KR890009366A - 치석 억제 조성물 - Google Patents
치석 억제 조성물 Download PDFInfo
- Publication number
- KR890009366A KR890009366A KR1019880013073A KR880013073A KR890009366A KR 890009366 A KR890009366 A KR 890009366A KR 1019880013073 A KR1019880013073 A KR 1019880013073A KR 880013073 A KR880013073 A KR 880013073A KR 890009366 A KR890009366 A KR 890009366A
- Authority
- KR
- South Korea
- Prior art keywords
- hydrogen
- acid
- composition
- group
- alkyl
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims 26
- 208000006558 Dental Calculus Diseases 0.000 title claims 13
- 230000002401 inhibitory effect Effects 0.000 title claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 25
- 239000001257 hydrogen Substances 0.000 claims 25
- -1 alkyl itaconate Chemical compound 0.000 claims 16
- 150000002431 hydrogen Chemical group 0.000 claims 12
- 229910052783 alkali metal Inorganic materials 0.000 claims 11
- 229920001577 copolymer Polymers 0.000 claims 10
- 150000003839 salts Chemical class 0.000 claims 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 9
- 150000001340 alkali metals Chemical group 0.000 claims 8
- 239000002253 acid Substances 0.000 claims 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 6
- 150000001342 alkaline earth metals Chemical group 0.000 claims 6
- 229940091249 fluoride supplement Drugs 0.000 claims 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 5
- 239000003112 inhibitor Substances 0.000 claims 5
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 5
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 4
- 239000011976 maleic acid Substances 0.000 claims 4
- 210000000214 mouth Anatomy 0.000 claims 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 3
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical group OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims 3
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 claims 3
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 3
- 150000008064 anhydrides Chemical class 0.000 claims 3
- 229920001519 homopolymer Polymers 0.000 claims 3
- 229910052751 metal Inorganic materials 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 2
- 208000004188 Tooth Wear Diseases 0.000 claims 2
- 150000007513 acids Chemical class 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 2
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 claims 2
- 235000019832 sodium triphosphate Nutrition 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 claims 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 1
- XGRSAFKZAGGXJV-UHFFFAOYSA-N 3-azaniumyl-3-cyclohexylpropanoate Chemical compound OC(=O)CC(N)C1CCCCC1 XGRSAFKZAGGXJV-UHFFFAOYSA-N 0.000 claims 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 claims 1
- FXBVGKCQLSQGBD-UHFFFAOYSA-N CCCCO.OP(=O)OP(O)=O Chemical compound CCCCO.OP(=O)OP(O)=O FXBVGKCQLSQGBD-UHFFFAOYSA-N 0.000 claims 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 1
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 1
- 125000005336 allyloxy group Chemical group 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 229910052791 calcium Inorganic materials 0.000 claims 1
- 239000011575 calcium Chemical group 0.000 claims 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims 1
- 229940018557 citraconic acid Drugs 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 239000006071 cream Substances 0.000 claims 1
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 1
- LRCFXGAMWKDGLA-UHFFFAOYSA-N dioxosilane;hydrate Chemical group O.O=[Si]=O LRCFXGAMWKDGLA-UHFFFAOYSA-N 0.000 claims 1
- 229940005740 hexametaphosphate Drugs 0.000 claims 1
- 229910052749 magnesium Inorganic materials 0.000 claims 1
- 239000011777 magnesium Chemical group 0.000 claims 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 claims 1
- DUDRFISLZJPLTJ-UHFFFAOYSA-N methane;phosphoric acid Chemical compound C.OP(O)(O)=O DUDRFISLZJPLTJ-UHFFFAOYSA-N 0.000 claims 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 claims 1
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 239000008008 oral excipient Substances 0.000 claims 1
- 239000000546 pharmaceutical excipient Substances 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 229920002959 polymer blend Polymers 0.000 claims 1
- 229910052700 potassium Inorganic materials 0.000 claims 1
- 239000011591 potassium Chemical group 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Chemical group 0.000 claims 1
- 235000013024 sodium fluoride Nutrition 0.000 claims 1
- 239000011775 sodium fluoride Substances 0.000 claims 1
- 229960000414 sodium fluoride Drugs 0.000 claims 1
- 229960004711 sodium monofluorophosphate Drugs 0.000 claims 1
- ANOBYBYXJXCGBS-UHFFFAOYSA-L stannous fluoride Chemical compound F[Sn]F ANOBYBYXJXCGBS-UHFFFAOYSA-L 0.000 claims 1
- 229960002799 stannous fluoride Drugs 0.000 claims 1
- 229920001187 thermosetting polymer Polymers 0.000 claims 1
- 239000004634 thermosetting polymer Substances 0.000 claims 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
- A61K8/21—Fluorides; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/92—Oral administration
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Cosmetics (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (17)
- (a)유효량의 불화물 소오스, (b)유효량의 치과용 마모제; 그리고 (c)C3-C5모노불포화 모노카르복실 및 디카르복실산, 이것의 염 및 무수물로부터, 그리고 이러한 산에서 선택된 카르복실 단량체를 최소한 30중량% 함유하는 공중합체로부터, 그리고 이들의 혼합물로부터 선택된 0.01내지 10중량%의 치석방지제를 포함하는 구강조성물.
