) | 2003-04-29 | 2007-11-27 | L'oreal S.A. | Dye composition comprising 2-chloro-6-methyl-3-aminophenol, at least two oxidation bases chosen from para-phenylenediamine derivatives and at least one associative thickening polymer |
US7276087B2 (en) * | 2003-04-29 | 2007-10-02 | L'oreal S.A. | Dye composition comprising 2-chloro-6-methyl-3-aminophenol as coupler, para-aminophenol and 3-methyl-4-aminophenol as oxidation bases and at least one associative thickening polymer |
US7377946B2 (en) * | 2003-07-09 | 2008-05-27 | L'oréal | Composition comprising at least one substituted 2-[2-(4-amino phenyl)ethenyl]-1-pyridinium derivative, process for treating keratin fibres using it, device and use thereof |
FR2860143B1 (fr) | 2003-09-26 | 2008-06-27 | Oreal | Composition cosmetique comprenant un polymere sequence et une huile siliconee non volatile |
FR2863884B1 (fr) * | 2003-12-19 | 2007-06-29 | Oreal | Composition coiffante comprenant, dans un milieu majoritairement aqueux, un polyurethane cationique elastique, procedes la mettant en oeuvre et utilisations |
US7294152B2 (en) * | 2004-01-07 | 2007-11-13 | L'oreal S.A. | Dyeing composition comprising at least one fluorindine compound for the dyeing of keratinic fibers, dyeing process comprising the composition and compound |
US20050204485A1 (en) * | 2004-01-28 | 2005-09-22 | Gregory Plos | Composition for dyeing keratin fibers, containing an alcohol oxidase and an anionic associative polymer, process using this composition |
US20050235432A1 (en) * | 2004-01-28 | 2005-10-27 | Gregory Plos | Composition for dyeing keratin fibers, comprising at least one alcohol oxidase, at least one oxidation dye precursor, and at least one azo, methine or azomethine cationic direct dye, and process using this composition |
US20050220723A1 (en) * | 2004-03-25 | 2005-10-06 | Katarina Benabdillah | Aerosol device comprising a propellant and a styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer and an additional fixing polymer; processes therefor and uses thereof |
US8728451B2 (en) | 2004-03-25 | 2014-05-20 | L'oreal | Styling composition comprising, in a predominantly aqueous medium, a pseudo-block polymer, processes employing same and uses thereof |
US20060078507A1 (en) * | 2004-09-09 | 2006-04-13 | Charles Gringore | Aerosol device containing a composition comprising at least one propellant, at least one acrylic associative polymer, and at least one fixative polymer |
US7425221B2 (en) * | 2004-09-13 | 2008-09-16 | L'oreal S.A. | Composition comprising at least one substituted derivative of carbocyanine, method for treating keratin fibers using it, device and use |
FR2875132B1 (fr) | 2004-09-13 | 2007-07-13 | Oreal | Composition comprenant au moins un derive substitue de carbocyanine, procede de traitement des fibres keratiniques la mettant en oeuvre, dispositif et utilisation |
US7427301B2 (en) * | 2004-09-13 | 2008-09-23 | L'ORéAL S.A. | Composition comprising at least one substituted carbocyanin derivative, process for treating keratin fibers using it, device therefor and use thereof |
FR2875131B1 (fr) | 2004-09-13 | 2007-09-28 | Oreal | Composition comprenant au moins un derive substitue de carbocyanine, procede de traitement des fibres keratiniques la mettant en oeuvre, dispositif et utilisation |
FR2875130B1 (fr) | 2004-09-13 | 2006-12-15 | Oreal | Composition comprenant au moins un derive substitue de carbocyanine, procede de traitement des fibres keratiniques la mettant en oeuvre, dispositif et utilisation |
US7419511B2 (en) * | 2004-09-13 | 2008-09-02 | L'oreal, S.A. | Compositions comprising at least one substituted carbocyanin derivative, processes for treating keratin fibers using them, device therefor and uses thereof |
JP4808393B2 (ja) * | 2004-10-28 | 2011-11-02 | 花王株式会社 | 水中油型乳化組成物 |
US20060140898A1 (en) * | 2004-11-22 | 2006-06-29 | Claude Dubief | Use of a combination of at least one associated polymer and at least one amphiphilic diblock copolymer for thickening cosmetic compositions |
US7429275B2 (en) * | 2004-12-23 | 2008-09-30 | L'oreal S.A. | Use of at least one compound chosen from porphyrin compounds and phthalocyanin compounds for dyeing human keratin materials, compositions comprising them, a dyeing process, and compounds therefor |
KR20070099038A (ko) * | 2005-01-28 | 2007-10-08 | 바스프 악티엔게젤샤프트 | 화장품 제제를 위한 증점제 형태의 수-중-수 에멀젼중합체의 용도 |
US20060286049A1 (en) * | 2005-02-28 | 2006-12-21 | Chrystel Grethen-Pourille | Cosmetic composition comprising a tribochromic compound, process using this composition and uses |
FR2882517B1 (fr) | 2005-02-28 | 2007-05-25 | Oreal | Composition cosmetique contenant un compose tribochrome, procede mettant en oeuvre cette composition et utilisations |
FR2884140B1 (fr) | 2005-04-07 | 2011-01-07 | Oreal | Composition aqueuse comprenant du peroxyde d'hydrogene et des particules inertes |
US7374581B2 (en) * | 2005-04-29 | 2008-05-20 | L'oreal, S.A. | Dye composition containing a particular cationic hydrazone direct dye, dyeing process, use and multi-compartment devices |
US7736395B2 (en) * | 2005-06-29 | 2010-06-15 | L'oreal S.A. | Composition for simultaneously bleaching and dyeing keratin fibers, comprising at least one dye chosen from anionic and nonionic dyes and at least one inert organic liquid |
US7799092B2 (en) * | 2005-06-29 | 2010-09-21 | L'oreal S.A. | Composition for simultaneously bleaching and dyeing keratin fibers, comprising at least one anionic or nonionic direct dye and at least one associative polymer |
DE102005034412A1 (de) * | 2005-07-22 | 2007-01-25 | Basf Ag | Ampholytisches Copolymer, dessen Herstellung und Verwendung |
DE102005034906A1 (de) * | 2005-07-26 | 2007-02-01 | Basf Ag | Silicongruppen-haltiges Copolymer, dessen Herstellung und Verwendung |
EP1912620B1 (de) * | 2005-07-22 | 2013-02-20 | Basf Se | Verwendung anionisch und kationisch ampholytischer copolymere |
US7838610B2 (en) * | 2005-09-30 | 2010-11-23 | Nippon Shokubai Co., Ltd. | Ion-sensitive super-absorbent polymer |
US20070104669A1 (en) * | 2005-10-26 | 2007-05-10 | Rainer Muller | Cosmetic composition comprising at least one ester, at least one acrylic polymer, at least one cyclodextrin and at least one surfactant, and uses thereof |
EP1780764A1 (en) | 2005-11-01 | 2007-05-02 | FEI Company | Stage assembly, particle-optical apparatus comprising such a stage assembly, and method of treating a sample in such an apparatus |
KR101290885B1 (ko) | 2005-11-14 | 2013-07-29 | 스미토모 세이카 가부시키가이샤 | 알킬변성 카복실기 함유 수용성 공중합체 |
JP5149626B2 (ja) * | 2005-11-21 | 2013-02-20 | 住友精化株式会社 | アルキル変性カルボキシル基含有水溶性共重合体 |
US7531008B2 (en) * | 2005-11-30 | 2009-05-12 | L'oreal S.A. | Use of at least one cationic cyanin derivative for dyeing the hair, composition containing it, process for treating keratin fibers using the composition, and device therefor |
US20070184001A1 (en) * | 2006-01-20 | 2007-08-09 | Sabine Vrignaud | Cosmetic composition comprising a nonionic fixing polymer and a specific ester of polyethylene glycol and of fatty acid, and a method for fixing the hairstyle |
