[go: up one dir, main page]

KR970707245A - 전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제(cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition) - Google Patents

전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제(cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition)

Info

Publication number
KR970707245A
KR970707245A KR1019970702963A KR19970702963A KR970707245A KR 970707245 A KR970707245 A KR 970707245A KR 1019970702963 A KR1019970702963 A KR 1019970702963A KR 19970702963 A KR19970702963 A KR 19970702963A KR 970707245 A KR970707245 A KR 970707245A
Authority
KR
South Korea
Prior art keywords
present
beta
group
component
phenolic hydroxyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
KR1019970702963A
Other languages
English (en)
Other versions
KR100211079B1 (ko
Inventor
조셉 티 발코
필립 포셰
리차드 에프 카라빈
토마 씨 모리아리띠
벤카타찰람 에스와라크리쉬난
부스커크 엘러 제이 반
그레고리 제이 맥컬럼
라파엘 오 콜라
Original Assignee
버그스트롬 리타
피피지 인더스트리즈 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 버그스트롬 리타, 피피지 인더스트리즈 인코포레이티드 filed Critical 버그스트롬 리타
Publication of KR970707245A publication Critical patent/KR970707245A/ko
Application granted granted Critical
Publication of KR100211079B1 publication Critical patent/KR100211079B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225—Polyamines
    • C08G18/3253—Polyamines being in latent form
    • C08G18/3256—Reaction products of polyamines with aldehydes or ketones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C08G18/0814—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4294—Polycondensates having carboxylic or carbonic ester groups in the main chain prepared from polyester forming components containing polyepoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/581—Reaction products of epoxy resins with less than equivalent amounts of compounds containing active hydrogen added before or during the reaction with the isocyanate component
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/58—Epoxy resins
    • C08G18/584—Epoxy resins having nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6407—Reaction products of epoxy resins with at least equivalent amounts of compounds containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/64—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63
    • C08G18/6415—Macromolecular compounds not provided for by groups C08G18/42 - C08G18/63 having nitrogen
    • C08G18/643—Reaction products of epoxy resins with at least equivalent amounts of amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
    • C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
    • C08G18/8048—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/34
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8064—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4453—Polyepoxides characterised by the nature of the curing agent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4457—Polyepoxides containing special additives, e.g. pigments, polymeric particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Molecular Biology (AREA)
  • Manufacturing & Machinery (AREA)
  • Paints Or Removers (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

(A) 폴리에폭사이드로부터 유도되고, 수지 분자내에 지방족 하이드록실, 1급 아미노 및 2급 아미노로부터 선택되는 활성 수소기 및 양이온염 기를 함유하는 겔화되지 않은 양이온 수지; 및 별도의 성분으로서 존재하는 (B) 유리이소시아네이트기를 실질적으로 함유하지 않는 완전히 캡핑된 폴리이소시아네이트 경화제를 포함하는 전착 조성물이 제공된다. 전착 조성물은 수지 고형분 g당 약 0.02 내지 1.0밀리당량의 페놀성 하이드록실기, 및 수지 고형분 g당 약 0.1 내지 2.0밀리당량의 베타-하이드록시 에스테르기를 함유한다. 조성물은 강철 기판상에 전착될 때 탁월한 내부식성을 제공하고, 배합시 납을 필요로 하지 않고 전착전에 강철 기판을 예비처리하기 위한 통상적인 크롬 세정을 이용하지도 않는다.

Description

전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제(CATIONIC RESIN AND CAPPED POLYISOCYANATE CURING AGENT SUITABLE FOR USE IN ELECTRODEPOSITION)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (35)

