KR970070067A - 열가소성수지발포체 및 그 제조방법 - Google Patents
열가소성수지발포체 및 그 제조방법 Download PDFInfo
- Publication number
- KR970070067A KR970070067A KR1019970012335A KR19970012335A KR970070067A KR 970070067 A KR970070067 A KR 970070067A KR 1019970012335 A KR1019970012335 A KR 1019970012335A KR 19970012335 A KR19970012335 A KR 19970012335A KR 970070067 A KR970070067 A KR 970070067A
- Authority
- KR
- South Korea
- Prior art keywords
- injection
- thermoplastic resin
- foam
- plunger
- blowing agent
- Prior art date
Links
- 239000006260 foam Substances 0.000 title claims abstract 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract 9
- 229920001169 thermoplastic Polymers 0.000 title 1
- 239000004416 thermosoftening plastic Substances 0.000 title 1
- 238000002347 injection Methods 0.000 claims abstract 28
- 239000007924 injection Substances 0.000 claims abstract 28
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract 18
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract 12
- 210000004027 cell Anatomy 0.000 claims abstract 10
- 239000004014 plasticizer Substances 0.000 claims abstract 9
- 239000004604 Blowing Agent Substances 0.000 claims abstract 7
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract 7
- 239000001569 carbon dioxide Substances 0.000 claims abstract 7
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract 6
- 239000007789 gas Substances 0.000 claims abstract 4
- 238000001746 injection moulding Methods 0.000 claims abstract 4
- 238000001816 cooling Methods 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims abstract 3
- 229920005989 resin Polymers 0.000 claims abstract 3
- 239000011347 resin Substances 0.000 claims abstract 3
- 239000002344 surface layer Substances 0.000 claims abstract 3
- 210000003855 cell nucleus Anatomy 0.000 claims abstract 2
- 239000010410 layer Substances 0.000 claims abstract 2
- 238000010309 melting process Methods 0.000 claims abstract 2
- 239000011342 resin composition Substances 0.000 claims 4
- 238000005187 foaming Methods 0.000 claims 2
- 238000002156 mixing Methods 0.000 claims 2
- 238000007664 blowing Methods 0.000 claims 1
- 238000007872 degassing Methods 0.000 claims 1
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/3469—Cell or pore nucleation
- B29C44/348—Cell or pore nucleation by regulating the temperature and/or the pressure, e.g. suppression of foaming until the pressure is rapidly decreased
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
- B29C44/04—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities
- B29C44/0415—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles consisting of at least two parts of chemically or physically different materials, e.g. having different densities by regulating the pressure of the material during or after filling of the mould, e.g. by local venting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
- B29C44/34—Auxiliary operations
- B29C44/36—Feeding the material to be shaped
- B29C44/38—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length
- B29C44/42—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum
- B29C44/421—Feeding the material to be shaped into a closed space, i.e. to make articles of definite length using pressure difference, e.g. by injection or by vacuum by plastizising the material into a shot cavity and injecting using a plunger
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/122—Hydrogen, oxygen, CO2, nitrogen or noble gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/13—Cell size and distribution control while molding a foam
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Abstract
Description
Claims (10)
- 내부층이 평균셀직경이 0.01~50㎛, 평균셀밀도가 108~1016개/㎠인 발포부분과, 표면층에 두께 10~1,000㎛의 이발포부분과 일체화한 미발포부분을 가진 것을 특징으로 하는 열가소성수지발포사출성형체.
- 제1항에 있어서, 평균셀직경이 0.01~20㎛, 평균셀밀도가 108~1016개/㎠인 것을 특징으로 하는 열가소성수지발포사출성형체.
