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KR960700281A - 생물학적 분해성 공중합체, 이를 제조하는 방법 및 그 용도(biodegradable copolymers, method of producing them and their use) - Google Patents

생물학적 분해성 공중합체, 이를 제조하는 방법 및 그 용도(biodegradable copolymers, method of producing them and their use)

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KR960700281A
KR960700281A KR1019950702815A KR19950702815A KR960700281A KR 960700281 A KR960700281 A KR 960700281A KR 1019950702815 A KR1019950702815 A KR 1019950702815A KR 19950702815 A KR19950702815 A KR 19950702815A KR 960700281 A KR960700281 A KR 960700281A
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salts
polymer
hydrolysis
monoethylenically unsaturated
weight
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돌프 스톡하우젠
프랭크 크라우제
헬무트 클리멕
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브루노 케레스, 헬무트 클링멕
케미쉐 파브릭 스톡하우젠 게엠베하
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Publication of KR960700281A publication Critical patent/KR960700281A/ko

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Abstract

본 발명은, a) 모노에틸렌계 불포화된 디카르복실산 또는 이들의 염; b) 모노에틸렌계 불포화된 모노카르복실산 또는 이들의 염; c) 가수분해 또는 비누화 이후, C－C－쇄에 공유결합된 하나 또는 그 이상의 히드록실기를 가진 단량체 단위로 전환될 수 있는 단일 불포화된 단량체; 및 d) 부가의 라디칼 공중합성 단량체로 구성되고, 상기 a) 내지 d)에 따른 단량체의 합계가 100%인 생물학적 분해성 중합체에 관한 것이다.
본 발명은 수성매질중에서 라디칼 중합 및 가수분해를 통해 상기 중합체를 제조하는 방법, 및 면의 처리시 세제 및 세척제에서 첨가제 공동－성분으로서, 표백 안정화제, 직물인쇄시 보조제로서, 가죽의 제조시, 경수화의 억제 및 분산제로서 상기 중합체를 사용하는 방법에 관한 것이다.

Description

생물학적 분해성 공중합체, 이를 제조하는 방법 및 그 용도(BIODEGRADABLE COPOLYMERS, METHOD OF PRODUCING THEM AND THEIR USE)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (24)

