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KR930023066A - 탄화수소의 알킬화를 위한 촉매 및 탄화수소 알킬화 방법 - Google Patents

탄화수소의 알킬화를 위한 촉매 및 탄화수소 알킬화 방법 Download PDF

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Publication number
KR930023066A
KR930023066A KR1019930007581A KR930007581A KR930023066A KR 930023066 A KR930023066 A KR 930023066A KR 1019930007581 A KR1019930007581 A KR 1019930007581A KR 930007581 A KR930007581 A KR 930007581A KR 930023066 A KR930023066 A KR 930023066A
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Prior art keywords
alkylation
catalyst composition
hydrocarbons
hydrogen halide
sulfone compound
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KR1019930007581A
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KR100272030B1 (ko
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애벗트 로널드 고오든
비이 랜돌프 브루스
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제이 이이 휘립프스
휘립프스 피트로오리암 캄파니
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B01J31/0222—Sulfur-containing compounds comprising sulfonyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C07C2527/12—Fluorides
    • C07C2527/1206—Hydrogen fluoride

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

올레핀 탄화수소를 이소파라핀 탄화수소로 알킬화하여, 가솔린 자동차 연료의 배합성분으로서 사용하기 적합한 고옥탄 알킬레이트 생성물을 생산하기 위한 공정에 사용되는 신규한 알킬화 촉매가 기재되어 있다. 신규한 촉매는 할로겐화 수소, 설폰 및 물의 혼합물을 포함하고 알킬화 공정 시스템에서 그것의 이용을 가능케하는 적합한 부식 성질을 가진다. 신규한 알킬화 촉매는 이소파라핀 탄화수소로 올레핀 탄화수소를 알킬화하기 위한 신규한 방법에 이용된다.

Description

탄화수소의 알킬화를 위한 촉매 및 탄화수소 알킬화 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 불화수소 및 설폴란 혼합물내 다양한 물 농도에 대한 년당 부식 마일 단위로 탄소강의 부식률을 제시하는 막대도표이고, 제2도는 상이한 시험 용기내에서 불화 수소 및 설폴란 혼합물내 다양한 물 농도에 대한 탄소강의 부식률을 비교하는 막대 도표이며, 제3도는 여기에 기술된 신규한 촉매 조성물을 이용하는 알킬화 방법의 한 구체예의 도식적인 흐름도이다.

Claims (8)

  1. 알킬화를 실행시키기 위한 장치내에서 부식을 저해하기에 적당한 양의 물을 포함하는, 할로겐화 수소 및 설폰 화합물로 구성된 탄화수소의 알킬화를 위한 촉매 조성물.
  2. 제1항에 있어서, 상기 할로겐화 수소가 불화 수소인 촉매 조성물.
  3. 제1항에 있어서, 상기 설폰 화합물이 설폴란인 촉매 조성물.
  4. 제1-3항중 어느 한 항에 있어서, 상기 물이 상기 할로겐화수소 및 상기 설폰 화합물의 총 중량을 기준으로 약 0.25 내지 약 10.0중량%범위의 양으로 상기 조성물내에 존재하는 촉매 조성물.
  5. 제1-3항중 어느 한 항에 있어서, 상기 할로겐화 수소대 상기 설폰 화합물의 중량비가 약 1 : 1 내지 약 40 : 1의 범위인 촉매 조성물.
  6. 제5항에 있어서, 상기 물이 상기 할로겐화수소 및 상기 설폰 화합물의 총 중량을 기준으로 약 0.5 내지 약 10.0중량%범위의 양으로 상기 조성물 내에 존재하며 이때 상기 할로겐화 수소 대 상기 설폰 화합물의 중량비가 약 2.3 : 1 내지 약 19 : 1의 범위인 촉매 조성물.
  7. 제6항에 있어서, 상기 물이 상기 할로겐화 수소 및 상기 설폰 화합물의 총 중량을 기준으로 약 0.5 내지 약 5.0중량%범위의 양으로 상기 조성물 내에 존재하는 촉매 조성물.
  8. 올레핀 및 이소파라핀으로 구성된 탄화수소 혼합물을 적당한 알킬화 조건 하에서 제1-3항중 어는 한 항에 따른 촉매 조성물과 접촉시키는 것을 포함하는 탄화수소 알킬화 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930007581A 1992-05-01 1993-04-30 탄화수소의 알킬화를 위한 촉매 및 탄화수소 알킬화 방법 KR100272030B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US7/877,336 1992-05-01
US07/877,336 1992-05-01
US07/877,336 US5569807A (en) 1992-05-01 1992-05-01 Isoparaffin-olefin alkylation

