MX9505240A - Proceso de polimerizacion en estado solido para el poli(etilen-naftalato) espumado o alveolar. - Google Patents
Proceso de polimerizacion en estado solido para el poli(etilen-naftalato) espumado o alveolar.Info
- Publication number
- MX9505240A MX9505240A MX9505240A MX9505240A MX9505240A MX 9505240 A MX9505240 A MX 9505240A MX 9505240 A MX9505240 A MX 9505240A MX 9505240 A MX9505240 A MX 9505240A MX 9505240 A MX9505240 A MX 9505240A
- Authority
- MX
- Mexico
- Prior art keywords
- degree
- solid state
- pen polymer
- pen
- doamed
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/30—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by mixing gases into liquid compositions or plastisols, e.g. frothing with air
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
- C08G63/187—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings
- C08G63/189—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings containing a naphthalene ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Esta invencion comprende un proceso para la preparacion de un polímero o copolímero de poli(etilen-naftalato), (PEN), polimerizado en estado solido, caracterizado porque comprende: (1) la preparacion de un prepolímero fundido, con una viscosidad intrínseca de 0.25 dl/g a 0.50 dl/g; (2) la dispersion de un gas inerte, dentro del prepolímero fundido, para formar un prepolímero PEN espumado, con una fraccion vacía de 0.10 a 0.50; (3) la transformacion del prepolímero PEN espumado, en gránulos; (4) a una temperatura de 80 degree C a 140 degree C,; (5) la cristalizacion del prepolímero PEN desvolatilizado, a una temperatura de alrededor de 150 degree C a 260 degree C; y (6) la polimerizacion en estado solido del prepolímero PEN cristalizado, a una temperatura de 235 degree C hasta cerca de 265 degree C, para formar un polímero o copolímero PEN, polimerizado en estado solido.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/357,619 US5449701A (en) | 1994-12-15 | 1994-12-15 | Solid state polymerization process for foamed poly(ethylene naphthalate) |
Publications (1)
Publication Number | Publication Date |
---|---|
MX9505240A true MX9505240A (es) | 1997-01-31 |
Family
ID=23406366
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX9505240A MX9505240A (es) | 1994-12-15 | 1995-12-13 | Proceso de polimerizacion en estado solido para el poli(etilen-naftalato) espumado o alveolar. |
Country Status (20)
Country | Link |
---|---|
US (2) | US5449701A (es) |
EP (1) | EP0717062B1 (es) |
JP (1) | JP3477471B2 (es) |
KR (1) | KR960022679A (es) |
CN (1) | CN1076026C (es) |
AR (1) | AR000321A1 (es) |
AT (1) | ATE206726T1 (es) |
BR (1) | BR9505811A (es) |
CA (1) | CA2165149A1 (es) |
CZ (1) | CZ290438B6 (es) |
DE (1) | DE69523122T2 (es) |
DK (1) | DK0717062T3 (es) |
ES (1) | ES2165406T3 (es) |
HU (1) | HU214043B (es) |
MX (1) | MX9505240A (es) |
MY (1) | MY116003A (es) |
NO (1) | NO307838B1 (es) |
PT (1) | PT717062E (es) |
SG (1) | SG34331A1 (es) |
ZA (1) | ZA9510591B (es) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5670606A (en) * | 1996-01-05 | 1997-09-23 | E. I. Du Pont De Nemours And Compant | Crystalline form of poly(ethylene 2,6-naphthalate) and a method for its production |
US5870676A (en) * | 1996-02-16 | 1999-02-09 | Hughes Electronics Corporation | Method and apparatus for monitoring killer channels in a cellular system |
AU738285B2 (en) * | 1997-08-18 | 2001-09-13 | Teijin Limited | A copolyester for molding a bottle |
AU1370800A (en) | 1999-02-04 | 2000-08-25 | Buhler Ag | Process for upgrading plastic material |
TWI299047B (en) | 2002-02-14 | 2008-07-21 | Mitsui Chemicals Inc | Polyester resin, catalyst for the production of polyester, process for the production of polyester resin by using the catalyst, and hollow shaped container made from the polyester resin |
