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KR910021352A - 코올리고머화 방법 및 이로써 제조된 선형 올레핀 - Google Patents

코올리고머화 방법 및 이로써 제조된 선형 올레핀 Download PDF

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KR910021352A
KR910021352A KR1019910002663A KR910002663A KR910021352A KR 910021352 A KR910021352 A KR 910021352A KR 1019910002663 A KR1019910002663 A KR 1019910002663A KR 910002663 A KR910002663 A KR 910002663A KR 910021352 A KR910021352 A KR 910021352A
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group
catalyst system
component
oligomerization
ethene
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KR100190560B1 (ko
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존 도일 마이클
터어로우 빌렘
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오노 알버어스
셀 인터나쵸 나아레 레사아치 마아츠샤피 비이부이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

코올리고머화 방법 및 이로써 제조된 선형 올레핀
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (14)

  1. 에텐을 하나 이상의 알파 올레핀과 올리고머화 조건하에서 양이온과 반응할 수 있는 치환체를 갖는 비스(시클로펜타디에닐)IVA족 금속 화합물인 제1성분과 다수의 붕소 원자를 가지며, 반응조건하에서 실질적으로 비결합적인 부피가 큰 음이온과 양이온을 갖는 화합물인 제2성분의 조합물로 구성되는 촉매 시스템의 존재하에 반응시키고, 선형 올레핀으로 구성되는 올리고머 생성물을 회수함으로 구성되는 선형 올레핀의 제조방법.
  2. 제1항에 있어서, 알파 올레핀 코모노머는 1-부텐이 포함되는 방법.
  3. 제2항에 있어서, 1-부텐은 에텐 올리고머화 방법으로 부터 유도되는 C4올레핀 획분으로 부터 유도되는 방법.
  4. 제1 내지 3항중 한 항에 있어서, 올리고머화는 20내지 175℃범위내의 온도에서 수행되는 방법.
  5. 제1 내지 4항중 한 항에 있어서, 올리고머화는 1내지 100바아 범위내의 압력에서 수행되는 방법.
  6. 제1 내지 5항중 한 항에 있어서, 올리고머화 조건은 0.3내지 0.8범위의 K인자를 갖는 올레핀 생성물을 생성하도록 선택하는 방법.
  7. 제1 내지 6항중 한 항에 있어서, 알파 올레핀 코모노머에 대한 에텐의 비율은 코모노머 몰당 에텐 0.1 내지 100몰 범위 내인 방법.
  8. 제1 내지 7항중 한 항에 있어서, 촉매 시스템의 제1성분은 일반식(Cp)2MR1R2화합물로, 각 Cp기는 동일 또는 상이한 것으로서 치환된 또는 비치환된 시클로펜타디에닐기를 나타내고, M은 IVA족 금속원자를 나타내고, R1과 R2는 동일 또는 상이한 것으로서 각각이 수소원자 또는 치환된 또는 비치환된 하이드로 카르빌기를 나타내는 것인 방법.
  9. 제8항에 있어서, M은 지르코늄 또는 하프늄인방법.
  10. 제8 또는 제9항에 있어서, 각 Cp기는 비치환된 시클로펜타디에닐기 또는 펜타메틸시클로펜타디에닐기를 나타내고 R1및 R2는 각 알킬기의 방법.
  11. 제1항 내지 10항중 한 항에 있어서, 촉매 시스템의 제2성분은 실질적으로 비결합적인 음이온인 카르보란 음이온으로 구성되는 방법.
  12. 제1항 내지 11항중 한 항에 있어서, 촉매 시스템의 제2성분은 양자 생성 양이온으로 구성되는 방법.
  13. 제11항 및 12항에 있어서, 촉매 시스템의 제2성분은 트리알킬 암모늄 카르보란으로, 카르보란 음이온은 구조식 B11CH12-로 표시되는 방법.
  14. 제1항 내지 13항중 한항의 방법에 의해 제조되는 선형 올레핀.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910002663A 1990-02-22 1991-02-19 코올리고머화방법 Expired - Fee Related KR100190560B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB90040148 1990-02-22
GB909004014A GB9004014D0 (en) 1990-02-22 1990-02-22 Co-oligomerization process

Publications (2)

Publication Number Publication Date
KR910021352A true KR910021352A (ko) 1991-12-20
KR100190560B1 KR100190560B1 (ko) 1999-06-01

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EP (1) EP0443686B1 (ko)
JP (1) JP2987599B2 (ko)
KR (1) KR100190560B1 (ko)
CN (1) CN1045197C (ko)
BR (1) BR9100673A (ko)
CA (1) CA2036762C (ko)
DE (1) DE69105545T2 (ko)
ES (1) ES2065605T3 (ko)
GB (1) GB9004014D0 (ko)
IN (1) IN181265B (ko)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9116297D0 (en) * 1991-07-29 1991-09-11 Shell Int Research Co-oligomerisation process
TW254950B (ko) * 1992-03-02 1995-08-21 Shell Internat Res Schappej Bv
DE69310479T2 (de) * 1992-10-23 1997-10-02 Shell Int Research Katalytische Zusammensetzung für die Oligomerisierung und die Co-oligomerisierung von Alkene
TW307777B (ko) * 1993-04-28 1997-06-11 Shell Int Research
US8497330B2 (en) 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
US6242545B1 (en) 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US6936675B2 (en) 2001-07-19 2005-08-30 Univation Technologies, Llc High tear films from hafnocene catalyzed polyethylenes
CA2454460C (en) 2001-07-19 2008-09-30 Univation Technologies, Llc. Polyethylene films with improved physical properties
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
US7683140B2 (en) 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7078467B1 (en) 2005-06-14 2006-07-18 Univation Technologies, Llc Single catalyst low, medium and high density polyethylenes
US8273834B2 (en) 2006-09-07 2012-09-25 Univation Technologies, Llc Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
CN101511882B (zh) 2006-09-07 2011-09-21 尤尼威蒂恩技术有限责任公司 使用降低熔融起始温度的模型在线测定树脂粘着性程度的方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4658078A (en) * 1986-08-15 1987-04-14 Shell Oil Company Vinylidene olefin process
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
CA2000182C (en) * 1988-10-27 1999-04-06 Lynn H. Slaugh Ethylene oligomerization process and catalyst

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Publication number Publication date
KR100190560B1 (ko) 1999-06-01
EP0443686A3 (en) 1991-12-04
EP0443686B1 (en) 1994-12-07
IN181265B (ko) 1998-05-02
ES2065605T3 (es) 1995-02-16
CA2036762A1 (en) 1991-08-23
EP0443686A2 (en) 1991-08-28
CA2036762C (en) 2001-10-16
DE69105545T2 (de) 1995-04-13
BR9100673A (pt) 1991-10-29
CN1045197C (zh) 1999-09-22
JP2987599B2 (ja) 1999-12-06
DE69105545D1 (de) 1995-01-19
GB9004014D0 (en) 1990-04-18
JPH04211616A (ja) 1992-08-03
CN1054987A (zh) 1991-10-02

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