KR930023292A - 액상과 접촉할 때 납 및/또는 바륨을 함유하는 결정 유리제품의 납 및/또는 바륨 방사를 감소시키는 방법 - Google Patents
액상과 접촉할 때 납 및/또는 바륨을 함유하는 결정 유리제품의 납 및/또는 바륨 방사를 감소시키는 방법 Download PDFInfo
- Publication number
- KR930023292A KR930023292A KR1019930008726A KR930008726A KR930023292A KR 930023292 A KR930023292 A KR 930023292A KR 1019930008726 A KR1019930008726 A KR 1019930008726A KR 930008726 A KR930008726 A KR 930008726A KR 930023292 A KR930023292 A KR 930023292A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- minutes
- barium
- lead
- hydroxide solution
- Prior art date
Links
- 229910052788 barium Inorganic materials 0.000 title claims abstract 8
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 title claims abstract 8
- 239000007791 liquid phase Substances 0.000 title abstract 2
- 239000002253 acid Substances 0.000 claims abstract 14
- 238000000034 method Methods 0.000 claims abstract 13
- 239000011521 glass Substances 0.000 claims abstract 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims abstract 6
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 2
- 150000001247 metal acetylides Chemical class 0.000 claims 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 1
- 230000002378 acidificating effect Effects 0.000 claims 1
- 239000003513 alkali Substances 0.000 claims 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims 1
- 229910052810 boron oxide Inorganic materials 0.000 claims 1
- 239000001569 carbon dioxide Substances 0.000 claims 1
- 229910002092 carbon dioxide Inorganic materials 0.000 claims 1
- 238000002425 crystallisation Methods 0.000 claims 1
- 230000008025 crystallization Effects 0.000 claims 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims 1
- 238000010494 dissociation reaction Methods 0.000 claims 1
- 230000005593 dissociations Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 239000005355 lead glass Substances 0.000 claims 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 claims 1
- 229910001947 lithium oxide Inorganic materials 0.000 claims 1
- 235000006408 oxalic acid Nutrition 0.000 claims 1
- 238000007539 photo-oxidation reaction Methods 0.000 claims 1
- BYTCDABWEGFPLT-UHFFFAOYSA-L potassium;sodium;dihydroxide Chemical compound [OH-].[OH-].[Na+].[K+] BYTCDABWEGFPLT-UHFFFAOYSA-L 0.000 claims 1
- 230000005855 radiation Effects 0.000 claims 1
- 230000035484 reaction time Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- ABTOQLMXBSRXSM-UHFFFAOYSA-N silicon tetrafluoride Chemical compound F[Si](F)(F)F ABTOQLMXBSRXSM-UHFFFAOYSA-N 0.000 claims 1
- 239000011593 sulfur Substances 0.000 claims 1
- 229910052717 sulfur Inorganic materials 0.000 claims 1
- 239000011975 tartaric acid Substances 0.000 claims 1
- 235000002906 tartaric acid Nutrition 0.000 claims 1
- 239000011787 zinc oxide Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract 2
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 1
- 229910052601 baryte Inorganic materials 0.000 abstract 1
- 239000010428 baryte Substances 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 235000020094 liqueur Nutrition 0.000 abstract 1
- 235000015041 whisky Nutrition 0.000 abstract 1
- 235000014101 wine Nutrition 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/04—Compositions for glass with special properties for photosensitive glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C23/00—Other surface treatment of glass not in the form of fibres or filaments
- C03C23/008—Other surface treatment of glass not in the form of fibres or filaments comprising a lixiviation step
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C15/00—Surface treatment of glass, not in the form of fibres or filaments, by etching
- C03C15/02—Surface treatment of glass, not in the form of fibres or filaments, by etching for making a smooth surface
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Glass Compositions (AREA)
Abstract
액상과 접촉할 때 납 및/또는 바륨을 함유하는 결정 유리제품의 납 및/또는 바륨 방사를 감소시키는 방법.
액상 특히, 아세트산 용액, 포도주, 위스키, 리큐트 및 이와 유사한 것과 같은 수성, 수성-산성, 알코올성 및 수성-알코올성 액체와 접촉할 때 납 및/또는 바륨을 함유하는 결정 유리제품, 특히 소위 납 결정 및 바리테(baryte)유리제품이라 불리는 것의 납 및/또는 바륨 방사를 감소시키는 방법으로 결정 유리제품을 20~60℃도의 온도에서 수산화알카리 용액 5-45중량%로 산 광택호 전 및/또는 후에 적절하게 처리하는 방법이다.
