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KR910009785A - 고 충격성 그라프트 공중합체 및 수지 조성물 - Google Patents

고 충격성 그라프트 공중합체 및 수지 조성물 Download PDF

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Publication number
KR910009785A
KR910009785A KR1019900019286A KR900019286A KR910009785A KR 910009785 A KR910009785 A KR 910009785A KR 1019900019286 A KR1019900019286 A KR 1019900019286A KR 900019286 A KR900019286 A KR 900019286A KR 910009785 A KR910009785 A KR 910009785A
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South Korea
Prior art keywords
graft copolymer
polyorganosiloxane
resin
resin composition
high impact
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KR1019900019286A
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KR0184671B1 (ko
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나오끼 야마모토
아키라 야나가세
마사카즈 이토오
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나가이 야타로오
미쯔비시레이욘 가부시끼가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/08—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

내용 없음

Description

고 충격성 그라프트 공중합체 및 수지 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 폴리오르가노실록산 고무성분 1 내지 10wt%와 폴리알킬(메타) 아크릴레이트 고무성분 99내지 90wt%를 분리되지 않도록 서로 엉킨 구조를 가지며, 동시에 톨루엔용매로 측정되는, 85%이상의 겔함량 및 3 내지 15의 팽윤도와, 0.08 내지 0.6㎛의 평균입자크기를 가지는 복합고무에 1이상의 비닐 모노머를 그라프트 중합시켜 되는 폴리오르가노실록산 그라프트 공중합체.
  2. 제1항에 있어서, 겔 함량이 90%이상이고, 팽윤도가 4 내지 14인 폴리오르가노실록산 그라프트 공중합체.
  3. 제1항에 있어서, 폴리오르가노실록산 성분은, 디메틸실록산의 반복단위를 가지며, 폴리알킬(메타)아크릴레이트성분은, n-부틸아크릴레이트의 반복단위를 가지는 폴리오르가노실록산 그라프트 공중합체.
  4. 제1항에 의한 폴리오르가노실록산 그라프트 공중합체와, 폴리카보네이트수지 및 폴리에스테르수지로 구성되는 군으로부터 선택된 적어도 어느하나와로 구성되는 고충격성수지 조성물.
  5. 제4항에 있어서, 상기 폴리카보네이트 수지는, 4,4′-디히드록시-2,2-디페닐프로판(비스페놀A) 및 포스겐으로부터 제조되는 수지인 수지조성물.
  6. 제4항에 있어서, 상기 폴리에스테르 수지는, 폴리부틸렌 테레프탈레이트 수지인 수지 조성물.
  7. 제1항에 의한 폴리오르가노실록산 그라프트 공중합체(A)와, 방향족 알케닐 화합물, 시안화비닐 화합물 및 (메타) 아크릴레이트로 구성되는 군으로부터 선택되는 적어도 하나의 비닐모노머 70 내지 10wt%를, 이들 비닐모노머와 공중합가능한 다른 비닐모노머 0 내지 30wt%와 중합시켜 얻어진 단독 중합체 또는 공중합체 와로 구성되는 고충격성 수지 조성물.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019900019286A 1989-11-27 1990-11-27 고 충격성 그라프트 공중합체 및 수지 조성물 Expired - Lifetime KR0184671B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP30726389 1989-11-27
JP307263 1989-11-27

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KR910009785A true KR910009785A (ko) 1991-06-28
KR0184671B1 KR0184671B1 (ko) 1999-05-15

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EP (1) EP0430134B1 (ko)
KR (1) KR0184671B1 (ko)
DE (1) DE69027976T2 (ko)

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Also Published As

Publication number Publication date
EP0430134A3 (en) 1991-11-06
EP0430134B1 (en) 1996-07-31
DE69027976T2 (de) 1997-03-06
EP0430134A2 (en) 1991-06-05
KR0184671B1 (ko) 1999-05-15
DE69027976D1 (de) 1996-09-05

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EXPY Expiration of term
PC1801 Expiration of term

Termination date: 20110810

Termination category: Expiration of duration