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MA31467B1 - Composes 1, 3-dione bicycliques actifs sur le plan herbicide. - Google Patents

Composes 1, 3-dione bicycliques actifs sur le plan herbicide.

Info

Publication number
MA31467B1
MA31467B1 MA32455A MA32455A MA31467B1 MA 31467 B1 MA31467 B1 MA 31467B1 MA 32455 A MA32455 A MA 32455A MA 32455 A MA32455 A MA 32455A MA 31467 B1 MA31467 B1 MA 31467B1
Authority
MA
Morocco
Prior art keywords
bicyclic compounds
active bicyclic
dione herbicide
dione
herbicide
Prior art date
Application number
MA32455A
Other languages
Arabic (ar)
English (en)
Inventor
Christopher John Mathews
Matthew Brian Hotson
Alan John Dowling
James Nicholas Scutt
Mangala Govenkar
Lee Challinor
Original Assignee
Syngenta Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Syngenta Ltd filed Critical Syngenta Ltd
Publication of MA31467B1 publication Critical patent/MA31467B1/fr

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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N35/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical
    • A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/42—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing seven carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/44—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing eight carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2602/00—Systems containing two condensed rings
    • C07C2602/36—Systems containing two condensed rings the rings having more than two atoms in common
    • C07C2602/46—Systems containing two condensed rings the rings having more than two atoms in common the bicyclo ring system containing nine carbon atoms

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  • Chemical & Material Sciences (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pyridine Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

Composés bicycliques de dione de formule (i) et leurs dérivés appropriés pour une utilisation en tant qu'herbicides.
MA32455A 2007-05-29 2009-12-29 Composes 1, 3-dione bicycliques actifs sur le plan herbicide. MA31467B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0710223.9A GB0710223D0 (en) 2007-05-29 2007-05-29 Novel Herbicides
PCT/EP2008/004195 WO2008145336A1 (fr) 2007-05-29 2008-05-27 Composés bicycliques de 1,3-dione actifs sur le plan herbicide

Publications (1)

Publication Number Publication Date
MA31467B1 true MA31467B1 (fr) 2010-06-01

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Application Number Title Priority Date Filing Date
MA32455A MA31467B1 (fr) 2007-05-29 2009-12-29 Composes 1, 3-dione bicycliques actifs sur le plan herbicide.