  1. (A) 폴리에폭사이드로부터 유도되고, 지방족 하이드록실, 1급 아미노 및 2급 아미노로부터 선택된 활성 수소기 및 양이온염 기를 수지내에 함유하는 양이온 수지; 및 별도의 성분으로서 존재하는 (B) 유리 이소시아네이트기를 실질적으로 함유하지 않는 완전히 캡핑된 폴리이소시아네이트 경화제를 포함하며, 수지 고형분 g당 하기 일반식(1)로 계산된 페놀성 하이드록실기 약 0.02 내지 1.0밀리당량 및 수지 고형분 g당 하기 일반식(2)로 계싼된 베타-하이드록시 에스테르기 약 0.1 내지 2.0밀리당량을 함유하는 것을 특징으로 하는 전착조성물 :
  2. 제1항에 있어서, 페놀성 하이드록실기가 성분(A)에 존재하는 전착 조성물.
  3. 제1항에 있어서, 베타-하이드록시 에스테르기가 성분(A)에 존재하는 전착 조성물.
  4. 제1항에 있어서, 페놀성 하이드록시기가 성분(B)에 존재하는 전착 조성물.
  5. 제1항에 있어서, 베타-하이드록시 에스테르기가 성분(B)에 존재하는 전착 조성물.
  6. 제1항에 있어서, 페놀성 하이드록실기 및 베타-하이드록시 에스테르기가 성분(B)에 존재하는 전착 조성물.
  7. 제1항에 있어서, 페놀성 하이드록실기 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 전착 조성물.
  8. 제1항에 있어서, 베타-하이드록시 에스테르기가 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 전착 조성물.
  9. 제1항에 있어서, 페놀성 하이드록실기 및 베타-하이드록시 에스테르기가 둘다 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재한느 전착 조성물.
  10. 제1항에 있어서, 페놀성 하이드록실기가 별도의 성분(C)에 존재하고, 베타-하이드록시 에스테르기가 별도의 성분(D)에 존재하며, (C) 및 (D)가 서로 상이하고 또한 (A) 및 (B)와도 상이한 전착 조성물.
  11. 제1항에 있어서, 페놀성 하이드록실기가 성분(A) 또는 (B)에 존재하고, 베타-하이드록시 에스테르기가 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 전착 조성물.
  12. 제1항에 있어서, 베타-하이드록시 에스테르기가 성분(A) 및 (B)에 존재하고, 페놀성 하이드록실기가 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 전착 조성물.
  13. 제1항에 있어서, 페놀성 하이드록실기가 다가 페놀로부터 유도되는 전착 조성물.
  14. 제13항에 있어서, 다가 페놀이 비스페놀 A인 전착 조성물.
  15. 제1항에 있어서, 베타-하이드록시 에스테르기가 1,2-에폭시기-함유 물질을 카복실산으로 개환반응시킴으로써 형성되는 전착 조성물.
  16. 제15항에 있어서, 카복실산이 하이드록실기-함유 카복실산인 전착 조성물.
  17. 제16항에 있어서, 하이드록실기-함유 카복실산인 디메틸올로프로피온산인 전착 조성물.
  18. 제15항에 있어서, 1,2-에폭시기-함유 물질이 폴리에폭사이드인 전착 조성물.
