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KR900018217A - 수용성 중합체의 제법 - Google Patents

수용성 중합체의 제법 Download PDF

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Publication number
KR900018217A
KR900018217A KR1019890007405A KR890007405A KR900018217A KR 900018217 A KR900018217 A KR 900018217A KR 1019890007405 A KR1019890007405 A KR 1019890007405A KR 890007405 A KR890007405 A KR 890007405A KR 900018217 A KR900018217 A KR 900018217A
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KR
South Korea
Prior art keywords
mol
monomers
weight
unsaturated
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
KR1019890007405A
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English (en)
Inventor
젤만-에게베르트 한스-페터
빅크 디이터
하르트만 하인리히
트리젤트 볼프강
바우어 리카르트
Original Assignee
리허터스, 바르츠
바스프 악티엔게젤샤프트
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 리허터스, 바르츠, 바스프 악티엔게젤샤프트 filed Critical 리허터스, 바르츠
Publication of KR900018217A publication Critical patent/KR900018217A/ko
Withdrawn legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44—Polyester-amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

내용 없음

Description

수용성 중합체의 제법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 200℃이하의 온도에서 중합개시제의 존재하에, 수용액중에서 다음 a) 및 b)의 단량체혼합물의 중합함으로써 5내지100의 K값(이 K값 온도가 25℃이고 pH가 7이며 중합체중의 나트륨염의 농도가 1중량%인 수용액중에서 H.Fikentscher의 방식에 따라 중합체의 나트륨염에 관해서 측정된 값이다)을 갖는 수용성 중합체의 제조방법에 있어서, 20-100몰%이하의 다음 성분(b)을 함유하는 단량체혼합물을 사용된 단량체에 근거하여 50중량%이하의 중합개시제의 존재하에서 중합함을 특징으로하는 수용성 중합체의 제조방법; (a)모노에틸렌으로 불포화된 C3-C6모노카르복실산 및 (b)하나이상의 에스테르 또는 아미드작용기를 통해서 연결된 두개 이상의 에틸렌으로 불포화된 이중결합을 함유하며 둘 이상의 -CO-OX그룹(여기서, X는수소, 알칼리금속 또는 알카리토금속 또는 암모늄이다)를 갖는 단량체.
  2. 제1항에 있어서, 중합된 단량체 혼합물이 다음(c)내지 (f)의 단량체를 부가적으로 함유하며 성분(a) 내지 (f)의 몰%의 합은 항상 100이 되고 성분(c)내지 (f)중의 하나이상의 성분이 0.1몰%의 양으로 단량체혼합물에 존재하는 것을 특징으로 하는 방법; (c)모노에틸렌으로 불포화된 C4-C6-디카르복실산 0내지 79.9몰%, (d)모노에틸렌으로 불포화된 C3-C6-카르복실산의 히드록시 알킬에스테르(여기서 히드록시 알킬그룹은 C2-C6이다)0내지 20몰%, (e) (a) 내지 (b)그룹 단량체들과 공중합될 수 있는 기타 수용성, 모노에틸렌으로 불포화된 단량체 0내지 30몰% (f)둘이상의 에틸렌으로 불포화되고 비공액화된 이중결합을 갖고 단량체(b)와 다른 단량체 0내지 10몰%.
  3. 제1항 또는 제2항에 있어서, 다음 성분 (a),(b)및(c)단량체의 혼합물을 사용된 단량체에 근거하여 바람직하게는 30중량%이하의 중합개시제의 존재하에서 중합됨을 특징으로 하는 방법; (a)아크릴산 및/또는 메타아크릴산 79.9내지 10몰%, (b)다음 일반식(Ⅰ)의 화합물 20.1내지 90몰%
    XOOC-CH=CH=CO-O-(CH2-CH2-O)n-CO-CH=CH-COOX (Ⅰ)
    상기에서 X는 H, 알카리금속 또는 암모늄그룹이고, n은 1내지 120이다. 그리고 (c)말레산 0내지 69.9몰%.
  4. 제1항 또는 제2항에 있어서, 다음 성분(a),(b)및(c)의 단량체 혼합물을 사용된 단량체에 근거하여 30중량%이하의 중합개시제의 존재하에서 중합함을 특징으로하는 방법; (a)아크릴산 및/또는 메타아크릴산 79.9내지 10몰% (b)다음 일반식(Ⅰ)의 화합물 20.1내지 90몰%
    XOOC-CH=CH=CO-NH-CH2-(CH2)n-CH2-NH-CO-CH=CH-COOX (Ⅱ)
    상기에서 X는 H, 알카리금속 또는 암모늄그룹이고, n은 0내지 4, 그리고 (c)말레산 0내지 69.9몰%.
  5. 제1내지 4항의 어느한 항에 따라 얻어질 수 있는 중합체를 0.5내지 25중랑% 양으로 세제 및 크리너에서의 첨가제로 사용함을 특징으로 상기의 중합체의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890007405A 1988-05-31 1989-05-31 수용성 중합체의 제법 Withdrawn KR900018217A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3818426.5 1988-05-31
DE3818426A DE3818426A1 (de) 1988-05-31 1988-05-31 Verfahren zur herstellung von wasserloeslichen polymerisaten und ihre verwendung

