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KR960703371A - COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE - Google Patents

COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE

Info

Publication number
KR960703371A
KR960703371A KR1019950705968A KR19950705968A KR960703371A KR 960703371 A KR960703371 A KR 960703371A KR 1019950705968 A KR1019950705968 A KR 1019950705968A KR 19950705968 A KR19950705968 A KR 19950705968A KR 960703371 A KR960703371 A KR 960703371A
Authority
KR
South Korea
Prior art keywords
composite structure
elastomer
thermoplastic polymer
thermoplastic
vulcanized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
KR1019950705968A
Other languages
Korean (ko)
Inventor
쎄르 마르띤느
에르 마리우스
두쏭 크리스띠앙
Original Assignee
앙리 니일
엘프 아토켐 에스.에이.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 앙리 니일, 엘프 아토켐 에스.에이. filed Critical 앙리 니일
Publication of KR960703371A publication Critical patent/KR960703371A/en
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/02—Temperature
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00—Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/04—Time
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2437/00—Clothing
    • B32B2437/02—Gloves, shoes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oral & Maxillofacial Surgery (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Thermal Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Road Paving Structures (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 열가소성 시퀸스-함유 중합체와 직접 회합된, 카르복시산 작용기를 함유하는 기황화된 엘라스토머로 이루어진 복합구조물에 관한 것이다. 또한 본 발명은 열가소성 중합체 상에서 엘라스토머를 현장에서 가황화시키는 것으로 구성되는 제조방법에 관한 것이다.FIELD OF THE INVENTION The present invention relates to composite structures consisting of sulfurized elastomers containing carboxylic acid functionality, directly associated with thermoplastic sequence-containing polymers. The present invention also relates to a production process consisting in the field vulcanization of an elastomer on a thermoplastic polymer.

Description

엘라스토머 및 열가소성 중합체로 구성되는 복합구조물, 그의 제조 방법 및 상기 구조물을 포함하는 물품[COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE)COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE

본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음As this is a public information case, the full text was not included.

Claims (19)