  19. 양극과 음극 사이에 전류를 통과시켜, (A) 폴리에폭사이드로부터 유도되고, 지방족 하이드록실, 1급 아미노 및 2급 아미노로부터 선택되는 활성 수소기 및 양이온염 기를 수지내에 함유하는 양이온 수지; 및 별도의 성분으로서 존재하는 (B) 유리 이소시아네이트기를 실질적으로 함유하지 않는 완전히 캡핑된 폴리이소시아네이트 경화제를 포함하며, 수지 고형분 g당 하기 일반식(1)로 계산된 페놀성 하이드록실기 약 0.02 내지 1.0밀리당량 및 수지 고형분 g당 하기 일반식(2)로 계산된 베타-하이드록시 에스테르기 약 0.1 내지 2.0밀리당량을 함유함을 특징으로 하는 전착 조성물을 실질적인 연속 필름으로서 음극상에 전착시키고, 전착된 필름을 승온에서 가열하여 필름을 경화시킴을 포함하는, 수분산성 양이온 수지를 함유하는 수성 전착 조성물에 침지된 음극 및 양극을 포함하는 전기회로에서 음극으로서 작용하는 전기전도성 기판을 전기코팅시키는 방법 :
  20. 제19항에 있어서, 페놀성 하이드록실기가 성분(A)에 존재하는 방법.
  21. 제19항에 있어서, 베타-하이드록시 에스테르기가 성분(A)에 존재하는 방법.
  22. 제19항에 있어서, 페놀성 하이드록실기가 성분(B)에 존재하는 방법.
  23. 제19항에 있어서, 베타-하이드록시 에스테르기가 성분(A)에 존재하는 방법.
  24. 제19항에 있어서, 페놀성 하이드록실기 및 베타-하이드록시 에스테르기가 성분(B)에 존재하는 방법.
  25. 제19항에 있어서, 페놀성 하이드록실기가 성분(A) 및 성분(B)와는 상이한 별도의 성분(C)에 존재하는 방법.
  26. 제19항에 있어서, 베타-하이드록시 에스테르기가 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 방법.
  27. 제19항에 있어서, 페놀성 하이드록실기 및 베타-하이드록시 에스테르기가 둘다 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 방법.
  28. 제19항에 있어서, 페놀성 하이드록실기가 닥 페놀로부터 유도되는 방법.
  29. 제19항에 있어서, 다가 페놀이 비스페놀 A인 방법.
  30. 제19항에 있어서, 베타-하이드록시 에스테르기가 1,2-에폭시기-함유 물질을 카복실산으로 개환반응시켜 제조되는 방법.
  31. 제30항에 있어서, 카복실산이 하이드록실기-함유 카복실산인 방법.
  32. 제31항에 있어서, 하이드록실기-함유 카복실산인 디메틸올로프로피온산인 방법.
  33. 제30항에 있어서, 1,2-에폭시기-함유 물질이 폴리에폭사이드인 방법.
  34. 제19항에 페놀성 하이드록실기가 성분(A) 또는 (B)에 존재하고, 베타-하이드록시 에스테르기가 성분(A) 및 (B)와는 상이한 제3성분(C)에 존재하는 방법.
  35. 제19항에 있어서, 베타-하이드록시 에스테르기가 성분(A) 및 (B)에 존재하고, 페놀성 하이드록실기가 성분(A) 및 (B)와는 상이한 별도의 성분(C)에 존재하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970702963A 1994-11-04 1995-10-17 전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제 Expired - Fee Related KR100211079B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/334,712 US5582704A (en) 1994-11-04 1994-11-04 Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition
US08/334,712 1994-11-04
US8/334,712 1994-11-04
PCT/US1995/012993 WO1996014363A1 (en) 1994-11-04 1995-10-17 Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition

Publications (2)

Publication Number Publication Date
KR970707245A true KR970707245A (ko) 1997-12-01
KR100211079B1 KR100211079B1 (ko) 1999-07-15

Family

ID=23308478

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970702963A Expired - Fee Related KR100211079B1 (ko) 1994-11-04 1995-10-17 전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제

Country Status (15)

Country Link
US (2) US5582704A (ko)
EP (1) EP0789732B1 (ko)
JP (2) JP3110047B2 (ko)
KR (1) KR100211079B1 (ko)
CN (1) CN1128849C (ko)
AT (1) ATE182353T1 (ko)
AU (1) AU691046B2 (ko)
CA (1) CA2204434C (ko)
DE (1) DE69510951T2 (ko)
ES (1) ES2136884T3 (ko)
MY (1) MY113409A (ko)
TR (1) TR199501366A2 (ko)
TW (1) TW339352B (ko)
WO (1) WO1996014363A1 (ko)
ZA (1) ZA958960B (ko)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5789468A (en) * 1997-03-27 1998-08-04 E. I. Du Pont De Nemours And Company Internal anticratering agent for cathodic electrocoating compositions
US6017432A (en) * 1997-07-03 2000-01-25 Ppg Industries Ohio, Inc. Electrodepositable coating compositions and their use in a method of cationic electrodeposition
US6110341A (en) * 1998-10-22 2000-08-29 Ppg Industries Ohio, Inc. Electrodeposition baths containing organic phosphorous-based compounds
US6440580B1 (en) 1998-12-01 2002-08-27 Ppg Industries Ohio, Inc. Weldable, coated metal substrates and methods for preparing and inhibiting corrosion of the same
US6312812B1 (en) 1998-12-01 2001-11-06 Ppg Industries Ohio, Inc. Coated metal substrates and methods for preparing and inhibiting corrosion of the same
US6180181B1 (en) 1998-12-14 2001-01-30 Ppg Industries Ohio, Inc. Methods for forming composite coatings on substrates
US6270905B1 (en) 1999-02-16 2001-08-07 Ppg Industries Ohio, Inc. Multi-component composite coating composition and coated substrate
US6093298A (en) * 1999-02-22 2000-07-25 Ppg Industries Ohio, Inc. Electrocoating compositions containing high aspect ratio clays as crater control agents
US6190525B1 (en) * 1999-04-22 2001-02-20 Ppg Industries Ohio, Inc. Electrodeposition baths containing yttrium
US6291027B1 (en) 1999-05-26 2001-09-18 Ppg Industries Ohio, Inc. Processes for drying and curing primer coating compositions
US7011869B2 (en) * 1999-05-26 2006-03-14 Ppg Industries Ohio, Inc. Multi-stage processes for coating substrates with multi-component composite coating compositions
US6113764A (en) * 1999-05-26 2000-09-05 Ppg Industries Ohio, Inc. Processes for coating a metal substrate with an electrodeposited coating composition and drying the same
US6863935B2 (en) 1999-05-26 2005-03-08 Ppg Industries Ohio, Inc. Multi-stage processes for coating substrates with multi-component composite coating compositions
US6596347B2 (en) 1999-05-26 2003-07-22 Ppg Industries Ohio, Inc. Multi-stage processes for coating substrates with a first powder coating and a second powder coating
US6231932B1 (en) 1999-05-26 2001-05-15 Ppg Industries Ohio, Inc. Processes for drying topcoats and multicomponent composite coatings on metal and polymeric substrates
US6221441B1 (en) 1999-05-26 2001-04-24 Ppg Industries Ohio, Inc. Multi-stage processes for coating substrates with liquid basecoat and powder topcoat
US6383643B1 (en) * 1999-08-24 2002-05-07 Badger Meter, Inc. Leach-protective coatings for water meter components
US6290830B1 (en) 1999-10-29 2001-09-18 Ppg Industries Ohio, Inc. Electrodepositable coatings, aqueous rinsing systems for treating electrocoated substrates and processes related thereto
US6296706B1 (en) 1999-11-15 2001-10-02 Ppg Industries Ohio, Inc. Method and apparatus for dynamically coating a substrate
US6641666B2 (en) 1999-11-15 2003-11-04 Ppg Industries Ohio, Inc. Method and apparatus for coating a substrate
US6423774B1 (en) 2000-03-21 2002-07-23 Ppg Industries Ohio, Inc. Cationic aliphatic polyester resins and their electrodeposition
US6531043B1 (en) 2000-06-29 2003-03-11 Ppg Industries Ohio, Inc. Methods for electrocoating a metallic substrate with a primer-surfacer and articles produced thereby
US6897168B2 (en) 2001-03-22 2005-05-24 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
US7070854B2 (en) 2001-03-22 2006-07-04 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
US6908966B2 (en) 2001-03-22 2005-06-21 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
US6828014B2 (en) 2001-03-22 2004-12-07 Kimberly-Clark Worldwide, Inc. Water-dispersible, cationic polymers, a method of making same and items using same
JP3490991B2 (ja) * 2001-09-17 2004-01-26 関西ペイント株式会社 カチオン性塗料組成物
US6694804B1 (en) * 2002-09-23 2004-02-24 Ppg Industries Ohio, Inc. Method and device for evaluating and/or adjusting the cleaning performance of a cleaning liquid