- (Ⅰ) 발포제를 공급하는 라인을 가진 연속가소화장치(1)내에서, 100~450℃에서 열가소성수지 100중량부를 용융하고, 초임계상태의 2산화탄소 및/또는 질소를, 열가소성수지 100중량부를 용융하고, 초임계상태의 2산화탄소 및/또는 질소를, 열가소성수지 100중량부당 0.1~30중량부 첨가해서, 열가소성수지와 초임계상태의 2산화탄소 및/또는 질소의 상용상태의 용융수지조성물을 형성하는 가스용해공정, (Ⅱ) 연속가소화장치(1)내에서, 상기 2산화탄소 및/또는 질소의 임계압력이상의 압력을 유지한 그대로 이 용융수지조성물을 50~300℃의 온도로 내리는 냉각공정, (Ⅲ) 연속가소화장치(1)에 접속한 사출플런저(6)를 가진 사출장치(7)에 의해, 냉각한 이 용융수지조성물을 계량하고, 금형(8)내에 충전하는 계량사출공정, 및 (Ⅳ)금형(8)내의 압력을 2산화탄소 및/또는 질소의 상기 임계압력이하의 압력으로 저하하므로서 셀핵을 발생시키고, 이 셀직경을 제어하는 발포제어공정으로 이루어지고, 계량사출공정까지는, 2산화탄소 및/또는 질소의 초임계상태를 유지하고, 또한 연속가소화장치(1)에 의한 가스용해공정 및 냉각공정과 사출장치(7)에 의한 계량사출공정을 독립적으로 행하는 것을 특징으로 하는 청구항 1 또는 청구항 2에 기재된 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 발포제를 공급하는 라인을 가진 연속가소화장치(1)와, 사출플런저(6)를 가진 사출장치(7)의 사이에, 개폐밸브(5)를 개재해서 사출장치(7)와 선택적으로 접속되는 이 연속가소화장치(1)의 유출로에 접속된, 혼합부를 가진 어댑터(2)를 설치하는 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 두께가 0.5~50㎜의 발포체가 제조가능한 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 두께가 10~50㎜의 발포체가 제조가능한 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 발포제어공정을, 용융수지조성물을 사출한 후에 금형(8)내에 충전한 고압가스의 탈가스 및/또는 금형(8)의 코어의 적어도 일부의 후퇴에서 행하는 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 열가소성수지에 또 정포제를 0.1~10중량부 첨가하는 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제3항에 있어서, 발포제를 공급하는 라인을 가진 연속가소화장치(1)와, 사출플런저(6)를 가진 사출장치(7)의 사이에, 개폐밸브(5)를 개재해서 사출장치(7)와 선택적으로 접속되는, 플런저를 가진 수지어큠레이터장치(4)를 설치하는 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.
- 제9항에 있어서, 혼합부를 가진 어댑터(2)와, 사출플런저(6)를 가진 사출장치(7)의 사이에, 개폐밸브(5)를 개재해서 사출장치(7)와 선택적으로 접속되는, 플런저를 가진 수지어큠레이터장치(4)를 설치하는 것을 특징으로 하는 열가소성수지발포사출성형체의 제조방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8249396 | 1996-04-04 | ||
JP96-82493 | 1996-04-04 | ||
JP33970296 | 1996-12-19 | ||
JP96-339702 | 1996-12-19 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR970070067A true KR970070067A (ko) | 1997-11-07 |
KR100200201B1 KR100200201B1 (ko) | 1999-06-15 |
Family
ID=26423502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019970012335A KR100200201B1 (ko) | 1996-04-04 | 1997-04-03 | 열가소성수지발포체 및 그 제조방법 |
Country Status (7)
Country | Link |
---|---|
US (1) | US5997781A (ko) |
EP (1) | EP0799853B2 (ko) |
KR (1) | KR100200201B1 (ko) |
CN (1) | CN1104316C (ko) |
DE (1) | DE69724688T3 (ko) |
MY (1) | MY119010A (ko) |
TW (1) | TW438848B (ko) |
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- 1997-04-01 MY MYPI97001411A patent/MY119010A/en unknown
- 1997-04-01 TW TW086104152A patent/TW438848B/zh not_active IP Right Cessation
- 1997-04-03 EP EP97302308A patent/EP0799853B2/en not_active Expired - Lifetime
- 1997-04-03 KR KR1019970012335A patent/KR100200201B1/ko not_active IP Right Cessation
- 1997-04-03 DE DE69724688T patent/DE69724688T3/de not_active Expired - Lifetime
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CN1170662A (zh) | 1998-01-21 |
DE69724688T3 (de) | 2008-01-24 |
DE69724688T2 (de) | 2004-07-29 |
CN1104316C (zh) | 2003-04-02 |
DE69724688D1 (de) | 2003-10-16 |
TW438848B (en) | 2001-06-07 |
US5997781A (en) | 1999-12-07 |
MY119010A (en) | 2005-03-31 |
EP0799853B2 (en) | 2007-07-11 |
EP0799853B1 (en) | 2003-09-10 |
EP0799853A1 (en) | 1997-10-08 |
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