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KR930009968A - 치환된 인덴의 제조방법 및 메탈로센 촉매용 리간드 시스템으로서의 이의 용도 - Google Patents

치환된 인덴의 제조방법 및 메탈로센 촉매용 리간드 시스템으로서의 이의 용도 Download PDF

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KR930009968A
KR930009968A KR1019920022688A KR920022688A KR930009968A KR 930009968 A KR930009968 A KR 930009968A KR 1019920022688 A KR1019920022688 A KR 1019920022688A KR 920022688 A KR920022688 A KR 920022688A KR 930009968 A KR930009968 A KR 930009968A
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로어만 위르겐
퀴버 프랑크
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훽스트 아크티엔게젤샤프트
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Abstract

본 발명은 일반식(I)의 화합물을 일반식(Ⅱ)의 화합물과 반응시켜 상응하는 인다논을 수득하고, 당해 화합물을 환원 및 탈수시킴으로써 일반식(Ⅳ)또는 (Ⅳa)의 화합물로 전환시킴을 특징으로 하여, 일반식(Ⅳ)또는 일반식(Ⅳa)의 화합물을 제조하는 방법에 관한 것이다.
상기식에서, R1내지 R5는 바람직하게는 수소 또는 알킬이고, X1및 X2는 바람직하게는 할로겐이다. 일반식 (Ⅳ) 및 (Ⅳa)의 화합물은 올레핀 중합용으로 적합한 촉매 성분인 키랄 메탈로센 착물을 제조하기 위한 중요한 중간 생성물이다.

Description

치환된 인덴의 제조방법 및 메탈로센 촉매용 리간드 시스템으로서의 이의 용도
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (22)

