KR960701980A - 과립화 공정 전의 액상 비이온성 계면활성제의 구조화 방법(Structuring liquid nonionic surfactants prior to granulation process) - Google Patents
과립화 공정 전의 액상 비이온성 계면활성제의 구조화 방법(Structuring liquid nonionic surfactants prior to granulation process)Info
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C11D17/065—High-density particulate detergent compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3792—Amine oxide containing polymers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/525—Carboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain two or more hydroxy groups per alkyl group, e.g. R3 being a reducing sugar rest
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Abstract
기술된 발명은 중합체를 포함하는 구조화제를 비이온성 계면활성제에 용해시켜 유입가능한 예비혼합물을 생성시키고 예비혼합물의 점도가, 처리 온도 및 25s-1의 전단속도에서 측정할 경우,350mPas 이상인 주어진 처리온도에서 예비혼합물을 유효량의 분말로 미세 분산시켜 벌크 밀크가 650g/ℓ이상인 과립상 세탁 세제 성분 또는 조성물을 제조하는 방법이다. 바람직한 구조화제는 하나 이상의 작용성 하이드록실 그룹을 갖는 중합체,특히 폴리비닐알큘, 폴리하이드록시아크릴산 중합체, 및 폴리비닐 피롤리돈 및 PVNO와 같은 중합체 뿐만 아니라, 망, 인공 감미제 및 이의 유도체를 포함한다. 다음에 예비혼합물을 과립상세제로 적합한 방법으로 가공한다. 예비혼합물을 과립상 기제 생성물에 미세 분산 혼합, 응집 또는 분무하는 것이 바람직하다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (15)
- a)중합체를 모합하는 구조화제(structuring agent)를 비이온성 계면활성제에 용해시켜 유입 가능한 예비혼합물을 생성시키는 단계 및 b)예비혼합물의 미세 분산을 예비혼합무의 점도가, 처리 온도 및 25s-1의 전단속도에서 측정할 켱우,350mPas 이상인 처리 온도에서 수행함을 특징으로 하여 예비혼합물을 유효량이 분말로 미세 분산시키는 단계를 포함하여 벌크 밀크가 650g/ℓ 이상인 과립상 세탁 세제 성분 또는 조성물을 제조하는방법.
- 제1항에 있어서, 구조화제가 하이드록시 작용성 그룹을 하나 이상 갖는 성분을 하나 이상 포함하는 방법.
- 제1항 또는 제2항에 있어서, 구조화제가 폴리비닐 피롤리돈, PVNO, 폴리비닐 알콜, 폴리하이드록시아크릴산 중합체 및 이의 혼합물로 이루어진 그룹으로부터 선택된 성분을 하나 이상 포함하는 방법.
- 제2항 또는 제3항에 있어서, 구조화제가 덱스트로스, 락토스, 스크로스, 사카린 및 폴리하이드록시 지방산 아미드를 포함하는 유도체로 이루어진 그룹으로부터 선택된 성분을 하나이상 포함하는 방법.
- 제1항 내지 제4항 중의 어느 한 항에 있어서, 구조화제가 프탈이미드, 파라-톨루엔 설폰아미드, 말레이미드 및 이의 혼합물로 이루어진 그룹으로부터 선택된 성분을 하나 이상 포함하는 방법.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, 구조화제가 분자량이 2,000 이상인 중합체임을 특징으로 하는 방법.
- 제1항 내지 제6항 중의 어느 한 항에 있어서, 과립상 세탁 세제 성분 또는 조성물이 비이온성 계면활성제를 10중량% 이상 포함하는 방법.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 단계 b)의 분말이 제올라이트, 실리카, 탄산염, 규산염, 황산염, 인산염, 시트르산염, 시트르산 및 이의 혼합물로 이루어진 그룹으로부터 선택되는 방법.