- 제1항에 있어서, 상기 공중합체의 최소한 한공단량체는 아크릴아미드, 알킬 아크릴레이트, 알킬 이타콘 에이트, 비닐술포산, 히드록시알킬 아크릴레이트, 알콕시알킬아크릴레이트,저급알케닐카르복실레이트. 스티렌술폰산, 알릴옥시히드록시알칸 술폰산, 아크릴아미도알칸술폰산, 포스포노알칸 카르복실산, 술포알킬아크릴레이트, 이들의 염 및 무수물, 그리고 이를 공단량체들의 혼합물로부터 선택된 것을 특징으로 하는 조성물.
- 제2항에 있어서, 불화물 소오스의 양은 상기의 구강조성물에 기초하여 0.005중량% 내지 3.0중량%이고, 상기의 카르복실산 단량체의 양은 상기의 공중합체에 기초하여 40내지 90중량%이고, 그리고 상기의 단독중합체와 공중합체의 분자량은 약400내지 100,000의 범위에 있는 것을 특징으로 하는 조성물.
- 제3항에 있어서, 상기의 공중합체는 상기 공단량체중의 최소한 한 공단량체를 60 내지 10%함유하고, 상기의 불화물 소오스의 양은 0.05내지 1%이고, 그리고 상기의 치석 방지제의 양은 0.1내지 5%인 것을 특징으로 하는 조성물.
- 제4항에 있어서, 상기의 카르복실산 단량체는 아크릴산, 메타크릴산, 이타콘산, 말레산, 말레산무수물, 시트라콘산, 메사콘산, 상기 산들의 염, 그리고 이들의 혼합물로부터 선택되며; 여기서의 아크릴아미드는 아래와 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1및 R2은 수소 및 C1-C12알킬그룹으로부터 개별적으로 선택된다); 알킬 아크릴레이트는 아래의 시과 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1은 C1-C6알킬그룹으로부터 그리고 R1이 R3-Y(R2는 C1-C6알킬그룹이고 Y는 -SO3X, C(O)R3또는 -CO2X(X는 수소, 알칼리금속, 알칼리토금속, 또는 암모늄이다)이다)인 치환된 알킬그룹이고, 그리고 R3는 C1-C3알킬이다); 알킬 이타콘에이트는 아래의 식과 같이 정의되며(식중, R2및 R3는 C1-C4알킬그룹 및 수소로부터 개별적으로 선택되며, 단 R2또는 R3중의 하나가 수소일 수 있긴 하지만 R2및 R3둘 모두가 수소일수는 없다); 비닐 술폰산 및 이들의 염은 아래의 식과 같이 정의되며(식중, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 히드록시알킬 아크릴레이트는 아래의 식과 정의되며(식중, R은 수소 및 C1-C4알킬그룹으로부터 선택된 것이고, R1은 C2-C4알킬렌그룹에서 선택된 것이고 n은 1내지 5이다); 알콕시알킬 아크릴레이트는 아래와 같이 정의되며(식중, R은 수소 및 메틸그룹에서 선택되고 R1은 C2-C4알킬렌 그룹으로부터 선택된 것이고, R2는 C1-C10알킬그룹으로부터 선택된 것이고, n은 1내지 5이다); 저급 알케닐 카르복시레이트는 아래의 식과 같이 정의되며(식중 R은 수소 또는 C1-C6저급알킬그룹이고, R1은 C1-C12알킬그룹에서 선택된 것이다); 비닐알콜은 아래의 식과 같이 정의되며(식중, R은 C1-C6저급알킬그룹이다); 스티렌술포산 및 이것의 염은 아래의 식과 같이 정의되며(식중 R은 