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KR930012651A - 카르복실산 알킬에스테르의 촉매적 수소첨가반응에 의한 고급알코올 제조방법 - Google Patents

카르복실산 알킬에스테르의 촉매적 수소첨가반응에 의한 고급알코올 제조방법 Download PDF

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Publication number
KR930012651A
KR930012651A KR1019920024840A KR920024840A KR930012651A KR 930012651 A KR930012651 A KR 930012651A KR 1019920024840 A KR1019920024840 A KR 1019920024840A KR 920024840 A KR920024840 A KR 920024840A KR 930012651 A KR930012651 A KR 930012651A
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KR
South Korea
Prior art keywords
catalyst
higher alcohol
carboxylic acid
acid alkyl
producing higher
Prior art date
Application number
KR1019920024840A
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English (en)
Inventor
슈나이더 미카엘
코흘로에플레 카를
말레체 게르하르트
Original Assignee
원본 미기재
슈트-케미 아크티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by 원본 미기재, 슈트-케미 아크티엔게젤샤프트 filed Critical 원본 미기재
Publication of KR930012651A publication Critical patent/KR930012651A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

카르복실산 알킬에스테르의 촉매적 수소첨가반응으로 고급알코올을 제조하는 방법을 발표하며 이것은 촉매가 산화물 선구물질일때 다름 조성으로 되고 이 반응은 150 내지 250℃온도와 또한 100 내지 400 바아의 압력을 사이폰화수가 5를 넘지않을때까지 실행하는 것을 특징으로 한다.
CoZnO.0.5-2Mn0.001-0.5Ox
여기서는 x는 전기적 중성을 위한 구조식 유닛당 산소원자수이다.

Description

카르복실산 알킬에스테르의 촉매적 수소첨가반응에 의한 고급알코올 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 카르복실산 일킬 에스테르의 촉매적 수소첨가 반응으로 고급알코올을 제조하고 이때 촉매는 산화물 선구물질 단계에서 다음의 조성으로 되며 또한 이 반응은 사이폰화(seponification)수가 5를 넘지 않도록 150 내지 250℃ 온도 및 100 내지 400 바아의 압력으로 실행되는 것을 특징으로 하는 고급알코올 제조방법.
    CoZnO.0.5-2Mn0.001-0.5Ox
    (여기서는 x는 전기적 중성을 위한 구조식 유닛당 산소원자수이다)
  2. 제1항에 있어서, 반응은 180 내지 230℃온도와 200 내지 350 바아의 압력으로 실행하는 것을 특징으로 하는 고급알코올 제조방법.
  3. 제1항 또는 2항에 있어서, 다음 조성을 가진 촉매를 사용하는 것을 특징으로 하는 고급알코올 제조방법.
    CoZnO.0.5-2Mn0.001-0.5Ox
  4. 제1항 내지 3항에 있어서, 촉매성형물을 사용하며 이것의 기공부피(Hg 기공측정법으로 측정)가 0.15 내지 1.2 특히 0.20 내지 0.70㎤/g인 것을 특징으로 하는 고급알코올 제조방법.
  5. 제1항 내지 4항에 있어서, 촉매의 비표면적이 20 내지 180㎤/g 특히 40 내지 120㎤/g인 것을 특징으로 하는 고급알코올 제조방법.
  6. 제1항 내지 5항에 잇어서, 산화물 형태일때 촉매 성형물의 횡방향 압축강도가 평균 40N 이상 특히 60N인 것을 특징으로 하는 고급알코올 제조방법.
  7. 제1항 내지 6항에 있어서, 촉매성형물로서 원통형, 구형, 고리형, 바퀴형, 또는 벌집형 성형물을 사용하는 것을 특징으로 하는 고급알코올 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920024840A 1991-12-23 1992-12-21 카르복실산 알킬에스테르의 촉매적 수소첨가반응에 의한 고급알코올 제조방법 KR930012651A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4142899A DE4142899A1 (de) 1991-12-23 1991-12-23 Verfahren zur herstellung von alkoholen durch katalytische hydrierung von carbonsaeurealkylestern
DEP4142899.4 1991-12-23