US7507440B2 (en) 2005-02-23 2009-03-24 Ppg Industries Ohio, Inc. Methods of forming composite coatings
US20070029200A1 (en) * 2005-08-05 2007-02-08 Toshiaki Sakamoto Cationic electrodeposition coating composition and coated article therewith
KR100929040B1 (ko) * 2007-01-23 2009-11-26 주식회사 케이씨씨 전착 도료용 양이온성 마이크로겔의 제조 방법 및 그로부터제조된 마이크로겔을 포함하는 전착 도료 조성물
JP5441802B2 (ja) * 2009-05-26 2014-03-12 関西ペイント株式会社 カチオン電着塗料組成物
US20120082795A1 (en) 2010-10-01 2012-04-05 Ppg Industries Ohio, Inc. Method for using a primer comprising a self-emulsified polyester microgel
JP2013221865A (ja) * 2012-04-17 2013-10-28 Daiwa:Kk 多機能シート
US9522413B2 (en) 2013-02-28 2016-12-20 Ppg Industries Ohio, Inc. Methods and compositions for coating substrates
US8846156B2 (en) 2013-02-28 2014-09-30 Ppg Industries Ohio, Inc. Methods and compositions for coating substrates
US9518193B2 (en) 2014-01-27 2016-12-13 Ppg Industries Ohio, Inc. Coating processes using waterborne curable film-forming compositions containing polymers derived from natural gas raw materials
EP3191551B1 (en) 2014-09-08 2020-01-01 PPG Industries Ohio, Inc. Methods and compositions for coating substrates
CA2973766C (en) 2015-02-10 2024-02-13 Valspar Sourcing, Inc. Electrodeposition system for compositions containing inorganic bismuth
EP3390484A2 (en) 2015-12-14 2018-10-24 PPG Industries Ohio, Inc. Branched polyester-urethane resins and coatings comprising the same
EP3429763B1 (en) 2016-03-18 2021-06-02 PPG Industries Ohio, Inc. Multi-layer coatings and methods of preparing the same
US9938366B2 (en) 2016-06-10 2018-04-10 Ppg Industries Ohio, Inc. Acrylic copolymer composition prepared from vinyl ester or amide functional monomers
WO2018022788A1 (en) 2016-07-26 2018-02-01 Ppg Industries Ohio, Inc. Acid-catalyzed curable coating compositions containing 1,1-di-activated vinyl compounds and related coatings and processes
US11078376B2 (en) 2016-07-26 2021-08-03 Ppg Industries Ohio, Inc. Polyurethane coating compositions containing 1,1-di-activated vinyl compounds and related coatings and processes
EP4151689B1 (en) 2016-07-26 2024-09-04 PPG Industries Ohio, Inc. Curable compositions containing 1,1-di-activated vinyl compounds and related coatings and processes
JP6770633B2 (ja) 2016-07-26 2020-10-14 ピーピージー・インダストリーズ・オハイオ・インコーポレイテッドＰＰＧ Ｉｎｄｕｓｔｒｉｅｓ Ｏｈｉｏ，Ｉｎｃ． １，１−二活性化ビニル化合物生成物を含有する複数層硬化性組成物および関連方法
CA3039666C (en) 2016-10-28 2022-08-23 Ppg Industries Ohio, Inc. Coatings for increasing near-infrared detection distances
US10577518B2 (en) 2017-06-29 2020-03-03 Ppg Industries Ohio, Inc. Aqueous dispersions, coating compositions formed with aqueous dispersions, and multi-layer coatings
US10865326B2 (en) 2017-09-20 2020-12-15 Ppg Industries Ohio, Inc. Coating compositions, elastic barrier coatings formed therefrom, and methods of applying such coatings
US11760836B2 (en) 2018-04-21 2023-09-19 Natural Fiber Welding, Inc. Curative
KR102538880B1 (ko) 2018-04-21 2023-06-05 네추럴 파이버 웰딩 인코포레이티드 경화제
US10882951B2 (en) 2018-04-21 2021-01-05 Natural Fiber Welding, Inc. Curative and method
US11542365B2 (en) 2018-04-21 2023-01-03 Natural Fiber Welding, Inc. Curative
US12247098B2 (en) 2018-04-21 2025-03-11 Natural Fiber Welding, Inc. Curative
US11980912B2 (en) 2018-06-11 2024-05-14 Ppg Industries Ohio, Inc. Multi-layer coatings and methods of preparing the same
US11059993B2 (en) 2018-09-07 2021-07-13 Ppg Industries Ohio, Inc. Coating composition exhibiting specific gloss properties for extreme washable coatings
CN113056746B (zh) 2018-11-13 2023-12-29 Ppg工业俄亥俄公司 检测隐藏图案的方法
US11111409B2 (en) 2019-01-03 2021-09-07 Ppg Industries Ohio, Inc. Coating composition comprising self-crosslinkable core-shell particles and imparting improved stain resistance
US11561329B2 (en) 2019-01-07 2023-01-24 Ppg Industries Ohio, Inc. Near infrared control coating, articles formed therefrom, and methods of making the same
KR102229059B1 (ko) 2019-02-01 2021-03-18 주식회사 케이씨씨 전착 수지 조성물 및 이를 포함하는 전착 도료
US10836924B2 (en) 2019-03-15 2020-11-17 Ppg Industries Ohio, Inc. Coating compositions and elastic barrier coatings formed therefrom
US10829664B2 (en) 2019-03-15 2020-11-10 Ppg Industries Ohio, Inc. Coating compositions containing polythioethers and elastic barrier coatings formed therefrom
CA3145750A1 (en) * 2019-07-01 2021-01-07 Natural Fiber Welding, Inc. Curative & method
EP4010436B1 (en) 2019-08-05 2023-10-11 PPG Industries Ohio, Inc. Low temperature cure coating composition
CN115466563A (zh) * 2022-09-19 2022-12-13 枣阳新和化工有限公司 一种用于阴极双组份电泳漆生产的乳化工艺

