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KR920700240A - 고급 α-올레핀계 공중합체, 그 제조방법 및 그 가황물 및 가황 가능한 고무조성물 - Google Patents

고급 α-올레핀계 공중합체, 그 제조방법 및 그 가황물 및 가황 가능한 고무조성물

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KR920700240A
KR920700240A KR1019900701995A KR900701995A KR920700240A KR 920700240 A KR920700240 A KR 920700240A KR 1019900701995 A KR1019900701995 A KR 1019900701995A KR 900701995 A KR900701995 A KR 900701995A KR 920700240 A KR920700240 A KR 920700240A
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rubber
olefin
olefin copolymer
carbon atoms
alpha
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KR1019900701995A
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KR930003891B1 (ko
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마사아끼 가와사끼
슈지 미나미
데스오 도조
게이지 오까다
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다께바야시 쇼오고
미쓰이세끼유 가가꾸고오교오 가부시끼가이샤
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Priority claimed from JP10368089A external-priority patent/JP2656111B2/ja
Priority claimed from JP10368189A external-priority patent/JP2758433B2/ja
Application filed by 다께바야시 쇼오고, 미쓰이세끼유 가가꾸고오교오 가부시끼가이샤 filed Critical 다께바야시 쇼오고
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Abstract

내용 없음

Description

고급 α－올레핀계 공중합체, 그 제조방법 및 그 가황물 및 가황 가능한 고무조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명에 의한 고급 α－올레핀계 공중합체를 제조할때에 사용되는 올레핀 중합용 촉매의 조제 공정 및 본 발명에 있어서의 고급 α－올레핀계 공중합체고무(1)의 제조시에 사용되는 올레핀 중합용 촉매의 조제공정을 나타낸 플로우챠트도이다.

Claims (13)

  1. 탄소수 6－12의 고급 α－올레핀과 하기 일반식〔Ⅰ〕로 표시되는 비공역디엔으로 된 공중합체이며, (a)비공역디엔 함량이 0.01∼30몰%의 범위내이고, (b) 135℃의 데칼린용매중에서 측정한 극한 점도 〔n〕가 1.0∼10.0㎗/g의 범위내인 것을 특징으로 하는 고급 α－올레핀계 공중합체
    (식중 R1은 탄소수 1∼4의 알킬기, R2및 R3은 수소원자 또는 탄소수 1∼4의 알킬기를 나타낸다. 단 R2및 R3이 같이 수소원자인 경우는 없다).
  2. 〔A〕마그네슘, 티탄, 할로겐 및 전자공여체를 필수성분으로서 함유하는 고체티탄 촉매성분, 〔B〕유기 알루미늄 화합물 촉매성분, 및 〔C〕전자공여체 촉매성분으로 형성된 올레핀 중합용 촉매의 존재하에 탄소수 6－12의 고급 α－올레핀과 하기 일반식 〔Ⅰ〕로 표시되는 비공식 디엔을 공중합시키는 제1항의 고급 α－올레핀계 공중합체의 제조방법.
    (식중 R1은 탄소수 1∼4의 알킬기, R2및 R3은 수소원자 또는 탄소수 1∼4의 알킬기를 나타낸다. 단 R2및 R3이 같이 수소원자인 경우는 없다).
  3. 제1항 기재의 고급 α－올레핀계 공중합체의 가황물.
  4. 탄소수 6∼12의 고급 α－올레핀 및 하기 일반식〔Ⅰ〕로 표시되는 비공식 디엔으로 구성된 α－올레핀계 공중합체의 고무(1)와 디엔계 고무(2)로 되고 상기 고급 구성된 α－올레핀계 공중합체의 고무(1)와 디엔 고무(2)의 중량비 〔(1)/(2)가 5/95∼95/5인 것을 특징으로 하는 가황 가능한 고무 조성물;
    (식중 R1은 탄소수 1∼4의 알킬기, R2및 R3은 수소원자 또는 탄소수 1∼4의 알킬기를 나타낸다. 단 R2및 R3이 같이 수소원자인 경우는 없다).
  5. 제4항에 있어서, 상기 고급 α－올레핀계 공중합체 고무(1)의 135℃ 데칼린 용매중에서 측정한 극한 점도〔n〕가 1.0∼10.0㎗/g의 범위내인 것을 특징으로 하는 가황가능한 고무 조성물.
  6. 제4항 또는 제5항에 있어서, 상기 고급 α－올레핀계 공중합체 고무(1)의 옥소가가 1∼50인 것을 특징으로 하는 가황가능한 고무 조성물.
  7. 제4항∼제6항중 어느 한 항에 있어서, 상기 디엔계고무(2)가 천연고무, 이소프렌 고무, SBR, BR 또는 이들의 혼합물인 것을 특징으로 하는 가황가능한 고무조성물.
  8. 탄소수 6－12의 고급 α－올레핀과 하기 일반식〔Ⅰ〕로 표시되는 비공역디엔으로 구성된 고급 α－올레핀계 공중합체 고무(1)과, 에틸렌 및 탄소수 3∼6의 α－올레핀으로 구성된 에틸렌, α－올레핀 공중합체 고무(3)로 되고, 상기 고급 α－올레핀계 공중합체고무(1)과 에틸렌, α－올레핀 공중합체 고무(3)의 중량비〔(1)/(3)〕가 5/95∼95/5인 것을 특징으로 하는 가황 가능한 고무 조성물;
    (식중 R1은 탄소수 1∼4의 알킬기, R2및 R3은 수소원자 또는 탄소수 1∼4의 알킬기를 나타낸다. 단 R2및 R3이 같이 수소원자인 경우는 없다).
  9. 제8항에 있어서, 상기 고급 α－올레핀계 공중합체 고무(1)의 135℃ 데칼린 용매중에서 측정한 극한점도〔n〕가 1.0∼10.0㎗/g의 범위내인 것을 특징으로 하는 가황가능한 고무 조성물.
  10. 제8항 또는 제9항에 있어서, 상기 고급 α－올레핀계 공중합체 고무(1)의 옥소가가 1∼50인 것을 특징으로 하는 가황가능한 고무 조성물.
  11. 제8항∼제12항중 어느 한 항에 있어서, 상기 에틸렌, α－올레핀 공중합체 고무(3)을 구성하는 α－올레핀이 프로필렌 또는 1－부텐인 것을 특징으로 하는 가황가능한 고무조성물.
  12. 제8항∼제12항중 어느 한 항에 있어서, 상기 에틸렌, α－올레핀 공중합체 고무(3)의 135℃ 데칼린 용매중에서 측정한 극한점도 〔η〕가 0.8∼5.0㎗/g의 범위내인 것을 특징으로 하는 가황가능한 고무조성물.
  13. 제8항∼제12항중 어느 한 항에 있어서, 상기 에틸렌, α－올레핀 공중합체 고무(3)가 비공역 폴리앤을 0.1∼5몰%를 함유하는 것을 특징으로 하는 가황가능한 고무조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개되는 것임.
KR1019900701995A 1989-04-24 1990-04-24 고급 α-올레핀계 공중합체, 그 제조방법 및 그 가황물 및 가황 가능한 고무조성물 KR930003891B1 (ko)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
JP1103679A JP2737795B2 (ja) 1989-04-24 1989-04-24 高級α―オレフィン系共重合体、その製造方法およびその加硫物
JP1-103679 1989-04-24
JP10368089A JP2656111B2 (ja) 1989-04-24 1989-04-24 加硫可能なゴム組成物
JP1-103680 1989-04-24
JP1-103681 1989-04-24
JP10368189A JP2758433B2 (ja) 1989-04-24 1989-04-24 加硫可能なゴム組成物
PCT/JP1990/000527 WO1990012818A1 (en) 1989-04-24 1990-04-24 HIGHER α-OLEFIN COPOLYMER, METHOD OF PRODUCTION THEREOF, PRODUCT OF VULCANIZATION THEREOF, AND VULCANIZABLE RUBBER COMPOSITION

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KR920700240A true KR920700240A (ko) 1992-02-19
KR930003891B1 KR930003891B1 (ko) 1993-05-15

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CA (1) CA2028149C (ko)
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WO (1) WO1990012818A1 (ko)

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US3291780A (en) * 1960-10-05 1966-12-13 Du Pont Slurry process for the preparation of hydrocarbon interpolymers
US3224985A (en) * 1962-11-19 1965-12-21 Du Pont Elastomeric blends of an ethylene/1,4-hexadiene copolymer and a diene rubber
US4284535A (en) * 1978-08-29 1981-08-18 The Goodyear Tire & Rubber Company Rubber composites suitable for tire sidewalls from hexadiene polymer
JPS5655409A (en) * 1979-10-11 1981-05-16 Mitsubishi Petrochem Co Ltd Production of unsaturated copolymer
JPS59117509A (ja) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS59159831A (ja) * 1983-03-02 1984-09-10 Mitsui Petrochem Ind Ltd オレフイン共重合ゴム粉末の製造方法
US4843128A (en) * 1986-05-23 1989-06-27 Uniroyal Chemical Company, Inc. Elastomeric composition having increased ozone resistance
CA1310955C (en) * 1987-03-13 1992-12-01 Mamoru Kioka Process for polymerization of olefins and polymerization catalyst
JP2684696B2 (ja) * 1988-08-12 1997-12-03 日本合成ゴム株式会社 不飽和性エチレン−α−オレフィンランダム共重合体およびその組成物

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CA2028149A1 (en) 1990-10-25
EP0423363B1 (en) 1997-07-09
ATE155148T1 (de) 1997-07-15
KR930003891B1 (ko) 1993-05-15
WO1990012818A1 (en) 1990-11-01
CA2028149C (en) 1997-11-25
EP0423363A1 (en) 1991-04-24
EP0423363A4 (en) 1992-08-05
DE69031022T2 (de) 1998-01-02
US5354828A (en) 1994-10-11
DE69031022D1 (de) 1997-08-14

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