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KR910016676A - α,β-불포화카르복시산 에스테르의 제조 방법 - Google Patents

α,β-불포화카르복시산 에스테르의 제조 방법 Download PDF

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Publication number
KR910016676A
KR910016676A KR1019910003960A KR910003960A KR910016676A KR 910016676 A KR910016676 A KR 910016676A KR 1019910003960 A KR1019910003960 A KR 1019910003960A KR 910003960 A KR910003960 A KR 910003960A KR 910016676 A KR910016676 A KR 910016676A
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South Korea
Prior art keywords
acid ester
unsaturated carboxylic
carboxylic acid
catalyst
producing
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KR1019910003960A
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KR960000042B1 (ko
Inventor
요시까즈 시마
다까후미 아베
히로후미 히구찌
고이찌 기다
Original Assignee
니시까오 레이지
미쓰비시 가스가가꾸 가부시끼가이샤
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Publication of KR910016676A publication Critical patent/KR910016676A/ko
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Publication of KR960000042B1 publication Critical patent/KR960000042B1/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/587—Monocarboxylic acid esters having at least two carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/317—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C07C67/327—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups by elimination of functional groups containing oxygen only in singly bound form

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

내용 없음

Description

α,β-불포화카르복시산 에스테르의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. α-히드록시카르복시산에스테르를 결정성 알루미노규산염에 촉매에 접촉반응시키고, 이어서 얻어진 반응생성물을 고체산촉매로 접촉시키는 것을 특징으로 하는 α, β-불포화카르복시산에스테르의 제조방법.
  2. 제1항에 있어서, 결정성 알루미노규산염이 X형 제올라이트 또는 Y형 제올라이트인 α, β-불포화카르복시산에스테르의 제조방법.
  3. 제1항에 있어서, 고체산촉매가 인산염을 함유하는 촉매, 고체인산촉매, 황산염을 함유하는 촉매, 실리카-알루미나, 실리카-티타니아, 실리카-지르코니아 또는 제올라이트인 α, β-불포화카르복시산에스테르의 제조방법.
  4. 제1항에 있어서, α-히드록시카르복시산에스테르가, α-히드록시이소부티르산메틸 및 락트산메틸인 α, β-불포화카르복시산에스테르의 제조방법.
  5. 제1항에 있어서, 원료인 α-히드록시카르복시산에스테르의 알콕시부분에 상당하는 알코올을 반응용매로서 사용하는 α,β-불포화카르복시산에스테르의 제조방법.
  6. 제1항에 있어서, 반응용매로서 알코올을 α-히드록시카르복시산에스테르에 대하여 1-10배몰의 범위로 사용하는 α, β-불포화카르복시산에스테르의 제조방법.
  7. 제1항에 있어서, 결정성 알루미노규산염촉매와의 접촉반응시의 온도가 150-450℃이며, 고체산촉매와의 접촉반응시의 온도가 50-450℃인 α, β-불포화카르복시산에스테르의 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019910003960A 1990-03-15 1991-03-13 α, β-불포화카르복시산에스테르의 제조방법 KR960000042B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62751/1990 1990-03-15
JP2062751A JP2906547B2 (ja) 1990-03-15 1990-03-15 α，β―不飽和カルボン酸エステルの製造方法

Publications (2)

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KR910016676A true KR910016676A (ko) 1991-11-05
KR960000042B1 KR960000042B1 (ko) 1996-01-03

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Application Number Title Priority Date Filing Date
KR1019910003960A KR960000042B1 (ko) 1990-03-15 1991-03-13 α, β-불포화카르복시산에스테르의 제조방법

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Country Link
US (1) US5075493A (ko)
EP (1) EP0446446B1 (ko)
JP (1) JP2906547B2 (ko)
KR (1) KR960000042B1 (ko)
DE (1) DE69013490T2 (ko)
ES (1) ES2065462T3 (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3189858B2 (ja) * 1992-11-16 2001-07-16 三菱瓦斯化学株式会社 メタクリル酸メチルの製造法
EP0768296B1 (en) * 1995-10-10 2001-06-13 Rohm And Haas Company A method for making alpha, beta-unsaturated-beta-trifluoromethyl-carboxylates
EP1186592A1 (en) * 2000-09-11 2002-03-13 Mitsubishi Gas Chemical Company, Ltd. Production of methacrylates
JP4810770B2 (ja) * 2001-07-18 2011-11-09 三菱瓦斯化学株式会社 メタクリル酸アリルの製造方法
WO2005095320A1 (en) * 2004-04-02 2005-10-13 Ciba Specialty Chemicals Water Treatments Limited Preparation of acrylic acid derivatives from alpha or beta-hydroxy carboxylic acids
JP6694641B2 (ja) * 2015-06-30 2020-05-20 国立研究開発法人産業技術総合研究所 アクリル酸等のα、β−不飽和カルボン酸、その誘導体の製造法
EP4452919A1 (de) 2021-12-23 2024-10-30 Röhm GmbH Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen
WO2023169810A1 (de) 2022-03-11 2023-09-14 Röhm Gmbh Verfahren zur herstellung von alpha-hydroxyisobuttersäuremethylester und dessen anwendung in der elektronik-industrie

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2376704A (en) * 1943-10-01 1945-05-22 Goodrich Co B F Preparation of esters of alpha-beta unsaturated monocarboxylic acids
US2485510A (en) * 1946-02-13 1949-10-18 American Cyanamid Co Preparation of acrylic acid and esters thereof
DE1211153B (de) * 1957-10-29 1966-02-24 Escambia Chem Corp Verfahren zur Herstellung von Methacrylsaeure und bzw. oder deren Estern durch Umsetzung der Daempfe von alpha-Oxyisobuttersaeure oder deren Estern
US3022337A (en) * 1958-06-03 1962-02-20 Wacker Chemie Gmbh Process for the catalytic production of unsaturated mono-carboxylic acid esters
JPS5767534A (en) * 1980-10-16 1982-04-24 Mitsui Toatsu Chem Inc Preparation of alpha,beta-unsaturated carboxylic ester and alpha,beta-unsaturated carboxylic acid
US4812593A (en) * 1986-08-27 1989-03-14 Basf Aktiengesellschaft Preparation of bifunctional compounds
JPH0727519B2 (ja) * 1987-10-09 1995-03-29 株式会社日立製作所 数式編集方式
JP2727618B2 (ja) * 1989-01-26 1998-03-11 三菱瓦斯化学株式会社 不飽和カルボン酸エステルの製造方法

Also Published As

Publication number Publication date
DE69013490T2 (de) 1995-03-23
JP2906547B2 (ja) 1999-06-21
KR960000042B1 (ko) 1996-01-03
JPH03264548A (ja) 1991-11-25
ES2065462T3 (es) 1995-02-16
EP0446446A3 (en) 1992-03-04
EP0446446A2 (en) 1991-09-18
DE69013490D1 (de) 1994-11-24
US5075493A (en) 1991-12-24
EP0446446B1 (en) 1994-10-19

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