KR890010273A - 금속표면의인산처리방법 - Google Patents
금속표면의인산처리방법 Download PDFInfo
- Publication number
- KR890010273A KR890010273A KR1019880016866A KR880016866A KR890010273A KR 890010273 A KR890010273 A KR 890010273A KR 1019880016866 A KR1019880016866 A KR 1019880016866A KR 880016866 A KR880016866 A KR 880016866A KR 890010273 A KR890010273 A KR 890010273A
- Authority
- KR
- South Korea
- Prior art keywords
- ions
- solution
- zinc
- tungsten
- phosphate
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title claims 8
- 239000002184 metal Substances 0.000 title claims 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 title claims 4
- 229910019142 PO4 Inorganic materials 0.000 title 1
- 239000010452 phosphate Substances 0.000 title 1
- 238000000034 method Methods 0.000 claims 12
- 150000003658 tungsten compounds Chemical class 0.000 claims 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 6
- 229910052721 tungsten Inorganic materials 0.000 claims 5
- 239000010937 tungsten Substances 0.000 claims 5
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims 4
- -1 alkali metal tungstate Chemical class 0.000 claims 4
- 239000011260 aqueous acid Substances 0.000 claims 4
- 238000007739 conversion coating Methods 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 claims 2
- 229910052915 alkaline earth metal silicate Inorganic materials 0.000 claims 2
- XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims 2
- 238000005507 spraying Methods 0.000 claims 2
- 229940077935 zinc phosphate Drugs 0.000 claims 2
- 229910000165 zinc phosphate Inorganic materials 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 229940125904 compound 1 Drugs 0.000 claims 1
- OHAVYOCBYILSBZ-UHFFFAOYSA-M dihydroxyboron;hydroxy(dioxo)tungsten Chemical compound O[B]O.O[W](=O)=O OHAVYOCBYILSBZ-UHFFFAOYSA-M 0.000 claims 1
- 238000007598 dipping method Methods 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910001437 manganese ion Inorganic materials 0.000 claims 1
- 229910001453 nickel ion Inorganic materials 0.000 claims 1
- 229940005654 nitrite ion Drugs 0.000 claims 1
- 229940071182 stannate Drugs 0.000 claims 1
- 230000008719 thickening Effects 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
- C23C22/40—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates
- C23C22/42—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing molybdates, tungstates or vanadates containing also phosphates
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (16)
- 텅스텐으로서 약 0.01 내지 20.0g/1의 가용성 텅스텐화합물로 이루어진 수성의 산 아연-인산처리용액과 금속표면을 접촉시키는 것을 특징으로 하는 금속표면의 아연 인산처리 방법.
- 제 1 항에 있어서, 수성의 산용액이 (a) 아연이온 약 0.1 내지 2.0g/1, (b) 인산이온 약 5 내지 40g/1, (c) 텅스텐화합물의 텅스텐으로서 약 0.01 내지 20.0g/1, 및 (d) 전환 피복 촉진제로 이루어진 것을 특징으로 하는 방법.
- 제 1 항에 있어서, 가용성 텅스텐 화합물이 다음이 적어도 하나인 것을 특징으로 하는 방법 : (1) 알칼리금속 텅스테이트, (2) 텅스텐산 암모늄, (3) 보로텅스텐산, (4) 실리코팅스텐산, (5) 알칼리금속 실리코팅스테이트, (6) 실리코팅스텐산 암모늄, 및 (7) 알칼리토금속 실리코팅스테이트.
- 제 3 항에 있어서, 가용성 텅스텐 화합물이 다음의 적어도 하나인 것을 특징으로 한느 방법 : 실리코팅스텐산, 알칼리금속 실리코팅스테이트, 암모늄 실리코팅스테이트, 및 알칼리토금속 실리코팅스테이트.
- 제 2 항에 있어서, (d)중의 전환피복 촉진제가 다음의 적어도 하나로부터 선택되는 것을 특징으로 하는 방법 : (1) 아질산이온 약 0.01 내지 0.5g/1, (2)m-니트로벤젠 술포네이트이온 약 0.05 내지 5g/1, 및 (3) 과산화수소 약 0.5 내지 10g/1.
- 제 1 항에 있어서, 상기 용액이 또한 다음의 적어도 하나를 함유하는 것을 특징으로 하는 방법 : (4) 망간이온 약 약 0.1 내지 3g/1, (5) 니켈이온 약 0.1 내지 4g/1, (6) 플루오르화이온 약 0.05 내지 4g/1, 및 (7) 질산이온 약 0.1 내지 15g/1.
- 제 1 항 내지 제 6항중의 어느 하나에 있어서, 상기 접촉이 금속표면을 용액중에 침지시킴으로써 시행되는 것을 특징으로 하는 방법.
- 제 1 항 내지 제6항중의 어느 하나에 있어서, 상기 접촉이 금속표면에 용액을 스프레이함으로써 시행되는 것을 특징으로 하는 방법.
- 제 1 항 내지 제6항중의 어느 하나에 있어서, 상기 접촉이 침지 및 스프레이처리를 병용함으로써 시행되는 것을 특징으로 하는 방법.
- 제 7 항 또는 제 9 항에 있어서, 상기 용액이 또한 약 0.05 내지 2g/1의 염소산 이온을 함유하는 것을 특징으로 하는 방법.
- 제 8 항 또는 제 9 항에 있어서, 상기 용액이 또한 약 2 내지 5.0g/1의 염소산 이온을 함유하는 것을 특징으로 하는 방법.
- 제11항에 있어서, 약 0.4 내지 1.3g/1의 아연이온이 존재하는 것을 특징으로 하는 방법.
- 제 1 항에 있어서, 금속표면이 다음의 어느 하나인 것을 특징으로 하는 방법 : 철-기재 표면, 아연-기재표면, 및 이들의 결합.
- 수성의 산 아연-인산처리용액의 처방에 사용되는 수성 농축조성물에 있어서, 아연이온, 인산이온 및 가용성 텅스텐화합물 형태의 텅스텐의 중량비가 1:2.5 내지 400:0.005 내지 200으로 이루어진 성분(A)와, 전환피부 촉진제를 함유하는 성분(B)로 구성된 것을 특징으로 하는 상기 농축 조성물.
- 제14항에 있어서, 가용성 텅스텐화합물 형태의 텅스텐이 상기 성분(b)에 포함되는 것을 특징으로 하는 수성 농축 조성물.
- (a) 아연이온 약 0.1 내지 2.0g/1, (b) 인산이온 약 5 내지 40g/1, (c) 가용성 텅스텐화합물의 텅스텐으로서 약 0.01 내지 20.0g/1, 및 (d) 전환피복 촉진제로 이루어진 수성 산용액으로 금속표면을 처리함으로써 얻어지는 것을 특징으로 하는 인산처리된 금속.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32173787A JPH01162780A (ja) | 1987-12-18 | 1987-12-18 | 塗装用金属表面のリン酸亜鉛処理方法 |
| JP62-321737 | 1987-12-18 | ||
| JP63-65271 | 1988-03-17 | ||
| JP6527188A JPH01240671A (ja) | 1988-03-17 | 1988-03-17 | 塗装用金属表面のリン酸亜鉛処理方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR890010273A true KR890010273A (ko) | 1989-08-07 |
Family
ID=26406399
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880016866A KR890010273A (ko) | 1987-12-18 | 1988-12-17 | 금속표면의인산처리방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5039363A (ko) |
| EP (1) | EP0321059B1 (ko) |
| KR (1) | KR890010273A (ko) |
| AU (1) | AU610313B2 (ko) |
| CA (1) | CA1333683C (ko) |
| DE (1) | DE3875459T2 (ko) |
| ES (1) | ES2092983T3 (ko) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100597759B1 (ko) * | 1998-04-16 | 2006-07-05 | 니혼 파커라이징 가부시키가이샤 | 금속의 표면처리 방법 및 이 표면처리 방법으로 얻어진 표면을 가진 금속부재 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3392008B2 (ja) | 1996-10-30 | 2003-03-31 | 日本表面化学株式会社 | 金属の保護皮膜形成処理剤と処理方法 |
| JPH0696773B2 (ja) * | 1989-06-15 | 1994-11-30 | 日本ペイント株式会社 | 金属表面のリン酸亜鉛皮膜形成方法 |
| ES2111949T3 (es) * | 1993-09-06 | 1998-03-16 | Henkel Kgaa | Procedimiento de fosfato exento de niquel. |
| US5653790A (en) * | 1994-11-23 | 1997-08-05 | Ppg Industries, Inc. | Zinc phosphate tungsten-containing coating compositions using accelerators |
| DE19500927A1 (de) * | 1995-01-16 | 1996-07-18 | Henkel Kgaa | Lithiumhaltige Zinkphosphatierlösung |
| DE19511573A1 (de) * | 1995-03-29 | 1996-10-02 | Henkel Kgaa | Verfahren zur Phosphatierung mit metallhaltiger Nachspülung |
| DE19541285C2 (de) * | 1995-11-06 | 2003-04-17 | Kluthe Gmbh Chem Werke | Verfahren und Mittel zur Phosphatierung von Metalloberflächen |