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Country Link
US (1) US8828908B2 (fr)
EP (1) EP2155645B1 (fr)
JP (1) JP5373775B2 (fr)
KR (1) KR20100017455A (fr)
CN (1) CN101679177B (fr)
AP (1) AP2521A (fr)
AR (1) AR069264A1 (fr)
AU (1) AU2008256487B2 (fr)
BR (1) BRPI0812027B1 (fr)
CA (1) CA2687202C (fr)
CL (1) CL2008001545A1 (fr)
CO (1) CO6251202A2 (fr)
CU (1) CU23836B1 (fr)
EA (1) EA020771B1 (fr)
EC (1) ECSP099760A (fr)
ES (1) ES2638441T3 (fr)
GB (1) GB0710223D0 (fr)
HN (1) HN2009003299A (fr)
MA (1) MA31467B1 (fr)
MX (1) MX2009012687A (fr)
NZ (1) NZ581078A (fr)
SA (1) SA08290322B1 (fr)
SV (1) SV2009003432A (fr)
TN (1) TN2009000499A1 (fr)
TW (1) TW200906300A (fr)
UA (1) UA99728C2 (fr)
WO (1) WO2008145336A1 (fr)
ZA (1) ZA200907894B (fr)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0712653D0 (en) 2007-06-28 2007-08-08 Syngenta Ltd Novel herbicides
GB0714981D0 (en) 2007-08-01 2007-09-12 Syngenta Ltd Novel herbicides
GB0715454D0 (en) 2007-08-08 2007-09-19 Syngenta Ltd Novel herbicides
GB0715576D0 (en) 2007-08-09 2007-09-19 Syngenta Ltd Novel herbicides
EP2300449A1 (fr) * 2008-06-12 2011-03-30 Syngenta Participations AG Compositions pesticides contenant un dérivé de pyrandione ou de thiopyrandione ou de cyclohexanetrione
GB0812310D0 (en) 2008-07-03 2008-08-13 Syngenta Ltd Novel herbicides
GB0819205D0 (en) 2008-10-20 2008-11-26 Syngenta Ltd Novel herbicides
GB0822834D0 (en) 2008-12-15 2009-01-21 Syngenta Ltd Novel herbicides
GB0900641D0 (en) * 2009-01-15 2009-02-25 Syngenta Ltd Novel herbicides
ES2427403T3 (es) * 2009-01-19 2013-10-30 Bayer Cropscience Ag 1,3-Dionas bicíclicas y su uso como insecticidas, acaricidas y/o fungicidas
GB0901086D0 (en) 2009-01-22 2009-03-11 Syngenta Ltd Novel herbicides
GB0901835D0 (en) 2009-02-04 2009-03-11 Syngenta Ltd Novel herbicides
GB0901834D0 (en) 2009-02-04 2009-03-11 Syngenta Ltd Novel herbicides
CA2754847C (fr) 2009-03-11 2017-07-11 Bayer Cropscience Ag Cetoenols a substitution halogenoalkylmethyleneoxy-phenyle
GB0912385D0 (en) 2009-07-16 2009-08-26 Syngenta Ltd Novel herbicides
JP5795581B2 (ja) 2009-07-31 2015-10-14 シンジェンタ リミテッド 除草活性を有するヘテロアリール置換環状ジオンまたはその誘導体
DE102010008644A1 (de) 2010-02-15 2011-08-18 Bayer Schering Pharma Aktiengesellschaft, 13353 Zyklische Ketoenole zur Therapie
MY172133A (en) 2012-01-26 2019-11-14 Bayer Ip Gmbh Phenyl-substituted ketoenols for controlling fish parasites
JP6047166B2 (ja) * 2012-10-04 2016-12-21 バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングＢａｙｅｒ Ｉｎｔｅｌｌｅｃｔｕａｌ Ｐｒｏｐｅｒｔｙ ＧｍｂＨ 農薬製剤及びその製造方法
ES2665568T3 (es) * 2012-12-21 2018-04-26 Syngenta Limited Compuestos de diona cíclica activos como herbicidas, o derivados de los mismos, sustituidos por un fenilo que tiene un sustituyente que contiene alquinilo
UA119145C2 (uk) * 2013-05-30 2019-05-10 Сінгента Лімітед Гербіцидно активні (алкінілфеніл)-заміщені циклічні діонові сполуки та їхні похідні
GB201310047D0 (en) 2013-06-05 2013-07-17 Syngenta Ltd Compounds
GB201411418D0 (en) * 2014-06-26 2014-08-13 Syngenta Participations Ag Compounds
GB201802558D0 (en) * 2018-02-16 2018-04-04 Syngenta Participations Ag Improvements in or relating to organic compounds
MX2023015190A (es) * 2021-07-09 2024-01-24 Syngenta Crop Protection Ag Composiciones herbicidas.
CN117545355A (zh) * 2021-07-09 2024-02-09 先正达农作物保护股份公司 除草组合物
PE20240596A1 (es) * 2021-07-09 2024-03-21 Syngenta Crop Protection Ag Composiciones herbicidas

