KR930703396A - 스티렌 공중합체 수지를 함유한 개선된 열가소성 조성물 - Google Patents
스티렌 공중합체 수지를 함유한 개선된 열가소성 조성물Info
- Publication number
- KR930703396A KR930703396A KR1019930702031A KR930702031A KR930703396A KR 930703396 A KR930703396 A KR 930703396A KR 1019930702031 A KR1019930702031 A KR 1019930702031A KR 930702031 A KR930702031 A KR 930702031A KR 930703396 A KR930703396 A KR 930703396A
- Authority
- KR
- South Korea
- Prior art keywords
- thermoplastic composition
- maleic anhydride
- primary amine
- styrene
- weight percent
- Prior art date
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract 20
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract 20
- 239000000203 mixture Substances 0.000 title claims abstract 19
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims abstract 14
- 229920006026 co-polymeric resin Polymers 0.000 title 1
- 150000003141 primary amines Chemical group 0.000 claims abstract 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract 8
- 229920001577 copolymer Polymers 0.000 claims abstract 7
- CYMRDAUUJQRTGL-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-en-5-amine Chemical compound C1C2C(N)CC1C=C2 CYMRDAUUJQRTGL-UHFFFAOYSA-N 0.000 claims abstract 3
- 229920000642 polymer Polymers 0.000 claims 6
- 229920001897 terpolymer Polymers 0.000 claims 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 3
- 239000005977 Ethylene Substances 0.000 claims 3
- 239000004711 α-olefin Substances 0.000 claims 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 2
- JEPPYVOSGKWVSJ-UHFFFAOYSA-N bicyclo[2.2.1]heptan-3-amine Chemical compound C1CC2C(N)CC1C2 JEPPYVOSGKWVSJ-UHFFFAOYSA-N 0.000 claims 2
- 150000001993 dienes Chemical class 0.000 claims 2
- UTPYTEWRMXITIN-YDWXAUTNSA-N 1-methyl-3-[(e)-[(3e)-3-(methylcarbamothioylhydrazinylidene)butan-2-ylidene]amino]thiourea Chemical compound CNC(=S)N\N=C(/C)\C(\C)=N\NC(=S)NC UTPYTEWRMXITIN-YDWXAUTNSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- -1 bicyclo [2.2.1] -hept-5-en-2-yl Chemical group 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920002943 EPDM rubber Polymers 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
- C08G81/02—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers at least one of the polymers being obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C08G81/021—Block or graft polymers containing only sequences of polymers of C08C or C08F
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/025—Copolymers of unspecified olefins with monomers other than olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L35/06—Copolymers with vinyl aromatic monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
스티렌과 무수 말레산의 공중합체와 같은 열가소성 성분과, 2-아미노-5-노르보넨과 같은 1급 아민 작용성 단량체로 개질된 EPM 또는 EPDM와 같은 개질된 탄성중합성 성분의 블렌드를 포함하는 열가소성 조성물을 제공한다. 상기 조성물은 개선된 충격 강도를 갖는다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (15)
- (a)스티렌과 무수 말레산의 공중합체, α메틸스티렌과 무수 말레산의 공중합체, 스티렌과 아크릴 산의 공중합체, 스티렌, 무수 말레산 및 메틸아크릴레이트의 삼원 공중합체, 스티렌, 무수 말레산 및 아크릴로 니트릴의 삼원 공중합체 및 이들의 혼합물로 이루어진 군중에서 선택된 열가소성 성분, 및 (b)(i)에틸렌, 하나 이상의 고급 α올레핀 및 1급 아민의 공중합체 및 (ii)에틸렌, 하나 이상의 고급 α올레핀, 비-공액 디엔 및 1급 아민의 삼원 공중합체로 이루어진 군중셋선택된 1급 아민-함유 탄성 중합성 중합체[이때, 상기 1급 아민은 일반식 CH2=CH함(C,H20)-NH2로 나타낸 선형 아민, 일반식 R-(C,H20)-NH2로 나타낸 노르보닐 아민(여기서 n은 0내지 10의 정수이고, R은 일반식의 비시이클로[2.2.1]-헵트-5-엔-2-일, 일반식의 비사이클로[2.2.1]-헵트-2-엔-7-일로 이루어진 군중에서 선택된 노르보닐 그룹이다] 및 이들의 혼합물로 이루어진 군중에서 선택된다]의 블렌드를 포함하는 열가소성 조성물.