  1. 중합된 모노에틸렌계 불포화된 디카르복실산 및/또는 이들의 염, 중합된 모노에틸렌계 불포화된 모노카르복실산 및/또는 이들의 염, 및 가수분해 또는 비누화 이후, C－C－쇄에 공유결합된 하나 또는 그 이상의 히드록실기를 가진 단위로 전환될 수 있는 중합된 모노에틸렌계 불포화된 단량체와 임의의 중합된 라디칼 공중합성 단량체로 구성된 세제 및 세척제로 사용하는데 적당한 생물학적 분해성 중합체에 있어서, 이들이 수성매질중의 라디칼 중합 및 가수분해 또는 비누화 통해 형성되고, 28일 후 60% (BOD)를 초과하는 생물학적 분해율을 나타내는 것을 특징으로 하는 생물학적 분해성 중합체.
  2. 제1항에 있어서, a) 10－70중량%의 모노에틸렌계 불포화된 C4-8－디카르복실산 또는 이들의 염; b) 20－85중량%의 모노에틸렌계 불포화된 C3-10－모노카르복실산 또는 이들의 염; c) 가수분해 또는 비누화 이후, C－C－쇄에 공유결합된 하나 또는 그 이상의 히드록실기를 가진 단량체 단위로 전환될 수 있는 1－50중량%의 단일 불포화된 단량체; 및 d) 0－10중량%의 부가의 라디칼 공중합성 단량체로 구성되고, 상기 a) 내지 d)에 따른 단량체의 합계가 100%인 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체.
  3. 제1항 또는 제2항에 있어서, a) 바람직하게는 20－60중량%, 가장 바람직하게는 25－55중량%의 모노에틸렌계 불포화된 C4-8－디카르복실산 또는 이들의 염; b) 바람직하게는 25－60중량%, 가장 바람직하게는 30－60중량%의 모노에틸렌계 불포화된 C3-10－모노카르복실산 또는 이들의 염; c) 가수분해 또는 비누화 이후, C－C－쇄에 공유결합된 하나 또는 그 이상의 히드록실기를 가진 단량체 단위로 전환될 수 있는, 바람직하게는 4－40중량%, 가장 바람직하게는 8－30중량%의 단일불포화된 단량체; 및 d) 0－10중량%의 부가의 라디칼 공중합성 단량체로 구성되고, 상기 a) 내지 d)의 단량체의 합계가 100%인 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 단량체 성분 a)로서, 말레산, 이타콘산, 및 푸마르산 또는 이들의 염을 포함하고, 단량체 성분 b)로서 아크릴산 또는 메타크릴산, 또는 이들의 염을 포함하며, 단량체 성분 c)로서 비닐 아세테이트, 비닐 프로피오네이트, 에틸렌 글리콜 모노비닐 에테르, 및/또는 메틸 비닐 에테르를 포함하는 것을 특징으로 하는, 세제 및 세척시에 적당한 생물학적 분해성 중합체.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 수성매질중에서 라디칼 중합 및 가수분해 또는 비누화를 통해 형성되고, 28일 후 생물학적 분해율이 80% (BOD)를 초과하는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체.
  6. 모노에틸렌계 불포화된 디카르복실산 및/또는 이들의 염 및/또는 디카르복실산 무수물, 모노에틸렌계 불포화된 모노카르복실산 및/또는 이들의 염, 가수분해 또는 비누화 이후, C－C－쇄에 공유결합된 하나 또는 그 이상의 히드록실기를 가진 단위로 전환될 수 있는, 모노에틸렌계 불포화된 단량체와, 임의의 라디칼 공중합성 단량체로 구성된 세제 및 세척제로 사용하는데 적당한 생물학적 분해성 중합체에 있어서, 수성매질중의 라디칼 중합 및 가수분해 또는 비누화 통해 형성되고, 28일 후 60% (BOD)를 초과하는 생물학적 분해율을 나타내는 것을 특징으로 하는 생물학적 분해성 중합체를 제조하는 방법.
  7. 제6항에 있어서, 중합반응을 40－180℃, 바람직하게는 60－120℃하에 수성용액중에서 수행하는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체를 제조하는 방법.
  8. 제6항 또는 제7항에 있어서, 디카르복실산, 디카르복실산 무수물, 및 적어도 부분량의 가수분해성 또는 비누화성 단량체를 반응용기에 함께 넣고, 나머지 단량체는 중합반응 동안에 첨가하며, 중합반응을 밀폐된 중합반응기내에서 수행하는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체를 제조하는 방법.
  9. 제6항 내지 제8항중 어느 한 항에 있어서, 디카르복실산 무수물을 가수분해하고 중합하기전에 적어도 부분 중화시키는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체를 제조하는 방법.
  10. 제6항 내지 제9항중 어느 한 항에 있어서, 단량체 성분 a)로서, 말레산, 말레산 무수물, 이타콘산, 이타콘산 무수물, 및 푸마르산 또는 이들의 염을 사용하고, 단량체 성분 b)로서 아크릴산 또는 메타크릴산, 또는 이들의 염을 사용하며, 단량체 성분 c)로서 비닐 아세테이트, 비닐 프로피오네이트, 에틸렌 글리콜 모노비닐 에테르, 및/또는 메틸 비닐 에테르를 사용하는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 분해성 중합체를 제조하는 방법.
  11. 제6항 내지 제10항중 어느 한 항에 있어서, 가수분해 또는 비누화를, 바람직하게는 중합반응 이후에 이산화황을 사용하거나 과산화수소의 존재하에 알칼리 수산화물을 사용하므로써 수행하는 것을 특징으로 하는, 세제 및 세척제에 적당한 생물학적 중합체를 제조하는 방법.
  12. 세제중의 첨가제 또는 공동 증강제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  13. 세척제중의 첨가제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  14. 면의 예비처리, 특히 열탕, 조내 세탁 및 표백에 사용하기 위한 화합물.
  15. 표백 안정화제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  16. 염색 처리과정에서 첨가제 또는 세척 보조제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  17. 직물 인쇄시 보조제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  18. 직물 섬유 사이즈(size)과정에 첨가제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  19. 가죽의 제조시 보조제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  20. 가죽 제조과정중 침지, 석회처리, 특히 석회처리후 세척과정, 및 특히 석회제거 및 CO2－석회제거 과정에서 보조제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  21. 예비－무두질, 무두질 및 재－무두질에서 첨가제로서 사용하기 위한 중합체.
  22. 경수화의 억제를 위한 용도 및 침착방지제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  23. 분산제로서 사용하기 위한 제1항 내지 제11항중 어느 한 항의 중합체.
  24. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950702815A 1993-01-14 1994-01-04 생물학적 분해성 공중합체, 이를 제조하는 방법 및 그 용도(biodegradable copolymers, method of producing them and their use) KR960700281A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4300772.4 1993-01-14
DE4300772A DE4300772C2 (de) 1993-01-14 1993-01-14 Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
PCT/EP1994/000006 WO1994015978A1 (de) 1993-01-14 1994-01-04 Biologisch abbaubare copolymere und verfahren zu ihrer herstellung und ihre verwendung

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