NL8000948A - Werkwijze voor het winnen van nikkel uit nikkeli- -ferrosulfidemateriaal. - Google Patents

Werkwijze voor het winnen van nikkel uit nikkeli- -ferrosulfidemateriaal. Download PDF

Info

Publication number: NL8000948A
Authority: NL; Netherlands
Prior art keywords: nickel; chloride; hydrogen; solution; sulfide
Prior art date: 1979-02-16

Application number

NL8000948A

Other languages

English (en)

Dutch (nl)

Original Assignee

Amax Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1979-02-16

Filing date

1980-02-15

Publication date

1980-08-19

1980-02-15 Application filed by Amax Inc filed Critical Amax Inc

1980-08-19 Publication of NL8000948A publication Critical patent/NL8000948A/nl

Links

PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 198
229910052759 nickel Inorganic materials 0.000 title claims description 95
238000000034 method Methods 0.000 title claims description 66
239000000463 material Substances 0.000 title claims description 40
FRWHRIRADSHXLL-UHFFFAOYSA-N iron(3+);nickel(2+);tetrasulfide Chemical compound [S-2].[S-2].[S-2].[S-2].[Fe+3].[Ni+2].[Ni+2].[Ni+2].[Ni+2] FRWHRIRADSHXLL-UHFFFAOYSA-N 0.000 title claims description 18
229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 106
QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 106
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 105
229910000041 hydrogen chloride Inorganic materials 0.000 claims description 79
IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 claims description 79
229910017052 cobalt Inorganic materials 0.000 claims description 67
239000010941 cobalt Substances 0.000 claims description 67
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 66
238000002386 leaching Methods 0.000 claims description 61
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 58
239000001257 hydrogen Substances 0.000 claims description 55
229910052739 hydrogen Inorganic materials 0.000 claims description 54
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 45
230000008569 process Effects 0.000 claims description 44
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 41
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 40
229910052751 metal Inorganic materials 0.000 claims description 40
239000002184 metal Substances 0.000 claims description 40
229910000037 hydrogen sulfide Inorganic materials 0.000 claims description 35
239000007789 gas Substances 0.000 claims description 33
239000007788 liquid Substances 0.000 claims description 32
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 31
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 30
229910000480 nickel oxide Inorganic materials 0.000 claims description 30
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims description 30
239000011593 sulfur Substances 0.000 claims description 27
229910052717 sulfur Inorganic materials 0.000 claims description 27
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 26
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 25
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 25
229910052802 copper Inorganic materials 0.000 claims description 25
239000010949 copper Substances 0.000 claims description 25
STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 24
229910052725 zinc Inorganic materials 0.000 claims description 24
239000011701 zinc Substances 0.000 claims description 24
150000002739 metals Chemical class 0.000 claims description 22
239000002244 precipitate Substances 0.000 claims description 22
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
238000006460 hydrolysis reaction Methods 0.000 claims description 20
229910052742 iron Inorganic materials 0.000 claims description 20
230000007062 hydrolysis Effects 0.000 claims description 19
150000001412 amines Chemical class 0.000 claims description 16
-1 anionic chloride complexes Chemical class 0.000 claims description 16
VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 15
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 15
JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 15
239000003960 organic solvent Substances 0.000 claims description 15
238000001556 precipitation Methods 0.000 claims description 15
238000000605 extraction Methods 0.000 claims description 14
239000002253 acid Substances 0.000 claims description 13
150000003856 quaternary ammonium compounds Chemical class 0.000 claims description 13
WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical compound [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 claims description 13
239000006096 absorbing agent Substances 0.000 claims description 11
239000000203 mixture Substances 0.000 claims description 11
239000000047 product Substances 0.000 claims description 11
CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 9
239000012298 atmosphere Substances 0.000 claims description 8
150000004763 sulfides Chemical class 0.000 claims description 8
239000012141 concentrate Substances 0.000 claims description 7
238000001704 evaporation Methods 0.000 claims description 7
239000002245 particle Substances 0.000 claims description 7
230000008020 evaporation Effects 0.000 claims description 6
238000010438 heat treatment Methods 0.000 claims description 6
MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 5
YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 claims description 5
239000002904 solvent Substances 0.000 claims description 5
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
150000002903 organophosphorus compounds Chemical class 0.000 claims description 4
230000015572 biosynthetic process Effects 0.000 claims description 3
239000002250 absorbent Substances 0.000 claims description 2
230000002745 absorbent Effects 0.000 claims description 2
150000001875 compounds Chemical class 0.000 claims description 2
238000000151 deposition Methods 0.000 claims description 2
230000003134 recirculating effect Effects 0.000 claims description 2
BWFPGXWASODCHM-UHFFFAOYSA-N copper monosulfide Chemical group [Cu]=S BWFPGXWASODCHM-UHFFFAOYSA-N 0.000 claims 2
230000002378 acidificating effect Effects 0.000 claims 1
230000001376 precipitating effect Effects 0.000 claims 1
239000007787 solid Substances 0.000 description 21
229940093635 tributyl phosphate Drugs 0.000 description 20
238000011282 treatment Methods 0.000 description 18
238000000926 separation method Methods 0.000 description 12
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 11
239000000460 chlorine Substances 0.000 description 11
229910052801 chlorine Inorganic materials 0.000 description 11
238000011084 recovery Methods 0.000 description 11
239000012535 impurity Substances 0.000 description 10
230000008018 melting Effects 0.000 description 10
238000002844 melting Methods 0.000 description 10
230000009467 reduction Effects 0.000 description 10
239000002002 slurry Substances 0.000 description 10
238000001816 cooling Methods 0.000 description 9
238000004090 dissolution Methods 0.000 description 9
230000008901 benefit Effects 0.000 description 8
239000000446 fuel Substances 0.000 description 8
150000002431 hydrogen Chemical class 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 6
239000000284 extract Substances 0.000 description 6
238000000746 purification Methods 0.000 description 6
125000000217 alkyl group Chemical group 0.000 description 5
238000002485 combustion reaction Methods 0.000 description 5
229910001510 metal chloride Inorganic materials 0.000 description 5
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
150000001805 chlorine compounds Chemical class 0.000 description 4
238000002425 crystallisation Methods 0.000 description 4
230000008025 crystallization Effects 0.000 description 4
238000005868 electrolysis reaction Methods 0.000 description 4
239000011368 organic material Substances 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
230000004913 activation Effects 0.000 description 3
238000009835 boiling Methods 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 3
OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 3
238000001035 drying Methods 0.000 description 3
239000008187 granular material Substances 0.000 description 3
238000006386 neutralization reaction Methods 0.000 description 3
230000003647 oxidation Effects 0.000 description 3
238000007254 oxidation reaction Methods 0.000 description 3
239000012716 precipitator Substances 0.000 description 3
238000010791 quenching Methods 0.000 description 3
KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
239000004215 Carbon black (E152) Substances 0.000 description 2
ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 2
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
QXZUUHYBWMWJHK-UHFFFAOYSA-N [Co].[Ni] Chemical compound [Co].[Ni] QXZUUHYBWMWJHK-UHFFFAOYSA-N 0.000 description 2
238000010521 absorption reaction Methods 0.000 description 2
150000001298 alcohols Chemical class 0.000 description 2
239000000956 alloy Substances 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
238000013459 approach Methods 0.000 description 2
239000006227 byproduct Substances 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
239000013078 crystal Substances 0.000 description 2
CYZASAMUYFRGTI-UHFFFAOYSA-N heptadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCOP(O)(O)=O CYZASAMUYFRGTI-UHFFFAOYSA-N 0.000 description 2
229930195733 hydrocarbon Natural products 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000003840 hydrochlorides Chemical class 0.000 description 2
239000000543 intermediate Substances 0.000 description 2
239000003456 ion exchange resin Substances 0.000 description 2
229920003303 ion-exchange polymer Polymers 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
238000012986 modification Methods 0.000 description 2
230000004048 modification Effects 0.000 description 2
239000012452 mother liquor Substances 0.000 description 2
230000020477 pH reduction Effects 0.000 description 2
238000002360 preparation method Methods 0.000 description 2
239000007858 starting material Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
150000003512 tertiary amines Chemical class 0.000 description 2
ZMBHCYHQLYEYDV-UHFFFAOYSA-N trioctylphosphine oxide Chemical compound CCCCCCCCP(=O)(CCCCCCCC)CCCCCCCC ZMBHCYHQLYEYDV-UHFFFAOYSA-N 0.000 description 2
239000012808 vapor phase Substances 0.000 description 2
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
GODZNYBQGNSJJN-UHFFFAOYSA-N 1-aminoethane-1,2-diol Chemical compound NC(O)CO GODZNYBQGNSJJN-UHFFFAOYSA-N 0.000 description 1
SWODTSOUHKLCPI-UHFFFAOYSA-N 2-[ethyl-(2-hydroxy-2-phenylethyl)amino]-1-phenylethanol Chemical compound C=1C=CC=CC=1C(O)CN(CC)CC(O)C1=CC=CC=C1 SWODTSOUHKLCPI-UHFFFAOYSA-N 0.000 description 1
BZUDVELGTZDOIG-UHFFFAOYSA-N 2-ethyl-n,n-bis(2-ethylhexyl)hexan-1-amine Chemical compound CCCCC(CC)CN(CC(CC)CCCC)CC(CC)CCCC BZUDVELGTZDOIG-UHFFFAOYSA-N 0.000 description 1
QCQCHGYLTSGIGX-GHXANHINSA-N 4-[[(3ar,5ar,5br,7ar,9s,11ar,11br,13as)-5a,5b,8,8,11a-pentamethyl-3a-[(5-methylpyridine-3-carbonyl)amino]-2-oxo-1-propan-2-yl-4,5,6,7,7a,9,10,11,11b,12,13,13a-dodecahydro-3h-cyclopenta[a]chrysen-9-yl]oxy]-2,2-dimethyl-4-oxobutanoic acid Chemical compound N([C@@]12CC[C@@]3(C)[C@]4(C)CC[C@H]5C(C)(C)[C@@H](OC(=O)CC(C)(C)C(O)=O)CC[C@]5(C)[C@H]4CC[C@@H]3C1=C(C(C2)=O)C(C)C)C(=O)C1=CN=CC(C)=C1 QCQCHGYLTSGIGX-GHXANHINSA-N 0.000 description 1
YKGBNAGNNUEZQC-UHFFFAOYSA-N 6-methyl-n,n-bis(6-methylheptyl)heptan-1-amine Chemical compound CC(C)CCCCCN(CCCCCC(C)C)CCCCCC(C)C YKGBNAGNNUEZQC-UHFFFAOYSA-N 0.000 description 1
JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical class C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000003213 activating effect Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000019270 ammonium chloride Nutrition 0.000 description 1
239000003957 anion exchange resin Substances 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
239000011324 bead Substances 0.000 description 1
230000005587 bubbling Effects 0.000 description 1
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000003841 chloride salts Chemical class 0.000 description 1
VEXZGXHMUGYJMC-IGMARMGPSA-N chlorine-35 Chemical compound [35ClH] VEXZGXHMUGYJMC-IGMARMGPSA-N 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical class [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
229940125898 compound 5 Drugs 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
239000002826 coolant Substances 0.000 description 1
229910001431 copper ion Inorganic materials 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001627 detrimental effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
239000010771 distillate fuel oil Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
239000003502 gasoline Substances 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000003317 industrial substance Substances 0.000 description 1
238000009434 installation Methods 0.000 description 1
239000003350 kerosene Substances 0.000 description 1
229910001710 laterite Inorganic materials 0.000 description 1
239000011504 laterite Substances 0.000 description 1
BXNFVPMHMPQBRO-UHFFFAOYSA-N magnesium nickel(2+) oxygen(2-) Chemical compound [O--].[O--].[Mg++].[Ni++] BXNFVPMHMPQBRO-UHFFFAOYSA-N 0.000 description 1
XKBGEWXEAPTVCK-UHFFFAOYSA-M methyltrioctylammonium chloride Chemical compound [Cl-].CCCCCCCC[N+](C)(CCCCCCCC)CCCCCCCC XKBGEWXEAPTVCK-UHFFFAOYSA-M 0.000 description 1
MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical class CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000012454 non-polar solvent Substances 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical class P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 description 1
239000012071 phase Substances 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
235000011007 phosphoric acid Nutrition 0.000 description 1
150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
150000003016 phosphoric acids Chemical group 0.000 description 1
239000003495 polar organic solvent Substances 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
230000000171 quenching effect Effects 0.000 description 1
239000000376 reactant Substances 0.000 description 1
230000001172 regenerating effect Effects 0.000 description 1
239000011347 resin Substances 0.000 description 1
229920005989 resin Polymers 0.000 description 1
239000011435 rock Substances 0.000 description 1
238000012216 screening Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000002912 waste gas Substances 0.000 description 1
239000002699 waste material Substances 0.000 description 1
239000008096 xylene Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/02—Obtaining nickel or cobalt by dry processes
- C22B23/025—Obtaining nickel or cobalt by dry processes with formation of a matte or by matte refining or converting into nickel or cobalt, e.g. by the Oxford process
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/0423—Halogenated acids or salts thereof
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0407—Leaching processes
- C22B23/0415—Leaching processes with acids or salt solutions except ammonium salts solutions
- C22B23/043—Sulfurated acids or salts thereof
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B23/00—Obtaining nickel or cobalt
- C22B23/04—Obtaining nickel or cobalt by wet processes
- C22B23/0453—Treatment or purification of solutions, e.g. obtained by leaching
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/282—Aliphatic amines
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/28—Amines
- C22B3/288—Quaternary ammonium
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/38—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds containing phosphorus
- C22B3/384—Pentavalent phosphorus oxyacids, esters thereof
- C22B3/3846—Phosphoric acid, e.g. (O)P(OH)3
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling

Landscapes

Engineering & Computer Science (AREA)
Chemical & Material Sciences (AREA)
Mechanical Engineering (AREA)
Manufacturing & Machinery (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Geochemistry & Mineralogy (AREA)
Geology (AREA)
General Life Sciences & Earth Sciences (AREA)
Environmental & Geological Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Manufacture And Refinement Of Metals (AREA)
Inorganic Compounds Of Heavy Metals (AREA)

NL8000948A 1979-02-16 1980-02-15 Werkwijze voor het winnen van nikkel uit nikkeli- -ferrosulfidemateriaal. NL8000948A (nl)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US1277479		1979-02-16
US06/012,774 US4214901A (en)	1979-02-16	1979-02-16	Hydrometallurgical refining of nickeliferous sulfides

Publications (1)

Publication Number	Publication Date
NL8000948A true NL8000948A (nl)	1980-08-19

Family

ID=21756620

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NL8000948A NL8000948A (nl)	1979-02-16	1980-02-15	Werkwijze voor het winnen van nikkel uit nikkeli- -ferrosulfidemateriaal.

Country Status (10)

Country	Link
US (1)	US4214901A (de)
JP (1)	JPS55113847A (de)
AU (1)	AU517712B2 (de)
BE (1)	BE881735A (de)
BR (1)	BR8000855A (de)
CA (1)	CA1143573A (de)
DE (1)	DE3005398A1 (de)
FR (1)	FR2449131A1 (de)
GB (1)	GB2042487B (de)
NL (1)	NL8000948A (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4561887A (en) *	1982-07-22	1985-12-31	Sociedad Minera Pudahuel Ltda., C.P.A.	Process for recovering metals from solution through solvent extraction and pyrometallurgical reduction
US4726937A (en) *	1986-07-23	1988-02-23	Texaco Inc.	Recovery of nickel chloride and sulfur from waste products
US4861565A (en) *	1987-01-27	1989-08-29	The Hall Chemical Company	Method of separately recovering metal values of petroleum refining catalyst
US5399322A (en) *	1992-10-15	1995-03-21	Hazen Research, Inc.	Selective recovery of dissolved metals and preparation of metal salt products
CA2137124C (en) *	1994-12-01	1999-03-16	Tao Xue	Pressure leaching of nickel and cobalt sulphides with chlorine under controlled redox potential conditions
US5752206A (en) *	1996-04-04	1998-05-12	Frink; Neal A.	In-situ decontamination and recovery of metal from process equipment
RU2158777C1 (ru) *	2000-02-28	2000-11-10	Ильенок Андрей Алексеевич	Способ переработки кобальтового концентрата
US6692719B1 (en)	2000-11-08	2004-02-17	Hatch Ltd.	Process for regeneration of acid halide solutions
US6391089B1 (en) *	2000-11-29	2002-05-21	Walter Curlook	Acid leaching of nickel laterite ores for the extraction of their nickel and cobalt values
CA2478516C (en) *	2003-09-30	2007-12-11	Jaguar Nickel Inc.	A process for the recovery of value metals from base metal sulfide ores
WO2006043154A1 (en) *	2004-10-21	2006-04-27	Anglo Operations Limited	Leaching process in the presence of hydrochloric acid for the recovery of a value metal from an ora
CN101090983B (zh) *	2004-10-21	2011-08-10	安格洛操作有限公司	盐酸存在下用于从矿石回收有价值金属的浸取工艺
ES2458866T3 (es) *	2005-01-18	2014-05-07	Idaho Research Foundation, Inc.	Método y sistema para la recuperación de metal de materiales que contienen metal
US20090056502A1 (en) *	2007-08-29	2009-03-05	Vale Inco Limited	Hydrometallurgical process for recovery of nickel and cobalt
JP5125371B2 (ja) *	2007-10-02	2013-01-23	住友金属鉱山株式会社	アミン系抽出剤のスクラビング方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US940292A (en) *	1909-02-19	1909-11-16	Horace L Wells	Method of separating copper, nickel, and other metals from copper-nickel matte.
US1067698A (en) *	1911-11-01	1913-07-15	Tom Cobb King	Method of electrolytically recovering nickel.
FR850651A (fr) *	1938-03-10	1939-12-22	Ig Farbenindustrie Ag	Procédé pour traiter la matte de nickel
BE495631A (de) *	1949-05-13
US2753259A (en) *	1950-11-18	1956-07-03	Basf Ag	Processing of nickel-copper mattes
US3085054A (en) *	1960-02-25	1963-04-09	Falconbridge Nickel Mines Ltd	Recovery of nickel
FR1284737A (fr) *	1961-02-15	1962-02-16	Falconbridge Nickel Mines Ltd	Récupération du nickel
US3642441A (en) *	1967-09-14	1972-02-15	Falconbridge Nickel Mines Ltd	Treatment of metal chlorides in fluidized beds
FI47380C (fi) *	1970-04-10	1973-11-12	Outokumpu Oy	Menetelmä rautaköyhän nikkelisulfidikiven valmistamiseksi nikkelin sul fidisista rikasteista näiden suspensiosulatuksessa.
FR2138332B1 (de) *	1971-05-24	1975-07-04	Nickel Le
US3761566A (en) *	1971-09-13	1973-09-25	American Metal Climax Inc	Leaching of nickel lateritic ores with waste iron sulfate solutions
JPS544323B2 (de) *	1973-09-21	1979-03-06
ZA745691B (en) *	1974-09-06	1976-01-28	Atok Platinum Mines Ltd	Improvements in to relating to the leaching of copper-nickel concentrates
FR2295128A1 (fr) *	1974-12-18	1976-07-16	Commissariat Energie Atomique	Procede d'extraction d'elements metalliques des nodules sous-marins
FR2297925A1 (fr) *	1975-01-16	1976-08-13	Nickel Le	Procede hydrometallurgique pour le traitement de mattes de nickel
DE2543310C2 (de) *	1975-09-27	1982-04-29	Gesellschaft für Strahlen- und Umweltforschung mbH, 8000 München	Einrichtung zum Zählen und Klassifizieren von in einer Flüssigkeit suspendierten Teilchen
US4044096A (en) *	1975-12-11	1977-08-23	Amax Inc.	Sulfuric acid leaching of nickeliferous laterite
CA1091036A (en) *	1977-05-13	1980-12-09	Victor A. Ettel	Roast-reductive leach process for copper recovery
US4098870A (en) *	1977-07-22	1978-07-04	Amax Inc.	Acid leaching of nickeliferous oxide ores with minimized scaling
US4110400A (en) *	1977-08-01	1978-08-29	Amax Inc.	Selective precipitation of nickel and cobalt sulfides from acidic sulfate solution
US4093526A (en) *	1977-09-08	1978-06-06	Amax Inc.	Hydrometallurgical leaching and refining of nickel-copper concentrates, and electrowinning of copper

1979
- 1979-02-16 US US06/012,774 patent/US4214901A/en not_active Expired - Lifetime
1980
- 1980-01-30 GB GB8003087A patent/GB2042487B/en not_active Expired
- 1980-02-04 CA CA000345002A patent/CA1143573A/en not_active Expired
- 1980-02-06 AU AU55274/80A patent/AU517712B2/en not_active Ceased
- 1980-02-13 BR BR8000855A patent/BR8000855A/pt unknown
- 1980-02-13 DE DE19803005398 patent/DE3005398A1/de not_active Ceased
- 1980-02-14 FR FR8003317A patent/FR2449131A1/fr active Granted
- 1980-02-14 JP JP1719080A patent/JPS55113847A/ja active Pending
- 1980-02-15 NL NL8000948A patent/NL8000948A/nl not_active Application Discontinuation
- 1980-02-15 BE BE1/9723A patent/BE881735A/fr not_active IP Right Cessation

Also Published As

Publication number	Publication date
BR8000855A (pt)	1980-10-29
AU5527480A (en)	1980-09-18
JPS55113847A (en)	1980-09-02
US4214901A (en)	1980-07-29
GB2042487A (en)	1980-09-24
BE881735A (fr)	1980-08-18
CA1143573A (en)	1983-03-29
GB2042487B (en)	1983-03-23
FR2449131A1 (fr)	1980-09-12
FR2449131B1 (de)	1983-05-06
DE3005398A1 (de)	1980-08-21
AU517712B2 (en)	1981-08-20

Publication	Publication Date	Title
Binnemans et al.	2020	Hydrometallurgical processes for the recovery of metals from steel industry by-products: a critical review
US8961649B2 (en)	2015-02-24	System and method for extracting base metal values from oxide ores
JP6025868B2 (ja)	2016-11-16	赤泥を処理するプロセス
NL8000948A (nl)	1980-08-19	Werkwijze voor het winnen van nikkel uit nikkeli- -ferrosulfidemateriaal.
US5482534A (en)	1996-01-09	Extraction or recovery of non-ferrous metal values from arsenic-containing materials
US6699446B2 (en)	2004-03-02	Methods for separation of titanium from ore
CA2752254C (en)	2017-02-14	Magnesium recycling and sulphur recovery in leaching of lateritic nickel ores
EA009841B1 (ru)	2008-04-28	Способ восстановления металлов из материала, содержащего оксиды неблагородных металлов
CA2788384A1 (en)	2011-08-11	Process for the recovery of titanium dioxide and value metals by reducing the concentration of hydrochloric acid in leach solution and system for same
EP1727916B1 (de)	2014-11-12	Rückgewinnung von metallen aus oxidierten metallhaltigen materialien
US4150976A (en)	1979-04-24	Method for the recovery of metallic copper
WO2008080209A1 (en)	2008-07-10	Process for recovery of nickel and cobalt from an ion-exchange resin eluate and product
CA2394658C (en)	2010-10-26	Process for the continuous production of high purity electrolytic zinc or zinc compounds from zinc primary or secondary raw materials
EP1361296B1 (de)	2006-07-26	Verfahren zur elektrolytischen herstellung von ultrareinem zink oder ultrareinen zinkverbindungen aus primären und sekundären zinkrohstoffen
AU2013211472B2 (en)	2016-03-17	System and method for extracting base metal values from oxide ores
SE452169B (sv)	1987-11-16	Forfarande for utvinning av metallverden ur jerninnehallande material
EP2604712B1 (de)	2017-10-11	Verfahren zur behandlung von flüssigkeitsausflüssen und zur rückgewinnung von metallen
EP2387624B1 (de)	2017-04-12	Rückgewinnung von metallen aus metallurgischen rückstanden durch chloridierung
FI56553C (fi)	1980-02-11	Foerfarande foer utfaellning av ickejaernmetaller fraon en vattenhaltig sur mineralloesning
US4030917A (en)	1977-06-21	Hydrometallurgical processing of metal sulfides
US3980752A (en)	1976-09-14	Precipitation of nickel, cobalt, lead sulphides in presence of iron oxides or hydroxides
US1737140A (en)	1929-11-26	Process for the recovery of tin and its associated metals from alloys, mechanical mixtures, and ores
JPH021093B2 (de)	1990-01-10
KR930006088B1 (ko)	1993-07-07	금속황화물로부터 금속과 황원소를 습식야금학적으로 회수하는 방법
COPPER	2017	WITH WATER

Legal Events

Date	Code	Title
1980-09-10	A1A	A request for search or an international-type search has been filed
1982-07-01	BB	A search report has been drawn up
1984-07-02	BC	A request for examination has been filed
1985-01-01	A85	Still pending on 85-01-01
1988-10-03	BV	The patent application has lapsed