- 제1항에 있어서, 상기 1급 아민 함유 탄성중합성 중합체가 약 5 내지 약 95중량% 범위의 양으로 존재하는 열가소성 조성물.
- 제1항에 있어서, 상기 1급 아민-함유 탄성중합성 중합체가 약 10 내지 약 90중량%의 상기 에틸렌을 포함하는 열가소성 조성물.
- 제1항에 있어서, 상기 1급 아민-함유 탄성중합성 중합체가 약 0.1 내지 약 15중량%의 상기 1급 아민을 포함하는 열가소성 조성물.
- 제1항에 있어서, 상기 삼원 공중합체가 약 0.1 내지 약 15중량%의 상기 디엔을 포함하는 열가소성 조성물.
- 제1항에 있어서, 상기 고급 α-올레핀이 프로필렌인 열가소성 조성물.
- 제1항에 있어서, 상기 1급 아민이 노르보닐 아민인 열가소성 조성물.
- 제1항에 있어서, 상기 노르보닐 아민이 2-아미노-5-노르보넨인 열가소성 조성물.
- 제8항에 있어서, 상기 2-아미노-5-노르보넨이 2-메틸아민-5-노르보넨인 열가소성 조성물.
- 제1항에 있어서, 상기 1급 아민-함유 탄성중합성 중합체가 약 0.01 내지 약 20μ범위의 크기를 갖는 입자로서 상기 열가소성 성분(a)중에 분산되어 있는 열가소성 조성물.
- 제1항에 있어서, 상기 열가소성 성분(a)이 약 1 내지 약 25중량%의 무수 말레산을 포함하는, 스티렌 또는 α메틸스티렌과 무수 말레산의 공중합체인 열가소성 조성물.
- 제10항에 있어서, 상기 스티렌-무수 말레산 공중합체 또는 α-메틸스티렌-무수 말레산 공중합체가 약 5 내지 약 20중량%의 무수 말레산을 포함하는 열가소성 조성물.
- 제1항에 있어서, ATSM D 790에 따라 1% 변형력에서 측정시 약 10,000kg/㎠ 내지 35,000kg/㎠ 범위의 굴곡 모듈러스를 갖는 열가소성 조성물.
- 제1항에 있어서, 상기 열가소성 성분(a)와 , 상기 1급 아민 함유 탄성중합성 중합체 (b)의 반응 생성물을 한 포함하는 열가소성 조성물.
- ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US638,715 | 1991-01-08 | ||
| US07/638,715 US5118761A (en) | 1991-01-08 | 1991-01-08 | Thermoplastic composition containing a styrene copolymer resin |
| PCT/US1991/006470 WO1992005228A1 (en) | 1990-09-17 | 1991-09-09 | Solder pastes containing acrylic acid and derivatives thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR930703396A true KR930703396A (ko) | 1993-11-29 |
Family
ID=24561146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930702031A KR930703396A (ko) | 1991-01-08 | 1991-12-16 | 스티렌 공중합체 수지를 함유한 개선된 열가소성 조성물 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5118761A (ko) |
| EP (1) | EP0567539B1 (ko) |
| KR (1) | KR930703396A (ko) |
| AT (1) | ATE143683T1 (ko) |
| AU (1) | AU9173091A (ko) |
| CA (1) | CA2098595A1 (ko) |
| DE (1) | DE69122516T2 (ko) |
| WO (1) | WO1992012203A1 (ko) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6013727A (en) | 1988-05-27 | 2000-01-11 | Exxon Chemical Patents, Inc. | Thermoplastic blend containing engineering resin |
| US5212239A (en) * | 1991-02-22 | 1993-05-18 | Arco Chemical Technology, L.P. | Resin blends containing crystalline propylene polymers and styrenic copolymers |
| US5364909A (en) * | 1992-07-23 | 1994-11-15 | Arco Chemical Technology, L.P. | Graft polymer compositions containing mono-amine functionalized polyoxyalkylene ethers |
| JPH0693151A (ja) * | 1992-09-10 | 1994-04-05 | Idemitsu Kosan Co Ltd | ポリスチレン系樹脂組成物 |
| US5346953A (en) * | 1993-02-08 | 1994-09-13 | General Electric Company | Core-shell ABS copolymers and method for their preparation |
| US5334659A (en) * | 1993-03-18 | 1994-08-02 | General Electric Company | Elastomeric blends and method for their preparation |