폴리에스테르, 폴리에테르 또는 폴리우레탄 시퀸스에 의해 분리된 폴리아마드 시퀸스를 함유하는 공중합체를 배제한, 시퀸스를 함유하는 열가소성 중합ㄹ체와 직접 화합된, 카르복시산 작용기를 함유하는 가황화된 엘라스토머로 이루어진 복합구조물.Composite structure consisting of vulcanized elastomers containing carboxylic acid functional groups, directly compounded with thermoplastic polymers containing sequences, excluding copolymers containing polyamide sequences separated by polyester, polyether or polyurethane sequences . 제1항에 있어서, 응집 파단을 나타내는 복합구조물.The composite structure of claim 1 exhibiting cohesive failure. 제1 또는 2항에 있어서, 앨라스토머가 단독으로 또는 혼합물로서 카르복시화 니트릴 엘라스토머, 아크릴산 엘라스토머, 카르복시화 폴리부타디엔, 그라프팅된 에틸렌/프로필렌/디엔 삼원공중합체 또는 그라프팅되지 않은 상기 엘라스토머와 상기 중합체들의 혼합물, 예컨대 니트릴 고무, 폴리부타디엔, 에틸렌/프로필렌/디엔 삼원공중합체로 구성되는 군으로부터 선택되는 복합구조물.3. The method of claim 1 or 2, wherein the elastomer, alone or as a mixture, comprises a carboxylated nitrile elastomer, an acrylic acid elastomer, a carboxylated polybutadiene, a grafted ethylene / propylene / diene terpolymer or the grafted elastomer and Mixtures of polymers such as nitrile rubber, polybutadiene, ethylene / propylene / diene terpolymers. 제1 내지 3항 중 어느 한 항에 있어서, 상기 가황화 엘라스토머는 엘라스토머를 기준으로 카르복시산기 0.3 내지 10중량 퍼센트를 함유하며 카르복시산 기의 중량은 유리 산 형태로 계산되는 복합구조물.The composite structure of claim 1, wherein the vulcanized elastomer contains from 0.3 to 10 weight percent carboxylic acid groups based on the elastomer and the weight of the carboxylic acid groups is calculated in free acid form. 제1 내지 4항 중 어느 한 항에 있어서, 시퀸스를 함유하는 열가소성 중합체가, 상기 시퀸스가 폴리머디올 시퀸스인 중합체인 복합구조물.The composite structure of claim 1, wherein the thermoplastic polymer containing the sequence is a polymer wherein the sequence is a polymerdiol sequence. 제1 내지 5항중 어느 한 항에 있어서, 열가소성 중합체가 120℃ 내지 250℃, 바람직하게 140 내지 220℃로 이루어지는 융점을 갖는 복합구조물.The composite structure according to claim 1, wherein the thermoplastic polymer has a melting point of 120 ° C. to 250 ° C., preferably 140 to 220 ° C. 7. 제1 내지 8항 중 어느 한 항에 있어서, 시퀸스를 함유하는 열가소성 중합체가 80 내지 200℃, 바람직하게 120 내지 170℃로 이루어진 비카트 포인트를 갖는 복합구조물.The composite structure according to claim 1, wherein the thermoplastic polymer containing the sequence has a vicat point consisting of 80 to 200 ° C., preferably 120 to 170 ° C. 10. 제1 내지 7항 중 어느 한 항에 있어서, 시퀸스를 함유하는 열가소성 중합체가 단독으로 또는 혼합물로 폴리에테르에스테르, 폴리우레탄에테르, 폴리우레탄에스테르, 폴리우레탄에테르에스테르로 구성되는 군으로 부터 선택되는 복합구조물.The composite structure according to any one of claims 1 to 7, wherein the thermoplastic polymer containing the sequence is selected from the group consisting of polyether esters, polyurethane ethers, polyurethane esters, polyurethane ether esters, alone or in mixtures. . 제1 내지 8항 중 어느 한 항에 있어서, 가황화된 엘라스토머 및/또는 열가소성 중합체는 충전제를 포함하는데, 상기 충전제는 엘라스토머 100부 당 100부 이하에 이르는 양으로 제공되는 복합구조물.The composite structure of claim 1, wherein the vulcanized elastomer and / or thermoplastic polymer comprises a filler, the filler being provided in an amount up to 100 parts per 100 parts of elastomer. 제1 내지 9항 중 어느 한 항에 있어서, 적충체의 형태인 복합구조물.10. The composite structure of any one of claims 1 to 9 in the form of a antagonist. 열가소성 중합체를 용융시키지 않고 열가소성 중합체에 대한 엘라스토머의 현장 가황화로 이루어짐을 특징으로 하는, 제1 내지 10항 중 어느 한 항에 따른 복합구조물 제조 방법.The process for producing a composite structure according to any one of claims 1 to 10, characterized by in situ vulcanization of the elastomer to the thermoplastic polymer without melting the thermoplastic polymer. 제11항에 있어서, 하기 단계들로 이루어지는 방법: (ⅰ) 열가소성 공중합체 형성단계; (ⅱ) 금형내 상기 열가소성 공중합체를 배치시키는 단계; (ⅲ) 가황화계를 함유하는 비- 가황화 엘라스토머 첨가 단계; 및 (ⅳ) 현장 가황화 수행 단계.12. The method of claim 11, comprising the following steps: (i) forming a thermoplastic copolymer; (Ii) placing the thermoplastic copolymer in a mold; (Iii) adding a non-vulcanized elastomer containing a vulcanized system; And (iii) performing field vulcanization. 제12항에 있어서, 열가소성 중합체가 금형내에서 직접 형성되는 방법.The method of claim 12, wherein the thermoplastic polymer is formed directly in the mold. 제11 내지 13항 중 어느 한 항에 있어서, 가황하는 열가소성 공중합체의 비카트 포인트에 상응하는 값 내지 상기 열가소성 중합체의 융점 이하의 값으로 이루어지는 온도에서 수행되어 열가소성 중합체가 금형에 접착하지 않으며, 그럼에도 불구하고 상기 값은 가황화하기에 충분한 방법.The method according to any one of claims 11 to 13, wherein the thermoplastic polymer does not adhere to the mold by being carried out at a temperature that consists of a value corresponding to the bit cart point of the vulcanized thermoplastic copolymer up to a value less than or equal to the melting point of the thermoplastic polymer. Nevertheless the value is sufficient to vulcanize. 제11 내지 14항 중 어느 한 항에 있어서, 현장 가황화는 130 내지 180℃의 온도에서 수횅되는 방법.The process according to claim 11, wherein the in situ vulcanization is carried out at a temperature of 130 to 180 ° C. 16. 제11 내지 15항 중 어느 한 항에 있어서, 가황화 특성 시간, t90은 15분 이하, 및 바람직하게 5 내지 10분인 방법.The method according to any one of claims 11 to 15, wherein the vulcanization time, t90 is 15 minutes or less, and preferably 5 to 10 minutes. 제11 내지 16항 중 어느 한 항에 있어서, 가황화 개시 시간은 4 내지 6분인 방법The method according to any one of claims 11 to 16, wherein the vulcanization start time is 4 to 6 minutes. 제1 내지 11항 중 어느 한 항에 따른 복합구조물에 의해 적어도 부분적으로 형성된 스포츠화용 밑창Outsole for sports shoes formed at least in part by the composite structure according to any one of claims 1 to 11. 제1 내지 11항 중 어느 한 항에 따른 복합구조물에 의해 적어도 부분적으로 형성된 스포츠 물품.A sporting article at least partially formed by the composite structure according to claim 1. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.※ Note: The disclosure is based on the initial application.
KR1019950705968A 1993-06-28 1994-06-28 COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE Ceased KR960703371A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR93/07850 1993-06-28
FR9307850 1993-06-28
PCT/FR1994/000781 WO1995000331A1 (en) 1993-06-28 1994-06-28 Composite structure comprising an elastomer and a thermoplastic polymer, method of preparation and object containing said structure