- a)중합체를 포함하는 구조화제를 비이온성 계면활성제에 용해시켜 예비혼합물을 생성시키는 단계 및 b)예비혼합물을 예비혼합물의 점도가, 처리 온도 및 25s-1의 전단 속도에서 측정할 경우,350mPas 이상인 처리온도에서 분무함을 특징으로 하여 예비혼합물을 저전단 혼합기 또는 회전 드럼에서 분말 위에 분무하여 예비혼합물을 유효량의 분말과 혼합하는 단계를 포함하여 과립상 세탁 세제 성분 또는 조성물을 제조하는 방법.
- 제9항에 있어서, 단계 b)의 분말이 분무 건조, 응집 또는 이의 병용에 의해 제조된 입자를 포함하는 과립상 세제인 방법.
- a)구조화제를 비이온성 계면활성제에 용해시켜 유입가능한 예비혼합물을 생성시키는 단계 및 b)예비혼합물의 미세 분산을 예비혼합률의 점도가, 처리 온도 및 25s-1의 전단 속도에서 측정할 경우,350mPas 이상인 처리 온도에서 수행하고 분말의 일부 이상은 수화가능한 형태임을 특징으로 하여 예비혼합물을 유효량의 분말로 미세분산시키는 단계 및 c)물을 단계 b)의 생성물 위에 분무하는 단계를 포함하여 벌크 밀도가650g/ℓ 이상인 과립상 세탁 세제 성분 또는 조성물을 제조하는 방법.
- i)비이온성 계면활성제 10 내지 50중량%, ii)당 및 인공 감미제, 폴리비닐 알콜, 폴리하이드록시 아크릴산 중합체 및 이의 유도체;및 폴리비닐 피롤리돈, PVNO, 프탈이미드, 파라-톨루엔 설폰아미드, 말레이미드 및 이의 혼합물로 이루어진 그룹으로부터 선택된 구조화제 5 내지 30중량%를 포함하며 벌크 밀도가 650g/ℓ이상인 세제 성분 또는 조성물.
- 제12항에 있어서, 비이온성 계면활성제 대 구조화재의 비가 20:1 내지 1:1인 세제 성분 또는 조성물.
- 제12항 또는 제13항에 있어서, 비이온성 계면활성제가 탄소수 8 내지 20의 쇄 길이를 갖고 알콜 분자당에 톡시 그룹을 평균 1 내지 25개, 바람직하게는 2 내지 10개 갖는 에톡시화 알콜을 포함하는 세제 성분 또는 조성물.
- 제14항에 있어서, 비이온성 계면활성제가 40℃ 미만의 온도에서 액체인 세제 성분 또는 조성물.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93870075.4 | 1993-04-30 | ||
EP93870075A EP0622454A1 (en) | 1993-04-30 | 1993-04-30 | Structuring liquid nonionic surfactants prior to granulation process |
PCT/US1994/004843 WO1994025553A1 (en) | 1993-04-30 | 1994-04-29 | Structuring liquid nonionic surfactants prior to granulation process |
Publications (1)
Publication Number | Publication Date |
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KR960701980A true KR960701980A (ko) | 1996-03-28 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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KR1019950704756A Withdrawn KR960701980A (ko) | 1993-04-30 | 1994-04-29 | 과립화 공정 전의 액상 비이온성 계면활성제의 구조화 방법(Structuring liquid nonionic surfactants prior to granulation process) |
Country Status (15)
Country | Link |
---|---|
EP (1) | EP0622454A1 (ko) |
JP (1) | JP2888983B2 (ko) |
KR (1) | KR960701980A (ko) |
CN (1) | CN1125462A (ko) |
AU (1) | AU693445B2 (ko) |
CA (1) | CA2160662C (ko) |
CZ (1) | CZ283895A3 (ko) |
EG (1) | EG20591A (ko) |
FI (1) | FI955143A7 (ko) |
HU (1) | HU216904B (ko) |
MA (1) | MA23182A1 (ko) |
NO (1) | NO954308L (ko) |
PE (1) | PE54094A1 (ko) |
PH (1) | PH31661A (ko) |
WO (1) | WO1994025553A1 (ko) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0643130B2 (en) * | 1993-09-13 | 2007-09-19 | The Procter & Gamble Company | Granular detergent compositions comprising nonionic surfactant and process for making such compositions |
GB9404821D0 (en) * | 1994-03-11 | 1994-04-27 | Unilever Plc | Detergent composition |
EP0765378A1 (en) * | 1994-06-13 | 1997-04-02 | The Procter & Gamble Company | Detergent composition containing anionic surfactants and water-soluble saccharides |
CA2208675C (en) * | 1995-01-26 | 2001-03-27 | The Procter & Gamble Company | Process for the manufacture of granular detergent compositions comprising nonionic surfactant |
US5858957A (en) * | 1995-01-26 | 1999-01-12 | The Procter & Gamble Company | Process for the manufacture of granular detergent compositions comprising nonionic surfactant |
EP0861318B1 (en) * | 1995-09-04 | 2001-11-14 | Unilever Plc | Detergent compositions and process for preparing them |
US5726139A (en) * | 1996-03-14 | 1998-03-10 | The Procter & Gamble Company | Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality |
ES2162324T3 (es) * | 1996-08-26 | 2001-12-16 | Procter & Gamble | Procedimiento de secado por pulverizacion para producir composiciones detergentes que implican premezclar polimeros de poliaminas modificadas. |
CA2264306A1 (en) * | 1996-08-26 | 1998-03-05 | The Procter & Gamble Company | Agglomeration process for producing detergent compositions involving premixing modified polyamine polymers |
GB9618877D0 (en) * | 1996-09-10 | 1996-10-23 | Unilever Plc | Process for preparing high bulk density detergent compositions |
GB9618875D0 (en) * | 1996-09-10 | 1996-10-23 | Unilever Plc | Process for preparing high bulk density detergent compositions |
US5733863A (en) * | 1997-01-17 | 1998-03-31 | The Procter & Gamble Company | Process for making a free-flowing particule detergent admix containing nonionic surfactant |
WO1999011749A1 (en) * | 1997-08-28 | 1999-03-11 | The Procter & Gamble Company | Agglomeration process for producing a particulate modifier polyamine detergent admix |
DE59711728D1 (de) * | 1997-09-11 | 2004-07-22 | Henkel Kgaa | Verfahren zur herstellung teilchenförmiger wasch- oder reinigungsmittel |
GB9805193D0 (en) * | 1998-03-10 | 1998-05-06 | Unilever Plc | Process for preparing granular detergent compositions |
DE10021113A1 (de) * | 2000-05-02 | 2001-11-15 | Henkel Kgaa | Partikuläre Compounds, enthaltend nichtionische Tenside |
GB0111863D0 (en) | 2001-05-15 | 2001-07-04 | Unilever Plc | Granular composition |
GB0111862D0 (en) | 2001-05-15 | 2001-07-04 | Unilever Plc | Granular composition |
EP2085461A1 (en) * | 2008-01-11 | 2009-08-05 | Unilever PLC | Laundry composition |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4839208B1 (ko) * | 1968-11-18 | 1973-11-22 | ||
US3849327A (en) * | 1971-11-30 | 1974-11-19 | Colgate Palmolive Co | Manufacture of free-flowing particulate heavy duty synthetic detergent composition containing nonionic detergent and anti-redeposition agent |
US4399049A (en) * | 1981-04-08 | 1983-08-16 | The Procter & Gamble Company | Detergent additive compositions |
SE459972B (sv) * | 1983-03-29 | 1989-08-28 | Colgate Palmolive Co | Smutsavvisande partikelformig tvaettmedelskomposition innehaallande en smutsavvisande polymer, foerfarande foer dess framstaellning och dess anvaendning vid tvaettning av syntetiska organiska polymera fibermaterial |
