KR890701184A - 다공성 아라미드막 및 막의 성형에 유용한 에멀젼 - Google Patents
다공성 아라미드막 및 막의 성형에 유용한 에멀젼Info
- Publication number
- KR890701184A KR890701184A KR1019880701783A KR880701783A KR890701184A KR 890701184 A KR890701184 A KR 890701184A KR 1019880701783 A KR1019880701783 A KR 1019880701783A KR 880701783 A KR880701783 A KR 880701783A KR 890701184 A KR890701184 A KR 890701184A
- Authority
- KR
- South Korea
- Prior art keywords
- resin
- membrane
- membranes
- pore
- pores
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title claims 8
- 239000004760 aramid Substances 0.000 title claims 5
- 229920003235 aromatic polyamide Polymers 0.000 title claims 5
- 239000000839 emulsion Substances 0.000 title claims 4
- 239000011148 porous material Substances 0.000 claims 8
- 238000000034 method Methods 0.000 claims 6
- 239000011347 resin Substances 0.000 claims 5
- 229920005989 resin Polymers 0.000 claims 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 239000006185 dispersion Substances 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- 239000004952 Polyamide Substances 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000012071 phase Substances 0.000 claims 2
- 229920002647 polyamide Polymers 0.000 claims 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims 2
- BOSAWIQFTJIYIS-UHFFFAOYSA-N 1,1,1-trichloro-2,2,2-trifluoroethane Chemical compound FC(F)(F)C(Cl)(Cl)Cl BOSAWIQFTJIYIS-UHFFFAOYSA-N 0.000 claims 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 claims 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims 1
- XOBKSJJDNFUZPF-UHFFFAOYSA-N Methoxyethane Chemical compound CCOC XOBKSJJDNFUZPF-UHFFFAOYSA-N 0.000 claims 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 claims 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 claims 1
- -1 aliphatic alcohols Chemical group 0.000 claims 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims 1
- 150000001412 amines Chemical group 0.000 claims 1
- 230000001054 cortical effect Effects 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 239000000499 gel Substances 0.000 claims 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 claims 1
- 239000007791 liquid phase Substances 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 claims 1
- 239000003607 modifier Substances 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 230000008961 swelling Effects 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0009—Organic membrane manufacture by phase separation, sol-gel transition, evaporation or solvent quenching
- B01D67/0011—Casting solutions therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/15—Use of additives
- B01D2323/16—Swelling agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/15—Use of additives
- B01D2323/18—Pore-control agents or pore formers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/0283—Pore size
- B01D2325/02834—Pore size more than 0.1 and up to 1 µm
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (6)
- 충분한 량의 수지를 포함하는 균일한 용액을 제조하고 이를 표면상에서 성형한 다음, 성형된 필름을 습식방법을 이용한 상전환성형으로 겔화하는 완전한 방향족 폴리아미드 수지로 구성된 막의 성형방법에 있어서, 평균체류 포아의 크기가 0.05-3.0 마이크론인 다공성 막을 성형하기 위하여 용액중에 다공성막의 성형에는 충분한 량이나 이보다 미만인 경우에는 혼탁한 상태가 나타나는 용액에 대해서는 혼화성이 있으나, 수지에 대해 비용매이거나 또는 약용매에는 혼화성이 없는 포아조절제를 용액중량에 대해 40-50%의 량으로 첨가하여 분산액을 형성한후, 정치시킬 경우에는 액상으로 분리가 되며 적은 경우에는 이와같은 상의 분리를 방지시키기 위해 적당한 교반을 필요로 하는 에멀젼의 형성에는 충분한 량인 분산액에 대하여 5-40%의 분산액 중에 존재하는 용매와 실질적인 혼화성이 있는 침전데를 가하는 것을 특징으로 하는 다공성 아라미드막의 제조방법.
- 제 1 항에 있어서, 에멀젼은 5-8.5%의 폴리아미드를 포함하고 포아조절제는 수지에 대한 팽윤제임을 특징으로 하는 방법.
- 제 2 항에 있어서, 포아조절제는 지방족알코올이나 아민, 지방족 또는 지방족환상에테르, 디옥산, 메틸이소부틸케톤, 니트로푸로판 및 메톡시에탄올로 구성된 군으로부터 선택됨을 특징으로 하는 방법.
- 제 3 항에 있어서, 침전제는 부틸아세테이트, 지방족탄화수소, 트리클로로-트리플루오로에탄, 메톡시에탄, 사염화탄소, 에틸렌글리콜 및 물로 구성된 군으로터 선택됨을 특징으로 하는 방법.
- 제 1 항에 있어서, 에멀젼중 폴리아미드는 5-7%의 아라미드수지로 구성되고, 성형된 막의 평균체류포아의 크기는 0.1-0.5마이크론임을 특징으로 하는 방법.
- 0.5-3마이크론이내의 포아를 포함하는 피층부와, 피층부로부터 거리가 멀어질수록 크기가 증가하여 가장 큰 포아의 평균직경이 피층부의 포아직경 보다 10-300배인 포아가 피충부의 포아와 상호 연결되어 지지부를 구성하고 있음을 특징으로 하는 적충된 피층 및 다공성을 갖는 완전한 방향족 폴리아미드막.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/046,387 US4900443A (en) | 1980-03-14 | 1987-05-06 | Porous aramid membranes and emulsions useful for the casting thereof |
| US46,387 | 1987-05-06 | ||
| PCT/US1988/000228 WO1988008738A1 (en) | 1987-05-06 | 1988-01-27 | Preparation of porous aramide membranes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR890701184A true KR890701184A (ko) | 1989-12-19 |
Family
ID=21943181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880701783A KR890701184A (ko) | 1987-05-06 | 1988-01-27 | 다공성 아라미드막 및 막의 성형에 유용한 에멀젼 |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP0363364B1 (ko) |
| JP (1) | JPH03500734A (ko) |
| KR (1) | KR890701184A (ko) |
| AT (1) | ATE181679T1 (ko) |
| AU (1) | AU611424B2 (ko) |
| DE (1) | DE3856346D1 (ko) |
| WO (1) | WO1988008738A1 (ko) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DK0539870T3 (da) * | 1991-10-26 | 1996-12-09 | Hoechst Ag | Hydrofile, asymmetriske, kemikaliebestandige polyaramidmembraner |
| EP0543171B1 (de) * | 1991-10-26 | 1997-02-05 | Hoechst Aktiengesellschaft | Semipermeable, poröse, asymmetrische Polyetheramidmembranen |
| US5562826A (en) * | 1991-10-26 | 1996-10-08 | Hoechst Aktiengesellschaft | Semipermeable, porous, asymmetric polyether amide membranes |
| DE102010001482A1 (de) | 2010-02-02 | 2011-08-04 | Wacker Chemie AG, 81737 | Verfahren zur Herstellung poröser Siliconformkörper |
| DE102012215881A1 (de) | 2012-09-07 | 2014-03-13 | Wacker Chemie Ag | Poröse Membranen aus vernetzbaren Siliconzusammensetzungen |
| DE102012219544A1 (de) | 2012-10-25 | 2014-04-30 | Wacker Chemie Ag | Poröse Membranen aus vernetzten Siliconzusammensetzungen |
| DE102013203127A1 (de) | 2013-02-26 | 2014-08-28 | Wacker Chemie Ag | Poröse Membranen aus vernetztem thermoplastischem Siliconelastomer |
| DE102013213321A1 (de) | 2013-07-08 | 2015-01-08 | Wacker Chemie Ag | Symmetrisch poröse Membranen aus aldehydvernetztem thermoplastischen Siliconelastomer |
| EP3085435A4 (en) * | 2013-12-16 | 2017-10-11 | Toray Industries, Inc. | Semipermeable membrane manufacturing method and semipermeable membrane |
| CN117624714A (zh) * | 2023-11-27 | 2024-03-01 | 天津工业大学 | 一种芳香族聚酰胺多孔膜及制备方法、包含其的二次电池 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3817386A (en) * | 1972-05-03 | 1974-06-18 | Westinghouse Electric Corp | Reverse osmosis membranes from pyrrone polymer precursors |
| JPS5223346B2 (ko) * | 1972-08-30 | 1977-06-23 | ||
| US4629563B1 (en) * | 1980-03-14 | 1997-06-03 | Memtec North America | Asymmetric membranes |
| DE3220376A1 (de) * | 1982-05-29 | 1983-12-01 | Seitz-Filter-Werke Theo & Geo Seitz GmbH und Co, 6550 Bad Kreuznach | Membranfilter fuer mikrofiltration und verfahren zu seiner herstellung |
| DE3342823A1 (de) * | 1983-11-26 | 1985-06-05 | Seitz-Filter-Werke Theo & Geo Seitz GmbH und Co, 6550 Bad Kreuznach | Verfahren zum herstellen von filterelementen auf der basis von aromatischem polyamid |
-
1988
- 1988-01-27 EP EP88901983A patent/EP0363364B1/en not_active Expired - Lifetime
- 1988-01-27 KR KR1019880701783A patent/KR890701184A/ko not_active Application Discontinuation
- 1988-01-27 AT AT88901983T patent/ATE181679T1/de active
- 1988-01-27 AU AU13403/88A patent/AU611424B2/en not_active Ceased
- 1988-01-27 WO PCT/US1988/000228 patent/WO1988008738A1/en active IP Right Grant
- 1988-01-27 JP JP63501887A patent/JPH03500734A/ja active Pending
- 1988-01-27 DE DE3856346T patent/DE3856346D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0363364B1 (en) | 1999-06-30 |
| AU611424B2 (en) | 1991-06-13 |
| JPH03500734A (ja) | 1991-02-21 |
| AU1340388A (en) | 1988-12-06 |
| WO1988008738A1 (en) | 1988-11-17 |
| ATE181679T1 (de) | 1999-07-15 |
| DE3856346D1 (de) | 1999-08-05 |
| EP0363364A1 (en) | 1990-04-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19881231 |
|
| PG1501 | Laying open of application | ||
| PC1203 | Withdrawal of no request for examination | ||
| WITN | Application deemed withdrawn, e.g. because no request for examination was filed or no examination fee was paid |