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KR930009647A - 엠에프아이 구조를 가진 촉매, 및 2 내지 12개의 탄소원자를 함유하는 탄화수소의 방향족화에 그것을 사용하는 방법 - Google Patents

엠에프아이 구조를 가진 촉매, 및 2 내지 12개의 탄소원자를 함유하는 탄화수소의 방향족화에 그것을 사용하는 방법 Download PDF

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KR930009647A
KR930009647A KR1019920021412A KR920021412A KR930009647A KR 930009647 A KR930009647 A KR 930009647A KR 1019920021412 A KR1019920021412 A KR 1019920021412A KR 920021412 A KR920021412 A KR 920021412A KR 930009647 A KR930009647 A KR 930009647A
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catalyst
matrix
zeolite
group
weight
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KR1019920021412A
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KR100245782B1 (ko
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파비오 아라리오
쟝-마리 드베
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프랑소와 앙드레에프
앵스띠뛰 프랑세 뒤 뻬뜨롤
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Priority claimed from FR9114208A external-priority patent/FR2683742A1/fr
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    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
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  • Crystallography & Structural Chemistry (AREA)
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 하기의 성분들을 포함하는 합성 촉매에 관한 것이다.
- 알칼리금속 및 알칼리토금속으로 이루어진 군중에서 선택된 적어도 하나의 요소를 함유하고, 골격내에 적어도 실리콘, 알루미늄 및/또는 칼륨을 함유하는 MFI 구조의 제올라이트, - 매트릭스, - 적어도 하나의 백금족 귀금속, 주석, 게르마늄, 인듐, 구리, 철, 몰리브덴, 갈륨, 탈륨, 금, 은, 루테늄, 크롬, 텅스텐 및 납으로 이루어진 군중에서 선택된 적어도 하나의 부가의 금속, - 플루오로, 염소, 브롬 및 요오드로 이루어진 군중에서 선택된 적어도 하나의 할로겐 - 임의로 포함되는 갈륨 및 아연으로 이루어진 군중에서 선택된 적어도 하나의 금속, 및 - 임의로, 바람직하게는 매트릭스내에 포함되는, 알칼리 금속 및 알칼리토금속으로 이루어진 군중에서 선택된 적어도 하나의 요소.
또한, 본 발명은 상기 촉매를 분자 1개당 2 내지 12개의 탄소원자를 함유하는 탄화수소의 방향족화 반응에 사용하는 방법에 관한 것이다.

Description

엠에프아이 구조 가진 촉매, 및 2 내지 12개의 탄소원자를 함유하는 탄화수소의 방향족화에 그것을 사용하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (16)

  1. 골격내에 실리콘 및 알루미늄과 갈륨으로 이루어진 군중에서 선택된 적어도 하나의 요소를 함유하는 MFI구조의 제올라이트 및 매트릭스를 포함하되, 상기 제올라이트는 알칼리 금속과 알칼리토금속으로 이루어진 군중에서 선택된 적어도 하나의 부가의 알칼리 요소를 함유하며, (i) 매트릭스 및/또는 제올라이트상에 융착된, 적어도 하나의 백금족 귀금속, (ii) 매트릭스 및/또는 제올라이트상에 용착된, 주석, 게르마늄, 인듐, 납, 갈륨, 탈륨, 구리, 금, 은, 니켈, 루테늄, 철, 크롬, 모리브덴 및 텅스텐으로 이루어지는 군중에서 선택된 적어도 하나의 부가의 금속, 및 (iii) 매트릭스 및/또는 제올라이트상에 용착된, 플루오르, 염소, 브롬 및 요오드로 이루어진 군중에서 선택된 적어도 하나의 할로겐 요소를 부가로 포함하는 합성 촉매.
  2. 제1항에 있어서, 매트릭스 및/또는 제올라이트상에 융착된, 갈륨 및 아연으로 이루어진 군중에서 선택된 도우핑 요소를 부가로 포함하는 촉매.
  3. 제1항 또는 제2항에 있어서, 상기 제올라이트의 함량이 촉매의 중량을 기준으로 하여 1 내지 99중량%인 촉매.
  4. 제1항 내지 제3항중 어느 한 항에 있어서, 상기 부가의 알칼리의 함량이 제올라이트의 중량에 대해 0.001 내지 5중량%인 촉매.
  5. 제1항 내지 제4항중 어느 한 항에 있어서, 상기 백금족 귀금속의 함량이 매트릭스의 중량에 대해 0.01 내지 2중량%인 촉매.
  6. 제1항 내지 제5항중 어느 한 항에 있어서, 상기 부가의 금속의 함량은, 부가의 금속이 주석일 경우에는 매트릭스의 중량에 대해 0.005 내지 2%이고, 부가의 금속이 기타의 금속중에서 선택되는 경우에는 0.005 내지 0.7%인 촉매.
  7. 제1항 내지 제6항중 어느 한 항에 있어서, 적어도 두가지의 부가의 금속이 존재할 경우에 부가의 금속 총 함량이 매트릭스의 중량에 대해 0.02 내지 1.20%인 촉매.
  8. 제1항 내지 제7항중 어느 한 항에 있어서, 상기 할로겐의 함량이 매트릭스의 중략에 대해 0.1 내지 15%인 촉매.
  9. 제1항 내지 제8항중 어느 한 항에 있어서, 상기 도우핑 요소의 함량이 제올라이트의 중량에 대해 0.01 내지 10%인 촉매.
  10. 제9항에 있어서, 상기 도우핑 요소가 갈륨인 촉매.
  11. 제9항 또는 제10항에 있어서, 상기 도우핑 요소가 제올라이트내에 용착되어 있는 촉매.
  12. 제1항 내지 제11항중 어느 한 항에 있어서, 상기 매트릭스가 알칼리금속 및 알칼리토금속으로 이루어진 군중에서 선택된 0.01 내지 4중량%의 금속을 부가로 포함하는 촉매.
  13. 제12항에 있어서, 상기 금속이 리튬 또는 칼륨중에서 선택되는 촉매.
  14. 제1항 내지 제11항중 어느 한 항에 있어서, 상기 매트릭스가 알루미나인 촉매.
  15. 분자 1개당 2 내지 12개의 탄소원자를 포함하는 탄화수소의 방향족화 방법에 제1항 내지 제14항중 어느 한 항에서 정의한 촉매를 사용하는 방법.
  16. ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019920021412A 1991-11-15 1992-11-14 엠에프아이 구조의 촉매, 및 그 촉매를 사용하여 2 내지 12개의 탄소원자를 갖는 탄화수소를 방향족화시키는 방법 KR100245782B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR91/14.208 1991-11-15
FR91/14.206 1991-11-15
FR9114206A FR2683816B1 (fr) 1991-11-15 1991-11-15 Procede d'aromatisation d'hydrocarbures contenant 2 a 4 atomes de carbone en presence d'un catalyseur a structure mfi.
FR9114208A FR2683742A1 (fr) 1991-11-15 1991-11-15 Catalyseur a structure mfi et son utilisation en aromatisation d'hydrocarbures comportant 5 a 12 atomes de carbone.

