KR960033744A - 열가소성 다층 복합품 - Google Patents
열가소성 다층 복합품 Download PDFInfo
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- KR960033744A KR960033744A KR1019960005205A KR19960005205A KR960033744A KR 960033744 A KR960033744 A KR 960033744A KR 1019960005205 A KR1019960005205 A KR 1019960005205A KR 19960005205 A KR19960005205 A KR 19960005205A KR 960033744 A KR960033744 A KR 960033744A
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- 229920001169 thermoplastic Polymers 0.000 title claims abstract 22
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract 22
- 239000002131 composite material Substances 0.000 title claims 21
- 238000000465 moulding Methods 0.000 claims abstract 12
- 239000004952 Polyamide Substances 0.000 claims abstract 6
- 229920002647 polyamide Polymers 0.000 claims abstract 6
- 239000002033 PVDF binder Substances 0.000 claims abstract 5
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract 5
- 229920000098 polyolefin Polymers 0.000 claims abstract 2
- 239000000203 mixture Substances 0.000 claims 14
- 101000623895 Bos taurus Mucin-15 Proteins 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 239000007822 coupling agent Substances 0.000 claims 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 3
- 125000004018 acid anhydride group Chemical group 0.000 claims 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 2
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims 2
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims 2
- 125000001424 substituent group Chemical group 0.000 claims 2
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 claims 1
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 1
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- 229920001155 polypropylene Polymers 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 239000002318 adhesion promoter Substances 0.000 abstract 1
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Abstract
본 발명은 열적, 기계적 성질이 개선된 복합품을 제공한다.
이는 폴리비닐리덴 플루오라이드 성형 조성물 층Ⅰ, 폴리아미드 (a)와 폴리글루타르이미드(b)의 혼합물을 기본으로 하는 성형 조성물을 포함하고 층Ⅰ에 직접 인접한 층Ⅱ, 반응성 그룹을 함유하는 적절한 커플링제층Ⅲ 및 폴리올레핀 성형 조성물을 포함하고 층Ⅲ에 직접 인접한 층Ⅳ를 인접한 층이 서로 견고하게 결합되어 있는 상태로 하나 이상 함유하는 열가소성 다층 복합품으로써 성취된다.
본 발명에 의해 특성이 바람직하게 개선된 복합품을 수득할 수 있다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (21)
- 폴리비닐리텐 플루오라이드 성형 조성물 층Ⅰ, 폴리아미드(a)와 폴리글루타르이미드(b)의 혼합물을 기본으로 하는 성형 조성물을 포함하고 층Ⅰ에 직접 인접한 층Ⅱ; 반응성 그룹을 함유하는 적절한 커플링제 층Ⅲ 및 폴리올레핀 성형 조성물을 포함하고 층Ⅲ에 직접 인접한 층Ⅳ를 인접한 층이 서로 견고하게 결합되어 있는 상태로 하나 이상 함유하는 열가소성 다층 복합품.
- 제1항에 있어서, 층Ⅰ이 용융 유동 지수가 17g/10분 미만인 폴리비닐리덴 플루오라이드계 성형 조성물을 포함함을 특징으로 하는 열가소성 다층 복합품
- 제1항 또는 제2항에 있어서, 층Ⅰ이 용융 유동 지수가 2 내지 13g/10분인 폴리비닐리덴 플루오라이드계 성형 조성물을 포함함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제 3항 중의 어느 한 항에 있어서, 층Ⅰ이 폴리비닐리덴 플루오라이드 공중합체를 기본으로 하는 성형조성물을 포함함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제4항 중의 어느 한 항에 있어서, 층Ⅱ가 폴리아미드(a) 40 내지 90중량%와 폴리글루타르이미드(b) 10 내지 60중량%의 혼합물을 기본으로 하는 성형조성물을 포함함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제5항 중의 어느 한 항에 있어서, 층Ⅱ가 폴리아미드(a) 60 내지 80중량%와 폴리글루타르이미드(b) 20 내지 40중량%의 혼합물을 기본으로 하는 성형 조성물을 포함함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제 6항 중의 어느 한 항에 있어서, 성분 Ⅱ,b,가 하나 이상의 다음 기본 구성 단위를 함유함을 특징으로 하는 열가소성 다층 복합품.1.2 내지 20중량%상기 식에서, 알킬은 메틸, 에틸, 프로필, 부틸, 펜틸 또는 헥실이고, R1내지 R5는 CnH2n+1(여기서, n은 0 내지 6이다) 이며, 치환체들은 동일하거나 상이하다.