US20070184002A1 (en) * | 2006-01-20 | 2007-08-09 | Sabine Vrignaud | Non-washing cosmetic composition comprising at least one ionic fixing polymer and at least one ester of polyethylene glycol and of fatty acid, and method for fixing a hairstyle |
JP5073210B2 (ja) * | 2006-01-20 | 2012-11-14 | 花王株式会社 | 水中油型乳化組成物 |
CN101405304A (zh) * | 2006-01-23 | 2009-04-08 | 巴斯夫欧洲公司 | 在含水溶剂中制备聚合物的方法 |
US7481847B2 (en) * | 2006-03-28 | 2009-01-27 | L'oreal S.A. | Dye composition comprising at least one cationic hydrazone direct dye, dyeing process, and multi-compartment devices |
JP5302882B2 (ja) * | 2006-03-31 | 2013-10-02 | ビーエーエスエフ ソシエタス・ヨーロピア | アクリレートコポリマーの製造方法 |
EP2023892A1 (de) * | 2006-05-04 | 2009-02-18 | Basf Se | Neutralisierte säuregruppenhaltige polymere und deren verwendung |
JP5271079B2 (ja) * | 2006-05-12 | 2013-08-21 | 住友精化株式会社 | 顆粒状カルボキシル基含有重合体粒子の製造方法及び顆粒状カルボキシル基含有重合体粒子 |
FR2903001B1 (fr) * | 2006-07-03 | 2008-09-26 | Oreal | Composition cosmetique associant un derive c-glycoside a un polymere associatif |
FR2904320B1 (fr) | 2006-07-27 | 2008-09-05 | Oreal | Polymeres sequences, et leur procede de preparation |
JP2010515465A (ja) * | 2007-01-12 | 2010-05-13 | ザ リージェンツ オブ ザ ユニバーシティー オブ コロラド,ア ボディー コーポレート | 微生物によって生成される有機化学物質の生成に対する耐性を高めるための組成物および方法 |
FR2911277A1 (fr) * | 2007-01-12 | 2008-07-18 | Oreal | Composition cosmetique comprenant un polymere cationique et un polymere anionique a chaine hydrophobe |
BRPI0812513B1 (pt) | 2007-06-19 | 2019-01-15 | Sumitomo Seika Chemicals Co., Ltd. | método para a produção de partícula granulada de polímero contendo grupo carboxila |
EP2011474A1 (fr) | 2007-06-29 | 2009-01-07 | L'Oréal | Composition anhydre comprenant au moins un colorant d'oxydation, au moins un complexe de peroxyde d'hydrogene et d'un polymere particulier et procédé de coloration la mettant en oeuvre |
FR2917972B1 (fr) | 2007-06-29 | 2009-10-16 | Oreal | Composition anhydre sous forme de pate pour la decoloration des fibres keratiniques |
FR2920976B1 (fr) | 2007-09-14 | 2009-12-04 | Oreal | Composition cosmetique comprenant un copolymere cationique et un polymere associatif anionique et procede de traitement cosmetique. |
US8048624B1 (en) | 2007-12-04 | 2011-11-01 | Opx Biotechnologies, Inc. | Compositions and methods for 3-hydroxypropionate bio-production from biomass |
KR101539128B1 (ko) * | 2007-12-28 | 2015-07-23 | 스미또모 세이까 가부시키가이샤 | (메트)아크릴산/(메트)아크릴산알킬에스테르 공중합체 및, 그것을 배합한 화장료 |
FR2926986B1 (fr) | 2008-01-31 | 2012-12-28 | Oreal | Composition cosmetique comprenant un copolymere vinylformanide/vinylformanine et un polymere epaississant |
KR20100115790A (ko) | 2008-02-01 | 2010-10-28 | 바스프 에스이 | 선형 침전 중합체 |
DE102008011767B4 (de) | 2008-02-28 | 2012-07-26 | Basf Se | Verfahren zur Herstellung von olefinisch ungesättigten Carbonylverbindungen durch oxidative Dehydrierung von Alkoholen |
FR2932070B1 (fr) | 2008-06-10 | 2012-08-17 | Oreal | Ensemble de maquillage et/ou de soin des cils |
JP2012502128A (ja) * | 2008-09-04 | 2012-01-26 | ビーエーエスエフ ソシエタス・ヨーロピア | グリセリンモノステアレートの存在下での沈殿重合 |
JP5703231B2 (ja) * | 2008-11-21 | 2015-04-15 | ハーキュリーズ・インコーポレーテッドHercules Incorporated | 非ヒドロカルビル疎水性変性ポリカルボン酸ポリマー |
EP2191813A1 (en) * | 2008-11-26 | 2010-06-02 | L'oreal | Cosmetic compositions with a spongy texture |
FR2939033B1 (fr) | 2008-12-02 | 2012-08-31 | Oreal | Composition cosmetique de maquillage et/ou de soin des matieres keratiniques, et procede de maquillage |
FR2939657B1 (fr) | 2008-12-15 | 2011-02-11 | Oreal | Composition cosmetique comprenant une polyamine portant des groupes diazirines et utilisation pour le photo-greffage d'un polymere non saccharidique different des polymeres polyamines |
FR2940102B1 (fr) | 2008-12-19 | 2016-03-11 | Oreal | Composition de teinture d'oxydation des fibres keratiniques comprenant un corps gras, un epaississant et un precurseur de colorant d'oxydation |
WO2010075327A1 (en) * | 2008-12-22 | 2010-07-01 | Serenity Pharmaceuticals Corporation | Desmopressin composition |
JP5893832B2 (ja) * | 2009-01-19 | 2016-03-23 | Necエナジーデバイス株式会社 | 非水電解液二次電池及びその製造方法 |
CN102695799A (zh) | 2009-09-27 | 2012-09-26 | Opx生物工艺学公司 | 用于制备3-羟基丙酸和其它产物的方法 |
US8809027B1 (en) | 2009-09-27 | 2014-08-19 | Opx Biotechnologies, Inc. | Genetically modified organisms for increased microbial production of 3-hydroxypropionic acid involving an oxaloacetate alpha-decarboxylase |
US20110123473A1 (en) * | 2009-11-26 | 2011-05-26 | Basf Se | Use of highly-branched polycarbonates in cosmetic and dermatological formulations |
CN102665669B (zh) | 2009-11-26 | 2014-04-16 | 巴斯夫欧洲公司 | 超支化聚碳酸酯在化妆品和皮肤病配制剂中的用途 |
KR101722805B1 (ko) | 2009-11-26 | 2017-04-05 | 바스프 에스이 | 화장품 및 피부과용 제제에서의 초분지형 폴리에스테르의 용도 |
EP2353582A1 (fr) | 2009-12-18 | 2011-08-10 | L'Oréal | Composition de maquillage des cils et des sourcils |
FR2954093B1 (fr) | 2009-12-22 | 2012-02-24 | Oreal | Agent de coloration et/ou de decoloration des fibres keratiniques en deux parties ou plus sous forme d'emulsion et de dispersion |
US20110218295A1 (en) * | 2010-03-02 | 2011-09-08 | Basf Se | Anionic associative rheology modifiers |
US8673275B2 (en) | 2010-03-02 | 2014-03-18 | Basf Se | Block copolymers and their use |
JP2013521363A (ja) | 2010-03-02 | 2013-06-10 | ビーエイエスエフ・ソシエタス・エウロパエア | ブロックコポリマーおよびその使用 |
CN105919832A (zh) | 2010-06-11 | 2016-09-07 | 宝洁公司 | 用于处理皮肤的组合物 |
FR2961815B1 (fr) | 2010-06-25 | 2013-05-10 | Coatex Sas | Emulsions acryliques alkali gonflables a l'acide acrylique, leur utilisation dans des formulations aqueuses et formulations les contenant. |
FR2961816B1 (fr) | 2010-06-25 | 2012-07-06 | Coatex Sas | Emulsions acryliques alkali gonflables sans tensio-actif, leur utilisation dans des formulations aqueuses et formulations les contenant. |
FR2964317B1 (fr) | 2010-09-06 | 2013-04-12 | Oreal | Composition cosmetique comprenant un polymere fixant et un epaississant particulier et utilisations en coiffage |
FR2964565B1 (fr) | 2010-09-14 | 2012-09-07 | Oreal | Composition cosmetique comprenant un polymere fixant et un agent antipelliculaire |
JP5774706B2 (ja) | 2010-09-20 | 2015-09-09 | ロレアルL′Oreal | アルキルセルロースを含む水性化粧料組成物 |
US11819563B2 (en) | 2010-09-20 | 2023-11-21 | L'oreal | Aqueous cosmetic composition comprising alkylcellulose |
FR2965728B1 (fr) * | 2010-10-12 | 2012-10-26 | Oreal | Composition comprenant un derive silicie et un polymere epaississant particuliers et son utilisation en cosmetique |
EP2627311A1 (en) * | 2010-10-12 | 2013-08-21 | L'Oréal | Cosmetic composition comprising a particular silicon derivative and one or more acrylic thickening polymers |
FR2966729B1 (fr) | 2010-11-02 | 2014-03-21 | Oreal | Composition de coloration mousse comprenant un polymere associatif |
FR2967350B1 (fr) | 2010-11-15 | 2015-05-01 | Oreal | Composition cosmetique solide sous forme de poudre compacte |
FR2967351B1 (fr) | 2010-11-15 | 2016-06-10 | Oreal | Composition cosmetique solide sous forme de poudre compacte |