ITTO20020714A1 (it) * | 2002-08-09 | 2004-02-10 | Giuliano Cavaglia | Procedimento per la polimerizzazione continua di |
KR20050020414A (ko) * | 2003-08-22 | 2005-03-04 | 주식회사 효성 | 폴리에틸렌나프탈레이트의 고상중합 |
DE102004012579A1 (de) * | 2004-03-12 | 2005-09-29 | Bühler AG | Verfahren zur Herstellung eines teilkristallinen Polykondensates |
ITTO20070084A1 (it) | 2007-02-06 | 2008-08-07 | K & E Srl | Dispositivi di miscelazione radiale per reattori inclinati rotanti. |
CN101987912B (zh) * | 2009-08-07 | 2013-01-09 | 骏马化纤股份有限公司 | 一种聚萘二甲酸乙二醇酯的改性方法及纺丝工艺 |
WO2011088084A1 (en) | 2010-01-13 | 2011-07-21 | Mitsubishi Polyester Film, Inc. | Process for recycling waste film and product made therefrom |
WO2016105541A1 (en) | 2014-12-24 | 2016-06-30 | Reald Inc. | Adjustment of perceived roundness in stereoscopic image of a head |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3586647A (en) * | 1968-07-10 | 1971-06-22 | Mobil Oil Corp | Solid state polycondensation with porous polyester prepolymer particles |
US4876326A (en) * | 1987-03-26 | 1989-10-24 | The Goodyear Tire & Rubber Company | Solid state polymerization of polyester prepolymers |
US4755587A (en) * | 1987-03-26 | 1988-07-05 | The Goodyear Tire & Rubber Company | Solid state polymerization of polyester prepolymers |
US4917845A (en) * | 1988-04-01 | 1990-04-17 | The Goodyear Tire & Rubber Company | Preparation of ultra-high moleclar weight polyester |
US4957945A (en) * | 1988-04-01 | 1990-09-18 | The Goodyear Tire & Rubber Company | Preparation of ultra high molecular weight polyester |
US4849497A (en) * | 1988-08-03 | 1989-07-18 | The Goodyear Tire & Rubber Company | Solid state polymerization of porous pills made by compacting polyester prepolymers |
US4977196A (en) * | 1988-08-03 | 1990-12-11 | The Goodyear Tire & Rubber Company | Solid state polymerization of porous pills made by compacting polyester prepolymers |
US4963644A (en) * | 1989-09-18 | 1990-10-16 | The Goodyear Tire & Rubber Company | Process for crystallization of polyethylene naphthalate |
US5314927A (en) * | 1992-05-13 | 1994-05-24 | Showa Highpolymer Co., Ltd. | Polyester foamed articles and method for producing the same |
US5225448A (en) * | 1992-11-19 | 1993-07-06 | The Goodyear Tire & Rubber Company | Preparation of porous polyester beads |
US5229432A (en) * | 1992-11-24 | 1993-07-20 | E. I. Du Pont De Nemours And Company | High melt strength pet polymers for foam applications and methods relating thereto |
US5288764A (en) * | 1993-01-29 | 1994-02-22 | Amoco Corporation | Increased throughput in foaming and other melt fabrication of polyester |
-
1994
- 1994-12-15 US US08/357,619 patent/US5449701A/en not_active Expired - Fee Related
-
1995
- 1995-05-08 US US08/436,077 patent/US5478868A/en not_active Expired - Fee Related
- 1995-12-12 CZ CZ19953273A patent/CZ290438B6/cs not_active IP Right Cessation
- 1995-12-12 CN CN95120838A patent/CN1076026C/zh not_active Expired - Fee Related
- 1995-12-12 AR AR33457095A patent/AR000321A1/es unknown
- 1995-12-13 CA CA002165149A patent/CA2165149A1/en not_active Abandoned
- 1995-12-13 EP EP95203470A patent/EP0717062B1/en not_active Expired - Lifetime
- 1995-12-13 NO NO955048A patent/NO307838B1/no not_active IP Right Cessation
- 1995-12-13 DE DE69523122T patent/DE69523122T2/de not_active Expired - Fee Related
- 1995-12-13 ZA ZA9510591A patent/ZA9510591B/xx unknown
- 1995-12-13 PT PT95203470T patent/PT717062E/pt unknown
- 1995-12-13 AT AT95203470T patent/ATE206726T1/de not_active IP Right Cessation
- 1995-12-13 JP JP34624995A patent/JP3477471B2/ja not_active Expired - Fee Related
- 1995-12-13 MY MYPI95003845A patent/MY116003A/en unknown