Publications (1)

Publication Number Publication Date
KR930012651A true KR930012651A (ko) 1993-07-21

Family

ID=6448079

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019920024840A KR930012651A (ko) 1991-12-23 1992-12-21 카르복실산 알킬에스테르의 촉매적 수소첨가반응에 의한 고급알코올 제조방법

Country Status (6)

Country Link
US (1) US5386066A (ko)
EP (1) EP0548920B1 (ko)
JP (1) JPH05255156A (ko)
KR (1) KR930012651A (ko)
DE (2) DE4142899A1 (ko)
DK (1) DK0548920T3 (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69408813T2 (de) * 1993-12-28 1998-08-06 Ube Industries Verfahren zur Herstellung von Diol-Verbindungen
DE10020849B4 (de) * 2000-04-28 2004-07-15 Sasol Germany Gmbh Verfahren zur Herstellung von Dihydroxy- und Polyhydroxy-Verbindungen dimerisierter und oligomerisierter Fettsäuren
EP1566372B1 (en) * 2002-11-27 2018-01-10 New Japan Chemical Co., Ltd. Method of hydrogenation reaction
FR2874377A1 (fr) * 2004-08-20 2006-02-24 Cognis Deutschland Gmbh Procede pour la preparation d'alcools
TWI564072B (zh) * 2011-11-09 2017-01-01 China Petrochemical Technology Co Ltd Hydrogenation catalyst and preparation method thereof
JP6732431B2 (ja) 2014-11-20 2020-07-29 花王株式会社 脂肪族アルコールの製造方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE284167C (ko) *
US3213145A (en) * 1960-03-28 1965-10-19 Standard Oil Co Catalytic hydrogenation of esters of aromatic monocarboxylic acids to aryl-substituted methanols
GB975134A (en) * 1961-02-15 1964-11-11 Metallgesellschaft Ag Process for the production of fatty alcohols
BE622853A (ko) * 1961-09-02 1900-01-01
FR1408438A (fr) * 1964-08-11 1965-08-13 V E B Deutsches Hydrierwerk Ro Procédé pour l'hydrogénation continue d'acides gras libres en alcools gras
SU399097A3 (ko) * 1965-08-25 1973-09-27
DE2026182A1 (en) * 1970-05-29 1971-12-09 Badische Anilin- & Soda-Fabrik Ag, 6700 Ludwigshafen Catalyst for methanol prepn-contng copper zinc manganese - and aluminium
JPS5453691A (en) * 1977-10-06 1979-04-27 Mitsubishi Gas Chem Co Inc Methanol synthesis catalyst
PL120574B1 (en) * 1978-07-15 1982-03-31 Instytut Ciezkiej Syntezy Organicznej Blachownia Method of manufacture of copper catalyst
CA1137519A (en) * 1978-08-29 1982-12-14 Chao-Chyan Pai Heterogeneous vapor phase process for the catalytic hydrogenation of aldehydes to alcohols
DE3005551A1 (de) * 1980-02-14 1981-08-20 Süd-Chemie AG, 8000 München Katalysator zur synthese von methanol und hoehere alkohole enthaltenden alkoholgemischen
IT1190783B (it) * 1981-04-29 1988-02-24 Davy Mckee Oil & Chem Processo per l'idrogenolisi di esteri di acidi carbossilici
US5004845A (en) * 1981-08-20 1991-04-02 Davy Mckee (London) Limited Hydrogenation of aldehydes
DD284167A5 (de) * 1988-10-21 1990-11-07 Akad Wissenschaften Ddr Verfahren zur herstellung von katalysatoren fuer die alkoholsynthese

Also Published As

Publication number Publication date
US5386066A (en) 1995-01-31
DE4142899A1 (de) 1993-06-24
JPH05255156A (ja) 1993-10-05
DK0548920T3 (da) 1995-06-06
DE59201724D1 (de) 1995-04-27
EP0548920B1 (de) 1995-03-22
EP0548920A1 (de) 1993-06-30

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Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19921221

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