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KR930019605A - 데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 - Google Patents

데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도 Download PDF

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KR930019605A
KR930019605A KR1019930004235A KR930004235A KR930019605A KR 930019605 A KR930019605 A KR 930019605A KR 1019930004235 A KR1019930004235 A KR 1019930004235A KR 930004235 A KR930004235 A KR 930004235A KR 930019605 A KR930019605 A KR 930019605A
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South Korea
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decyl alcohol
mixture
hydroformylation
butadiene
isomeric
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KR1019930004235A
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KR100290220B1 (ko
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바르만 헬무트
그레브 볼프강
하이만스 페터
라페 페터
스잠마이타트 위르겐
뭘러 토마스
비부스 에른스트
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페터스, 라이켈트
훽스트 아크티엔게젤샤프트
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Publication of KR930019605A publication Critical patent/KR930019605A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • C07C29/175—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds with simultaneous reduction of an oxo group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
    • C07C45/74—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups combined with dehydration
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 부타디엔을 하이드로포밀화시켜 알데하이드 혼합물을 수득하고, 이 반응으로부터 분리한 알데하이드 혼합물을 축합시켜 알돌 혼합물을 형성시킨 다음 이 알돌 혼합물을 분리 및 수소화시켜 이성체성 데실알콜의 혼합물을 수득하는 것에 관한 것이다. 프탈산을 사용하여 이성체성 데실 알콜 혼합물을 에스테르화하면 가소제로서 사용되는 이성체성 데실 프탈레이트가 수득된다.

Description

데실 알콜 혼합물, 이로부터 수득가능한 프탈산 에스테르 및 가소제로서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 부타디엔을 하이드로포밀화시켜 알데하이드 혼합물을 수득하고, 반응 생성물로부터 생성된 알데하이드 혼합물을 분리한 다음,알데하이드혼합물을 축합시켜 알돌 혼합물을 형성시키고, 이 알돌 혼합물을 분리 및 수소화 시켜 이성체성 데실 알콜의 혼합물을 형성시킴으로써 수득한 이성체성 데실 알콜 혼합물.
  2. 제1항에 있어서, 부타디엔의 하이드로포밀화를 로듐촉매 존재하에 수행함을 특징으로 하는 이성체성 데실알콜 혼합물.
  3. 제1항 또는 제2항에 있어서, 부타디엔의 하이드로 포르밀화를 촉매로서 물 및 수용성 로듐-포스핀 착물존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
  4. 제3항에 있어서, 부타다엔의 하이드로포밀화를 리간드로서 설폰화된 포스핀을 함유하는 촉매인 수용성 로듐착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
  5. 제3항 또는 제4항에 있어서, 부타디엔의 하이드로포밀화를 리간드로서 설폰화된 알킬-또는 아릴포스핀을 함유하는 수용성 로듐 착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
  6. 제3항 또는 제4항에 있어서, 부타디엔의 하이드로포밀화를 리간드로서 설폰화된 아릴알킬-또는 알킬아릴디 포스핀을 함유하는 촉매인 수용성 로듐 착물 존재하에 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
  7. 제3항 내지 제6항중 어느 한 항 이상에 있어서, 부타디엔의 하이드로포밀화를 촉매로서 물 및 수용성 로듐-포스핀 착물 존재하에 70내지 150℃의 온도에서 및 0.4내지 30MPa의 압력하에, 수성상 대 유기상의 용적비를 0.1내지 10:1로 하고, 수성 촉매 용액중 로듐 농도를 20 내지 2000ppm로 하여 로륨 몰당 4내지 100몰의 포스핀을 사용하여 수행함을 특징으로 하는 이성체성 데실 알콜 혼합물.
  8. 제9항 내지 제7항중 어느 한 항 이상에 있어서, 수성 촉매 용액이 상이동 시약을 함유하는 이성체성 데실 알콜 혼합물.
  9. 프탈산 또는 프탈살 무수물을 제1항 내지 제8항중 어느 한 항 이상에서 청구된 이성체성 데실 알콜 혼합물로 에스테르화시켜 수득한 이성체성 디데실 프탈레이트 혼합물.
  10. 제9항에서 청구된 이성체성 디데실 프탈레이트 혼합물의 가소제로서의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930004235A 1992-03-27 1993-03-19 데실 알콜 혼합물의 제조 방법 및 이에 의해 제조되는 데실 알콜 혼합물로부터 수득가능한 가소제로서의 이성체성 디데실 프탈레이트 혼합물 KR100290220B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19924210028 DE4210028A1 (de) 1992-03-27 1992-03-27 Decyclalkoholgemische, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
DEP4210028.3 1992-03-27