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KR930009647A true KR930009647A (ko) 1993-06-21
KR100245782B1 KR100245782B1 (ko) 2000-03-02

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EP (1) EP0542613B1 (ko)
JP (1) JPH05212289A (ko)
KR (1) KR100245782B1 (ko)
AT (1) ATE124295T1 (ko)
AU (1) AU655334B2 (ko)
DE (1) DE69203211T2 (ko)
ES (1) ES2076718T3 (ko)
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US7186872B2 (en) * 2004-03-03 2007-03-06 Saudi Basic Industries Corporation Catalyst for aromatization of alkanes, process of making and process of using thereof
US7909988B2 (en) 2008-04-17 2011-03-22 Uop Llc Process and system for the transfer of a metal catalyst component from one particle to another
US7799729B2 (en) 2009-02-23 2010-09-21 Uop Llc Reforming catalyst
CN108479846B (zh) * 2018-02-08 2019-12-31 中国石油大学(北京) 一种芳构化催化剂及其制备方法和再生方法及芳构化方法
CN115212918B (zh) * 2022-07-06 2023-11-21 山东省科学院能源研究所 一种Zn调控KL分子筛载Pt催化剂的制备方法和应用

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JPS55129232A (en) * 1979-03-29 1980-10-06 Teijin Yuka Kk Isomerization of xylenes
GB8610527D0 (en) * 1986-04-30 1986-06-04 British Petroleum Co Plc Aromatics
US4806701A (en) * 1987-08-05 1989-02-21 Amoco Corporation Process for upgrading light paraffins
FR2662437B1 (fr) * 1990-05-23 1992-08-28 Inst Francais Du Petrole Catalyseur contenant une zeolithe, un metal noble de la famille du platine, un metal alcalin ou alcalino terreux et un metal additionnel et son utilisation dans l'aromatisation des hydrocarbures contenant de 2 a 4 atomes de carbone par molecule.
FR2665375B1 (fr) * 1990-07-31 1992-10-16 Inst Francais Du Petrole Catalyseur de type galloaluminosilicate et son utilisation en aromatisation des hydrocarbures contenant entre 2 et 7 atomes de carbone par molecule.
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AU2835792A (en) 1993-05-20
AU655334B2 (en) 1994-12-15
JPH05212289A (ja) 1993-08-24
EP0542613A1 (fr) 1993-05-19
TW235927B (ko) 1994-12-11
DE69203211T2 (de) 1995-11-02
ATE124295T1 (de) 1995-07-15
EP0542613B1 (fr) 1995-06-28
DE69203211D1 (de) 1995-08-03
ES2076718T3 (es) 1995-11-01
KR100245782B1 (ko) 2000-03-02
MY109061A (en) 1996-11-30

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