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KR970059230A - 굴곡상에서 매우 유연한 폴리아미드 및 폴리올레핀 기재의 조성물 - Google Patents

굴곡상에서 매우 유연한 폴리아미드 및 폴리올레핀 기재의 조성물 Download PDF

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Publication number
KR970059230A
KR970059230A KR1019970003110A KR19970003110A KR970059230A KR 970059230 A KR970059230 A KR 970059230A KR 1019970003110 A KR1019970003110 A KR 1019970003110A KR 19970003110 A KR19970003110 A KR 19970003110A KR 970059230 A KR970059230 A KR 970059230A
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South Korea
Prior art keywords
composition according
copolymer
composition
ethylene
maleic anhydride
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Ceased
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KR1019970003110A
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Inventor
알랭 부일루
프랑수와 페르나귀
Original Assignee
니일 앙리
엘프 아토켐 에스. 에이.
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Publication of KR970059230A publication Critical patent/KR970059230A/ko
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Laminated Bodies (AREA)

Abstract

본 발명은 하기 : -하나이상의 폴리아미드 (A) -폴리아미드 블럭 및 폴리에테르 블럭으로 이루어진 하나이상의 중합체 (B) -하나이상의 폴리올레핀 (C) -하나이상의 폴리올레핀 (D) 및 ISO 178-93에 따른 굴곡 모듈러스가 폴리아미드 (A)의 굴곡 모듈러스의 0.05 내지 0.3배인 것으로 이루어진 조성물에 관한 것이다.
상세하게는, 170 내지 350 MPa 사이의 굴곡 모듈러스를 갖는 폴리아미드를 수득할 수 있다.

Description

굴곡상에서 매우 유연한 폴리아미드 및 폴리올레핀 기재의 조성물
내용없음

Claims (13)

  1. -하나이상의 폴리아미드 (A) -폴리아미드 블럭 및 폴리에테르 블럭으로 이루어진 하나이상의 중합체 (B) -하나이상의 폴리올레핀 (C) -하나이상의 폴리올레핀 (D)으로 이루어져 있으며, 온도의 기능(DMA)으로서 인장 동적 모듈러스에서 중합체 (A), (C) 및 기재하고 (B)는 함유하지 않는 동일한 크기의 실온에서 굴곡 모듈러스를 갖는 조성물보다 감소가 작을 것을 특징으로 하는 조성물.
  2. 제1항에 있어서, ISO 178-93에 따른 조성물의 굴곡 모듈러스가 (A)의 굴곡 모듈러스의 0.05 내지 0.3배인 것을 특징으로 하는 조성물.
  3. 제1항 또는 2항에 있어서, (A)가 PA-6 또는 PA-6.6인 것을 특징으로 하는 조성물.
  4. 제1항 또는 2항에 있어서, (B)가 PA-6 및 PTMG 블럭으로 이루어진 공중합체인 것을 특징으로 하는 조성물.
  5. 제1항 또는 2항에 있어서, (C)가 LLDPE, VLDPE, 폴리프로필렌, 에틸렌/비닐 아세테이트 공중합체 또는 에틸렌/알킬 (메트)아크릴레이트 공중합체인 것을 특징으로 하는 조성물.
  6. 제1항 또는 2항에 있어서, (D)는 에틸렌/알킬 (메티)아크릴레이트/말레산 무수물 공중합체, 에틸렌/비닐 아세테이트/말레산 무수물 공중합체 또는 에틸렌-프로필렌 공중합체로부터 선택되고, 대부분 프로필렌, 말레산 무수물과 그래프트되고 모노아미노화된 폴리아미드-6 또는 모노아미네이트 카르로락탐 올리고머로써 축합되는 것으로부터 선택되는 것을 특징으로 하는 조성물.
  7. 제1항 또는 2항에 있어서, 50%≤A+B≤80%, 20%≤C+D≤50%, 총 100 중량%인 것을 특징으로 하는 조성물.
  8. 제7항에 있어서, 0.06≤A/B≤15인 것을 특징으로 하는 조성물.
  9. 제7항에 있어서, 0.1≤D/C≤0.5인 것을 특징으로 하는 조성물.
  10. 제1항 또는 2항에 있어서, 55%≤A+B≤65%, 35%≤C+D≤45%, 총 100%, 0.05≤A/B≤5, 0.2≤D/C≤0.3, (A)는 PA-6 또는 PA-6.6, (B)는 PA-6 블럭 및 PTMG 블럭을 함유한 공중합체, (C)는 VLDPE, (D)는 에틸렌/알킬 (메트)아크릴레이트/말레산 무수물 공중합체인 것을 특징으로 하는 조성물.
  11. 필름, 파이프, 팔넬 또는 다양한 형태의 성분과 같이 제1항 내지 10항중 어느 한 항에 따른 조성물로부터 제조된, 성형, 압출 또는 블로우된 물질.
  12. 제2항에 있어서, ISO 178-93에 따른 조성물의 굴곡 모듈러스가 150 내지 750 MPa인 것을 특징으로 하는 조성물.
  13. 제8항에 있어서, 0.05≤A/B≤12인 것을 특징으로 하는 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970003110A 1996-01-31 1997-01-31 굴곡상에서 매우 유연한 폴리아미드 및 폴리올레핀 기재의 조성물 Ceased KR970059230A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9601144 1996-01-31
FR9601144 1996-01-31

Publications (1)

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KR970059230A true KR970059230A (ko) 1997-08-12

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EP (1) EP0787771A1 (ko)
JP (1) JPH09241503A (ko)
KR (1) KR970059230A (ko)
CA (1) CA2196445A1 (ko)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10168298A (ja) * 1996-12-10 1998-06-23 Elf Atochem Japan Kk 熱可塑性樹脂組成物及び成形品
FR3012816B1 (fr) 2013-11-05 2017-12-08 Arkema France Composition thermoplastique resistante aux chocs
FR3051475B1 (fr) * 2016-05-17 2020-02-21 Arkema France Composition transparente resistante aux chocs

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2580656B1 (fr) * 1985-04-23 1987-09-11 Charbonnages Ste Chimique Compositions thermoplastiques multiphases et articles obtenus
FR2592388B1 (fr) * 1985-12-30 1988-02-26 Atochem Alliages a base de polyamide, polyetheramide et elastomere thermoplastique
FR2689514B1 (fr) * 1992-04-03 1994-05-20 Elf Atochem Sa Composition thermoplastique multiphase a base de resine polyamide contenant un polymere d'ethylene a fonction epoxyde.
US5416171A (en) * 1993-03-22 1995-05-16 Industrial Technology Research Institute Blending compositions of polyamides and block copolyetheramides

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JPH09241503A (ja) 1997-09-16
CA2196445A1 (fr) 1997-08-01
EP0787771A1 (fr) 1997-08-06

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