- 제1항 내지 제7항 중의 어느 한 항에 있어서, 성분Ⅱ.b.가 하나 이상의 다음 기본 구성 단위를 함유함을 특징으로 하는 열가소성 다층 복합품.상기 식에서, 알킬은 메틸, 에틸, 프로필, 부틸, 펜틸 또는 헥실이고, R1내지 R5는 CnH2n+1(여기서, n은 0 내지 6이다)이며, 치환체들은 동일하거나 상이할 수 있다.
- 제1항에 내지 제7항 중의 어느 한 항에 있어서, 성분Ⅱ.b.가 다음의 기본 구성 단위를 함유함을 특징으로 하는 열가소성 다층 복합품.2 내지 10중량%상기 식에서, R5는 CnH2n+1(여기서, n은 0 내지 6이다)이다.
- 제7항 내지 제9항 중의 어느 한 항에 있어서, 알킬과 R1내지 R5가 각각 메틸 그룹임을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제10항 중의 어느 한 항에 있어서, 층 Ⅳ가 폴리에틸렌 또는 폴리프로필렌계 성형 조성물을 포함함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제11항 중의 어느 한 항에 있어서, 층Ⅲ의 커플링제가 산 무수물 그룹, 카복실산 그룹, 에폭사이드 그룹, 옥사졸린 그룹 또는 트리알콕시실란 그룹을 함유함을 특징으로 하는 열가소성 다층 복합품.
- 제12항에 있어서, 층Ⅲ의 커플링제가 산 무수물 그룹을 0.05 내지 10중량%, 바람직하게는 0.2 내지 3중량% 함유함을 특징으로 하는 열가소성 다층 복합품.
- 제13항에 있어서, 층Ⅱ에서 폴리아미드의 아미노 말단 그룹 함량이 10mmol/kg 이상 임을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제14항 중의 어느 한 항에 있어서, 성분Ⅱ.a.의 폴리아미드가 폴리아미드 12임을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제15항 중의 어느 한 항에 있어서, 하나 이상의 층Ⅰ, 층Ⅱ, 층Ⅲ 및/또는 층Ⅳ를 함유함을 특징으로 하는 열가소성 다층 복합품.
- 제1항 내지 제16항 중의 어느 한 항에 있어서, 층 배열이 층Ⅳ, 층Ⅲ, 층Ⅱ, 층Ⅰ, 층Ⅱ, 층Ⅲ, 층Ⅳ임을 특징으로 하는 열가소성 다층 복합품.
- 성형품을 생산하기 위한, 제1항 내지 제17항 중의 어느 한 항에 따르는 열가소성 다층 복합품의 용도.
- 중공 제품을 생산하기 위한, 제1항 내지 제17항 중의 어느 한 항에 따르는 열가소성 다층 복합품의 용도.
- 다층 파이프를 생산하기 위한, 제1항 내지 제17항 중의 어느한 항에 따르는 열가소성 다층 복합품의 용도.