| BE1007078A3 (nl) * | 1993-05-14 | 1995-03-07 | Dsm Nv | Polymeersamenstelling. |
| US7056979B1 (en) | 1998-06-12 | 2006-06-06 | Bridgestone Corporation | Reaction product derived from amine-functionalized elastomers and maleated polyolefins |
| US20080188607A1 (en) * | 2007-02-07 | 2008-08-07 | Nova Chemicals Inc. | Low odor resin compositions |
| KR101585992B1 (ko) * | 2007-12-20 | 2016-01-19 | 삼성전자주식회사 | 반사방지 코팅용 고분자, 반사방지 코팅용 조성물 및 이를 이용한 반도체 장치의 패턴 형성 방법 |
| TW201917018A (zh) * | 2017-10-25 | 2019-05-01 | 美商陶氏全球科技有限責任公司 | 含有具有良好黏著力之經底漆塗佈基材之瓷磚 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3748316A (en) * | 1969-06-02 | 1973-07-24 | Du Pont | Functionally substituted terpolymers and tetrapolymers of alpha-olefins and process for manufacturing functional substituted copolymers |
| US3856765A (en) * | 1969-06-02 | 1974-12-24 | J Collette | Functionally substituted terpolymers of alpha-olefins |
| US4251644A (en) * | 1979-10-01 | 1981-02-17 | Copolymer Rubber & Chemical Corporation | Polar resins having improved characteristics by blending with EPM and EPDM polymers |
| JPS58198530A (ja) * | 1982-05-17 | 1983-11-18 | Toa Nenryo Kogyo Kk | ポリオレフイン系共重合体の製造方法 |
| NL8303377A (nl) * | 1983-10-01 | 1985-05-01 | Stamicarbon | Werkwijze voor de bereiding van een slagvaste thermoplastische vormmassa. |
| NL8303378A (nl) * | 1983-10-01 | 1985-05-01 | Stamicarbon | Thermoplastische vormmassa. |
| US4987200A (en) * | 1987-06-08 | 1991-01-22 | Exxon Chemical Patents Inc. | Preparation of polymer incorporating masked functional group-containing monomers |
| DK701288A (da) * | 1987-12-18 | 1989-06-19 | Exxon Chemical Patents Inc | Harpiksblanding med indhold af polybuthylenteraphthalat |
-
1991
- 1991-01-08 US US07/638,715 patent/US5118761A/en not_active Expired - Fee Related
- 1991-12-16 CA CA002098595A patent/CA2098595A1/en not_active Abandoned
- 1991-12-16 EP EP92903818A patent/EP0567539B1/en not_active Expired - Lifetime
- 1991-12-16 WO PCT/US1991/009470 patent/WO1992012203A1/en active IP Right Grant
- 1991-12-16 KR KR1019930702031A patent/KR930703396A/ko not_active Application Discontinuation
- 1991-12-16 AU AU91730/91A patent/AU9173091A/en not_active Abandoned
- 1991-12-16 AT AT92903818T patent/ATE143683T1/de active
- 1991-12-16 DE DE69122516T patent/DE69122516T2/de not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US5118761A (en) | 1992-06-02 |
| WO1992012203A1 (en) | 1992-07-23 |
| EP0567539A1 (en) | 1993-11-03 |
| EP0567539B1 (en) | 1996-10-02 |
| AU9173091A (en) | 1992-08-17 |
| ATE143683T1 (de) | 1996-10-15 |
| DE69122516T2 (de) | 1997-02-13 |
| DE69122516D1 (de) | 1996-11-07 |
| CA2098595A1 (en) | 1992-07-09 |
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