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MX2019005169A - Proceso de polimerizacion de olefinas en un reactor en fase gaseosa que comprende una unidad de tubo de subida y un tubo de bajada. - Google Patents

Proceso de polimerizacion de olefinas en un reactor en fase gaseosa que comprende una unidad de tubo de subida y un tubo de bajada.

Info

Publication number
MX2019005169A
MX2019005169A MX2019005169A MX2019005169A MX2019005169A MX 2019005169 A MX2019005169 A MX 2019005169A MX 2019005169 A MX2019005169 A MX 2019005169A MX 2019005169 A MX2019005169 A MX 2019005169A MX 2019005169 A MX2019005169 A MX 2019005169A
Authority
MX
Mexico
Prior art keywords
downcomer
gas
polymer particles
polymerization process
riser unit
Prior art date
Application number
MX2019005169A
Other languages
English (en)
Inventor
Meier Gerhardus
Schueller Ulf
Mei Gabriele
Covezzi Massimo
Baita Pietro
Marturano Lorella
Original Assignee
Basell Polyolefine Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from EP16198262.4A external-priority patent/EP3321288A1/en
Application filed by Basell Polyolefine Gmbh filed Critical Basell Polyolefine Gmbh
Publication of MX2019005169A publication Critical patent/MX2019005169A/es

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818Feeding of the fluidising gas
    • B01J8/1827Feeding of the fluidising gas the fluidising gas being a reactant
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1845Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised
    • B01J8/1863Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles with particles moving upwards while fluidised followed by a downward movement outside the reactor and subsequently re-entering it
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/01Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • C08F4/6545Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium and metals of C08F4/64 or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/12Melt flow index or melt flow ratio
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/18Bulk density

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Un proceso para preparar un polímero de etileno que comprende homopolimerizar etileno o copolimerizar etileno con uno o más comonómeros en un reactor de polimerización en fase gaseosa que comprende una unidad de tubo de subida, en la que las partículas poliméricas crecientes fluyen hacia arriba en condiciones de fluidización, fluidización rápida o transporte, y un tubo de bajada, en el que partículas poliméricas crecientes fluyen hacia abajo en una forma densificada, en donde la retención de partículas poliméricas en el tubo de bajada es de 55%p. a 80%p. de la retención de partículas poliméricas total en el reactor de polimerización en fase gaseosa.
MX2019005169A 2016-11-10 2017-11-09 Proceso de polimerizacion de olefinas en un reactor en fase gaseosa que comprende una unidad de tubo de subida y un tubo de bajada. MX2019005169A (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP16198262.4A EP3321288A1 (en) 2016-11-10 2016-11-10 Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer
EP17179386 2017-07-03
PCT/EP2017/078729 WO2018087214A1 (en) 2016-11-10 2017-11-09 Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer

Publications (1)

Publication Number Publication Date
MX2019005169A true MX2019005169A (es) 2019-08-05

Family

ID=60262941

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2019005169A MX2019005169A (es) 2016-11-10 2017-11-09 Proceso de polimerizacion de olefinas en un reactor en fase gaseosa que comprende una unidad de tubo de subida y un tubo de bajada.

Country Status (15)

Country Link
US (1) US10968291B2 (es)
EP (1) EP3510057B1 (es)
JP (1) JP6932190B2 (es)
KR (1) KR102006024B1 (es)
CN (1) CN109923130B (es)
AU (1) AU2017358715B2 (es)
BR (1) BR112019008857B1 (es)
CA (1) CA3043121C (es)
IL (1) IL266421B (es)
MX (1) MX2019005169A (es)
MY (1) MY187826A (es)
PT (1) PT3510057T (es)
RU (1) RU2703716C1 (es)
SG (1) SG11201903559YA (es)
WO (1) WO2018087214A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3898709A1 (en) 2018-12-18 2021-10-27 Basell Polyolefine GmbH Gas-phase process for preparing ethylene polymers
EP3834923A1 (en) * 2019-12-11 2021-06-16 Basell Polyolefine GmbH Apparatus and process for the gas-phase polymerization

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5825309A (ja) * 1981-08-07 1983-02-15 Asahi Chem Ind Co Ltd α−オレフイン重合体の製造方法およびその装置
IT1275573B (it) * 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
TR200000617T1 (tr) * 1998-07-08 2000-10-23 Montell Tecnology Company Bv Gazı-fazı polimerizasyonu için işlem ve aygıt.
DE19907021A1 (de) * 1999-02-19 2000-08-24 Elenac Gmbh Verfahren und Apparatur zur Gasphasenpolymerisation von alpha-Olefinen
CA2551017A1 (en) * 2003-08-20 2005-03-03 Basell Poliolefine Italia S.R.L. Process and apparatus for the polymerization of ethylene
DE10344500A1 (de) 2003-09-24 2005-05-19 Basell Polyolefine Gmbh Suspensionspolymerisationsverfahren mit hohen Feststoffkonzentrationen im Schleifenreaktor
EP1663475B1 (en) * 2003-09-24 2016-11-09 Basell Polyolefine GmbH Process with a loop reactor with varying diameter for olefin polymerization
GB0426057D0 (en) * 2004-11-26 2004-12-29 Solvay Chemical process
EP1896513B1 (en) 2005-05-13 2010-01-20 Basell Poliolefine Italia S.r.l. Process for the gas-phase polymerization of olefins
EP2046845B1 (en) 2006-07-28 2012-06-06 Basell Poliolefine Italia S.r.l. Propylene polymers
BRPI0713834B1 (pt) * 2006-07-28 2018-12-26 Basell Poliolefine Italia Srl polímeros de propileno
EP2225022B1 (en) * 2007-12-21 2011-06-08 Basell Poliolefine Italia S.r.l. Process for the gas-phase polymerization of olefins
CN102060943B (zh) 2009-11-13 2012-10-03 中国石油化工股份有限公司 一种烯烃聚合的多区循环反应装置和反应方法
EP2722347A1 (en) 2012-10-22 2014-04-23 Basell Polyolefine GmbH Multistage process for the polymerization of olefins
BR112015020142B1 (pt) 2013-02-27 2020-07-07 Basell Polyolefine Gmbh processos para polietileno e composições deste material
EP2816062A1 (en) 2013-06-18 2014-12-24 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
SG11201705983VA (en) 2015-03-26 2017-08-30 Basell Polyolefine Gmbh Polymerization process in the presence of antistatic agent

Also Published As

Publication number Publication date
IL266421A (en) 2019-06-30
CN109923130A (zh) 2019-06-21
CA3043121C (en) 2020-01-14
CN109923130B (zh) 2020-05-15
BR112019008857A2 (pt) 2019-07-09
IL266421B (en) 2020-01-30
CA3043121A1 (en) 2018-05-17
US20190322775A1 (en) 2019-10-24
EP3510057A1 (en) 2019-07-17
KR102006024B1 (ko) 2019-07-31
KR20190060860A (ko) 2019-06-03
AU2017358715B2 (en) 2019-06-20
JP6932190B2 (ja) 2021-09-08
MY187826A (en) 2021-10-26
BR112019008857B1 (pt) 2022-10-25
US10968291B2 (en) 2021-04-06
PT3510057T (pt) 2020-04-06
JP2019533749A (ja) 2019-11-21
SG11201903559YA (en) 2019-05-30
RU2703716C1 (ru) 2019-10-22
WO2018087214A1 (en) 2018-05-17
EP3510057B1 (en) 2020-01-01

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