Family Cites Families (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT67818A (en) 1977-03-28 1978-04-01 Union Carbide Corp Process for the synthesis of biocidal 2-aryl-1,3-cycloalkanedionas and their enol esters
US4209532A (en) 1977-03-28 1980-06-24 Union Carbide Corporation Biocidal 2-aryl-1,3-cyclohexane dione compounds and alkali metal and ammonium salts thereof
US4422870A (en) 1977-03-28 1983-12-27 Union Carbide Corporation Biocidal 2-aryl-1, 3-cyclohexanedione enol ester compounds
US4659372A (en) * 1977-03-28 1987-04-21 Union Carbide Corporation Biocidal 2-aryl-1,3-cyclohexanedione enol ester compounds
US4175135A (en) * 1978-07-18 1979-11-20 Union Carbide Corporation Method of controlling acarina ectoparasites on warmblooded animals by orally administering to the animal an ectoparasitically effective amount of a 2-aryl-1,3-cyclohexanedione compound, and alkali metal salts, ammonium salts and enol esters thereof
US4436666A (en) 1978-09-22 1984-03-13 Union Carbide Corporation Biocidal enol derivatives of 2-aryl-1,3-cycloalkanedione compounds
US4526723A (en) * 1978-09-27 1985-07-02 Union Carbide Corporation Biocidal enol esters of non-ortho substituted 2-aryl-1-3-cycloalkanedione compounds
US4409153A (en) 1980-03-28 1983-10-11 Union Carbide Corporation O-(2-Aryl-3-oxo-1-cyclohexenyl) phosphates
US4489012A (en) * 1982-02-23 1984-12-18 Union Carbide Corporation Enol-phosphorous esters of 2-aryl-1,3-cycloalkanediones compounds
BR8600161A (pt) 1985-01-18 1986-09-23 Plant Genetic Systems Nv Gene quimerico,vetores de plasmidio hibrido,intermediario,processo para controlar insetos em agricultura ou horticultura,composicao inseticida,processo para transformar celulas de plantas para expressar uma toxina de polipeptideo produzida por bacillus thuringiensis,planta,semente de planta,cultura de celulas e plasmidio
US4834908A (en) 1987-10-05 1989-05-30 Basf Corporation Antagonism defeating crop oil concentrates
CN1038093A (zh) * 1988-04-18 1989-12-20 山道士有限公司 对有机化合物和关于有机化合物的改进
ES2054088T3 (es) 1988-10-20 1994-08-01 Ciba Geigy Ag Sulfamoilfenilureas.
EP0374753A3 (fr) 1988-12-19 1991-05-29 American Cyanamid Company Toxines insecticides, gènes les codant, anticorps les liant, ainsi que cellules végétales et plantes transgéniques exprimant ces toxines
EP0427529B1 (fr) 1989-11-07 1995-04-19 Pioneer Hi-Bred International, Inc. Lectines larvicides, et résistance induite des plantes aux insectes
AU9152191A (en) 1990-12-31 1992-08-17 Monsanto Company Reducing pesticidal interactions in crops
UA48104C2 (uk) 1991-10-04 2002-08-15 Новартіс Аг Фрагмент днк, який містить послідовність,що кодує інсектицидний протеїн, оптимізовану для кукурудзи,фрагмент днк, який забезпечує направлену бажану для серцевини стебла експресію зв'язаного з нею структурного гена в рослині, фрагмент днк, який забезпечує специфічну для пилку експресію зв`язаного з нею структурного гена в рослині, рекомбінантна молекула днк, спосіб одержання оптимізованої для кукурудзи кодуючої послідовності інсектицидного протеїну, спосіб захисту рослин кукурудзи щонайменше від однієї комахи-шкідника
US5530195A (en) 1994-06-10 1996-06-25 Ciba-Geigy Corporation Bacillus thuringiensis gene encoding a toxin active against insects
AU2928195A (en) * 1994-07-21 1996-02-22 Bayer Aktiengesellschaft 2-(2,4,6-trimethyl phenyl)cyclopentane-1,3-dione derivatives
AU715538B2 (en) 1996-03-15 2000-02-03 Syngenta Participations Ag Herbicidal synergistic composition and method of weed control
DE19808261A1 (de) * 1998-02-27 1999-10-28 Bayer Ag Arylphenylsubstituierte cyclische Ketoenole
US6410480B1 (en) 1998-03-13 2002-06-25 Syngenta Crop Protection, Inc. Herbicidally active 3-hydroxy-4-aryl-5-oxopyrazoline derivatives
DE19813354A1 (de) * 1998-03-26 1999-09-30 Bayer Ag Arylphenylsubstituierte cyclische Ketoenole
DE69925610T2 (de) * 1998-09-15 2006-04-27 Syngenta Participations Ag Als herbicide verwendbare pyridin-ketone
BR9916396A (pt) 1998-12-21 2001-09-11 Syngenta Participations Ag Herbicidas
DE19935963A1 (de) * 1999-07-30 2001-02-01 Bayer Ag Biphenylsubstituierte cyclische Ketoenole
PL356456A1 (en) 1999-09-07 2004-06-28 Syngenta Participations Ag Novel herbicides
ATE282597T1 (de) 1999-09-07 2004-12-15 Syngenta Participations Ag P-tolyl-heterocyclen als herbizide
DE10016544A1 (de) 2000-04-03 2001-10-11 Bayer Ag C2-phenylsubstituierte Ketoenole
GT200100103A (es) * 2000-06-09 2002-02-21 Nuevos herbicidas
DE10139465A1 (de) 2001-08-10 2003-02-20 Bayer Cropscience Ag Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern
AU2002361696A1 (en) 2001-12-17 2003-06-30 Syngenta Participations Ag Novel corn event
AU2003203482B2 (en) * 2002-04-09 2005-06-02 Syngenta Participations Ag Process for the preparation of cyclic diketones
AU2003203479B2 (en) 2002-04-09 2005-10-06 Syngenta Participations Ag Process for the preparation of bicyclic diketone salts
GT200300290A (es) * 2002-12-30 2004-10-13 Herbicidas novedosos
DE10326386A1 (de) * 2003-06-12 2004-12-30 Bayer Cropscience Ag N-Heterocyclyl-phenylsubstituierte cyclische Ketoenole
CA2530581A1 (fr) 2003-06-23 2005-01-06 Auspex Pharmaceuticals Nouveaux agents therapeutiques permettant de traiter le cancer, les maladies metaboliques et les affections cutanees
WO2005105717A1 (fr) * 2004-04-30 2005-11-10 Syngenta Participations Ag Procede de production de dicetones cycliques
BRPI0510502B1 (pt) * 2004-04-30 2015-07-21 Syngenta Participations Ag Processo para a produção de dicetonas cíclicas, bem como seus intermediários
US7179943B2 (en) 2004-06-14 2007-02-20 Wyeth Bicyclic derivatives that modulate voltage-gated potassium channels and methods of use thereof
WO2005123667A1 (fr) 2004-06-22 2005-12-29 Syngenta Participations Ag Bicyclooctenes substitues et leur utilisation en tant qu'herbicides
MX2007003330A (es) 2004-09-20 2007-06-05 Xenon Pharmaceuticals Inc Derivados heterociclicos y su uso como agentes terapeuticos.
BRPI0515483A (pt) 2004-09-20 2008-07-22 Xenon Pharmaceuticals Inc derivados heterocìclicos para o tratamento de doenças mediadas por enzimas estearoil-coa desaturase
TWI417048B (zh) * 2006-12-14 2013-12-01 Syngenta Participations Ag 新穎的除草劑
GB0704653D0 (en) 2007-03-09 2007-04-18 Syngenta Participations Ag Novel herbicides
GB0704652D0 (en) * 2007-03-09 2007-04-18 Syngenta Participations Ag Novel herbicides
GB0714981D0 (en) * 2007-08-01 2007-09-12 Syngenta Ltd Novel herbicides