DE3434854A1 (de) * | 1984-09-22 | 1986-04-03 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung einer koernigen, freifliessenden waschmittelkomponente |
GB2174712B (en) * | 1985-05-10 | 1988-10-19 | Unilever Plc | Detergent granules |
CA1293421C (en) * | 1985-07-09 | 1991-12-24 | Mark Edward Cushman | Spray-dried granular detergent compositions containing nonionicsurfactant, polyethylene glycol, and polyacrylate |
GB8522621D0 (en) * | 1985-09-12 | 1985-10-16 | Unilever Plc | Detergent powder |
JPH0774355B2 (ja) * | 1986-05-09 | 1995-08-09 | ライオン株式会社 | 顆粒状非イオン洗剤組成物の製造方法 |
DE3835918A1 (de) * | 1988-10-21 | 1990-04-26 | Henkel Kgaa | Verfahren zur herstellung von tensidhaltigen granulaten |
EP0508034B1 (en) * | 1991-04-12 | 1996-02-28 | The Procter & Gamble Company | Compact detergent composition containing polyvinylpyrrolidone |
JP3192469B2 (ja) * | 1991-05-17 | 2001-07-30 | 花王株式会社 | ノニオン洗剤粒子の製造方法 |
-
1993
- 1993-04-30 EP EP93870075A patent/EP0622454A1/en not_active Withdrawn
-
1994
- 1994-04-20 PH PH48115A patent/PH31661A/en unknown
- 1994-04-27 EG EG23894A patent/EG20591A/xx active
- 1994-04-28 MA MA23488A patent/MA23182A1/fr unknown
- 1994-04-29 FI FI955143A patent/FI955143A7/fi unknown
- 1994-04-29 JP JP6524624A patent/JP2888983B2/ja not_active Expired - Lifetime
- 1994-04-29 CZ CZ952838A patent/CZ283895A3/cs unknown
- 1994-04-29 CA CA002160662A patent/CA2160662C/en not_active Expired - Fee Related
- 1994-04-29 WO PCT/US1994/004843 patent/WO1994025553A1/en not_active Application Discontinuation
- 1994-04-29 CN CN94192424A patent/CN1125462A/zh active Pending
- 1994-04-29 KR KR1019950704756A patent/KR960701980A/ko not_active Withdrawn
- 1994-04-29 AU AU67804/94A patent/AU693445B2/en not_active Ceased
- 1994-04-29 PE PE1994241261A patent/PE54094A1/es not_active Application Discontinuation
- 1994-04-29 HU HU9503082A patent/HU216904B/hu not_active IP Right Cessation
-
1995
- 1995-10-27 NO NO954308A patent/NO954308L/no unknown
Also Published As
Publication number | Publication date |
---|---|
CA2160662C (en) | 1999-08-31 |
PE54094A1 (es) | 1995-01-05 |
CA2160662A1 (en) | 1994-11-10 |
AU6780494A (en) | 1994-11-21 |
NO954308D0 (no) | 1995-10-27 |
AU693445B2 (en) | 1998-07-02 |
PH31661A (en) | 1999-01-12 |
WO1994025553A1 (en) | 1994-11-10 |
MA23182A1 (fr) | 1994-12-31 |
CN1125462A (zh) | 1996-06-26 |
EG20591A (en) | 1999-09-30 |
EP0622454A1 (en) | 1994-11-02 |
FI955143A0 (fi) | 1995-10-27 |
FI955143L (fi) | 1995-10-27 |
JP2888983B2 (ja) | 1999-05-10 |
HU9503082D0 (en) | 1995-12-28 |
HUT72275A (en) | 1996-04-29 |
CZ283895A3 (en) | 1996-02-14 |
FI955143A7 (fi) | 1995-10-27 |
HU216904B (hu) | 1999-10-28 |
JPH08509775A (ja) | 1996-10-15 |
NO954308L (no) | 1995-11-16 |
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Patent event date: 19951030 Patent event code: PA01051R01D Comment text: International Patent Application |
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