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (12)
- 납 및/또는 바륨을 함유하는 결정 유리제품을 산 광택화 및/또는 후에 적절하게 20~60도의 온도를 갖는 수산화 알카리 용액5~45%로 처리하는, 상기 결정 유리제품이 액상과 접촉할 때 납 및/또는 바륨 방사를 감소시키는 방법.
- 제 1항에 있어서, 5~45%의 수산화나트륨,수산화칼륨 또는 수산화나트륨-칼륨 용액을 사용하는 방법.
- 제 1항 또는 제 2항에 있어서, 상기 유리제품이 상기 수산화 알카리 용액에 도입되고 그 안에서 이동시켜서 반응 시간을 단축시키는 방법.
- 제 1항에 있어서, 수산화 알칼리 용액으로 처리하는 것을 적어도 10분간, 바람직하게는 적어도 20분간 지속하는 방법.
- 제 1항에 있어서, 상기 유리제품을 수사나화 알카리 용액으로 상기 산광택화하기전에 적어도 10분, 바람직하게는 10~25분 처리하고 상기 산 광택화된 후에는 적어도 10분, 바람직하게는 10~40분간 처리하는 방법.
- 제 1항에 있어서, 상기 산 광책화가 20~40%의 불화수소산과 15~30%의 황상의 혼합물로 실시되고, 상기 유리제품들은 상기 산 광책화후에 상기 수산화 알카리 용액으로 10~40분간 처리하는 방법.
- 제 1항에 있어서, 상기 산 광책화가 0.5~10%의 불화수소산과 40~75%의 황산의 혼합물로 일어나고 상기 유리제품들은 수산화 알카리 용액으로 상기 산 광책화하기 전에 10~40분간 처리하고 상기 산 광책화후에 10~40분간 처리하는 방법.
- 제 1항에 있어서, 상기 산 광책화에서의 불소 이온 농도가 상기 불화수소산보다 더 큰 해리상수를 갖는 제 3의 산에 의해 조절되는 방법.
- 제8항에 있어서, 타르타르산, 옥살산, 말론산, 시트르산, 아세트산, 인산 또는 불화규산 또는 이들의 혼합물이 상기 제3의 산으로 사용되는 방법.
- 제 8항에 있어서, 상기 제3의 산이 상기 유리제품의 조성에 따라 처리산의 리터당0.5~14g의 농도로 사용되는 방법.
- 제 1항에 있어서, 상기 수산화 알카리 용액내로의 이산화탄소의 도입 및/또는 탄화물의 첨가에 의해, 그 안에 용해되어 있는 납염들이 납 탐화물로 침전하고 적절하게는 상기 납 탄화물이 분리되는 방법.
- 제 1항에 있어서, 산화보론 0.3~1.0 중량% 산화리튬 0.2~0.5 중량% 및 산화아연 0.2~0.5 중량%를 함유하는 유리제품에 상기 방법을 행하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4217057A DE4217057A1 (de) | 1992-05-22 | 1992-05-22 | Verfahren zur Verminderung der Blei- und/oder Bariumemission von Blei und/oder Barium enthaltenden Kristallglasgegenständen bei Berührung mit einer flüssigen Phase |
| DEP4217057.5 | 1992-05-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR930023292A true KR930023292A (ko) | 1993-12-18 |
| KR100253613B1 KR100253613B1 (ko) | 2000-04-15 |
Family
ID=6459548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019930008726A KR100253613B1 (ko) | 1992-05-22 | 1993-05-21 | 액상과 접촉할 때 납 및/또는 바륨을 함유하는 결정 유리제품의 납 및/또는 바륨 방출을 감소시키는 방법 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5372633A (ko) |
| EP (1) | EP0575740B1 (ko) |
| JP (1) | JP3262637B2 (ko) |
| KR (1) | KR100253613B1 (ko) |
| CN (1) | CN1034413C (ko) |
| CZ (1) | CZ283877B6 (ko) |
| DE (2) | DE4217057A1 (ko) |
| PL (1) | PL174191B1 (ko) |
| SK (1) | SK279093B6 (ko) |
| TW (1) | TW222613B (ko) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105585255B (zh) * | 2016-03-07 | 2017-12-19 | 秦皇岛玻璃工业研究设计院 | 一种防止含铅玻璃铅离子溶出的钝化设备和钝化方法 |
| FR3101076B1 (fr) | 2019-09-20 | 2022-01-14 | Commissariat Energie Atomique | Procédé de traitement d’un verre comprenant du plomb permettant de limiter la migration en solution du plomb contenu dans ce verre |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1185780B (de) * | 1962-11-10 | 1965-01-21 | Erich Saelzle Dipl Chem Dr | Verfahren zum Polieren von Gegenstaenden aus Kristall- oder Bleikristallglas |
| DE1496666C3 (de) * | 1965-05-26 | 1974-04-04 | Erich Dipl.-Chem.Dr. 8000 Muenchen Saelzle | Verfahren zum Polieren von Glasgegenständen in einem Flußsäure und Schwefelsäure enthaltenden Polierbad |
| US3389047A (en) * | 1965-10-20 | 1968-06-18 | Monsanto Co | Treatment of coverplates for glass laminates |
