[go: up one dir, main page]

KR890008269A - 우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로 하는 도장 조성물 - Google Patents

우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로 하는 도장 조성물 Download PDF

Info

Publication number
KR890008269A
KR890008269A KR1019880014915A KR880014915A KR890008269A KR 890008269 A KR890008269 A KR 890008269A KR 1019880014915 A KR1019880014915 A KR 1019880014915A KR 880014915 A KR880014915 A KR 880014915A KR 890008269 A KR890008269 A KR 890008269A
Authority
KR
South Korea
Prior art keywords
composition
component
anhydride
film forming
group
Prior art date
Application number
KR1019880014915A
Other languages
English (en)
Other versions
KR920002989B1 (ko
Inventor
챤 웬-슈앙
리 듀포드 에드위드
류 클라니카 조셉앤드
Original Assignee
헬렌에이·파블릭크
피피지 인더스트리즈, 인코포레이티드
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 헬렌에이·파블릭크, 피피지 인더스트리즈, 인코포레이티드 filed Critical 헬렌에이·파블릭크
Publication of KR890008269A publication Critical patent/KR890008269A/ko
Application granted granted Critical
Publication of KR920002989B1 publication Critical patent/KR920002989B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10—Epoxy resins modified by unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4263—Polycondensates having carboxylic or carbonic ester groups in the main chain containing carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/423—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof containing an atom other than oxygen belonging to a functional groups to C08G59/42, carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/06—Polyurethanes from polyesters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Epoxy Resins (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

내용 없음

Description

우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로 하는 도장 조성물
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (21)

  1. 수지상 결합제와 임의로 희석제, 안료 및 도장 조성물에 보통 존재하는 다른 성분들을 포함하는 도장 조성물에 있어서, (A) 50중량% 이상의 디에폭사이드를 함유한 폴리에폭사이드: 및 (B)분자당 적어도 3개의 하이드로실 그룹을 갖는 폴리올 성분(ⅰ), 폴리이소시아네이트(ⅱ), 및 폴리카복실산 무수물(ⅲ)을 반응시켜 제조한, 500미만의 산 당량과 분자당 평균 3개 이상의 카복실산 그룹을 갖는 우레탄 함유 다가산 경화제를 포함하는 수지상 결합제를 특징으로 하는 도장 조성물.
  2. 제1항에 있어서, 디에폭사이드가 사이클로헥센 옥사이드 잔기 함유 디에폭사이드, 지환족 폴리올의 디글리시딜 에테르 및 이들의 혼합물로 구성된 군으로 부터 선택된 조성물.
  3. 제2항에 있어서, 조성물에 에폭시 그룹 함유 아크릴 중합체를 포함하는 조성물.
  4. 제1항에 있어서, 폴리올 성분(ⅰ)이 1000이하의 수평균 분자량과 분자당평균 3개 이상의 하이드록실 그룹을 갖는 올리고머 에스테르를 포함하는 조성물.
  5. 제4항에 있어서, 올리고머 에스테르가 카복실 그룹들 사이에 2개 이상의 탄소원자를 갖는 선형 지방족 디카복실산 또는 그이 작용성 등가물(a)를 적어도 3개의 하이드록실 그룹을 갖는 유기 폴리올(b)와 반응시켜 제조된 조성물.
  6. 제5항에 있어서, 지방족 디카복실산 또는 그의 작용성 등가물(a)이 적어도 6개의 탄소원자를 갖는 조성물.
  7. 제5항에 있어서, 유기 폴리올(b)이 탄소원자 3개 내지 12개를 갖는 지방족 폴리올인 조성물.
  8. 제4항에 있어서, 폴리올 성분이 폴리에테르디올을 더 포함한 조성물.
  9. 제8항에 있어서, 폴리에테르 디올이폴리(옥시테트라메틸렌)디올인 조성물.
  10. 제1항에 있어서, 폴리이소시아네이트가 지방족 디이소시아네이트인 조성물.
  11. 제10항에 있어서, 지방족 디이소시아네이트가 적어도 4개의 탄소원자를 갖는 선형 지방족 잔기를 함유한 조성물.
  12. 제1항에 있어서, 무수물(ⅲ)이 사이클릭 디카복실산의 1,2-무수물인 조성물.
  13. 제12항에 있어서, 사이클릭 디카복실산이 지환족 디카복실산인 조성물.
  14. 제12항에 있어서, 무수물이 헥사하이드로프탈산 무수물, 알킬 치환된 헥사하이드로프탈산 무수물 및 이들의 혼합물로 구성된 군으로 부터 선택된 조성물.
  15. 제1항에 있어서, 성분(A)의 에폭시 그룹에 대한 성분(B)의 산 그룹의 당량비가 1.2 내지 0.8:1이고 이 당량비가 경화 생성물을 생성하기에 충분한 조성물.
  16. 제1항에 있어서, 성분(ⅰ)의 하아드로실 그룹에 대한 성분(ⅱ)의 이소시아네이트 그룹의 당량비가 0.4미만이고 성분(ⅰ)의 하이드록실 그룹에 대한 성분(ⅲ)의 무수물 그룹의 당량비가 0.6보다 크며; 언급한 반응 생성물은 이소시아네이트 작용기가 없고 분자당 적어도 3개의 카복실산 그룹을 함유하는 조성물.
  17. 기판에 유색 막 형성 조성물을 도포하여 하도막을 형성하고 이 하도막에 투명한 막 형성 조성물을 도포하여 하도막 위에 투명한 상도막을 형성하는 것을 포함하는 기판의 혼합 도장 방법에 있어서, 투명한 막 형성 조성물이 제1항의 수지상 결합제를 포함함을 특징으로 하는 방법.
  18. 제17항에 있어서, 투명한 막 형성 조성물이 제2항의 수지상 결합제를 포함하는 방법.
  19. 제17항에 있어서, 투명한 막 형성 조성물이 제4항의 수지상 결합제를 포함하는 방법.
  20. 제17항에 있어서, 투명한 막 형성 조성물이 제15항의 수지상 결합제를 포함하는 방법.
  21. 제17항에 있어서, 투명한 막 형성 조성물이 제16항의 수지상 결합제를 포함하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880014915A 1987-11-13 1988-11-12 우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로하는 도장 조성물 KR920002989B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12027187A 1987-11-13 1987-11-13
US120.271 1987-11-13
US120,271 1987-11-13