US11406578B2 (en) | 2010-11-25 | 2022-08-09 | L'oreal | Process for stripping keratin fibres using a composition comprising a sulfinic acid derivative and an acidic aqueous composition |
FR2971937B1 (fr) | 2011-02-25 | 2013-02-15 | Oreal | Composition pour colorer les fibres keratiniques comprenant un colorant direct a fonction disulfure/thiol, un polymere epaississant non cellulosique, un agent alcalin, et un agent reducteur |
FR2971938B1 (fr) | 2011-02-25 | 2013-08-02 | Oreal | Composition pour colorer les fibres keratiniques comprenant un colorant direct a fonction disulfure/thiol, un alcool gras faiblement ou non ethoxyle, un tensioactif cationique, un agent alcalin, et un agent reducteur |
FR2971936B1 (fr) | 2011-02-25 | 2013-02-15 | Oreal | Composition pour colorer les fibres keratiniques comprenant un colorant direct a fonction disulfure/thiol, un tensioactif non ionique, un tensioactif amphotere, un alcool gras ethoxyle, un agent alcalin, et un agent reducteur |
FR2971935B1 (fr) | 2011-02-25 | 2013-02-15 | Oreal | Composition pour colorer les fibres keratiniques comprenant un colorant direct a fonction disulfure/thiol, un polymere epaississant, un tensioactif non ionique, un agent alcalin, et un agent reducteur |
FR2971939B1 (fr) | 2011-02-25 | 2013-02-15 | Oreal | Composition pour colorer les fibres keratiniques comprenant un colorant direct a fonction disulfure/thiol, un corps gras, un agent alcalin, et un agent reducteur |
ES2657616T3 (es) | 2011-02-25 | 2018-03-06 | L'oréal | Composición para teñir fibras queratinosas que comprende un tinte directo que tiene un grupo funcional disulfuro/tiol, un polímero espesante, un alcohol graso etoxilado y/o un tensioactivo no iónico, un agente alcalino y un agente reductor |
FR2972370B1 (fr) | 2011-03-07 | 2013-03-01 | Coatex Sas | Procede d'epaississement d'une formulation cosmetique a partir d'une emulsion alkali gonflable d'un polymere a l'amps et riche en acide acrylique. |
MX2013010481A (es) | 2011-03-22 | 2014-03-05 | Opx Biotechnologies Inc | Produccion microbiana de productos quimicos y composiciones, metodos y sistemas relacionados. |
FR2975290B1 (fr) | 2011-05-20 | 2013-08-09 | Oreal | Composition de decoloration des fibres keratiniques sous forme de tablette avec persulfate et un polymere particulier |
FR2975291B1 (fr) | 2011-05-20 | 2013-11-08 | Oreal | Composition de decoloration des fibres keratiniques sous forme de tablette avec persulfate et un sel d'ammonium |
WO2012159929A2 (en) | 2011-05-20 | 2012-11-29 | L'oreal | Process for bleaching keratin fibres comprising the application of a composition in compressed form |
MX340441B (es) | 2011-06-01 | 2016-07-08 | Oreal | Proceso para tratar fibras queratinicas alaciadas. |
EP2739659B1 (en) | 2011-08-03 | 2015-06-17 | Air Products and Chemicals, Inc. | Ionic/ionogenic comb copolymer compositions and personal care products containing the same |
FR2982159B1 (fr) | 2011-11-03 | 2013-11-29 | Oreal | Composition cosmetique solide sous forme de poudre compacte |
WO2013069166A1 (en) | 2011-11-09 | 2013-05-16 | L'oreal | Cosmetic composition for keratin fibers |
WO2013069167A1 (en) | 2011-11-09 | 2013-05-16 | L'oreal | Cosmetic composition for keratin fibers |
WO2013069168A1 (en) | 2011-11-09 | 2013-05-16 | L'oreal | Cosmetic composition for keratin fibers |
WO2013069165A1 (en) | 2011-11-09 | 2013-05-16 | L'oreal | Cosmetic composition for keratin fibers |
US9243142B2 (en) | 2011-11-16 | 2016-01-26 | Momentive Performance Materials Inc. | Association product of amino functional hydrophobic polymers with hydrophilic polymers containing acid groups, methods of preparation, and applications for employing the same |
FR2984137B1 (fr) | 2011-12-19 | 2013-12-20 | Oreal | Composition cosmetique comprenant un polymere associatif anionique ou non ionique, un polymere fixant et un tensioactif particulier et utilisation en coiffage |
FR2984136B1 (fr) | 2011-12-19 | 2013-12-20 | Oreal | Composition cosmetique comprenant un polymere associatif anionique ou non ionique, un polymere fixant et un tensioactif particulier et utilisation en coiffage |
FR2984135B1 (fr) | 2011-12-19 | 2013-12-20 | Oreal | Composition cosmetique comprenant un polymere associatif anionique ou non ionique, un polymere fixant et un tensioactif particulier et utilisation en coiffage |
FR2985180B1 (fr) | 2012-01-02 | 2020-06-19 | L'oreal | Emulsion eau dans huile comprenant de l'alkylcellulose, des huiles non volatiles, et au moins un tensioactif |
FR2985178B1 (fr) | 2012-01-02 | 2014-01-31 | Oreal | Composition cosmetique aqueuse comprenant de l'alkylcellulose, des huiles non volatiles, une cire particuliere et un agent tensioactif |
FR2985174B1 (fr) | 2012-01-02 | 2014-03-07 | Oreal | Composition cosmetique aqueuse comprenant de l'alkylcellulose, des huiles non volatiles, au moins une cire et au moins un gelifiant hydrophile particulier |
FR2985176B1 (fr) | 2012-01-02 | 2015-05-29 | Oreal | Composition cosmetique liquide aqueuse comprenant de l'alkylcellulose, des huiles non volatiles et au moins un tensioactif |
FR2985175B1 (fr) | 2012-01-02 | 2015-11-06 | Oreal | Composition cosmetique aqueuse comprenant de l'alkylcellulose, des huiles non volatiles, au moins une cire et au moins un tensioactif gemine |
US20130196890A1 (en) | 2012-01-30 | 2013-08-01 | Reckitt Benckiser Llc | Stable, viscous, peroxide containing lavatory treatment compositions |
JP2015506906A (ja) | 2012-02-14 | 2015-03-05 | ロレアル | ヒトケラチン繊維を処理するための化粧料組成物及び方法 |
EP3769817A1 (en) | 2012-03-30 | 2021-01-27 | L'oreal Sa | Composition comprising (2,5-diaminophenyl) ethanol and a carboxylic anionic polymer in a medium rich in fatty substances, dyeing process and device |
WO2013150661A1 (en) | 2012-04-04 | 2013-10-10 | L'oreal | Cosmetic composition for keratin fibers |
JP2015512864A (ja) | 2012-04-10 | 2015-04-30 | ロレアル | ケラチン繊維用化粧料組成物 |
US9662290B2 (en) | 2012-04-24 | 2017-05-30 | L'oreal | Dyeing process using a mixture comprising a thickening polymer, obtained from an aerosol device, and device therefor |
FR2989578A1 (fr) | 2012-04-24 | 2013-10-25 | Oreal | Procede de coloration mettant en oeuvre un melange comprenant un polyol ramifie en c6-c12, obtenu a partir d'un dispositif aerosol et dispositif |
EP2841046B1 (en) | 2012-04-24 | 2017-07-26 | L'Oréal | Dyeing process using a mixture obtained from an aerosol device comprising a nonionic fatty amide, and device therefor |
WO2013160258A2 (en) | 2012-04-24 | 2013-10-31 | L'oreal | Dyeing process using a mixture obtained from an aerosol device comprising a glycerolated surfactant, and device therefor |
BR112014026538A2 (pt) | 2012-04-24 | 2017-06-27 | Oreal | processo para tingir as fibras queratínicas e dispositivo. |
EP2879650B1 (en) | 2012-08-02 | 2017-07-26 | L'oreal | Dyeing composition comprising a fatty substance, a non-ionic guar gum, an amphoteric surfactant and a non-ionic or anionic surfactant, and an oxidizing agent, dyeing process and suitable device |