Publications (1)

Publication Number Publication Date
KR960703371A true KR960703371A (en) 1996-08-17

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KR1019950705968A Ceased KR960703371A (en) 1993-06-28 1994-06-28 COMPOSITE STRUCTURE COMPRISING AN ELASTOMER AND A THERMOPLASTIC POLYMER, METHOD OF PREPARATION AND OBJECT CONTAINING SAID STRUCTURE

Country Status (9)

Country Link
EP (1) EP0706454A1 (en)
JP (2) JPH08511741A (en)
KR (1) KR960703371A (en)
CN (1) CN1128971A (en)
AU (1) AU678491B2 (en)
CA (1) CA2166215A1 (en)
FI (1) FI956268A7 (en)
NO (1) NO955316L (en)
WO (1) WO1995000331A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3277497A (en) * 1996-07-05 1998-02-02 Dsm N.V. Vulcanized rubber product
KR100356150B1 (en) * 2000-02-15 2002-10-11 한국신발피혁연구소 Manufacture method of footwear out sole of using heating-cooling
ES2168979B1 (en) * 2000-08-11 2003-09-16 Indesproin S L COMPACTED MATERIAL THAT INCLUDES AN ELASTOMERO OF POLYURETHANE AND RUBBER, A PROCEDURE FOR ITS OBTAINING AND APPLICATIONS.
FR2918065B1 (en) * 2007-06-28 2011-04-15 Michelin Soc Tech PROCESS FOR THE PREPARATION OF POLYETHER BLOCK DIENE COPOLYMER, REINFORCED RUBBER COMPOSITION AND PNEUMATIC WRAPPING.
JP5705427B2 (en) 2008-12-11 2015-04-22 美津濃株式会社 Shoe sole and method of manufacturing shoe sole
BR112013021937B1 (en) 2011-03-11 2020-12-08 Daicel-Evonik Ltd. sheet, composite article shaped like a shoe sole, and process for producing a composite article shaped like a shoe sole
EP3981280B1 (en) * 2016-11-09 2024-07-31 NIKE Innovate C.V. An article comprising a reflowed material and an anionic dyed element, and processes for making the same

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1426735A (en) * 1972-06-15 1976-03-03 Dunlop Ltd Composite structures
GB2040223B (en) * 1978-12-27 1983-05-25 Asahi Chemical Ind Laminate with inerlaminate adhesion
AU607718B2 (en) * 1986-10-30 1991-03-14 Mitsui Chemicals, Inc. Laminated and molded article prepared therefrom
FR2685660A1 (en) * 1991-12-31 1993-07-02 Atochem PROCESS FOR PREPARING COMPOSITE MATERIAL FORMED OF A VULCANIZED ELASTOMER ASSOCIATED WITH A THERMOPLASTIC ELASTOMER HAVING A POLYAMIDE SEQUENCE AND COMPOSITE MATERIAL.

Also Published As

Publication number Publication date
NO955316L (en) 1996-02-06
AU678491B2 (en) 1997-05-29
EP0706454A1 (en) 1996-04-17
CA2166215A1 (en) 1995-01-05
FI956268A0 (en) 1995-12-27
JPH11245339A (en) 1999-09-14
AU7128394A (en) 1995-01-17
CN1128971A (en) 1996-08-14
JPH08511741A (en) 1996-12-10
WO1995000331A1 (en) 1995-01-05
FI956268L (en) 1996-02-23
NO955316D0 (en) 1995-12-27
FI956268A7 (en) 1996-02-23

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