- 자동차 섹터에서 충전 포트, 탱크 및 연료 충전제를 생산하기 위한, 제1항 내지 제17항 중의 어느 한 항에 따르는 열가소성 다층 복합품의 용도.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19507026A DE19507026A1 (de) | 1995-03-01 | 1995-03-01 | Thermoplastische Mehrschichtverbunde |
| DE19507026.7 | 1995-03-01 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR960033744A true KR960033744A (ko) | 1996-10-22 |
| KR100403877B1 KR100403877B1 (ko) | 2004-03-10 |
Family
ID=7755280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019960005205A KR100403877B1 (ko) | 1995-03-01 | 1996-02-29 | 열가소성 다층 복합체 및 이로부터 제조된 제품 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5858492A (ko) |
| EP (1) | EP0729830B1 (ko) |
| JP (1) | JP3535652B2 (ko) |
| KR (1) | KR100403877B1 (ko) |
| AT (1) | ATE224813T1 (ko) |
| BR (1) | BR9600857A (ko) |
| CA (1) | CA2170579C (ko) |
| DE (2) | DE19507026A1 (ko) |
| ES (1) | ES2180667T3 (ko) |
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| EP0969958A1 (de) * | 1997-03-29 | 2000-01-12 | Hewing GmbH | Mehrschicht-kunststoffrohr |
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| US6197393B1 (en) * | 1997-06-27 | 2001-03-06 | 3M Innovative Properties Company | Multi-layer compositions comprising a fluoropolymer |
| DE29905010U1 (de) * | 1999-03-18 | 1999-06-10 | Veritas Gummiwerke AG, 63571 Gelnhausen | Kraftstoffleitung |
| FR2794837B1 (fr) * | 1999-06-10 | 2001-08-10 | Atofina | Tube pour le transport d'essence |
| ES2220536T5 (es) † | 1999-09-30 | 2013-03-12 | Asahi Glass Company, Limited | Manguera de combustible |
| EP1270208B1 (en) * | 2000-02-10 | 2019-01-30 | Daikin Industries, Ltd. | Laminated resin |
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| CA2349939C (en) * | 2000-06-30 | 2008-04-15 | Kuraray Co., Ltd. | A method of producing a shaped article having excellent barrier properties |
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| DE10065177A1 (de) * | 2000-12-23 | 2002-06-27 | Degussa | Mehrschichtverbund auf Polyamid/Polyolefin-Basis |
| TW592960B (en) * | 2001-01-22 | 2004-06-21 | Atofina | Thermoforming multilayer film for protecting substrates, and objects obtained |
| AU2002241008A1 (en) * | 2001-02-06 | 2002-08-19 | Atofina | Multilayer structure having a fluorinated polymer layer |
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| WO2004005391A1 (de) * | 2002-07-05 | 2004-01-15 | Creavis Gesellschaft Für Technologie Und Innovation Mbh | Polymerzusammensetzungen aus polymeren und ionischen flüssigkeiten |
| US6805927B2 (en) * | 2002-08-16 | 2004-10-19 | Guardian Industries Corporation | Composite laminate structures especially useful for automotive trim components, and methods and tie layers employed to make the same |
| DE10245355A1 (de) * | 2002-09-27 | 2004-04-08 | Degussa Ag | Rohrverbindung |
| AU2004320079C1 (en) * | 2004-05-27 | 2010-12-23 | Greif International Holding B.V. | Bi-layered container for hazardous substances and process for producing the same |
| DE102004029217A1 (de) * | 2004-06-16 | 2006-01-05 | Degussa Ag | Mehrschichtfolie |
| DE102004036179A1 (de) * | 2004-07-26 | 2006-03-23 | Degussa Ag | Kühlmittelleitung |
| DE102004048776A1 (de) * | 2004-10-07 | 2006-04-13 | Degussa Ag | Mehrschichtverbund mit EVOH-Schicht und Schutzschicht |
| DE102004048777A1 (de) * | 2004-10-07 | 2006-04-13 | Degussa Ag | Mehrschichtverbund mit Polyesterschicht und Schutzschicht |
| DE102004049653A1 (de) * | 2004-10-11 | 2006-04-20 | Degussa Ag | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE102004049652A1 (de) * | 2004-10-11 | 2006-04-20 | Degussa Ag | Leitungssystem für Fluide und Gase in einer Brennstoffzelle |
| DE102004063220A1 (de) * | 2004-12-29 | 2006-07-13 | Degussa Ag | Transparente Formmassen |
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| DE102005007663A1 (de) * | 2005-02-19 | 2006-08-24 | Degussa Ag | Transparente, dekorierbare mehrschichtige Folie |