| FR1497041A (fr) * | 1965-10-20 | 1967-10-06 | Monsanto Co | Perfectionnements aux procédés pour améliorer la résistance au choc de verres de sécurité stratifiés, et aux articles ainsi obtenus |
| DE2949383C2 (de) * | 1979-12-07 | 1982-01-21 | Sälzle, Erich, Dr., 8000 München | Verfahren zur Schwefelsäure-Flußsäure-Polieren von Glasgegenständen |
| ES8500612A1 (es) * | 1982-10-13 | 1984-11-16 | Saelzle Erich | Metodo de pulir articulos de vidrio |
| FR2627768B1 (fr) * | 1988-02-29 | 1990-06-29 | Baccarat Cristalleries | Recipient en cristal traite pour empecher la migration du plomb vers son contenu |
| ATE107913T1 (de) * | 1990-05-23 | 1994-07-15 | Baccarat Cristalleries | Verfahren zur verkleinerung der bleimigration von einer kristallflasche zu einer in dieser flasche enthaltenden flüssigkeit. |
| US5232753A (en) * | 1990-05-23 | 1993-08-03 | Compagnie Des Cristalleries De Baccarat | Crystal flask treated with an alumino-silicate slip and heat |
-
1992
- 1992-05-22 DE DE4217057A patent/DE4217057A1/de not_active Withdrawn
-
1993
- 1993-05-12 SK SK460-93A patent/SK279093B6/sk unknown
- 1993-05-12 JP JP13383893A patent/JP3262637B2/ja not_active Expired - Fee Related
- 1993-05-13 EP EP93107806A patent/EP0575740B1/de not_active Expired - Lifetime
- 1993-05-13 DE DE59300939T patent/DE59300939D1/de not_active Expired - Fee Related
- 1993-05-14 PL PL93298962A patent/PL174191B1/pl unknown
- 1993-05-14 TW TW082103782A patent/TW222613B/zh active
- 1993-05-18 CZ CZ93932A patent/CZ283877B6/cs not_active IP Right Cessation
- 1993-05-21 KR KR1019930008726A patent/KR100253613B1/ko not_active IP Right Cessation
- 1993-05-21 US US08/065,265 patent/US5372633A/en not_active Expired - Fee Related
- 1993-05-22 CN CN93106111A patent/CN1034413C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE4217057A1 (de) | 1993-11-25 |
| CN1078960A (zh) | 1993-12-01 |
| JP3262637B2 (ja) | 2002-03-04 |
| US5372633A (en) | 1994-12-13 |
| JPH069248A (ja) | 1994-01-18 |
| PL298962A1 (en) | 1993-11-29 |
| KR100253613B1 (ko) | 2000-04-15 |
| TW222613B (ko) | 1994-04-21 |
| CZ93293A3 (en) | 1994-11-16 |
| CN1034413C (zh) | 1997-04-02 |
| EP0575740A1 (de) | 1993-12-29 |
| CZ283877B6 (cs) | 1998-06-17 |
| SK279093B6 (sk) | 1998-06-03 |
| SK46093A3 (en) | 1993-12-08 |
| DE59300939D1 (de) | 1995-12-21 |
| EP0575740B1 (de) | 1995-11-15 |
| PL174191B1 (pl) | 1998-06-30 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19930521 |
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| PG1501 | Laying open of application | ||
| A201 | Request for examination | ||
| PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19980317 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19930521 Comment text: Patent Application |
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| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
Comment text: Notification of reason for refusal Patent event date: 19990825 Patent event code: PE09021S01D |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19991119 |
|
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