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KR880011087A - 제초제 - Google Patents

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Publication number
KR880011087A
KR880011087A KR1019880002943A KR880002943A KR880011087A KR 880011087 A KR880011087 A KR 880011087A KR 1019880002943 A KR1019880002943 A KR 1019880002943A KR 880002943 A KR880002943 A KR 880002943A KR 880011087 A KR880011087 A KR 880011087A
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KR
South Korea
Prior art keywords
formula
compound
alkyl
optionally substituted
hydrogen
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KR1019880002943A
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English (en)
Inventor
미첼 글린
Original Assignee
알란 브라이안 백
임페리알 케미칼 인더스트리스 피엘씨
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Publication of KR880011087A publication Critical patent/KR880011087A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
    • C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
    • C07D207/32—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/33—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms with substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C07D207/333—Radicals substituted by oxygen or sulfur atoms
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    • A01N35/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having two bonds to hetero atoms with at the most one bond to halogen, e.g. aldehyde radical containing keto or thioketo groups as part of a ring, e.g. cyclohexanone, quinone; Derivatives thereof, e.g. ketals
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    • A01N43/24—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms
    • A01N43/32—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with two or more hetero atoms six-membered rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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    • A01N43/38—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings condensed with carbocyclic rings
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
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Abstract

내용 없음

Description

제초제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. (a) 다음 구조식 (2) 화합물을
    [식중, R2, R3, R4및 R5는 구조식 (1)에 관해 정의된 바와 같음] 염기 및 루이스 산의 존재에서 다음 구조직 (3) 화합물과 반응시키거나 : 또는 R1COCN (3) [식중, R1은 구조식 (1)에 관해 정의된 바와 같음]
    b) 다음 구조식 (6) 화합물을
    루이스 산의 존재에서 다음 구조식 (10) 화합물과 반응시키거나 또는
    [식중, R1은 상기 정의된 바와 같음]
    c) R2, R3, R4및 R5가 같을 경우, 다음 구조식 (Ⅱ) 화합물을
    염기의 존재에서 X'가 이탈 그룹인 구조식 R2X' 화합물과 반응시키고 원한다면 그 후에 염, 또는 설포네이트 유도체를 형성시키는 것으로 구성되는, 다음 구조식 (1) 화합물 또는 그것의 염, 아실레이트 또는 설포네이트 유도체의 제조방법.
    식중, R1은 임의 치환된 아릴 그룹, R2, R3, R4및 R5는 수소, C1-4알킬, C1-4알카노일 또는 Ra가 C1-4알킬인 -CO2Ra로 부터 선택되거나 또는 최소한 R2및 R3또는 R4및 R5가 둘다 수소가 아니고 R2, R3, R4및 R5의 둘 이하가 C1-4알카노일 또는 -CO2Ra이라면 R2및 R3또는 R4및 R5는 그것이 부착된 탄소원자와 함께 C3-6사이클로알킬 환을 형성.
  2. 제1항에 있어서, R1이 임의 치환된 페닐 그룹인 구조식 (1) 화합물의 제조방법.
  3. 제1항 또는 제2항에 있어서, 그룹 R1이 오르토 위치에 치환체를 함유하는 방법.
  4. 제3항에 있어서, 구조식 (1) 화합물이 파라 위치에서 부가적인 치환체를 함유하는 방법.
  5. 전기한 항의 어느 한 항에 있어서, R1이 불소, 염소 및 브롬 같은 할로겐 C1-4알킬 C1-4알콕시 : 트리플루오로메톡시 및 테트라플루오로에톡시 같은 할로(C1-4)알콕시 : 시아노 : 니트로 : 트리플루오로메틸 같은 C1-4할로알킬 : n이 0.1 또는 2이고 R1이 할로겐 또는 시아노로 임의 치환된 C1-4알킬, 페닐 또는 벤질인 R7SOn- : R8및 R9가 독립적으로 수소 또는 C1-4알킬인 NR8R9: R10이 C1-4알킬 또는 C1-4알콕시인 R10CO- : 또는 R8및 R9가 상기 정의된 바와 같은 SO2NR8R9로 부터 선택된 3개 그룹까지에 의해 임의로 치환된 방법.
  6. 전기한 항의 어느 한 항에 있어서, R2, R3, R4및 R5가 C1-4알킬, 특히 메틸인 방법.
  7. 구조식 (1) 화합물의 염, 아실테이트 또는 설포네이트 유도체 또는 다음 구조식 (1A) 화합물 및 그것의 호변이성체.
    식중, R13는 임의 치환된 아릴이고 하나 또는 두개 그룹 R14, R15, R16및 R17는 C1-4알카노일 또는 R9가 C1-4알킬인 CO2R9이며 그 나머지는 수소 또는 C1-4알킬로 부터 선택되거나 : 또는 R13는 비치환된 이릴이고 R14, R15, R16, R17및 R18은 각각 R2, R3, R4및 R5와 같음.
  8. 다음 구조식 (12) 화합물을
    식중, R13, R14, R15, R16및 R17는 제7항에 정의된 바와 같음.
    시안화물 소스(source) 및 적당한 염기의 존재에서 재배열시키는 것으로 구성되는, 제7항에 정의된 바와 같은 구조식 (1A) 화합물의 제조방법.
  9. 제1항에 정의된 바와 같은 구조식 (1)의 염, 아실레이트 또는 설포네이트 유도체 또는 제7항에 정의된 바와 같은 구조식 (1A) 화합물과 함께 담체 또는 희석제로 구성되는 제초성 조성물.
  10. 제1항에 정의된 바와 같은 구조식 (1) 화합물의 염, 아실레이트 또는 설포네이트 유도체 또는 제7항에 정의된 바와 같은 구조식 (1A) 화합물의 제초적으로 효과적인 양을 식물에 또는 식물의 소재지에 사용하는 것으로 구성되는, 원치않는 식물 종을 죽이거나 조절하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019880002943A 1987-03-19 1988-03-19 제초제 KR880011087A (ko)

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IL91083A (en) * 1988-07-25 1993-04-04 Ciba Geigy Cyclohexanedione derivatives, their preparation and their use as herbicides
US5245990A (en) * 1992-02-14 1993-09-21 Millo Bertinin Apparatus for enhancing venous circulation and for massage
DE4305696A1 (de) 1993-02-25 1994-09-01 Hoechst Ag Nachweisverfahren zur Identifizierung von Inhibitoren
CA2375651A1 (en) 1999-06-02 2000-12-14 Basf Aktiengesellschaft Method for producing 2,2,4,4-tetra-substituted 1,3,5-cyclohexanetriones
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US4202840A (en) * 1978-09-29 1980-05-13 Stauffer Chemical Company 1-Hydroxy-2-(alkylketo)-4,4,6,6-tetramethyl cyclohexen-3,5-diones
EP0090262B1 (en) * 1982-03-25 1992-08-05 Stauffer Chemical Company Certain 2-(2-substituted benzoyl)-1,3-cyclohexanediones
PH21446A (en) * 1983-09-16 1987-10-20 Stauffer Chemical Co Certain 2-(2-substituted benzoyl)-1,3-cyclohexanediones
US4695673A (en) * 1985-11-20 1987-09-22 Stauffer Chemical Company Process for the production of acylated 1,3-dicarbonyl compounds
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