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| DE202011103017U1 (de) * | 2011-07-08 | 2012-10-15 | Rehau Ag + Co. | Desinfektionsbeständiges Mehrschichtverbundrohr |
| US8905083B2 (en) | 2012-01-27 | 2014-12-09 | Titeflex Corporation | Energy dissipative tubes and methods of fabricating and installing the same |
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| US4415706A (en) * | 1982-11-10 | 1983-11-15 | Rohm And Haas Company | Compatible blends of polyglutarimides and polyamides |
| US4758455A (en) * | 1985-07-10 | 1988-07-19 | Handy & Harman Automotive Group Inc. | Composite fuel and vapor tube having increased heat resistance |
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| DE4112668A1 (de) * | 1991-04-18 | 1992-10-22 | Huels Chemische Werke Ag | Thermoplastische mehrschichtverbunde |
| US5478620A (en) * | 1991-04-18 | 1995-12-26 | Huels Aktiengesellschaft | Multilayer plastic pipe |
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| DE4137434A1 (de) * | 1991-11-14 | 1993-05-19 | Huels Chemische Werke Ag | Thermoplastische mehrschichtverbunde |
| ES2098422T3 (es) * | 1991-11-14 | 1997-05-01 | Huels Chemische Werke Ag | Compuestos termoplasticos de varias capas. |
| DE4137431A1 (de) * | 1991-11-14 | 1993-05-19 | Huels Chemische Werke Ag | Mehrschichtiges kunststoffrohr |
| DE4215609A1 (de) * | 1992-05-12 | 1993-11-18 | Huels Chemische Werke Ag | Thermoplastische Mehrschichtverbunde |
| DE4215608A1 (de) * | 1992-05-12 | 1993-11-18 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| US5330810A (en) * | 1992-10-06 | 1994-07-19 | Nitta Moore Company | Liquid transfer tube |
| DE4240658A1 (de) * | 1992-12-03 | 1994-06-09 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4310884A1 (de) * | 1993-04-02 | 1994-10-06 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
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| DE4326130A1 (de) * | 1993-08-04 | 1995-02-09 | Huels Chemische Werke Ag | Thermoplastische Mehrschichtverbunde |
| DE4336289A1 (de) * | 1993-10-25 | 1995-04-27 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4336290A1 (de) * | 1993-10-25 | 1995-04-27 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
| DE4336291A1 (de) * | 1993-10-25 | 1995-04-27 | Huels Chemische Werke Ag | Thermoplastische Mehrschichtverbunde |
| DE4410148A1 (de) * | 1994-03-24 | 1995-09-28 | Huels Chemische Werke Ag | Mehrschichtiges Kunststoffrohr |
-
1995
- 1995-03-01 DE DE19507026A patent/DE19507026A1/de not_active Withdrawn
-
1996
- 1996-01-13 DE DE59609704T patent/DE59609704D1/de not_active Expired - Fee Related
- 1996-01-13 AT AT96100448T patent/ATE224813T1/de not_active IP Right Cessation
- 1996-01-13 ES ES96100448T patent/ES2180667T3/es not_active Expired - Lifetime
- 1996-01-13 EP EP96100448A patent/EP0729830B1/de not_active Expired - Lifetime
- 1996-02-28 CA CA002170579A patent/CA2170579C/en not_active Expired - Fee Related
- 1996-02-29 US US08/610,150 patent/US5858492A/en not_active Expired - Fee Related
- 1996-02-29 BR BR9600857A patent/BR9600857A/pt not_active IP Right Cessation
- 1996-02-29 KR KR1019960005205A patent/KR100403877B1/ko not_active IP Right Cessation
- 1996-03-01 JP JP04514796A patent/JP3535652B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BR9600857A (pt) | 1997-12-30 |
| CA2170579A1 (en) | 1996-09-02 |
| ATE224813T1 (de) | 2002-10-15 |
| JP3535652B2 (ja) | 2004-06-07 |
| ES2180667T3 (es) | 2003-02-16 |
| DE19507026A1 (de) | 1996-09-05 |
| EP0729830A2 (de) | 1996-09-04 |
| EP0729830B1 (de) | 2002-09-25 |
| US5858492A (en) | 1999-01-12 |
| EP0729830A3 (de) | 1998-04-22 |
| KR100403877B1 (ko) | 2004-03-10 |
| CA2170579C (en) | 2004-09-14 |
| DE59609704D1 (de) | 2002-10-31 |
| JPH08252891A (ja) | 1996-10-01 |
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