KR910003001A - 내후성이 우수한 내열 난연성 스티렌계 수지조성물 - Google Patents
내후성이 우수한 내열 난연성 스티렌계 수지조성물 Download PDFInfo
- Publication number
- KR910003001A KR910003001A KR1019890010678A KR890010678A KR910003001A KR 910003001 A KR910003001 A KR 910003001A KR 1019890010678 A KR1019890010678 A KR 1019890010678A KR 890010678 A KR890010678 A KR 890010678A KR 910003001 A KR910003001 A KR 910003001A
- Authority
- KR
- South Korea
- Prior art keywords
- represented
- resin composition
- following general
- bromostyrene
- general formula
- Prior art date
Links
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 title claims 10
- 239000011342 resin composition Substances 0.000 title claims 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims 3
- 239000003063 flame retardant Substances 0.000 title claims 3
- 239000000178 monomer Substances 0.000 claims 8
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 claims 4
- 239000011347 resin Substances 0.000 claims 4
- 229920005989 resin Polymers 0.000 claims 4
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- 125000005907 alkyl ester group Chemical group 0.000 claims 2
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 229920001577 copolymer Polymers 0.000 claims 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical group C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- 229920002554 vinyl polymer Polymers 0.000 claims 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 1
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims 1
- 238000012662 bulk polymerization Methods 0.000 claims 1
- 229920003244 diene elastomer Polymers 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 238000007720 emulsion polymerization reaction Methods 0.000 claims 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims 1
- 229920000578 graft copolymer Polymers 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
- 238000010557 suspension polymerization reaction Methods 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/10—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing bromine or iodine atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (4)
- A) 방향족 모노알케닐 단량체, 비닐시안 단량체, 아크릴산 또는 메타크릴산의 알킬에스테르 단량체 중에서 선택된 1종 또는 1종 이상의 단량체를 디엔형 고무성분 또는 알킬아크릴레이트 고무성분 및 하기 일반식(Ⅰ)로 표시되는 브로모스티렌 존재하에서 괴상, 현탁 또는 유화중합시켜 얻은 그라프트 공중합체(A-1), 방향족 모노알케닐 단량체, 비닐시안 단량체, 아크릴산 또는 메타크릴산의 알킬에스테르 단량체중에서 선택된 1종 또는 1종이상의 단량체를 하기 일반식(Ⅰ)로 표시되는 브로모스티렌 존재하에서 괴상, 현탁 또는 유중합시켜 얻은 중합체(A-2), 상기공중합체(A-1),(A-2)에서 하기 일반식(Ⅰ)로 표시되는 브로모스티렌이 반응되지 않은 공중 합체를 각각 (A-3),(A-4)로서 (A-1)과 (A-4), (A-2)와 (A-3), (A-1)과 (A-2)의 각각의 구성비가 5:95 내지 95:5의 중량비로 구성된 기본수지 중에서 하나의 수지 100중량부와 B) 유기난연제 0.5~30중량부 C) 삼산화안티몬 1~20중량부로 구성된 것을 특징으로하는 스티렌계 수지조성물.
- 제1항에 있어서, 브로모스티렌은 하기 일반식(Ⅰ)로 표시됨을 특징으로 하는 스티렌계 수지조성물.상기식에서 x는 1내지 5의 정수임.
- 제1항에 있어서, 유기난연제는 염화비닐수지, 염소화에틸렌수지, 테트라브로모 비스페놀-A 폴리카보네이트 올리고머, 테트라브로모 비스페놀A의 디글리시딜 에테르 중합체임을 특징으로 하는 스티렌계 수지조성물.
- 제3항에 있어서, 테트라브로모 비스페놀 A의 디글리시딜 에테르 중합체가 분자량이 500~2000이며, 하기 일반식(Ⅱ)와 (Ⅲ)으로 표시됨을 특징으로 하는 스티렌게 수지조성물.상기식에서, n은 0이상의 정수이며, R1은(x는 1내지 5의 정수임)이다.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890010678A KR910010074B1 (ko) | 1989-08-17 | 1989-08-17 | 내후성이 우수한 내열 난연성 스티렌계 수지조성물 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1019890010678A KR910010074B1 (ko) | 1989-08-17 | 1989-08-17 | 내후성이 우수한 내열 난연성 스티렌계 수지조성물 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR910003001A true KR910003001A (ko) | 1991-02-26 |
| KR910010074B1 KR910010074B1 (ko) | 1991-12-14 |
Family
ID=19288459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019890010678A KR910010074B1 (ko) | 1989-08-17 | 1989-08-17 | 내후성이 우수한 내열 난연성 스티렌계 수지조성물 |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR910010074B1 (ko) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100719212B1 (ko) * | 2005-12-29 | 2007-05-16 | 제일모직주식회사 | 내충격성 및 내열도가 우수한 난연성 스티렌계 수지 조성물 |
-
1989
- 1989-08-17 KR KR1019890010678A patent/KR910010074B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR910010074B1 (ko) | 1991-12-14 |
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