| DE19834796A1 (de) | 1998-08-01 | 2000-02-03 | Henkel Kgaa | Verfahren zur Phosphatierung, Nachspülung und kathodischer Elektrotauchlackierung |
| US6391384B1 (en) * | 2000-07-10 | 2002-05-21 | Carus Corporation | Method for providing a corrosion inhibiting solution |
| US10611986B1 (en) | 2018-03-15 | 2020-04-07 | Earthcare Labs, Llc | Cleaning composition comprising a cationic/nonionic mixture |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2502441A (en) * | 1946-11-22 | 1950-04-04 | Oakite Prod Inc | Phosphate coating of metals |
| FR1092299A (fr) * | 1953-03-27 | 1955-04-20 | Parker Ste Continentale | Revêtements noirs pour métaux et leur procédé d'obtention |
| US2854369A (en) * | 1957-10-04 | 1958-09-30 | Oakite Prod Inc | Increasing the solubility of metal accelerators in phosphatizing solutions |
| US3261723A (en) * | 1962-11-30 | 1966-07-19 | Lubrizol Corp | Method for reducing combustion chamber deposits in internal combustion engines |
| US3819424A (en) * | 1971-06-17 | 1974-06-25 | Oxy Metal Finishing Corp | Method and composition for treating metal surfaces |
| CA1133806A (en) * | 1978-05-08 | 1982-10-19 | George D. Howell | Detergent phosphatizer composition and method of using same |
| DE2905535A1 (de) * | 1979-02-14 | 1980-09-04 | Metallgesellschaft Ag | Verfahren zur oberflaechenbehandlung von metallen |
| US4673444A (en) * | 1981-03-16 | 1987-06-16 | Koichi Saito | Process for phosphating metal surfaces |
| US4486241A (en) * | 1981-09-17 | 1984-12-04 | Amchem Products, Inc. | Composition and process for treating steel |
| ES8606528A1 (es) * | 1985-02-22 | 1986-04-01 | Henkel Iberica | Procedimiento para el fosfatado de superficies metalicas, especialmente ferreas |
-
1988
- 1988-12-16 DE DE8888202896T patent/DE3875459T2/de not_active Expired - Fee Related
- 1988-12-16 CA CA000586120A patent/CA1333683C/en not_active Expired - Fee Related
- 1988-12-16 AU AU27023/88A patent/AU610313B2/en not_active Ceased
- 1988-12-16 ES ES88202896T patent/ES2092983T3/es not_active Expired - Lifetime
- 1988-12-16 EP EP88202896A patent/EP0321059B1/en not_active Expired - Lifetime
- 1988-12-17 KR KR1019880016866A patent/KR890010273A/ko not_active Application Discontinuation
-
1990
- 1990-05-30 US US07/532,241 patent/US5039363A/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100597759B1 (ko) * | 1998-04-16 | 2006-07-05 | 니혼 파커라이징 가부시키가이샤 | 금속의 표면처리 방법 및 이 표면처리 방법으로 얻어진 표면을 가진 금속부재 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0321059A1 (en) | 1989-06-21 |
| AU610313B2 (en) | 1991-05-16 |
| DE3875459T2 (de) | 1993-03-25 |
| AU2702388A (en) | 1989-06-22 |
| US5039363A (en) | 1991-08-13 |
| EP0321059B1 (en) | 1992-10-21 |
| DE3875459D1 (de) | 1992-11-26 |
| ES2092983T3 (es) | 1996-12-16 |
| CA1333683C (en) | 1994-12-27 |
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