Publications (1)

Publication Number Publication Date
KR900018217A true KR900018217A (ko) 1990-12-20

Family

ID=6355475

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019890007405A Withdrawn KR900018217A (ko) 1988-05-31 1989-05-31 수용성 중합체의 제법

Country Status (8)

Country Link
US (1) US5104951A (ko)
EP (1) EP0344591B1 (ko)
JP (1) JPH0236210A (ko)
KR (1) KR900018217A (ko)
AT (1) ATE89017T1 (ko)
AU (1) AU3528889A (ko)
CA (1) CA1333737C (ko)
DE (2) DE3818426A1 (ko)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1339231C (en) * 1989-03-30 1997-08-05 Ratana Kanluen Polyfunctional polymers as deinking agents
US5476885A (en) * 1989-07-25 1995-12-19 Nippon Shokubai Co., Ltd. Cement additive, method for producing the same, and cement composition
DE4123049A1 (de) * 1991-07-12 1993-01-14 Basf Ag Vernetzte copolymerisate mit vernetzbaren gruppen auf basis von acrylsaeure oder methacrylsaeure, verfahren zu ihrer herstellung und ihre verwendung
EP0529910B1 (en) * 1991-08-23 1996-03-13 Nippon Shokubai Co., Ltd. Biodegradable hydrophilic crosslinked polymer, process for producing it, and uses thereof
US5268437A (en) * 1992-01-22 1993-12-07 Rohm And Haas Company High temperature aqueous polymerization process
DE4300772C2 (de) * 1993-01-14 1997-03-27 Stockhausen Chem Fab Gmbh Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
US5348679A (en) * 1993-12-09 1994-09-20 H.E.R.C. Incorporated Aqueous multipurpose cleaning composition containing sulfites and glycol ethers
DE4343993A1 (de) * 1993-12-22 1995-06-29 Stockhausen Chem Fab Gmbh Pfropf-Copolymerisate von ungesättigten Monomeren und Polyhydroxyverbindungen, Verfahren zu ihrer Herstellung und ihre Verwendung
US6335404B1 (en) * 1994-04-05 2002-01-01 Rohm And Haas Company Aqueous process for preparing aqueous weight carboxyl containing polymers
JPH09324018A (ja) * 1996-04-04 1997-12-16 Idemitsu Kosan Co Ltd アクリル系重合体、その製造方法、生分解性ビルダー、洗剤組成物及び分散剤
DE10355401A1 (de) * 2003-11-25 2005-06-30 Basf Ag (Meth)acrylsäureester ungesättigter Aminoalkohole und deren Herstellung
DE102005012479A1 (de) * 2005-03-16 2006-09-21 Cognis Ip Management Gmbh Anionische Weichmacher auf Sulfosuccinatbasis
KR102311836B1 (ko) * 2015-11-06 2021-10-12 바스프 에스이 수성 시스템으로부터 물을 분리하는 방법
CN106866472A (zh) * 2017-01-04 2017-06-20 温州大学 一种含亚硫酸盐结构的聚合物加脂剂及其制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2768991A (en) * 1952-04-01 1956-10-30 Bayer Ag Preparation of cation exchangers from co-polymerized carboxylic acid and cross-linking agent
US2884336A (en) * 1955-01-27 1959-04-28 Rohm & Haas Methods for producing coated leather and the products thereof
NL100455C (ko) * 1955-12-27
US3769254A (en) * 1971-08-27 1973-10-30 Nat Starch Chem Corp High strength pressure-sensitive adhesives
US4267103A (en) * 1978-12-07 1981-05-12 The B. F. Goodrich Company Solvent polymerization of carboxyl containing monomers
DE3514364A1 (de) * 1985-04-20 1986-10-23 Henkel KGaA, 4000 Düsseldorf Koerniges waschmittel mit verbessertem reinigungsvermoegen
ES2056848T3 (es) * 1987-04-11 1994-10-16 Basf Ag Copolimeros hidrosolubles, un procedimiento para su obtencion y su empleo.
DE3875788D1 (de) * 1987-04-11 1992-12-17 Basf Ag Wasserloesliche copolymerisate, verfahren zu ihrer herstellung und ihre verwendung.

Also Published As

Publication number Publication date
EP0344591A3 (en) 1990-06-27
DE3818426A1 (de) 1989-12-07
EP0344591B1 (de) 1993-05-05
DE58904247D1 (de) 1993-06-09
ATE89017T1 (de) 1993-05-15
AU3528889A (en) 1989-12-07
US5104951A (en) 1992-04-14
JPH0236210A (ja) 1990-02-06
EP0344591A2 (de) 1989-12-06
CA1333737C (en) 1994-12-27

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PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19890531

PG1501 Laying open of application
PC1203 Withdrawal of no request for examination
WITN Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid