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KR870008858A - 2-하이드록시에틸-아졸유도체 및 그의 제조 방법 - Google Patents

2-하이드록시에틸-아졸유도체 및 그의 제조 방법 Download PDF

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KR870008858A
KR870008858A KR870001953A KR870001953A KR870008858A KR 870008858 A KR870008858 A KR 870008858A KR 870001953 A KR870001953 A KR 870001953A KR 870001953 A KR870001953 A KR 870001953A KR 870008858 A KR870008858 A KR 870008858A
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Prior art keywords
halogen
formula
represents hydrogen
general formula
hydroxyethyl
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KR870001953A
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란쯔쉬 라인하르트
브란데스 빌헬름
핸슬러 게르트
라이네케 파울
뤼르센 클라우스
Original Assignee
에리히 데브리츠
바이엘 아크티에게젤샤프트
요아힘 그렘
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Publication of KR870008858A publication Critical patent/KR870008858A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
    • C07C45/455—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation with carboxylic acids or their derivatives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/62—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by hydrogenation of carbon-to-carbon double or triple bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/255—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing ether groups, groups, groups, or groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

내용 없음

Description

2-하이드록시에틸-아졸유도체 및 그의 제조 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 일반식(Ⅰ)의 2-하이드록시에틸-아졸유도체, 및 그의 산부가염 및 금속염 컴플렉스(complex).
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타낸다.
  2. 제 1 항에 있어서, R이 동일하거나 상이한 치환체에 의해 임의로 일치환, 이치환 또는 삼치환된 페닐을 나타내며, 여기에서 가능한 치환체는 할로겐, 탄소수 1 내지 4의 알킬, 탄소수 1 내지 4의 알콕시, 탄소수 1 내지 4의 알킬티오, 1 또는 2개의 탄소원자와 1 내지 5개의 할로겐 원자를 함유하는 할로게노알킬, 1 또는 2 개의 탄소원자와 1 내지 5개의 할로겐원자를 함유하는 할로게노알콕시, 1 또는 2개의 탄소원자와 1 내지 5개의 할로겐원자를 함유하는 할로게노알킬티오, 탄소수 3 내지 7의 사이클로알킬, 페닐, 페녹시, 및 알콕시 그룹의 탄소수가 1 내지 4개이고 알킬 그룹의 탄소수는 1 내지 4개인 알콕시이미노알킬이고, X는 수소, 불소, 염소 또는 브롬을 나타내며, Y는 수소, 분소, 염소 또는 브롬을 나타내는 일반식(Ⅰ)의 2-하이드록시에틸-아졸 유도체.
  3. 일반식(Ⅱ)의 옥시란을 희석제의 존재하에 및, 경우에 따라 염기의 존재하에, 구조식(Ⅲ)의 1,2,4-트리아졸과 반응시키고, 경우에 따라 계속해서 수득된 일반식(Ⅰ)의 화합물에 산 또는 금속염을 가함을 특징으로 하여, 일반식(Ⅰ)의 2-하이드록시에틸-아졸유도체, 및 그의 산부가염 및 금속염 컴플렉스를 제조하는 방법.
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타낸다.
  4. 제 1 항에 따른 일반식(Ⅰ)의 2-하이드록시에틸-아졸유도체, 및 일반식(Ⅰ)의 하이드록시에틸-아졸 유도체의 산부가염 및 금속염 컴플렉스 중 적어도 하나를 함유함을 특징으로 하는 살진균제 및 식물성장 조절제.
  5. 진균을 퇴치하며 식물성장을 조절하기 위한 제 1 항에 따른 일반식(Ⅰ)의 2-하이드록시에틸-아졸유도체, 또는 그의 산부가염 및 금속염 컴플렉스의 용도.
  6. 제 1 항에 따른 일반식(Ⅰ)의 2-하이드록시에틸-아졸유도체, 또는 그의 산부가염 또는 금속염 컴플렉스를 증량제 및/또는 계면활성제와 혼합시킴을 특징으로 하여, 살진균제 및 식물성장 조절제를 제조하는 방법.
  7. 일반식(Ⅱ)의 옥시란.
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타낸다.
  8. 일반식(Ⅳ)의 페녹시프로필 케톤을 염기의 존재하에 및 희석제의 존재하에, 트리메틸설포늄 요오다이드 또는 트리메틸설포늄 메토설페이트와 반응시킴을 특징으로 하여, 일반식(Ⅱ)의 옥시란을 제조하는 방법.
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타낸다.
  9. 일반식(Ⅶ)의 페녹시-치환된 케톤.
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타낸다.
  10. 일반식(Ⅴ)의 산할로겐화물을, 경우에 따라 희석제의 존재하에, 및 경우에 따라 산결합제의 존재하에, 및 경우에 따라 촉매의 존재하에, 일반식(Ⅵ)의 페녹시프로파길 화합물과 반응시켜, 일반식(Ⅶ)의 페녹시 치환된 케톤을 수득한 다음, 수득된 일반식(Ⅶ)의 화합물을 수소화촉매의 존재하게, 및 희석제의 존재하에, 수소와 반응시킴을 특징으로하여, 일반식(Ⅳ)의 페톡시프로필케톤을 제조하는 방법.
    상기식에서,
    R은 임의로 치환된 페닐을 나타내고,
    X는 수소 또는 할로겐을 나타내며,
    Y는 수소 또는 할로겐을 나타내고,
    Hal은 할로겐을 나타낸다.
    ※ 참고사항: 최초출원 내용에 의하여 공개하는 것임.
KR870001953A 1986-03-06 1987-03-05 2-하이드록시에틸-아졸유도체 및 그의 제조 방법 KR870008858A (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DEP3607286.9 1986-03-06
DE3607286 1986-03-06
DE19873702301 DE3702301A1 (de) 1986-03-06 1987-01-27 2-hydroxyethyl-azol-derivate
DEP3702301.2 1987-01-27