Publications (2)

Publication Number Publication Date
KR930023066A true KR930023066A (ko) 1993-12-18
KR100272030B1 KR100272030B1 (ko) 2000-11-15

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Country Status (26)

Country Link
US (3) US5569807A (ko)
EP (1) EP0568090B1 (ko)
JP (1) JP3365649B2 (ko)
KR (1) KR100272030B1 (ko)
CN (2) CN1039117C (ko)
AT (1) ATE141906T1 (ko)
AU (1) AU642099B1 (ko)
BR (1) BR9301713A (ko)
CA (1) CA2092355C (ko)
CZ (1) CZ284049B6 (ko)
DE (1) DE69304242D1 (ko)
DK (1) DK0568090T3 (ko)
ES (1) ES2094408T3 (ko)
FI (1) FI107448B (ko)
GR (1) GR3021812T3 (ko)
HU (1) HU212116B (ko)
MX (1) MX9302316A (ko)
NO (1) NO304548B1 (ko)
PL (1) PL173140B1 (ko)
RU (1) RU2106198C1 (ko)
SG (1) SG47641A1 (ko)
SK (1) SK280340B6 (ko)
TR (1) TR26990A (ko)
TW (1) TW222618B (ko)
YU (1) YU48517B (ko)
ZA (1) ZA932854B (ko)

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Also Published As

Publication number Publication date
CN1102850A (zh) 1995-05-24
AU642099B1 (en) 1993-10-07
YU29793A (sr) 1996-01-09
YU48517B (sh) 1998-09-18
CN1047191C (zh) 1999-12-08
NO304548B1 (no) 1999-01-11
RU2106198C1 (ru) 1998-03-10
FI931945L (fi) 1993-11-02
GR3021812T3 (en) 1997-02-28
PL173140B1 (pl) 1998-01-30
NO931577L (no) 1993-11-02
HU9301241D0 (en) 1993-08-30
HUT64996A (en) 1994-03-28
DE69304242D1 (de) 1996-10-02
FI931945A0 (fi) 1993-04-29
CN1039117C (zh) 1998-07-15
JPH06106067A (ja) 1994-04-19
SK280340B6 (sk) 1999-12-10
SG47641A1 (en) 1998-04-17
BR9301713A (pt) 1994-03-01
ES2094408T3 (es) 1997-01-16
CA2092355C (en) 1999-07-20
TR26990A (tr) 1994-09-13
KR100272030B1 (ko) 2000-11-15
EP0568090A1 (en) 1993-11-03
MX9302316A (es) 1994-04-29
US5498818A (en) 1996-03-12
US5569807A (en) 1996-10-29
FI107448B (fi) 2001-08-15
PL298766A1 (en) 1993-12-27
ATE141906T1 (de) 1996-09-15
JP3365649B2 (ja) 2003-01-14
CA2092355A1 (en) 1993-11-02
SK41193A3 (en) 1994-06-08
HU212116B (en) 1996-02-28
CZ284049B6 (cs) 1998-07-15
CN1080213A (zh) 1994-01-05
CZ77693A3 (en) 1994-01-19
DK0568090T3 (da) 1996-09-16
TW222618B (ko) 1994-04-21
NO931577D0 (no) 1993-04-29
US5639932A (en) 1997-06-17
ZA932854B (en) 1993-11-23
EP0568090B1 (en) 1996-08-28

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