- 1995-12-13 MX MX9505240A patent/MX9505240A/es unknown
- 1995-12-13 SG SG1995002126A patent/SG34331A1/en unknown
- 1995-12-13 ES ES95203470T patent/ES2165406T3/es not_active Expired - Lifetime
- 1995-12-13 DK DK95203470T patent/DK0717062T3/da active
- 1995-12-13 BR BR9505811A patent/BR9505811A/pt not_active IP Right Cessation
- 1995-12-14 KR KR1019950051628A patent/KR960022679A/ko not_active Application Discontinuation
- 1995-12-14 HU HU9503586A patent/HU214043B/hu not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
BR9505811A (pt) | 1998-01-06 |
NO955048L (no) | 1996-06-17 |
NO955048D0 (no) | 1995-12-13 |
ZA9510591B (en) | 1996-06-19 |
EP0717062B1 (en) | 2001-10-10 |
HU9503586D0 (en) | 1996-02-28 |
CN1132760A (zh) | 1996-10-09 |
ES2165406T3 (es) | 2002-03-16 |
US5449701A (en) | 1995-09-12 |
JPH08231691A (ja) | 1996-09-10 |
EP0717062A2 (en) | 1996-06-19 |
CN1076026C (zh) | 2001-12-12 |
AR000321A1 (es) | 1997-06-18 |
SG34331A1 (en) | 1996-12-06 |
MY116003A (en) | 2003-10-31 |
KR960022679A (ko) | 1996-07-18 |
CZ327395A3 (en) | 1996-07-17 |
NO307838B1 (no) | 2000-06-05 |
HU214043B (en) | 1997-12-29 |
ATE206726T1 (de) | 2001-10-15 |
JP3477471B2 (ja) | 2003-12-10 |
HUT74307A (en) | 1996-12-30 |
CA2165149A1 (en) | 1996-06-16 |
DK0717062T3 (da) | 2002-02-04 |
EP0717062A3 (en) | 1996-09-25 |
CZ290438B6 (cs) | 2002-07-17 |
PT717062E (pt) | 2002-04-29 |
DE69523122T2 (de) | 2002-06-20 |
US5478868A (en) | 1995-12-26 |
DE69523122D1 (de) | 2001-11-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0260415A3 (en) | Synthesis and application of high molecular weight polyanhydrides | |
MY126503A (en) | Rheology modification of polymers prepared using metallocenes | |
MX9505240A (es) | Proceso de polimerizacion en estado solido para el poli(etilen-naftalato) espumado o alveolar. | |
DE3168357D1 (en) | Olefin polymerization process | |
FI990003A (fi) | Polymeerikoostumus, menetelmä sen valmistamiseksi ja siitä valmistetut kalvot | |
CA2336393A1 (en) | Process for producing polymers by free radical polymerization and condensation reaction, and apparatus and products related thereto | |
TW364912B (en) | Polyglycolic acid sheet and production process thereof | |
MY128257A (en) | Process for the manufacture of a composition comprising ethylene polymers | |
EP0096901A3 (en) | Bulk polymerization process and polymer product | |
ZA946975B (en) | Degradable polydioxaneone-based materials. | |
KR960007154A (ko) | 압출 성형기에서 폴리에틸렌의 변형방법 | |
WO1995026990A1 (en) | Process for producing polymers with multi-modal molecular weight distributions | |
CA2023005A1 (en) | Process for olefin polymerization | |
CA2021666A1 (en) | Thermoplastic polymer composition containing melt-rheology modifiers | |
AU2003259052A1 (en) | Polyolefin adhesive and production process therefor | |
TW367335B (en) | Cyclo-olefin polymers and preparation process thereof | |
BR9401988A (pt) | Processo para a fabricação de poli-(Epsilon) -caprolactonas e poli-(Epsilon)-cprolactonas que podem ser obtidas pelo mesmo | |
AU8444198A (en) | Process for the production of olefin polymers having a desirable molecular weight distribution | |
KR970706320A (ko) | 중합방법(polymerization process) | |
CA2072855A1 (en) | Anionic extruder polymerization | |
TW363974B (en) | Process for producing high molecular weight monovinylidene aromatic polymers | |
EP0522641A3 (en) | Anionic extruder polymerization | |
DE2964395D1 (en) | Process for widening the molecular distribution of polyethylene by using two reactors operating at very different pressures and temperatures and in the absence of hydrogen, and apparatus for carrying it out | |
Cowie | General(Chain Polymerization) Concepts | |
Promel | Process for preparing an ethylene polymer composition, ethylene polymer composition, and its use |