Publications (1)

Publication Number Publication Date
KR870008858A true KR870008858A (ko) 1987-10-21

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KR870001953A KR870008858A (ko) 1986-03-06 1987-03-05 2-하이드록시에틸-아졸유도체 및 그의 제조 방법

Country Status (8)

Country Link
US (1) US4921529A (ko)
KR (1) KR870008858A (ko)
BR (1) BR8701028A (ko)
CA (1) CA1297881C (ko)
DE (1) DE3702301A1 (ko)
DK (1) DK114187A (ko)
HU (1) HUT43247A (ko)
IL (1) IL81742A0 (ko)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19505938A1 (de) * 1995-02-21 1996-08-22 Bayer Ag Verfahren zur Herstellung von 1-(4-Chlorphenyl)-4,4-dimethyl-pentan-3-on
EP2443098A1 (en) 2009-06-18 2012-04-25 Basf Se Antifungal 1, 2, 4-triazolyl derivatives
EP2443097A1 (en) 2009-06-18 2012-04-25 Basf Se Antifungal 1, 2, 4-triazolyl derivatives
CN102803232A (zh) 2009-06-18 2012-11-28 巴斯夫欧洲公司 杀真菌的具有5-硫取代基的1,2,4-三唑衍生物
EP2654433B1 (en) 2010-12-21 2017-08-30 Bayer Cropscience LP Sandpaper mutants of bacillus and methods of their use to enhance plant growth, promote plant health and control diseases and pests
WO2013039937A1 (en) 2011-09-12 2013-03-21 Agraquest, Inc. Methods of enhancing health and/or promoting growth of a plant and/or of improving fruit ripening
EA201692076A1 (ru) * 2014-04-17 2017-04-28 Басф Се Новые ингибиторы нитрификации

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2918894A1 (de) * 1979-05-10 1980-11-20 Bayer Ag Fluorierte 1-triazolyl-butan-derivate, verfahren zu ihrer herstellung und ihre verwendung als fungizide
AU542623B2 (en) * 1980-05-16 1985-02-28 Bayer Aktiengesellschaft 1-hydroxyethyl-azole derivatives
DE3019049A1 (de) * 1980-05-19 1981-12-03 Basf Ag, 6700 Ludwigshafen Neue azolverbindungen
EP0052424B2 (en) * 1980-11-19 1990-02-28 Imperial Chemical Industries Plc Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them
DE3202601A1 (de) * 1982-01-27 1983-08-04 Bayer Ag, 5090 Leverkusen Substituierte 1 -hydroxyalkyl-azolyl-derivate, verfahren zu ihrer herstellung sowie ihrer verwendung als fungizide und pflanzenwachstumsregulatoren
DE3402166A1 (de) * 1984-01-23 1985-07-25 Hoechst Ag, 6230 Frankfurt Azolyl-aryl-alkanol-derivate, verfahren zu ihrer herstellung und ihre verwendung

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DK114187D0 (da) 1987-03-05
CA1297881C (en) 1992-03-24
HUT43247A (en) 1987-10-28
IL81742A0 (en) 1987-10-20
DK114187A (da) 1987-09-07
DE3702301A1 (de) 1987-09-10
BR8701028A (pt) 1988-01-05
US4921529A (en) 1990-05-01

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