FR2994084B1 (fr) | 2012-08-02 | 2014-10-31 | Oreal | Composition de coloration sous forme de creme comprenant au moins une huile, pas ou peu d'alcool gras solide, procede de coloration et dispositif approprie |
WO2014020146A2 (en) | 2012-08-02 | 2014-02-06 | L'oreal | Dyeing composition comprising at least one fatty substance, at least one oxidizing agent and at least one non-ionic, anionic and amphoteric surfactant |
FR2994091B1 (fr) | 2012-08-02 | 2014-08-01 | Oreal | Composition de coloration comprenant de la gomme de guar non ionique ou l'un de ses derives non ionique, procede et dispositif |
FR2994088B1 (fr) | 2012-08-02 | 2019-07-05 | L'oreal | Composition de coloration comprenant au moins un compose sulfonique, un polymere epaississant, procede de coloration et dispositif approprie |
SG11201501013PA (en) | 2012-08-10 | 2015-04-29 | Opx Biotechnologies Inc | Microorganisms and methods for the production of fatty acids and fatty acid derived products |
FR2994648B1 (fr) | 2012-08-23 | 2014-08-29 | Oreal | Composition de decoloration des fibres keratiniques sous forme comprimee comprenant deux couches |
WO2014083330A1 (en) | 2012-11-30 | 2014-06-05 | Reckitt & Colman (Overseas) Limited | Microbicidal personal care compositions comprising metal ions |
FR2999423B1 (fr) | 2012-12-14 | 2015-03-13 | Oreal | Composition cosmetique sous forme de poudre comprenant un polymere epaississant (meth)acrylique, un polymere fixant, des particules insolubles dans l'eau |
WO2014097258A2 (en) | 2012-12-20 | 2014-06-26 | L'oreal | Aqueous cosmetic composition comprising alkylcellulose |
EP2941238B1 (en) | 2012-12-21 | 2019-10-16 | L'Oréal | Cosmetic composition |
JP6356382B2 (ja) | 2012-12-21 | 2018-07-11 | ロレアル | 化粧品組成物 |
FR3002123B1 (fr) | 2013-02-21 | 2018-03-09 | L'oreal | Dispositif de distribution comprenant une composition aqueuse sous forme de gel ou de creme epaisse |
FR3002449B1 (fr) | 2013-02-25 | 2015-04-03 | Oreal | Composition cosmetique de type gel |
FR3002448B1 (fr) | 2013-02-25 | 2015-04-03 | Oreal | Composition cosmetique de type gel |
BR112015023473B1 (pt) | 2013-03-15 | 2023-04-11 | Cargill, Incorporated | Microrganismo geneticamente modificado e método de produzir um produto |
EP2976141A4 (en) | 2013-03-15 | 2016-10-05 | Cargill Inc | FLASHING FOR PRODUCTION CLEANING AND RECOVERY |
US20150057465A1 (en) | 2013-03-15 | 2015-02-26 | Opx Biotechnologies, Inc. | Control of growth-induction-production phases |
FR3003464B1 (fr) | 2013-03-19 | 2016-02-12 | Oreal | Composition cosmetique comprenant des particules creuses ou poreuses, un monoalcool et un polymere epaississant, procedes de traitement cosmetique et utilisations |
FR3003465B1 (fr) | 2013-03-25 | 2016-07-29 | Oreal | Composition de rouge a levres sous forme d'une emulsion comprenant un polymere filmogene particulier et procede de traitement la mettant en oeuvre |
FR3004343B1 (fr) | 2013-04-12 | 2015-06-19 | Oreal | Composition cosmetique de type gel |
US20160199276A1 (en) | 2013-04-25 | 2016-07-14 | L'oreal | Composition for straightening keratin fibres, comprising a urea and/or a urea derivative and a nonionic, cationic, amphoteric or anionic associative polymeric thickener, process and use thereof |
WO2014188007A1 (en) | 2013-05-24 | 2014-11-27 | L'oreal | Cosmetic composition comprising an aqueous phase and a fatty phase that are visually distinct |
EP3016631B1 (en) | 2013-05-30 | 2019-10-02 | L'oreal | Cosmetic composition |
US9795555B2 (en) | 2013-06-28 | 2017-10-24 | L'oreal | Compositions and methods for treating hair |
US9839600B2 (en) | 2013-06-28 | 2017-12-12 | L'oreal | Compositions and methods for treating hair |
US9795556B2 (en) | 2013-06-28 | 2017-10-24 | L'oreal | Compositions and methods for treating hair |
US9884004B2 (en) | 2013-06-28 | 2018-02-06 | L'oreal | Compositions and methods for treating hair |
US9801804B2 (en) | 2013-06-28 | 2017-10-31 | L'oreal | Compositions and methods for treating hair |
US9788627B2 (en) | 2013-06-28 | 2017-10-17 | L'oreal | Compositions and methods for treating hair |
US9884003B2 (en) | 2013-06-28 | 2018-02-06 | L'oreal | Compositions and methods for treating hair |
US9789051B2 (en) | 2013-06-28 | 2017-10-17 | L'oreal | Compositions and methods for treating hair |
US9789050B2 (en) | 2013-06-28 | 2017-10-17 | L'oreal | Compositions and methods for treating hair |
US9884002B2 (en) | 2013-06-28 | 2018-02-06 | L'oreal | Compositions and methods for treating hair |
US11408013B2 (en) | 2013-07-19 | 2022-08-09 | Cargill, Incorporated | Microorganisms and methods for the production of fatty acids and fatty acid derived products |
EP3022310B1 (en) | 2013-07-19 | 2019-10-16 | Cargill, Incorporated | Microorganisms and methods for the production of fatty acids and fatty acid derived products |
WO2015059084A1 (de) | 2013-10-21 | 2015-04-30 | Basf Se | Fällungspolymerisation in gegenwart eines tertiären amins und eines anhydrids |
JP2015129095A (ja) | 2013-12-19 | 2015-07-16 | ロレアル | 組成物 |
FR3015271B1 (fr) | 2013-12-20 | 2016-01-01 | Oreal | Composition comprenant un copolymere acrylique particulier et un polymere epaississant |
EP2907828A1 (de) | 2014-02-14 | 2015-08-19 | Basf Se | Verfahren zur Herstellung von kationogen-ampholytischen VP/VI-Copolymeren |
US20150265525A1 (en) | 2014-03-21 | 2015-09-24 | L'oreal | Composition for altering the color of keratin fibers |
US9364399B2 (en) | 2014-03-21 | 2016-06-14 | L'oreal | Water-based gel cosmetic compositions without film formers |
US9517188B2 (en) | 2014-03-21 | 2016-12-13 | L'oreal | Water-based gel cosmetic compositions containing emulsifier |
SG11201608963QA (en) | 2014-05-05 | 2016-12-29 | Lubrizol Advanced Mat Inc | Homogenous film compositions |
FR3021533B1 (fr) | 2014-05-28 | 2017-09-15 | Oreal | Composition cosmetique de type gel |
KR102455927B1 (ko) | 2014-07-09 | 2022-10-17 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 하이드로겔 조성물 |
FR3025100B1 (fr) | 2014-08-28 | 2016-12-09 | Oreal | Composition cosmetique de type gel a tenue amelioree |
FR3025075A1 (fr) | 2014-08-28 | 2016-03-04 | Oreal | Nouveau dispositif de soin et/ou maquillage comprenant une composition d’architecture gel/gel |
FR3025098B1 (fr) | 2014-08-28 | 2018-03-09 | Oreal | Composition cosmetique de type gel facilement demaquillable |
FR3025099B1 (fr) | 2014-08-28 | 2016-12-16 | Oreal | Composition cosmetique de type gel a tenue amelioree et non collante |
EP2993228B1 (en) | 2014-09-02 | 2019-10-09 | Cargill, Incorporated | Production of fatty acid esters |
CN106999408B (zh) | 2014-11-07 | 2021-06-01 | 欧莱雅 | 雪花膏组合物及其应用 |
US10966916B2 (en) | 2014-11-10 | 2021-04-06 | The Procter And Gamble Company | Personal care compositions |
CN107106429B (zh) | 2014-11-10 | 2021-06-29 | 宝洁公司 | 具有两种有益相的个人护理组合物 |
US10085924B2 (en) | 2014-11-10 | 2018-10-02 | The Procter & Gamble Company | Personal care compositions |
CN107106474B (zh) | 2014-11-10 | 2021-06-01 | 宝洁公司 | 具有两种有益相的个人护理组合物 |
US20160136085A1 (en) | 2014-11-13 | 2016-05-19 | L'oreal | Water-based liquid cosmetic compositions |
JP2016098221A (ja) | 2014-11-26 | 2016-05-30 | ロレアル | 油に富む組成物 |
JP2016098220A (ja) | 2014-11-26 | 2016-05-30 | ロレアル | シリコーン油に富む組成物 |
FR3029407B1 (fr) | 2014-12-08 | 2016-12-09 | Oreal | Procede de coloration capillaire mettant en œuvre au moins un colorant direct et/ou naturel, un sel de titane, un polysaccharide cellulosique et eventuellement un solvant organique particulier |
FR3029406B1 (fr) | 2014-12-08 | 2016-12-09 | Oreal | Procede de coloration capillaire mettant en œuvre au moins un colorant, un sel de titane, et un polymere epaississant anionique |
FR3029405B1 (fr) | 2014-12-08 | 2019-08-02 | L'oreal | Procede de coloration capillaire mettant en œuvre au moins un colorant, un sel de titane, et un silicate insoluble |
FR3029409B1 (fr) | 2014-12-08 | 2016-12-09 | Oreal | Procede de coloration capillaire mettant en œuvre au moins un colorant, un sel organique de titane, et un polysaccharide non cellulosique |
US9814669B2 (en) | 2014-12-19 | 2017-11-14 | L'oreal | Hair cosmetic composition containing latex polymers and a silicone-organic polymer compound |
US9750678B2 (en) | 2014-12-19 | 2017-09-05 | L'oreal | Hair coloring compositions comprising latex polymers |
US9801808B2 (en) | 2014-12-19 | 2017-10-31 | Loreal | Hair styling compositions comprising latex polymers and wax dispersions |
US10195122B2 (en) | 2014-12-19 | 2019-02-05 | L'oreal | Compositions and methods for hair |
US9814668B2 (en) | 2014-12-19 | 2017-11-14 | L'oreal | Hair styling compositions comprising latex polymers |
FR3030231B1 (fr) | 2014-12-23 | 2018-08-24 | L'oreal | Utilisation d'un ester d'acide gras pour matifier la peau et composition comprenant cet ester |
US10813853B2 (en) | 2014-12-30 | 2020-10-27 | L'oreal | Compositions and methods for hair |
KR102296836B1 (ko) | 2015-04-16 | 2021-09-01 | 에스케이이노베이션 주식회사 | 고내열성 고점도 수용성 폴리머 및 이를 포함하는 고점도 수용액의 제조방법 |
CN107666896A (zh) | 2015-05-07 | 2018-02-06 | 欧莱雅 | 清洁擦洗组合物 |
JP6687341B2 (ja) | 2015-07-29 | 2020-04-22 | ロレアル | ケラチン物質のための組成物 |
US10172776B2 (en) | 2015-07-30 | 2019-01-08 | L'oreal | Compositions for altering the color of hair |
US10111816B2 (en) | 2015-08-05 | 2018-10-30 | L'oreal | Composition for altering the color of keratin fibers |
WO2017030106A1 (en) | 2015-08-18 | 2017-02-23 | L'oreal | Oil-in-water emulsion composition |
WO2017079248A1 (en) | 2015-11-05 | 2017-05-11 | Lubrizol Advanced Materials, Inc. | Thermoformable dual network hydrogel compositions |
EP3389604B1 (en) | 2015-12-14 | 2020-04-08 | L'Oréal | Composition comprising a combination of particular alkoxysilanes and a fatty substance |
WO2017102856A1 (en) | 2015-12-14 | 2017-06-22 | L'oreal | Process for treating keratin fibres using an aqueous composition comprising a combination of particular alkoxysilanes |
FR3044879B1 (fr) | 2015-12-14 | 2018-01-19 | L'oreal | Dispositif de distribution d'un produit de coloration et/ou d'eclaircissement des fibres keratiniques comprenant un polymere associatif |
JP6772269B2 (ja) | 2015-12-17 | 2020-10-21 | ロレアル | 疎水性コーティングされた顔料および液体脂肪酸および/またはグリコール化合物をベースとするゲル/ゲル型の組成物 |
FR3045326B1 (fr) | 2015-12-18 | 2018-01-12 | L'oreal | Composition a base d'une phase aqueuse contenant une dispersion d'un materiau composite anhydre |
FR3045331B1 (fr) | 2015-12-21 | 2019-09-06 | L'oreal | Composition de coloration a ph acide comprenant un colorant direct de structure triarylmethane |
FR3045346B1 (fr) | 2015-12-21 | 2019-08-30 | L'oreal | Composition de coloration comprenant un colorant direct de structure triarylmethane, et une silicone |
US10792477B2 (en) | 2016-02-08 | 2020-10-06 | Orbusneich Medical Pte. Ltd. | Drug eluting balloon |
CN114225119A (zh) | 2016-02-08 | 2022-03-25 | 祥丰医疗私人有限公司 | 包含包衣的可膨胀的球囊 |
WO2017148973A1 (en) | 2016-03-04 | 2017-09-08 | L'oreal | Composition comprising a thickening polymer, a derivative of menthol and a particular non-ionic surfactant |
CN108883051B (zh) | 2016-03-31 | 2021-11-30 | 住友精化株式会社 | 凝胶组合物、化妆料、及凝胶组合物的制造方法 |
EP3437631B1 (en) | 2016-03-31 | 2022-01-19 | Sumitomo Seika Chemicals Co., Ltd. | Gel composition, cosmetic, and method for producing gel composition |
FR3052970B1 (fr) | 2016-06-23 | 2018-06-29 | L'oreal | Procede de traitement des fibres keratiniques mettant en œuvre une composition anhydre comprenant un compose de type azomethinique a deux motifs pyrazolopyridines et une composition aqueuse |
JP6903426B2 (ja) | 2016-12-15 | 2021-07-14 | ロレアル | 発泡性組成物 |
FR3060307B1 (fr) | 2016-12-16 | 2019-01-25 | L'oreal | Composition cosmetique comprenant des corps gras solides et un polymere gelifiant |
FR3060363B1 (fr) | 2016-12-20 | 2020-05-08 | L'oreal | Composition a forte teneur en eau thermale et/ou minerale |
FR3060985B1 (fr) | 2016-12-22 | 2020-02-14 | L'oreal | Procede de coloration directe des fibres keratiniques comprenant l'application de deux compositions particulieres |
FR3060986B1 (fr) | 2016-12-22 | 2020-02-14 | L'oreal | Composition cosmetique de coloration directe comprenant une phase aqueuse et une phase grasse visuellement distinctes l'une de l'autre |
JP2020506702A (ja) | 2017-02-02 | 2020-03-05 | カーギル インコーポレイテッド | C6−c10脂肪酸誘導体を生成する遺伝子組み換え細胞 |
US20200069533A1 (en) | 2017-03-23 | 2020-03-05 | Lubrizol Advanced Materials, Inc. | Denture adhesives |
US20200375890A1 (en) | 2017-03-23 | 2020-12-03 | Particle Sciences, Inc. | Implantable and removable drug delivery device |
KR20190139942A (ko) | 2017-05-02 | 2019-12-18 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 개선된 지속 방출형의 고도로 적재되는 약물 조성물 |
FR3067937B1 (fr) | 2017-06-27 | 2019-12-20 | L'oreal | Composition gel-gel comprenant une cire a l'etat cristallin. |
FR3067934B1 (fr) | 2017-06-27 | 2019-08-09 | L'oreal | Composition gelifiee comprenant une dispersion d'agregats solides. |
JP7063556B2 (ja) | 2017-07-04 | 2022-05-09 | ロレアル | 起泡性クレンザー |
CA3074047A1 (en) | 2017-08-30 | 2019-03-07 | Sumitomo Seika Chemicals Co., Ltd. | Alkyl-modified carboxyl group-containing copolymer, thickener containing said copolymer, and method for preparing said copolymer |
WO2019079405A1 (en) | 2017-10-20 | 2019-04-25 | The Procter & Gamble Company | AEROSOL FOAMING CLEANSER FOR THE SKIN |
EP3697375B1 (en) | 2017-10-20 | 2021-12-01 | The Procter & Gamble Company | Aerosol foam skin cleanser |
FR3073410B1 (fr) | 2017-11-15 | 2019-10-11 | L'oreal | Emulsion comprenant un copolymere acrylique anionique et un polymere lipophile |
WO2019113035A1 (en) | 2017-12-08 | 2019-06-13 | The Procter & Gamble Company | Methods of screening for mild skin cleanser |
FR3075053B1 (fr) | 2017-12-15 | 2020-07-10 | L'oreal | Composition de type gel/gel a base de pigments, d’au moins un dihydroxyalcane lineaire sature en c3-c8, d’acide salicylique sous forme libre |
FR3075611B1 (fr) | 2017-12-21 | 2021-11-19 | Oreal | Procede de traitement des fibres keratiniques mettant en œuvre un colorant direct fluoresceine halochrome, un revelateur alcalin puis un effaceur acide |
FR3075613B1 (fr) | 2017-12-21 | 2022-06-10 | Oreal | Procede de traitement des fibres keratiniques mettant en œuvre un colorant direct triarylmethane halochrome, un revelateur alcalin puis un effaceur acide |
FR3075616B1 (fr) | 2017-12-21 | 2022-06-10 | Oreal | Procede de traitement des fibres keratiniques mettant en œuvre un colorant direct oxazone ou phenazine halochrome, un revelateur puis un effaceur |
FR3075612B1 (fr) | 2017-12-22 | 2020-03-06 | L'oreal | Composition aqueuse comprenant un colorant direct, un systeme tampon, un solvant hydrotrope et un alcool inferieur. |
FR3075640B1 (fr) | 2017-12-22 | 2020-02-28 | L'oreal | Procede de coloration capillaire comprenant une etape de coloration avec du henne et/ou de l’indigo et une etape de traitement comprenant l’application comprenant un systeme tampon. |
FR3080038B1 (fr) | 2018-04-16 | 2020-10-09 | Oreal | Composition cosmetique pour fibres keratiniques |
JP2019196311A (ja) | 2018-04-16 | 2019-11-14 | ロレアル | O/w型の形態の組成物 |
FR3080037B1 (fr) * | 2018-04-16 | 2020-04-24 | L'oreal | Composition cosmetique pour fibres keratiniques |
FR3083098B1 (fr) | 2018-06-28 | 2021-10-29 | Oreal | Procede de bouclage des fibres keratiniques comprenant l'application sur les fibres d'une composition contenant de l'acide thiolactique |
EP3887824A1 (en) | 2018-11-29 | 2021-10-06 | The Procter & Gamble Company | Methods for screening personal care products |
FR3089813B1 (fr) | 2018-12-12 | 2021-03-05 | Oreal | Gelée de parfum |
FR3103700B1 (fr) | 2019-12-03 | 2024-01-19 | Oreal | Mélange antimicrobien contenant du 4-(3-éthoxy-4-hydroxyphényl)butan-2-one et le 4-hydroxyacétophenone, et composition le contenant |
EP3897146A1 (fr) | 2018-12-20 | 2021-10-27 | L'oreal | Mélange antimicrobien contenant du 4-(3-éthoxy-4-hydroxyphényl)butan-2-one et le 4-hydroxyacétophenone, et composition le contenant |
FR3090325B1 (fr) | 2018-12-21 | 2021-01-01 | Oreal | Composition du type gel/gel comprenant des particules de nitrure de bore et au moins un pigment encapsule |
EP3903762A4 (en) | 2018-12-28 | 2022-10-26 | Shiseido Company, Ltd. | Retinol-containing oil-in-water type emulsified cosmetic material |
JP7399620B2 (ja) | 2019-03-08 | 2023-12-18 | ロレアル | ケラチン繊維を処置するための組成物 |
CN113795435B (zh) | 2019-04-30 | 2023-04-25 | 莱雅公司 | 预先量取的粉状毛发漂白剂的可溶性包装 |
EP3994266A1 (en) | 2019-07-03 | 2022-05-11 | Aim Immunotech Inc. | Compositions and methods useful for ebola virus infection |
US11026874B2 (en) | 2019-07-31 | 2021-06-08 | L'oreal | Systems and methods for changing the color of hair |
FR3102358B1 (fr) | 2019-10-28 | 2022-05-27 | Oreal | Procede de preparation d’une composition colorante comprenant le melange d’au moins deux types de particules solides avec une composition aqueuse, et son utilisation |
FR3102359B1 (fr) | 2019-10-28 | 2021-11-26 | Oreal | Procede de preparation d’une composition colorante comprenant le melange de particules solides avec une composition aqueuse contenant de l’arginine, et son utilisation |
FR3102361B1 (fr) | 2019-10-28 | 2022-06-10 | Oreal | Particules solides colorantes enrobées comprenant au moins un colorant direct et/ou un précurseur de colorant d’oxydation |
FR3102360B1 (fr) | 2019-10-28 | 2022-06-10 | Oreal | Procede de preparation d’une composition colorante par melange de particules solides et une composition oxydante et une composition alcaline |
FR3102363B1 (fr) | 2019-10-28 | 2021-12-03 | Oreal | Procédé de traitement des fibres kératiniques au moyen d’une composition contenant de l’arginine et d’une composition oxydante |
FR3103678B1 (fr) | 2019-12-03 | 2022-07-01 | Oreal | Composition contenant du 4-(3-éthoxy-4-hydroxyphényl)butan-2-one, un conservateur et/ou antioxydant, un tensioactif, et un polymère, le procédé de traitement des matières kératiniques à partir de la composition |
FR3104978B1 (fr) | 2019-12-18 | 2023-11-03 | Oreal | Procédé de traitement cosmétique des fibres kératiniques comprenant l’application d’une composition prête à l’emploi obtenue par mélange de deux compositions |
JP2021095374A (ja) | 2019-12-18 | 2021-06-24 | ロレアル | 特定の成分の組み合わせを含む安定な組成物 |
WO2021124348A1 (en) | 2019-12-20 | 2021-06-24 | L'ORéAL S.A. | Multiple-compartment device comprising at least one internal frangible seal containing a keratin fibers dyeing composition |
FR3104997B1 (fr) | 2019-12-20 | 2021-11-26 | Oreal | Procédé de Préparation d’une Composition pour Colorer les Cheveux à partir d’une Composition Sous Forme de Poudre et d’une Composition Aqueuse |
WO2021151100A1 (en) | 2020-01-24 | 2021-07-29 | Aim Immunotech Inc. | Methods, compositions, and vaccines for treating a virus infection |
FR3111899A1 (fr) * | 2020-06-25 | 2021-12-31 | Snf Sa | Copolymère réticulé, procédé de préparation et pâte d’impression comprenant ledit copolymère |
FR3113599B1 (fr) | 2020-08-25 | 2024-04-26 | Oreal | Utilisation pour le traitement de la barbe d’une composition incluant une huile volatile sans silicone, une huile non volatile sans silicone, et de la silicone |
FR3115206B1 (fr) | 2020-10-16 | 2023-12-15 | Oreal | Composition pour modifier la couleur de fibres keratiniques |
US11839673B2 (en) | 2020-08-28 | 2023-12-12 | L'oreal | Compositions, kits, and methods for altering the color of keratinous fibers |
ES2969292T3 (es) | 2020-09-22 | 2024-05-17 | CHT Germany GmbH | Tinta de estampación libre de formaldehído para estampado en tejidos |
WO2022075204A1 (en) | 2020-10-07 | 2022-04-14 | L'oreal | Composition for keratin fibers |
FR3116199B1 (fr) | 2020-11-17 | 2023-12-08 | Oreal | Composition pour fibres kératineuses |
WO2022075203A1 (en) | 2020-10-07 | 2022-04-14 | L'oreal | Composition for keratin fibers |
FR3115987B1 (fr) | 2020-11-06 | 2023-05-19 | Oreal | Composition pour fibres kératineuses |
KR20230098331A (ko) | 2020-11-06 | 2023-07-03 | 로레알 | 케라틴 섬유용 조성물 |
FR3117017B1 (fr) | 2020-12-07 | 2023-04-21 | Oreal | Composition pour fibres kératiniques |
WO2022124385A1 (en) | 2020-12-07 | 2022-06-16 | L'oreal | Oil-in-water emulsion composition |
FR3118702B1 (fr) | 2021-01-12 | 2024-03-08 | Oreal | Composition d’émulsion huile-dans-eau |
FR3117032B1 (fr) | 2020-12-08 | 2023-10-27 | Oreal | Composition gélifiée comprenant de l’aérogel de silice et de l’éthylguar comme agents épaississants |
FR3117814B1 (fr) | 2020-12-17 | 2023-12-08 | Oreal | Composition comprenant une base de coloration d’oxydation particuliere, au moins une gomme de guar et au moins un corps gras. |
FR3118401B1 (fr) | 2020-12-30 | 2023-11-24 | Oreal | Dispositif avec applicateur amovible comprenant une composition contenant au moins un agent antichute, au moins un pigment et au moins un solvant |
FR3118420B1 (fr) | 2020-12-30 | 2023-11-24 | Oreal | Composition comprenant au moins un agent antichute, au moins un pigment, au moins un polymère filmogène hydrophobe, au moins un agent épaississant de phase aqueuse et au moins un solvant organique et de l’eau |
FR3119542B1 (fr) | 2021-02-08 | 2024-03-01 | Oreal | Procédé de traitement de fibres kératineuses comprenant l’application sur lesdites fibres kératineuses d’un substrat imprégné avec une composition particulière |
US20240166825A1 (en) | 2021-03-05 | 2024-05-23 | Lubrizol Advanced Materials, Inc. | Method For Wetting And Dispersion Of Acrylic Acid Polymers |
FR3120528A1 (fr) | 2021-03-10 | 2022-09-16 | L'oreal | Procédé pour retirer la couleur de fibres kératiniques capillaires préalablement colorées |
FR3120529A1 (fr) | 2021-03-10 | 2022-09-16 | L'oreal | Composition de coloration capillaire comprenant au moins un composé (poly)carbodiimide et au moins un composé comprenant au moins une fonction hydroxy |
FR3120527A1 (fr) | 2021-03-10 | 2022-09-16 | L'oreal | Procédé de coloration des fibres kératiniques capillaires comprenant l’application d’une composition comprenant au moins un composé (poly)carbodiimide et d’une composition comprenant au moins un polymère associatif et un composé particulier |
FR3120533A1 (fr) | 2021-03-10 | 2022-09-16 | L'oreal | Procédé pour retirer la couleur des fibres kératiniques capillaires ayant été préalablement colorées par une composition de coloration capillaire spécifique |
FR3120530B1 (fr) | 2021-03-10 | 2023-03-24 | Oreal | Procédé de coloration capillaire comprenant l’application d’une composition comprenant au moins un composé (poly)carbodiimide et d’une composition comprenant au moins un polymère associatif et un composé particulier |
FR3120532A1 (fr) | 2021-03-10 | 2022-09-16 | L'oreal | Composition de coloration capillaire comprenant au moins un composé (poly)carbodiimide et au moins un agent épaississant anionique non carboxylique |
FR3122335B1 (fr) | 2021-04-29 | 2024-04-19 | Oreal | Processus de traitement cosmétique des cheveux tressés avec une composition comprenant un polymère épaississant, un dérivé du menthol et un tensioactif non ionique particulier |
EP4313319A1 (en) | 2021-04-01 | 2024-02-07 | L'oreal | Process for the cosmetic treatment of braided hair with a composition comprising a thickening polymer, a derivative of menthol and a particular non-ionic surfactant |
FR3122088B1 (fr) | 2021-04-21 | 2024-06-14 | Oreal | Composition changeant de couleur sous forme de gel aqueux |
FR3122814B1 (fr) | 2021-05-12 | 2024-09-20 | Oreal | Dispositif pour la coloration d’oxydation des fibres kératiniques |
FR3125225B1 (fr) | 2021-07-19 | 2024-08-30 | Oreal | Composition comprenant une association particulière de tensioactifs et un polymère cationique |
FR3128120B1 (fr) | 2021-10-19 | 2024-11-08 | Oreal | compositions, nécessaires et procédés pour modifier la couleur de fibres kératineuses |
US11707420B2 (en) | 2021-08-31 | 2023-07-25 | L'oreal | Compositions, kits, and methods for altering the color of hair |
FR3131848B1 (fr) | 2022-01-19 | 2025-01-03 | Oreal | Composition lisse stable non collante |
WO2023113004A1 (en) | 2021-12-17 | 2023-06-22 | L'oreal | Non-sticky smooth stable composition |
FR3131843A1 (fr) | 2022-01-20 | 2023-07-21 | L'oreal | Composition de coloration d’oxydation comprenant un tensioactif anionique, un tensioactif amphotere choisi parmi une betaïne et un catalyseur metallique |
FR3137279A1 (fr) | 2022-06-29 | 2024-01-05 | L'oreal | Procédé d’éclaircissement des fibres kératiniques mettant en œuvre une composition comprenant un sel peroxygéné et un corps gras dans une teneur particulière et une composition comprenant du peroxyde d’hydrogène et un corps gras dans une teneur particulière. |
FR3137280A1 (fr) | 2022-06-29 | 2024-01-05 | L'oreal | Composition comprenant un sel peroxygéné, un polymère associatif, un polysaccharide non associatif et un hydrocarbure de point de fusion supérieur à 25°C. |
FR3137277A1 (fr) | 2022-06-29 | 2024-01-05 | L'oreal | Composition comprenant un sel peroxygéné, un hydrocarbure de point de fusion supérieur ou égal à 85°C et au moins 10% de corps gras. |
FR3137282A1 (fr) | 2022-06-29 | 2024-01-05 | L'oreal | Composition comprenant un sel peroxygéné, un hydrocarbure de point de fusion supérieur à 25°C et un composé de type aminoacide |
FR3137276A1 (fr) | 2022-06-29 | 2024-01-05 | L'oreal | Composition comprenant un sel peroxygéné, un corps gras dans une teneur particulière, un polymère associatif et un polysaccharide non associatif. |
FR3137283A1 (fr) | 2022-06-30 | 2024-01-05 | L'oreal | Utilisation d’une composition comprenant un carbonate d’alkyle ou d’alkylène pour retirer la couleur des fibres kératiniques capillaires préalablement colorées sans endommager les fibres kératiniques capillaires |
FR3137293A1 (fr) | 2022-06-30 | 2024-01-05 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’un composé (poly)carbodiimide, d’un composé ayant au moins un groupement acide carboxylique et d’un agent colorant |
FR3137285B1 (fr) | 2022-06-30 | 2024-07-12 | Oreal | Procédé pour retirer la couleur de fibres kératiniques capillaires préalablement colorées |
FR3137287A1 (fr) | 2022-06-30 | 2024-01-05 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’un composé (poly)carbodiimide, d’un composé comprenant au moins une fonction carboxylique, et d’un agent colorant comprenant de l’aluminium |
FR3137295A1 (fr) | 2022-06-30 | 2024-01-05 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’un composé (poly)carbodiimide, d’un composé ayant au moins un groupement acide carboxylique et d’un pigment ayant une granulométrie particulière |
FR3138314A1 (fr) | 2022-07-27 | 2024-02-02 | L'oreal | Composition cosmétique comprenant du 2,4-diaminopyrimidine-3-N-oxyde, de la piroctone olamine, de la caféine, et un extrait d’écorce d’Eperua falcata |
FR3138309A1 (fr) | 2022-07-27 | 2024-02-02 | L'oreal | Composition cosmétique comprenant du 2,4-diaminopyrimidine-3-N-oxyde, de la piroctone olamine, de la caféine, et au moins 0,5% en poids de composé hydroxylé particulier |
FR3145093A1 (fr) | 2023-01-19 | 2024-07-26 | L'oreal | Composition stable non collante et non grasse avec propriété de transformation de texture |
WO2024106520A1 (en) | 2022-11-18 | 2024-05-23 | L'oreal | Non-sticky stable composition with texture transformation property |
FR3143348A1 (fr) | 2022-12-16 | 2024-06-21 | L'oreal | Composition cosmétique comprenant du 2,4-diaminopyrimidine-3-N-oxyde , de la piroctone olamine, de la niacinamide, et au moins 1% en poids de composé hydroxylé particulier |
FR3143354A1 (fr) | 2022-12-16 | 2024-06-21 | L'oreal | Composition cosmétique comprenant de la niacinamide, un extrait de racine de gingembre, un polymère acrylique carboxylique, un actif antichute et/ou un actif antipelliculaire |
FR3143350A1 (fr) | 2022-12-16 | 2024-06-21 | L'oreal | Composition cosmétique comprenant de la piroctone olamine, au moins 1% de niacinamide et un extrait de racine de gingembre |
FR3143981B1 (fr) | 2022-12-21 | 2025-01-03 | Oreal | Procédé de coloration des cheveux comprenant l’application d’un traitement avec un alcool et d’une composition comprenant un composé (poly)carbodiimide spécifique et un agent colorant |
FR3143986B1 (fr) | 2022-12-21 | 2025-01-03 | Oreal | Procédé de coloration des cheveux comprenant l’application d’un composé (poly)carbodiimide et d’un agent colorant, l’application de vapeur d’eau et la mise en forme à une température particulière |
FR3143993A1 (fr) | 2022-12-21 | 2024-06-28 | L'oreal | Utilisation d’une composition de coloration des cheveux comprenant un composé (poly)carbodiimide, un composé ayant au moins une fonction carboxylique et un agent colorant pour augmenter le volume des cheveux |
FR3143989A1 (fr) | 2022-12-21 | 2024-06-28 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’un traitement au plasma froid et d’une composition comprenant un composé (poly)carbodiimide et un agent colorant |
FR3143983A1 (fr) | 2022-12-21 | 2024-06-28 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’une composition T particulière et l’application d’un composé (poly)carbodiimide et d’un agent colorant |
FR3143988A1 (fr) | 2022-12-21 | 2024-06-28 | L'oreal | Procédé de coloration des cheveux comprenant l’application d’une composition comprenant un composé (poly)carbodiimide, l’application de chaleur, et l’application d’une composition comprenant un composé (poly)carbodiimide |
US20240209226A1 (en) | 2022-12-23 | 2024-06-27 | Dupont Electronics, Inc. | Aqueous inkjet compositions including polymeric thickener |
FR3144513A1 (fr) | 2022-12-29 | 2024-07-05 | L'oreal | Composition comprenant au moins l’acide N,N-dicarboxyméthyl glutamique, au moins un colorant direct, et au moins un polymère associatif |
FR3144756A1 (fr) | 2023-01-09 | 2024-07-12 | L'oreal | Composition de soin du cuir chevelu comprenant un agent actif solide lipophile, un monoalcool et un épaississant hydrophile |
FR3145688A1 (fr) | 2023-02-15 | 2024-08-16 | L'oreal | Composition comprenant une émulsion de silicone particulière, un polymère vinylique amphotère ou cationique, des tensioactifs et un copolymère acrylique |
WO2024178538A1 (en) | 2023-02-27 | 2024-09-06 | L'oreal | Colorant composition for dyeing keratin fibers and dye kit containing the same |
FR3147099A1 (fr) | 2023-03-27 | 2024-10-04 | L'oreal | Composition à deux phases |
FR3147098A1 (fr) | 2023-03-28 | 2024-10-04 | L'oreal | Composition à deux phases |
FR3151975A1 (fr) | 2023-08-09 | 2025-02-14 | L'oreal | Poudre compacte avec une phase pulvérulente, un gélifiant hydrophile, un gel d’élastomère d’organopolysiloxane, un tensioactif non-ionique de HLB ≤ 8,0, un lysophospholipide et une huile non volatile |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2533376A (en) * | 1946-06-14 | 1950-12-12 | Libbey Owens Ford Glass Co | Copolymerization of maleic anhydride and allyl esters of long chain monocarboxylic acids |
US2798053A (en) * | 1952-09-03 | 1957-07-02 | Goodrich Co B F | Carboxylic polymers |
US2965617A (en) * | 1955-12-29 | 1960-12-20 | Shawinigan Resins Corp | Interpolymers of vinyl esters with long chain alkyl esters of maleic acid |
NL282672A (no) * | 1962-08-30 | |||
NL297274A (no) * | 1962-09-07 | |||
US3427382A (en) * | 1965-06-07 | 1969-02-11 | Procter & Gamble | Gel hairdressing composition |
US3697618A (en) * | 1967-03-16 | 1972-10-10 | Nat Starch Chem Corp | Pressure-sensitive adhesive |
DE1770371A1 (de) * | 1968-05-10 | 1971-10-21 | Basf Ag | Verfahren zur Herstellung von Mischpolymerisaten aethylenisch ungesaettigter Carbonsaeuren |
US3677991A (en) * | 1968-08-14 | 1972-07-18 | Dow Chemical Co | Anionic acrylate latexes that possess sensitivity to alkalinity |
US3551391A (en) * | 1968-12-09 | 1970-12-29 | Johnson & Johnson | Modified acrylate adhesive product |
US3788995A (en) * | 1971-06-03 | 1974-01-29 | Eastman Kodak Co | Liquid electrographic developers |
-
1974
- 1974-07-02 US US485125A patent/US3915921A/en not_active Expired - Lifetime
- 1974-07-02 CH CH657475A patent/CH606154A5/xx not_active IP Right Cessation
-
1975
- 1975-04-14 CA CA224,546A patent/CA1037643A/en not_active Expired
- 1975-04-18 ZA ZA00752489A patent/ZA752489B/xx unknown
- 1975-04-28 ES ES437098A patent/ES437098A1/es not_active Expired
- 1975-05-23 NL NLAANVRAGE7506067,A patent/NL180675C/xx not_active IP Right Cessation
- 1975-05-23 GB GB22450/75A patent/GB1514494A/en not_active Expired
- 1975-05-28 FR FR7516724A patent/FR2277109A1/fr active Granted
- 1975-05-30 JP JP50064442A patent/JPS6012361B2/ja not_active Expired
- 1975-06-19 NO NO752185A patent/NO752185L/no unknown
- 1975-06-25 DE DE19752528202 patent/DE2528202A1/de active Granted
- 1975-06-26 BE BE157703A patent/BE830668A/xx not_active IP Right Cessation
- 1975-06-27 SE SE7507402A patent/SE413773B/xx unknown
- 1975-07-01 BR BR5298/75A patent/BR7504140A/pt unknown
- 1975-07-01 DK DK298375A patent/DK298375A/da not_active Application Discontinuation
- 1975-07-01 IT IT68695/75A patent/IT1036409B/it active
- 1975-07-02 AT AT509275A patent/AT342007B/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
FR2277109B1 (no) | 1980-05-30 |
JPS6012361B2 (ja) | 1985-04-01 |
CH606154A5 (no) | 1978-11-15 |
BE830668A (fr) | 1975-10-16 |
GB1514494A (en) | 1978-06-14 |
ZA752489B (en) | 1976-03-31 |
NL7506067A (nl) | 1976-01-06 |
NL180675C (nl) | 1987-04-01 |
JPS516190A (no) | 1976-01-19 |
IT1036409B (it) | 1979-10-30 |
AU8022775A (en) | 1976-10-21 |
FR2277109A1 (fr) | 1976-01-30 |
SE413773B (sv) | 1980-06-23 |
CA1037643A (en) | 1978-08-29 |
DK298375A (da) | 1976-01-03 |
ATA509275A (de) | 1977-07-15 |
US3915921A (en) | 1975-10-28 |
BR7504140A (pt) | 1976-06-29 |
NL180675B (nl) | 1986-11-03 |
AT342007B (de) | 1978-03-10 |
DE2528202C2 (no) | 1989-09-14 |
ES437098A1 (es) | 1977-01-16 |
SE7507402L (sv) | 1976-01-05 |
DE2528202A1 (de) | 1976-01-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
NO752185L (no) | ||
US3940351A (en) | Polymerization of carboxylic acid monomers and alkyl acrylate esters in chlorofluoroethane | |
KR970007242B1 (ko) | 점도 부여 능력이 더 높고 투명성이 보다 더 우수한 폴리카르복실산 | |
AU676841B2 (en) | Easy to disperse polycarboxylic acid thickeners | |
US5844039A (en) | Polymers comprising reversible hydrophobic functionalities | |
JP3207228B2 (ja) | 新規n−アルキルアクリルアミド系コポリマー、その製法および用途 | |
CA2426128A1 (en) | Rheology modifying copolymer composition | |
JPS63502994A (ja) | 水性媒体中で増粘剤として使用できる新規な架橋カルボキシルコポリマ−およびその製法 | |
IE902222A1 (en) | Composite particle dispersion | |
TWI530506B (zh) | 吸水性樹脂的製造方法 | |
KR101778341B1 (ko) | 흡수성 수지의 제조 방법 | |
JPS5919127B2 (ja) | ビニルピロリドンポリマ−の分子量を増大させる方法 | |
JPH0317844B2 (no) | ||
KR100298515B1 (ko) | 카복실그룹을함유한가교중합체의제조방법 | |
EP1489114A1 (en) | Process for producing water-soluble carboxylated polymer | |
US6084032A (en) | Carboxylated polymer composition | |
US5849853A (en) | Preparation of water-insoluble polymers | |
KR970706312A (ko) | 공중합체 라텍스 및 그의 제조방법(copolymer latex and process for producing the same) | |
EP0343490A2 (en) | Process for producing crosslinked carboxyl group containing polymer | |
Candau et al. | Free‐radical polymerization in micellar media: Effect of microenvironment | |
EP0333499B1 (en) | Polymerisation processes and products obtained from these | |
AU4576699A (en) | New protective colloids in latices with improved film formation at low temperatures | |
JPS6386705A (ja) | 疎水性基を有するアクリルアミド−n−ビニルピロリドンポリマ− | |
JPS5813609A (ja) | 架橋型両性重合体の製造方法 | |
KR910012150A (ko) | 내산화성 중합체형 점도부여제 및 그의 제조방법 |