  1. 일반식 (I)의 화합물을 프리델-크라프츠 촉매의 존재하에 일반식(Ⅱ)의 화합물 또는 이의 무수물과 반응시켜 일반식(Ⅲ)또는 일반식(Ⅲa)의 화합물을 수득하고, 당해 화합물을 공지된 방법으로 환원 및 탈수시킴으로써 일반식(Ⅳ) 또는 (Ⅳa)의 화합물로 전환시킴을 특징으로 하여, 일반식(Ⅳ)의 화합물 또는 이의 이성체인 일반식(Ⅳa)의 화합물을 제조하는 방법.
  4. 상기식에서, R1, R2, R3, R4및 R5는 동일하거나 상이하고, 수소, (C1-C20)알킬, (C6-C14)아릴, (C1-C10)알콕시, (C2-C10)알케닐, (C7-C20)아릴알킬, (C7-C20)알킬아릴, (C6-C10)아릴옥시, (C1-C10)플루오로알킬, (C6-C10)할로게노아릴, (C2-C10)알키닐, 라디칼-SiR6 3(여기서, R6은 (C1-C10)알킬이다), 할로겐 원자 또는 1개 이상의 헤테로 원자를 함유할 수 있는 5 또는 6원환의 헤테로 방향족 라디칼이거나, 인접한 라디칼 R1내지 R4는 이들을 결합하는 원자와 함께 1개 이상의 환을 형성하고, X1및 X2는 동일하거나 상이하고, 친핵성 이탈그룹이다.
  5. 제1항에 있어서, 일반식(Ⅳ) 및 (Ⅳa)에서, R1, R2, R3및 R4가 동일하거나 상이하고, 수소, (C1-C10)알킬, (C6-C14)아릴, (C1-C4)알콕시, (C2-C6)알케닐, (C1-C6)플루오로알킬, 할로겐 원자 또는 1개 이상의 헤테로 원자를 함유할 수 있는 5 또는 6원환의 헤테로 방향족 라디칼이거나, 인접한 라디칼 R1내지 R4가 이들을 결합하는 원자와 함께 1개의 환을 형성하고, R5가 (C1-C10)알킬인 방법.
  6. 제1항 또는 제2항에 있어서, 일반식(Ⅳ) 및 (Ⅳa)에서, R1, R2, R3및 R4가 동일하거나 상이하고, 수소, (C1-C10)알킬이거나, 라디칼 R1및 R2또는 R3및 R4가 이들을 결합하는 원자와 함께 1개의 환을 형성하고, R5가 메틸인 방법.
  7. 제1항 내지 제3항 중의 어느 한 항에 있어서, 일반식(Ⅱ)에서 X1및 X2가 할로겐 원자인 방법.
  8. 제1항 내지 제4항 중의 어느 한 항에 있어서, AlCl3가 프리델-크라프츠 촉매로서 사용되는 방법.
  9. 제1항 내지 제3항 중의 어느 한 항에 따른 일반식(Ⅳ) 또는 (Ⅳa)의 화합물의 메탈로센 착물 제조시의 중간 생성물로서의 용도.
  10. 일반식(Ⅵ)의 화합물.
  12. 상기식에서, M1은 티탄, 지르코늄, 하프늄, 바나듐, 니오브 또는 탄탈이고, R1, R2, R3, R4및 R5는 동일하거나 상이하고, 수소, (C1-C20)알킬, (C6-C14) 아릴, (C1-C10)알콕시, (C2-C10)알케닐, (C7-C20)아릴알킬, (C7-C20)알킬아릴, (C6-C10)아릴옥시, (C1-C10)플루오로알킬, (C6-C10)할로게노아릴, (C2-C10)알키닐, 라디칼-SiR6 3(여기서, R6은 (C1-C10)알킬이다), 할로겐 원자 또는 1개 이상의 헤테로 원자를 함유할 수 있는 5 또는 6원환의 헤테로 방향족 라디칼이거나, 인접한 라디칼 R1내지 R4는 이들을 결합하는 원자와 함께 1개 이상의 환을 형성하며, R7은 라디칼
  14. (여기서, M2는 탄소, 규소, 게르마늄 또는 주석이고, R8및 R9는 동일하거나 상이하며, 수소, (C1-C20)알킬, (C6-C14)아릴, (C1-C10)알콕시, (C2-C10)알케닐, (C7-C20)아릴알킬, (C7-C20)알킬아릴, (C6-C10)아릴옥시, (C1-C10)플루오로알킬, (C6-C10)할로게노아릴, (C2-C10)알키닐 또는 할로겐이거나, R8및 R9는 이들을 결합하는 원자와 함께 환을 형성하고, p는 0, 1, 2 또는 3이다)이고, R10및 R11은 동일하거나 상이하며, (C1-C10)알킬, (C1-C10)알콕시, (C6-C10)아릴, (C6-C10)아릴옥시, (C2-C10)알케닐, , (C7-C40)아릴알킬, (C7-C40)알킬아릴, (C8-C40)아릴알케닐, 하이드록실 또는 할로겐 원자이다.
  15. 제7항에 있어서, M1이 지르코늄 또는 하프늄, 특히 지르코늄이고, R1, R2, R3및 R4는 동일하거나 상이하며 수소, (C1-C10)알킬, (C6-C14)아릴, (C1-C4)알콕시, (C2-C6)알케닐, (C1-C6)플로오로알킬, 할로겐 원자 또는 1개이상의 헤테로 원자를 함유할수 있는 5 또는 6원 환의 헤테로 방향족 라디칼이거나, 인접한 라디칼 R1내지 R4가 이들을 결합하는 원자와 함께 환을 형성하고, R5는 (C1-C10)알킬이며, M2가 탄소 또는 규소, 특히 규소이고, R8및 R9가 동일하거나 상이하며 수소, (C1-C6)알킬, (C6-C10)아릴, (C1-C6)알콕시, (C2-C4)알케닐, (C7-C10)아릴알킬 또는 (C7-C10)알킬아릴이거나, R8및 R9는 이들을 결합하는 원자와 함께 환을 형성하고, p가 1 또는 2, 바람직하게는 1이며, R10및 R11이 동일하거나 상이하고 수소, (C1-C3)알킬, 특히 메틸, (C1-C3)알콕시, (C6-C8)아릴, (C6-C8)아릴옥시, (C2-C4)알케닐, (C7-C10)아릴알킬, (C7-C10)알킬아릴, (C8-C12)아릴알케닐 또는 할로겐 원자, 바람직하게는 염소인 일반식(Ⅵ)의 화합물.
  16. 제7항 또는 제8항에 있어서, M2가 규소이고, R8및 R9가 동일하거나 상이하며 (C1-C6)알킬 또는 (C6-C10)아릴인 일반식(Ⅵ)의 화합물.
  17. 제7항 내지 제9항 중의 어느 한 항에 있어서, 일반식(Ⅵ)의 인데닐 라디칼이 2,6-위치, 2,4,6-위치, 2,4,5-위치, 2,4,5,6-위치 또는 2,4,5,6,7-위치에서 치환된 일반식(Ⅵ)의 화합물.
  18. 제7항 내지 제10항 중의 어느 한 항에 있어서, 일반식(Ⅵ)의 인데닐 라디칼이 2,4,6-위치와 2,4,5-위치에서 치환된 일반식 (Ⅵ)의 화합물.
  19. 제10항 또는 제11항에 있어서, 일반식(Ⅵ)의 인데닐 라디칼이 (C1-C4)알킬에 의해 치환된 일반식(Ⅵ)의 화합물.
  20. 제10항 또는 제11항에 있어서, 일반식(Ⅵ)의 인데닐 라디칼이 벤조-융합된 일반식 (Ⅵ)의 화합물.
  21. 올레핀의 중합에 있어서, 제7항 내지 제13항 중의 어느 한 항에 따른 일반식(Ⅵ)의 화합물의 촉매 성분으로서의 용도.
  22. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920022688A 1991-11-30 1992-11-28 메탈로센화합물,이의용도및이를포함하는촉매조성물 Expired - Fee Related KR100322976B1 (ko)

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EP0545304B1 (de) 2002-06-19
JPH06206890A (ja) 1994-07-26
US6051522A (en) 2000-04-18
DE59209962D1 (de) 2002-07-25
RU2103250C1 (ru) 1998-01-27
EP0545304A1 (de) 1993-06-09
US5852142A (en) 1998-12-22
ZA929215B (en) 1993-05-27
AU2972792A (en) 1993-06-03
ATE219494T1 (de) 2002-07-15
US5840948A (en) 1998-11-24
CA2084016A1 (en) 1993-05-31
JP3434288B2 (ja) 2003-08-04
ES2177523T3 (es) 2002-12-16
US5929264A (en) 1999-07-27
JP2002226405A (ja) 2002-08-14
CA2084016C (en) 2004-06-22
KR100322976B1 (ko) 2002-05-01
AU655088B2 (en) 1994-12-01
JP3290218B2 (ja) 2002-06-10
TW309523B (ko) 1997-07-01

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