Publications (2)

Publication Number Publication Date
KR890008269A true KR890008269A (ko) 1989-07-10
KR920002989B1 KR920002989B1 (ko) 1992-04-11

Family

ID=22389253

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019880014915A KR920002989B1 (ko) 1987-11-13 1988-11-12 우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로하는 도장 조성물

Country Status (8)

Country Link
EP (1) EP0317185B1 (ko)
JP (1) JPH07103344B2 (ko)
KR (1) KR920002989B1 (ko)
AU (1) AU592721B2 (ko)
CA (1) CA1340155C (ko)
DE (1) DE3874679T2 (ko)
ES (1) ES2052743T3 (ko)
MX (1) MX169370B (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5074979B1 (en) * 1990-06-20 1995-02-28 Ppg Industries Inc Cationic resin containing blocked isocyanate groups suitable for use in electrodeposition
JP4423513B2 (ja) 1997-10-20 2010-03-03 東洋紡績株式会社 接着用樹脂組成物及び接着用フィルム
US8415509B2 (en) 2003-11-20 2013-04-09 Solvay (Societe Anonyme) Process for producing dichloropropanol from glycerol, the glycerol coming eventually from the conversion of animal fats in the manufacture of biodiesel
KR20080019005A (ko) 2005-05-20 2008-02-29 솔베이(소시에떼아노님) 폴리히드록실화 지방족 탄화수소에서 출발하여클로로히드린을 제조하는 방법
EP2207617A1 (en) 2007-10-02 2010-07-21 SOLVAY (Société Anonyme) Use of compositions containing silicon for improving the corrosion resistance of vessels
TWI478875B (zh) 2008-01-31 2015-04-01 Solvay 使水性組成物中之有機物質降解之方法
US8008422B2 (en) * 2008-07-11 2011-08-30 3M Innovative Properties Company Curable resin composition
FR2935968B1 (fr) 2008-09-12 2010-09-10 Solvay Procede pour la purification de chlorure d'hydrogene
CN107759771A (zh) 2010-09-30 2018-03-06 索尔维公司 天然来源的环氧氯丙烷的衍生物

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3419510A (en) * 1966-11-14 1968-12-31 Ashland Oil Inc Carboxyl-terminated urethane-containing polyesters and coating composition derived therefrom
JPS57105461A (en) * 1980-12-22 1982-06-30 Asahi Denka Kogyo Kk Covering composition
AU574579B2 (en) * 1985-08-19 1988-07-07 Ppg Industries Ohio, Inc. Polyacid curing agents in clear topcoats on pigmented base
EP0263429A3 (en) * 1986-10-06 1989-01-25 Ppg Industries, Inc. Epoxy-functional polyurethanes and high solids thermosetting coating compositions thereof and color plus clear mode of applying the same
US5055524A (en) * 1987-07-16 1991-10-08 Ppg Industries, Inc. Polyol-modified polyanhydride curing agent for polyepoxide powder coatings
US4927868A (en) * 1987-08-19 1990-05-22 Ppg Industries, Inc. High solids coating compositions containing a polyepoxide and a copolymer of an alpha-olefin and an olefinically unsaturated monoanhydride

Also Published As

Publication number Publication date
JPH02626A (ja) 1990-01-05
DE3874679T2 (de) 1993-04-01
CA1340155C (en) 1998-12-01
AU2498188A (en) 1989-06-08
KR920002989B1 (ko) 1992-04-11
EP0317185B1 (en) 1992-09-16
MX169370B (es) 1993-06-30
EP0317185A3 (en) 1989-10-04
ES2052743T3 (es) 1994-07-16
JPH07103344B2 (ja) 1995-11-08
AU592721B2 (en) 1990-01-18
EP0317185A2 (en) 1989-05-24
DE3874679D1 (de) 1992-10-22

Similar Documents

Publication Publication Date Title
US3117099A (en) Curable mixtures comprising epoxide compositions and divalent tin salts
US3373221A (en) Reaction products of unsaturated esters of polyepoxides and unsaturated carboxylic acids, and polyisocyanates
US3012987A (en) Coating composition comprising a blend of polyurethane reaction products
US2935488A (en) Epoxide compositions and resins therefrom
EP0217364A3 (en) Polysiloxanes containing polyester groups for paints and their application
US4091049A (en) Powder coating compositions containing glycidyl ester copolymers and carboxyl terminated crosslinking agent
GB1379938A (en) Storagestable rapidly curable epoxide resin composition
KR910003045A (ko) 폴리올레핀 기재용 정착제 조성물
KR910009861A (ko) 수분산성 결합제 조성물, 연소 충진제의 제조방법 및 이로부터 제조한 피복물
US4113702A (en) Method of preparing polyester varnish resins of low viscosity
KR870008978A (ko) 복합피복의 적용방법 및 액상의 가교결합 조성물
US2890196A (en) Curable composition comprising a diepoxide, a polycarboxylic anhydride and a polyhydric compound
KR890008269A (ko) 우레탄 함유 다가산 경화제 및 폴리에폭사이드를 기재로 하는 도장 조성물
KR910011971A (ko) 저온 경화형 폴리에스테르 수지의 제조방법 및 이를 함유하는 분체도료 조성물
US4861832A (en) Flexible epoxy film from an epoxy resin reacted with a ketimine/amine terminated butadiene/acrylonitrile copolymer blend
KR890008270A (ko) 다가산 경화제 및 폴리에폭사이드를 기재로 하는 도장 조성물
KR840002010A (ko) 경화성 폴리(옥사졸리돈 및 우레탄) 조성물 및 그 제법
BR8501083A (pt) Resina plastica a base de poliepoxidos,processo para a preparacao,emprego e processo para o revestimento eletroforetico de um substrato ligado como catodo
MX9803667A (es) Poliesterdioles de baja viscosidad, altos solidos, y composiciones que los contienen.
US4179418A (en) Water-based epoxy resin coating composition
JPS6028435A (ja) 表面シ−ル用被覆組成物
US3806479A (en) Ester-containing liquid polyols
KR880002939A (ko) 높은 고형물 코우팅 조성물, 그 제법과 그것으로 만들어진 물품
DE3687238T2 (de) Polyamidharze.
GB1283653A (en) Process for the manufacture of crystalline elastomeric plastics products based on diepoxides and branched polyester-polycarboxylic acids

Legal Events

Date Code Title Description
A201 Request for examination
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19881112

PA0201 Request for examination
PG1501 Laying open of application
G160 Decision to publish patent application
PG1605 Publication of application before grant of patent

Comment text: Decision on Publication of Application

Patent event code: PG16051S01I

Patent event date: 19920312

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 19920711

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 19920921

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 19920921

End annual number: 3

Start annual number: 1

PR1001 Payment of annual fee

Payment date: 19950330

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 19960329

Start annual number: 5

End annual number: 5

PR1001 Payment of annual fee

Payment date: 19970402

Start annual number: 6

End annual number: 6

PR1001 Payment of annual fee

Payment date: 19980403

Start annual number: 7

End annual number: 7

PR1001 Payment of annual fee

Payment date: 19990331

Start annual number: 8

End annual number: 8

FPAY Annual fee payment

Payment date: 20000406

Year of fee payment: 9

PR1001 Payment of annual fee

Payment date: 20000406

Start annual number: 9

End annual number: 9

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee