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MY115846A - Esterification of (meth) acrylic acid with an alkanol - Google Patents

Esterification of (meth) acrylic acid with an alkanol

Info

Publication number
MY115846A
MY115846A MYPI96003665A MYPI19963665A MY115846A MY 115846 A MY115846 A MY 115846A MY PI96003665 A MYPI96003665 A MY PI96003665A MY PI19963665 A MYPI19963665 A MY PI19963665A MY 115846 A MY115846 A MY 115846A
Authority
MY
Malaysia
Prior art keywords
acid
bottom product
meth
alkanol
acrylic acid
Prior art date
Application number
MYPI96003665A
Inventor
Gerhard Nestler Dr
Heinrich Aichinger Dr
Holger Herbst Dr
Matthias Geisendorfer Dr
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Ag filed Critical Basf Ag
Publication of MY115846A publication Critical patent/MY115846A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/60—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/003—Esters of saturated alcohols having the esterified hydroxy group bound to an acyclic carbon atom

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

IN A PROCESS FOR ESTERIFYING (METH)ACRYLIC ACID WITH AN ALKANOL IN THE PRESENCE OF AN ACIDIC ESTRIFICATION CATALYST, IN WHICH UNCONVERTED STARTING COMPOUNDS AND THE (METH)ACRYLATES TO BE FORMED ARE SEPARATED OFF BY DISTILLATION AND AN OXYESTER-CONTAINING BOTTOM PRODUCT IS FORMED, THE BOTTOM PRODUCT IS SEPARATED OFF AND IS HEATED IN THE PRESENCE OF AN ACID TO 150-250?C AND THE PRESSURE IS ADJUSTED SO THAT THE CLEAVAGE PRODUCTS FORMED UNDER THE ABOVEMENTIONED CONDITIONS FROM THE OXYESTERS CONTAINED IN THE BOTTOM PRODUCT EVAPORATE DIRECTLY. THE PROCESS CAN BE CARRIED OUT IN THE PRESENCE OF MOLECULAR OXYGEN. MINERAL ACIDS, FOR EXAMPLE SULFURIC ACID OR PHOSPHORIC ACID AND/OR ALKANESULFONIC OR ARYLSULFONC ACIDS, FOR EXAMPLE METHANESULFONIC ACID OR P-TOLUENESULFONIC ACID, CAN BE ADDED TO THE BOTTOM PRODUCT.
MYPI96003665A 1995-09-28 1996-09-04 Esterification of (meth) acrylic acid with an alkanol MY115846A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19536191A DE19536191A1 (en) 1995-09-28 1995-09-28 Process for the esterification of (meth) acrylic acid with an alkanol

Publications (1)

Publication Number Publication Date
MY115846A true MY115846A (en) 2003-09-30

Family

ID=7773495

Family Applications (1)

Application Number Title Priority Date Filing Date
MYPI96003665A MY115846A (en) 1995-09-28 1996-09-04 Esterification of (meth) acrylic acid with an alkanol

Country Status (12)

Country Link
US (1) US5910603A (en)
EP (1) EP0767163B1 (en)
JP (2) JPH09110791A (en)
KR (1) KR100441360B1 (en)
CN (1) CN1084325C (en)
CA (1) CA2184197A1 (en)
CZ (1) CZ270196A3 (en)
DE (2) DE19536191A1 (en)
MX (1) MX9604041A (en)
MY (1) MY115846A (en)
SG (1) SG83651A1 (en)
TW (1) TW472039B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19851984A1 (en) * 1998-11-11 2000-05-18 Basf Ag Process for the esterification of (meth) acrylic acid with an alkanol
US6498272B1 (en) 1999-03-06 2002-12-24 Basf Aktiengesellschaft Method for producing acrylic acid
DE19922722A1 (en) 1999-05-18 2000-11-23 Basf Ag Process for the preparation of (meth) acrylic acid esters
DE10007213A1 (en) * 2000-02-17 2001-08-23 Basf Ag Process for the preparation of esters of alpha, beta-unsaturated carboxylic acids
WO2003045892A1 (en) * 2001-11-28 2003-06-05 Mitsubishi Chemical Corporation Process for producing (meth)acrylic acid compound
CN100494155C (en) 2001-12-04 2009-06-03 三菱化学株式会社 Process for producing (meth) acrylic acids
US7569721B2 (en) * 2003-02-28 2009-08-04 Union Carbide Chemicals And Plastics Technology Corporation Process for conducting equilibrium-limited reactions
WO2005007609A1 (en) 2003-07-11 2005-01-27 Basf Aktiengesellschaft Thermal separation method for separating at least one (meth)acrylmonomer-enriched material flow
KR100714631B1 (en) * 2004-04-29 2007-05-07 주식회사 엘지화학 Recovery method of acrylic acid
CN102105432B (en) * 2008-11-19 2013-10-16 Lg化学株式会社 Method for recovering (meth)acrylic acid ester
KR101346370B1 (en) 2009-07-23 2013-12-31 주식회사 엘지화학 Effective preparation method for (meth)acrylate
KR101344004B1 (en) 2010-04-08 2013-12-20 주식회사 엘지화학 Process for decomposing and collecting residues from the manufacture of (meth)acrylic acid ester
JP6036400B2 (en) * 2013-02-26 2016-11-30 三菱化学株式会社 Method for producing (meth) acrylic acid ester
CN109942424A (en) * 2019-04-19 2019-06-28 泰兴金江化学工业有限公司 A kind of n-butyl acrylate heavy constituent recovery process and device
EP4015498B1 (en) 2020-12-18 2024-04-24 Basf Se Method for the continuous production of acrylic acid n-butylester

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB923595A (en) * 1960-12-03 1963-04-18 Distillers Co Yeast Ltd Improvements in and relating to the production of acrylic esters
DE1949434C3 (en) * 1969-09-30 1973-09-20 Sumitomo Chemical Co., Ltd., Osaka (Japan) Process for the production of methyl methacrylate
US3868410A (en) * 1972-08-03 1975-02-25 Celanese Corp Conversion of oligomeric acrylates to acrylate monomers
JPS5762229A (en) * 1980-10-02 1982-04-15 Mitsubishi Petrochem Co Ltd Recovery of useful component from heavy substance obtained as by-product in preparation of acrylic ester
CN1058390A (en) * 1990-07-13 1992-02-05 梁效成 The treatment process of waste liquid containing alkoxyl propionic ester
JPH0768168B2 (en) * 1991-07-12 1995-07-26 東亞合成株式会社 Decomposition method of Michael adduct of acrylic acid ester
CN1026104C (en) * 1992-03-17 1994-10-05 侯玉里 Waste acrylate oil regeneration process
JP2943523B2 (en) * 1992-08-12 1999-08-30 東亞合成株式会社 Method for producing useful compound from Michael adduct of acrylic acid ester
DE19547485A1 (en) * 1995-12-19 1996-05-09 Basf Ag Methacrylic] acid esterification with alkanol for alkyl methacrylate]

Also Published As

Publication number Publication date
CA2184197A1 (en) 1997-03-29
JP4384185B2 (en) 2009-12-16
JP2007145857A (en) 2007-06-14
DE19536191A1 (en) 1997-04-03
KR100441360B1 (en) 2004-10-08
CN1084325C (en) 2002-05-08
EP0767163A1 (en) 1997-04-09
KR970015556A (en) 1997-04-28
SG83651A1 (en) 2001-10-16
US5910603A (en) 1999-06-08
TW472039B (en) 2002-01-11
CZ270196A3 (en) 1997-06-11
EP0767163B1 (en) 2001-01-10
DE59606299D1 (en) 2001-02-15
CN1150586A (en) 1997-05-28
MX9604041A (en) 1997-03-29
JPH09110791A (en) 1997-04-28

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