Publications (2)

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KR930019605A true KR930019605A (ko) 1993-10-18
KR100290220B1 KR100290220B1 (ko) 2001-05-15

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KR1019930004235A KR100290220B1 (ko) 1992-03-27 1993-03-19 데실 알콜 혼합물의 제조 방법 및 이에 의해 제조되는 데실 알콜 혼합물로부터 수득가능한 가소제로서의 이성체성 디데실 프탈레이트 혼합물

Country Status (16)

Country Link
US (1) US5382716A (ko)
EP (1) EP0562450B1 (ko)
JP (2) JPH0739360B2 (ko)
KR (1) KR100290220B1 (ko)
CN (2) CN1039706C (ko)
AT (1) ATE174317T1 (ko)
AU (1) AU659293B2 (ko)
BR (1) BR9301282A (ko)
CA (1) CA2092040A1 (ko)
DE (2) DE4210028A1 (ko)
DK (1) DK0562450T3 (ko)
ES (1) ES2127227T3 (ko)
MX (1) MX9301571A (ko)
SG (1) SG44987A1 (ko)
TW (1) TW241286B (ko)
ZA (1) ZA931988B (ko)

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DE4221472A1 (de) * 1992-06-30 1994-01-05 Hoechst Ag Gemische isomerer Decylalkohole, daraus erhältliche Phthalsäureester und ihre Verwendung als Weichmacher
DE4330489A1 (de) * 1993-09-09 1995-03-16 Hoechst Ag Verfahren zur Hydroformylierung von Butadien-1,3
DE19532394A1 (de) * 1995-09-02 1997-03-06 Hoechst Ag Verfahren zur Herstellung von Pentenalen
US5962680A (en) * 1997-04-15 1999-10-05 Union Carbide Chemicals & Plastics Technology Corporation Processes for producing epsilon caprolactams
US5925754A (en) * 1997-04-15 1999-07-20 Union Carbide Chemicals & Plastics Technology Corporation Epsilon caprolactam compositions
US5886236A (en) * 1997-04-15 1999-03-23 Union Carbide Chemicals & Plastics Technology Corporation Process for producing aldehyde acid salts
DE19956410A1 (de) 1999-11-24 2001-05-31 Oxeno Olefinchemie Gmbh Verfahren zur Durchführung von Aldolkondensationen
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US6969735B1 (en) 2004-05-23 2005-11-29 Exxonmobil Chemical Patents Inc. Plasticizers from less branched decyl alcohols
US6969736B1 (en) 2004-05-27 2005-11-29 Exxonmobil Chemical Patents Inc. Plasticizers from less branched nonyl alcohols
CN101427678B (zh) * 2008-07-05 2012-05-09 山西农业大学 一种植物源杀菌剂及其人工合成方法
US10633053B1 (en) 2013-03-15 2020-04-28 Kurt Manufacturing Company, Inc. Axle arrangement for a bicycle
PL3170805T3 (pl) * 2015-11-19 2019-02-28 Evonik Degussa Gmbh Wpływanie na lepkość mieszanin estrów bazujących na n-butenach poprzez celowe zastosowanie etenu podczas otrzymywania prekursorów estrów

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ES2127227T3 (es) 1999-04-16
DK0562450T3 (da) 1999-08-16
EP0562450A3 (en) 1994-11-23
KR100290220B1 (ko) 2001-05-15
DE59309198D1 (de) 1999-01-21
TW241286B (ko) 1995-02-21
ZA931988B (en) 1993-10-19
US5382716A (en) 1995-01-17
JPH0739360B2 (ja) 1995-05-01
DE4210028A1 (de) 1993-09-30
ATE174317T1 (de) 1998-12-15
JPH0672924A (ja) 1994-03-15
BR9301282A (pt) 1993-10-05
CN1122326A (zh) 1996-05-15
EP0562450B1 (de) 1998-12-09
CA2092040A1 (en) 1993-09-28
EP0562450A2 (de) 1993-09-29
JPH11222450A (ja) 1999-08-17
CN1039706C (zh) 1998-09-09
CN1076936A (zh) 1993-10-06
AU3545393A (en) 1993-09-30
SG44987A1 (en) 1997-12-19
AU659293B2 (en) 1995-05-11
MX9301571A (es) 1993-11-01

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