C1-C6알킬그룹에서 선택된 것이고 X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 알릴옥시 히드록시알칸술포산 및 그 염은 아래의 식과 같이 정의되며(식중 R및 R1은 수소 및 메틸그룹으로부터 저마다 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 아크릴아미도알칼 술포산 및 그 염은 아래의 식과 같이 정의되며(식중 R은 수소 및 메틸그룹으로부터 선택된 것이고 R1및 R2는 수소 및 C1-C4알킬그룹으로부터 저마다 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다); 술포알킬아크릴레이트는 아래의 식과 같이 정의되는(식중, R1은 수소, 메틸 그리고 일반식(이 식에서, R2은 C1-C12알킬렌 그룹에서 선택된 것이고, X는 수소, 알칼리금속, 알칼리토금속 및 암모늄기로부터 선택된 것이다)에서 선택된 것이다)것을 특징으로 하는 조성물.
- 제5항에 있어서, 상기의 아크릴아미드에서의 R1또는 R2둘 모두가 수소가 아니며; 상기의 알킬 아크릴레이트에 있어서의 R1는 C1-C4의 비치환된 알킬그룹이고; 상기의 알킬 이타콘에이트에 있어서의 R2및 R3는 C1-C4의 비치환된 알킬그룹에서 개별적으로 선택된 것이고; 상기의 술포산 및 그 염에 있어서의 X는 알칼리금속 및 암모늄 기로부터 선택된 것이고; 상기의 히드록시알킬 아크릴레이트에 있어서의 R은 수소 및 메틸그룹에서 선택된 것이고 R1는 C2-C3의 알킬렌 그룹으로부터 선택된 것이며; 상기의 알콕시알킬 아크릴레이트에 있어서의 R1는 C2-C3알킬렌 그룹으로부터 선택된 것이고, R2는 C1-C4알킬그룹으로부터 선택된 것이고, n은 1내지 3의 수이고; 상기의 스티렌술포산 및 그 염에 있어서의 R는 수소이고, X는 수소, 암모늄 및 알칼리금속 라디칼로부터 선택된 것이고, 그리고 상기의 -SO3X그룹은 상기의 페닐고리상의 3또는 4위치에 있고; 상기의 아크릴아미도알칼술폰산 및 그 염에 있어서의 R은 수소이고 R1및 R2는 C1-C3알킬그룹으로부터 개별적으로 선택된 것이고; 그리고 상기의 술포알킬 아크릴레이트에 있어서의 R2는 C2-C4알킬렌그룹으로부터 선택된 것이고 X는 수소, 나트륨, 칼륨, 칼슘, 마그네슘 및 그리고 암모늄기로부터 선택된 것임을 특징으로 하는 조성물.
- 제6항에 있어서, 치석의 형성을 억제하는 데에 효과적인 6내지 10의 pH를 가지며, 불화물 소오스의 양은 약50ppm내지 약 2,500ppm의 불화물이온을 제공하느데에 충분한 양이며; 상기의 치석방지제의 양은 1내지 1000ppm이며, 상기의 치과용 마모제의 양은 10내지 70%이며; 그리고 상기의 조성물은 구강용 부형제도 포함하는 것을 특징으로 하는 조성물.
- 제7항에 있어서, 상기의 마모제의 양은 0.1내지 7중량%이며, 이것은 알칼리금속 헥사메타포스페이트, 알칼리금속 트리폴리포스페이트, 디알칼리금속 이산, 트리알칼리금속 일산, 알칼리금속 트리폴리포스페이트, 테트라알칼리금속 피로포스페이트, 히드록시에틸에탄 디포스폰산, 그리고 이들의 혼합물로부터 선택된 것임을 특징으로 하는 조성물.
- 제6항에 있어서, 상기의 치석방지제의 양은 1내지 5%이며, 상기의 공중합체 치석방지제는 2,000내지 20,000의 분자량을 가지며 상기의 모노불포화 카르복실산은 아크릴산, 메타크릴산, 말레산, 말레산 무수물, 이타콘산, 그리고 이들의 혼합물로부터 선택되는 것을 특징으로 하는 조성물.
- 제9항에 있어서, 상기의 치석방지제는 아래와 같은 공중합체들로부터 선택된 것임을 특징으로 하는 조성물.(a)AA:MAA;t-BuAm의 60:20:20 공중합체(b)AA:HPA의 63:37 공중합체(c)AA:AMPS의 51:49 공중합체(d)말레산의 100단독중합체(e)아크릴산의 100단독중합체여기서, AA=아크릴산 MAA=메타크릴산 HPA=히드록시프로필 아크릴레이트 AMPS=2-아크릴아미드-2-메틸프로판술포산.
- 제5항에 있어서, 조성물이 크리임의 형태이고; 상기의 불화물 소오스는 불화나트륨, 불화제1주석, 모노플루오로인산나트륨 및 이들의 혼합물로부터 선택되 것이고; 상기의 치과용 마모제의 양은 10내지75%이며 그 마모제는 실리카, 수화된 알루미늄, 불용성 메탄인산염, 열경화성 중합체수지, 그리고 이들의 혼합물로부터 선택된 것이고; 그리고 상기의 구강을 부형제의 양은 10내지 90중량%인 것을 특징으로 하는 조성물.
- 제1항에 정의된 조성물을 구강에 가하는 것을 포함하는 치석 억제 방법.
- 제3항에 정의된 조성물을 구강에 가하는 것을 포함하는 치석 억제 방법.
- 제4항에 정의된 조성물을 구강에 바르는 것을 포함하는 치석 억제 방법.
- 제5항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.
- 제7항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.
- 제11항에 정의된 조성물을 치아에 바르는 것을 포함하는 치석 억제 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US135.803 | 1987-12-21 | ||
| US07/135,803 US4842847A (en) | 1987-12-21 | 1987-12-21 | Dental calculus inhibiting compositions |
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| Publication Number | Publication Date |
|---|---|
| KR890009366A true KR890009366A (ko) | 1989-08-01 |
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ID=22469747
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019880013073A KR890009366A (ko) | 1987-12-21 | 1988-10-07 | 치석 억제 조성물 |
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| Country | Link |
|---|---|
| US (1) | US4842847A (ko) |
| EP (1) | EP0321650A1 (ko) |
| JP (1) | JPH01172316A (ko) |
| KR (1) | KR890009366A (ko) |
| CN (1) | CN1034667A (ko) |
| AU (1) | AU2092988A (ko) |
| PT (1) | PT88612A (ko) |
| ZA (1) | ZA886021B (ko) |
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| US4436721A (en) * | 1983-06-08 | 1984-03-13 | Colgate-Palmolive Company | Oral composition having mole ratio of tetra (methylene phosphonate) to alkali metal fluoride of at least 1.4:1 |
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-
1987
- 1987-12-21 US US07/135,803 patent/US4842847A/en not_active Expired - Fee Related
-
1988
- 1988-08-13 EP EP88113194A patent/EP0321650A1/en not_active Withdrawn
- 1988-08-15 AU AU20929/88A patent/AU2092988A/en not_active Abandoned
- 1988-08-15 ZA ZA886021A patent/ZA886021B/xx unknown
- 1988-08-22 JP JP63206498A patent/JPH01172316A/ja active Pending
- 1988-09-28 PT PT88612A patent/PT88612A/pt unknown
- 1988-10-07 KR KR1019880013073A patent/KR890009366A/ko not_active Application Discontinuation
- 1988-12-17 CN CN88108695A patent/CN1034667A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| PT88612A (pt) | 1989-07-31 |
| US4842847A (en) | 1989-06-27 |
| AU2092988A (en) | 1989-06-22 |
| JPH01172316A (ja) | 1989-07-07 |
| CN1034667A (zh) | 1989-08-16 |
| EP0321650A1 (en) | 1989-06-28 |
| ZA886021B (en) | 1989-07-26 |
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