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928156A (en) * 1969-07-10 1975-12-23 Ppg Industries Inc Process for the electrodeposition of zwitterion-containing compositions
US3799854A (en) * 1970-06-19 1974-03-26 Ppg Industries Inc Method of electrodepositing cationic compositions
US3984299A (en) * 1970-06-19 1976-10-05 Ppg Industries, Inc. Process for electrodepositing cationic compositions
US3922253A (en) * 1971-10-28 1975-11-25 Ppg Industries Inc Self-crosslinking cationic electrodepositable compositions
US3793278A (en) * 1972-03-10 1974-02-19 Ppg Industries Inc Method of preparing sulfonium group containing compositions
US3935087A (en) * 1972-12-22 1976-01-27 Ppg Industries, Inc. Method for electrodeposition of self-crosslinking cationic compositions
US3959106A (en) * 1974-03-27 1976-05-25 Ppg Industries, Inc. Method of electrodepositing quaternary sulfonium group-containing resins
JPS538568B2 (ko) * 1974-09-20 1978-03-30
CA1111598A (en) * 1976-01-14 1981-10-27 Joseph R. Marchetti Amine acide salt-containing polymers for cationic electrodeposition
US4134866A (en) * 1977-06-03 1979-01-16 Kansai Paint Company, Limited Aqueous cationic coating from amine-epoxy adduct, polyamide, and semi-blocked polyisocyanate, acid salt
ATE1293T1 (de) * 1978-12-11 1982-07-15 Shell Internationale Research Maatschappij B.V. Zusammensetzungen auf der basis hitzehaertbarer harzartiger bindemittel, deren herstellung und deren verwendung als ueberzugsmittel.
AT366400B (de) * 1979-04-09 1982-04-13 Vianova Kunstharz Ag Verfahren zur herstellung kathodisch abscheidbarer lackbindemittel
US4340523A (en) * 1979-12-21 1982-07-20 E. I. Dupont De Nemours And Company Electrocoating composition with polyhydroxyamine and epoxy
US4362847A (en) * 1980-05-22 1982-12-07 Shell Oil Company Heat-curable thermosetting resin binder compositions comprising a non-acidic resinous compound, a non-acidic polyester cross-linking agent, and a transesterification catalyst
US4432850A (en) * 1981-07-20 1984-02-21 Ppg Industries, Inc. Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition
US4423166A (en) * 1981-07-20 1983-12-27 Ppg Industries, Inc. Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition
US4420574A (en) * 1981-07-20 1983-12-13 Ppg Industries, Inc. Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition
US4468307A (en) * 1981-09-14 1984-08-28 Ppg Industries, Inc. Method of cationic electrodeposition
US4435559A (en) * 1982-08-18 1984-03-06 Ppg Industries, Inc. β-Hydroxy urethane low temperature curing agents
DE3331903A1 (de) * 1983-09-03 1985-03-21 Basf Farben + Fasern Ag, 2000 Hamburg Wasserdispergierbare bindemittel fuer kationische elektrotauchlacke und verfahren zu ihrer herstellung
US4504606A (en) * 1983-12-27 1985-03-12 Ford Motor Company Thermosetting coating composition--I
WO1993013153A1 (en) * 1983-12-27 1993-07-08 Kordomenos Panagiotis I Chain extended epoxy-ester polymeric compositions for cationic electrodeposition
US4699955A (en) * 1985-11-22 1987-10-13 E. I. Du Pont De Nemours And Company Chip resistant primer composition VI"
US4931157A (en) * 1988-02-18 1990-06-05 Ppg Industries, Inc. Epoxy resin advancement using urethane polyols and method for use thereof
US4933056A (en) * 1988-09-26 1990-06-12 Ppg Industries, Inc. Cationic electrodepositable compositions through the use of sulfamic acid and derivatives thereof
JP2788053B2 (ja) * 1989-04-07 1998-08-20 関西ペイント株式会社 カチオン電着塗料
US5283124A (en) * 1990-03-02 1994-02-01 Kansai Paint Co., Ltd. Coating resin composition
US5074979B1 (en) * 1990-06-20 1995-02-28 Ppg Industries Inc Cationic resin containing blocked isocyanate groups suitable for use in electrodeposition
US5096556A (en) * 1990-06-25 1992-03-17 Ppg Industries, Inc. Cationic microgels and their use in electrodeposition
US5416137A (en) * 1994-06-01 1995-05-16 E. I. Du Pont De Nemours And Company Cathodic electrocoating compositions having improved throw power, containing multifunctional phenols

Also Published As

Publication number Publication date
ZA958960B (en) 1997-04-23
ES2136884T3 (es) 1999-12-01
CA2204434A1 (en) 1996-05-17
DE69510951T2 (de) 2000-03-30
DE69510951D1 (de) 1999-08-26
TW339352B (en) 1998-09-01
EP0789732B1 (en) 1999-07-21
KR100211079B1 (ko) 1999-07-15
AU691046B2 (en) 1998-05-07
MX9703240A (es) 1997-07-31
AU3891895A (en) 1996-05-31
CN1128849C (zh) 2003-11-26
WO1996014363A1 (en) 1996-05-17
CN1167497A (zh) 1997-12-10
MY113409A (en) 2002-02-28
TR199501366A2 (tr) 1996-06-21
JP3110047B2 (ja) 2000-11-20
US5760107A (en) 1998-06-02
JPH10500172A (ja) 1998-01-06
JP2001026744A (ja) 2001-01-30
CA2204434C (en) 2000-07-04
ATE182353T1 (de) 1999-08-15
EP0789732A1 (en) 1997-08-20
US5582704A (en) 1996-12-10

Similar Documents

Publication Publication Date Title
KR970707245A (ko) 전착에 사용하기 적합한 양이온 수지 및 캡핑된 폴리이소시아네이트 경화제(cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition)
WO1996014363B1 (en) Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition
KR900004888A (ko) 설팜산 및 그의 유도체를 사용하는 개선된 양이온 전착도장 조성물
AU528342B2 (en) Thermosetting resinous binder compositions
EP0189728B1 (en) Oxime blocked isocyanate cross-linker for cathodic electrocoat
JPS61238872A (ja) 陰極型電着可能な樹脂組成物
KR950703616A (ko) 황화가 감소된 전착성 코팅 조성물(reduced yellowing electrodepositable coating composition)
KR920000813A (ko) 전착에 사용하기 적합한, 차단된 이소시아네이트 그룹을 함유하는 양이온 수지
US3468779A (en) Electrocoating process
KR870700084A (ko) 폴리옥시알킬렌폴리아민 반응생성물 및 이들의 양이온성 전착에서의 용도
US3640926A (en) Aqueous dispersions of epoxy resin esters and method of preparing same
KR970707244A (ko) 경화 반응성을 향상시킨 전착성 코팅 조성물(electrodepositable coating compositions having improved cure response)
KR930005392B1 (ko) 안정성 조성물 및 전기피복 방법
JPS61246399A (ja) 物品の塗装方法
EP0159363B1 (en) Self-curing resin composition
KR880001761A (ko) 조절된 필름형성 에폭시 피복물
KR880701764A (ko) 음극 전착에 의하여 적용되는 조절된 필름 두께의 에폭시 피복물
US4321305A (en) Beta-diketone-epoxy resin reaction products useful for providing corrosion resistance
US4421620A (en) Novel process for pretreating and coating metallic substrates electrophoretically
KR0173117B1 (ko) 산으로 양성자 첨가 반응시에 수희석성이 되는 중합 반응 생성물
EP0056808B1 (en) Self-curable resinous compositions useful in coating applications
AU650310B2 (en) Polyol extended cathodic electrodeposition resins
US9133350B2 (en) Anticrater agent for electrocoat composition
EP0240876A3 (en) Thermosetting aqueous anionic electrocoating composition containing epoxy phosphates
US4414068A (en) Self-curable resinous compositions useful in coating applications

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 19970503

Patent event code: PA01051R01D

Comment text: International Patent Application

A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19970617

Comment text: Request for Examination of Application

PG1501 Laying open of application
E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 19990222

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 19990429

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 19990430

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20020423

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 20030418

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 20040421

Start annual number: 6

End annual number: 6

WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid
PR1001 Payment of annual fee

Payment date: 20050421

Start annual number: 7

End annual number: 7

FPAY Annual fee payment
PR1001 Payment of annual fee

Payment date: 20060421

Start annual number: 8

End annual number: 8

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

Termination category: Default of registration fee

Termination date: 20080610