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HN2009003299A (es) 2012-03-19
AU2008256487A1 (en) 2008-12-04
JP5373775B2 (ja) 2013-12-18
EP2155645A1 (fr) 2010-02-24
EA020771B1 (ru) 2015-01-30
ZA200907894B (en) 2010-08-25
CU23836B1 (es) 2012-10-15
EP2155645B1 (fr) 2017-06-14
NZ581078A (en) 2012-03-30
US8828908B2 (en) 2014-09-09
AU2008256487B2 (en) 2014-02-20
ECSP099760A (es) 2009-12-28
CA2687202A1 (fr) 2008-12-04
SA08290322B1 (ar) 2011-08-20
AP2009005043A0 (en) 2009-12-31
CO6251202A2 (es) 2011-02-21
WO2008145336A1 (fr) 2008-12-04
AR069264A1 (es) 2010-01-13
CL2008001545A1 (es) 2008-09-22
BRPI0812027B1 (pt) 2018-06-12
JP2010528074A (ja) 2010-08-19
US20100216638A1 (en) 2010-08-26
EA200901597A1 (ru) 2010-06-30
CU20090202A7 (es) 2011-07-11
CN101679177A (zh) 2010-03-24
WO2008145336A8 (fr) 2010-01-14
TN2009000499A1 (en) 2011-03-31
MX2009012687A (es) 2009-12-11
ES2638441T3 (es) 2017-10-20
AP2521A (en) 2012-11-29
CN101679177B (zh) 2013-08-21
UA99728C2 (ru) 2012-09-25
GB0710223D0 (en) 2007-07-11
BRPI0812027A2 (pt) 2014-11-18
CA2687202C (fr) 2015-08-11
KR20100017455A (ko) 2010-02-16
TW200906300A (en) 2009-02-16
SV2009003432A (es) 2011-10-03

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