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KR940006986A - 치환된 스티렌 - Google Patents

치환된 스티렌 Download PDF

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Publication number
KR940006986A
KR940006986A KR1019930019341A KR930019341A KR940006986A KR 940006986 A KR940006986 A KR 940006986A KR 1019930019341 A KR1019930019341 A KR 1019930019341A KR 930019341 A KR930019341 A KR 930019341A KR 940006986 A KR940006986 A KR 940006986A
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KR
South Korea
Prior art keywords
substituted
base
material composition
halogen
hydroxystyrene
Prior art date
Application number
KR1019930019341A
Other languages
English (en)
Other versions
KR100270182B1 (ko
Inventor
마이클 호울리헌 프랜시스
Original Assignee
비. 에스. 슈나이더
아메리칸 텔리폰 앤드 텔리그라프 캄파니
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by 비. 에스. 슈나이더, 아메리칸 텔리폰 앤드 텔리그라프 캄파니 filed Critical 비. 에스. 슈나이더
Publication of KR940006986A publication Critical patent/KR940006986A/ko
Application granted granted Critical
Publication of KR100270182B1 publication Critical patent/KR100270182B1/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C07C49/603—Unsaturated compounds containing a keto groups being part of a ring of a six-membered ring, e.g. quinone methides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/26—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids
    • C07C303/28—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfonic acids by reaction of hydroxy compounds with sulfonic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/017—Esters of hydroxy compounds having the esterified hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/96—Esters of carbonic or haloformic acids

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

치환된 스티렌은 간단한 저온 기법에 의해 합성된다, 보호된 페놀 스티렌을 염기의 존재하에 산 무수물, 디카보네이트, 할로겐 치환된 알킬 또는 산 클로라이드와 반응시켜 카보닐 치환된 스티렌을 생성시킨다. 생성물이 증류하지 않고 사용될 경도로 충분히 순수하여 증류로 인한 예상치 않은 수율 감소가 배제된다.

Description

치환된 스티렌
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 치환된 4-하이드록시스테렌을 화학적으로 반응시켜 물질 조성물을 제조하는 단계를 포함하는, 상기 치환된 4-하이드록시스티렌은 보호된 페놀을 염기로 처리하고 염기의 존재하에 생성된 탈보호된 페놀을 산 할라이드, 할로겐 치환된 알킬, 디카보네이트 및 산 무수물로 이루어진 그룹중에서 선택된 성분을 포함하는 시약과 상호작용시켜 제조하며, 상기 치환된 4-하이드록시스티렌을 미리 증류하지 않고 상기 화학반응에 적용함을 특징으로 하는, 물질 조성물의 제조방법.
  2. 제1항에 있어서, 상기 염기가 수산화 테트라알킬암모늄을 포함하는 방법.
  3. 제1항에 있어서, 상기 물질 조성물이 적어도 50,000달톤의 중량 평균 분자량을 갖는 중합체를 포함하는 방법.
  4. 제1항에 있어서, 상기 디카보네이트가 디-3급-부틸 디카보네이트를 포함하는 방법.
  5. 제1항에 있어서, 상기 산 클로라이드가 일반식 X-SO2R'''(여기서, X는 할로겐이고, R'''는 아릴 또는 알킬 이다)의 화합물을 포함하는 법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930019341A 1992-09-23 1993-09-22 치환된 스티렌 KR100270182B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US950,388 1992-09-23
US07/950,388 US6111133A (en) 1992-09-23 1992-09-23 Process for preparing substituted styrenes

Publications (2)

Publication Number Publication Date
KR940006986A true KR940006986A (ko) 1994-04-26
KR100270182B1 KR100270182B1 (ko) 2000-10-16

Family

ID=25490374

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930019341A KR100270182B1 (ko) 1992-09-23 1993-09-22 치환된 스티렌

Country Status (7)

Country Link
US (1) US6111133A (ko)
EP (1) EP0589621B1 (ko)
JP (1) JP2735467B2 (ko)
KR (1) KR100270182B1 (ko)
CA (1) CA2100037C (ko)
DE (1) DE69318917T2 (ko)
TW (1) TW297817B (ko)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6359069B1 (en) * 2000-08-10 2002-03-19 Bayer Corporation Transparent composition containing polycarbonate and a copolymer of methylmethacrylate
US7163777B2 (en) * 2001-09-07 2007-01-16 Eastman Kodak Company Thermally sensitive imageable element
DE60220554T2 (de) * 2002-12-19 2008-02-14 Council Of Scientific & Industrial Research Mikrowelleninduzierter prozess zur herstellung von substituierten 4-vinylphenolen
JP2016098181A (ja) * 2014-11-19 2016-05-30 セントラル硝子株式会社 ４−ヒドロキシスチレンの製造方法およびその保存方法
DE102015118667B3 (de) * 2015-10-30 2017-05-04 Yuan Li Hsing Industrial Co., Ltd. Doppelkopf-Universaladapter

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4491628A (en) * 1982-08-23 1985-01-01 International Business Machines Corporation Positive- and negative-working resist compositions with acid generating photoinitiator and polymer with acid labile groups pendant from polymer backbone
US4668748A (en) * 1984-10-19 1987-05-26 E. I. Du Pont De Nemours And Company Crosslinkable antistatic polymers and their manufacture
US4689371A (en) * 1986-07-07 1987-08-25 Celanese Corporation Process for the preparation of poly (vinylphenol) from poly (acetoxystyrene)
US4927455A (en) * 1986-09-12 1990-05-22 Kyodo Shiryo Co., Ltd. Plant growth medium
US4996136A (en) * 1988-02-25 1991-02-26 At&T Bell Laboratories Radiation sensitive materials and devices made therewith
US5082965A (en) * 1990-10-29 1992-01-21 E. I. Du Pont De Nemours And Company Process for preparation of alkoxycarbonyloxystyrene
US5241098A (en) * 1990-11-16 1993-08-31 Hoechst Celanese Corporation Method for preparing a salt of 4-hydroxystyrene and for preparing 4-tertiary-butoxycarbonyloxystyrene therefrom

Also Published As

Publication number Publication date
DE69318917D1 (de) 1998-07-09
US6111133A (en) 2000-08-29
DE69318917T2 (de) 1999-01-14
KR100270182B1 (ko) 2000-10-16
JPH06336451A (ja) 1994-12-06
CA2100037C (en) 2002-09-10
TW297817B (ko) 1997-02-11
EP0589621A1 (en) 1994-03-30
JP2735467B2 (ja) 1998-04-02
EP0589621B1 (en) 1998-06-03
CA2100037A1 (en) 1994-03-24

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