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KR870007874A - 글리시딜 화합물의 염소 함량을 감소시키는 방법 - Google Patents

글리시딜 화합물의 염소 함량을 감소시키는 방법 Download PDF

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Publication number
KR870007874A
KR870007874A KR870001369A KR870001369A KR870007874A KR 870007874 A KR870007874 A KR 870007874A KR 870001369 A KR870001369 A KR 870001369A KR 870001369 A KR870001369 A KR 870001369A KR 870007874 A KR870007874 A KR 870007874A
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KR
South Korea
Prior art keywords
ammonium
bicarbonate
glycidyl
compound
process according
Prior art date
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KR870001369A
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English (en)
Inventor
딘 팔리에 케멜
디사우게스 제랄드
Original Assignee
아놀드자일러, 에른스트알테르
시비-가이기 아계
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Application filed by 아놀드자일러, 에른스트알테르, 시비-가이기 아계 filed Critical 아놀드자일러, 에른스트알테르
Publication of KR870007874A publication Critical patent/KR870007874A/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/04—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups
    • C07C209/14—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups
    • C07C209/20—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of functional groups by amino groups by substitution of hydroxy groups or of etherified or esterified hydroxy groups with formation of quaternary ammonium compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C211/00—Compounds containing amino groups bound to a carbon skeleton
    • C07C211/62—Quaternary ammonium compounds
    • C07C211/63—Quaternary ammonium compounds having quaternised nitrogen atoms bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/32—Separation; Purification
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
    • C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
    • C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
    • C07D303/24—Ethers with hydroxy compounds containing no oxirane rings with polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Paints Or Removers (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Epoxy Resins (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

내용 없음

Description

글리시딜 화합물의 염소 함량을 감소시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (15)

  1. 비할로겐화, 비양자성 유기용매내에서 글리시딜기가 O,N 및/또는 S원자에 부착된 글리시딜 화합물과 암모늄염이 하기 일반식(Ⅰ) 또는 (Ⅱ)의 화합물인 암모늄 비카보네이트 또는 암모늄알킬카보네이트를 반응시키고 또 이어 반응 혼합물로부터 생성물을 분리하여 글리시딜 화합물내 염소함량을 감소시키는 방법.
    상기속에서,
    R1내지 R4는 각각 독립적으로 C1-C8알킬, 페닐, 벤질, C1-C8알콕시 또는 페녹시를 나타내고;또 R은 C1-C4알킬이다.
  2. 제1항에 있어서, 글리시딜 화합물이 글리시딜에테르, 바람직하게는 다핵성 페놀의 폴리글리시딜에테르인 방법.
  3. 제1항에 있어서, 글리시딜 화합물을 일반식(Ⅰ)의 암모늄비카보네이트와 반응시키는 방법.
  4. 제1항에 있어서, 치환체 R1내지 R4가 각각 독립적으로 페닐, 벤질 또는 C1-C|4알킬, 바람직하게는 메틸인 방법.
  5. 제1항에 있어서, 알킬카보네이트가 에틸카보네이트, 바람직하게는 메틸카보네이트인 방법.
  6. 제3항에 있어서, 암모늄비카보네이트가 테트라에틸암모늄비카보네이트, 테트라프로필암모늄비카보네이트, 페닐트리메틸암모늄비카보네이트, 메틸트리부틸암모늄비카보네이트 또는 바람직하게는 테트라메틸암모늄비카보네이트인 방법.
  7. 제1항에 있어서, CO2또는 N2블랭킷하에서 진행시키는 방법.
  8. 제1항에 있어서, 반응수를 건조제 또는, 바람직하게는 공비증류에 의해 제거시키는 방법.
  9. 제1항에 있어서, 반응후 존재하는 과잉 암모늄비카보네이트 및 반응중 형성된 암모늄클로라이드를 여과 흡착 또는 물로 세척함으로써 반응홉합물로부터 제거시키는 방법.
  10. 제1항에 있어서, 암모늄비카보네이트를 사용하는 방법.
  11. 제7항에 있어서, 암모늄비카보네이트를 상응하는 암모늄하이드록사이드 및 CO2로 부터 자체내에서 형성하는 방법.
  12. 제7항에 있어서, 적당한 4급 암모늄 알콕사이드 및 CO2로부터 암모늄 알킬카보네이트를 자체내에서 형성하는 방법.
  13. 제1항에 있어서, 글리시딜화합물을 기준으로 하여 0.1 내지 10.5중량%, 바람직하게는 0.2 내지 5중량%의 암모늄염을 사용하는 방법.
  14. 제1항에 있어서, 10。내지 120℃, 바람직하게는 20。내지 100℃ 온도범위에서 반응을 진행시키는 방법.
  15. 제1항에 따른 방법으로 수득한 글리시딜 화합물을 전자부품용 캡슐화수지, 점착제, 또는 전자부품용 회로판에 부착시키는 보호피복("구형마개", "이형태 피복")으로의 용도.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR870001369A 1986-02-20 1987-02-19 글리시딜 화합물의 염소 함량을 감소시키는 방법 KR870007874A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH67586 1986-02-20
CH00675 1986-02-20

Publications (1)

Publication Number Publication Date
KR870007874A true KR870007874A (ko) 1987-09-22

Family

ID=4192538

Family Applications (1)

Application Number Title Priority Date Filing Date
KR870001369A KR870007874A (ko) 1986-02-20 1987-02-19 글리시딜 화합물의 염소 함량을 감소시키는 방법

Country Status (4)

Country Link
EP (1) EP0233843A3 (ko)
JP (1) JPS62205069A (ko)
KR (1) KR870007874A (ko)
BR (1) BR8700777A (ko)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2702515B2 (ja) * 1988-08-10 1998-01-21 旭チバ株式会社 エポキシ樹脂の精製法
JPH0286675A (ja) * 1988-09-22 1990-03-27 Nitto Denko Corp プリント基板固着材
JP3018483B2 (ja) * 1990-11-21 2000-03-13 三菱瓦斯化学株式会社 グリシジルアクリレート又はグリシジルメタクリレートの精製法
WO2001030881A1 (en) * 1999-10-27 2001-05-03 Shell Internationale Research Maatschappij B.V. Process for glycidation of carboxylic acids
WO2002059177A2 (en) * 2000-12-22 2002-08-01 Dow Global Technologies Inc. Poly (hydroxyaminoethers) having a low chloride content
JP2014040508A (ja) * 2012-08-21 2014-03-06 Asahi Kasei E-Materials Corp エポキシ樹脂の製造方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU671318A1 (ru) * 1977-04-26 1984-10-07 Предприятие П/Я В-8413 Способ получени эпоксидных смол
DD140256A1 (de) * 1978-12-04 1980-02-20 Manfred Gaikowski Verfahren zur herstellung von aktiviertem epoxidharz
US4284573A (en) * 1979-10-01 1981-08-18 The Dow Chemical Company Preparation of glycidyl ethers
JPS59146017U (ja) * 1983-03-16 1984-09-29 松下電器産業株式会社 空気清浄器
DD218375A1 (de) * 1983-07-04 1985-02-06 Leuna Werke Veb Verfahren zur dehydrohalogenierung von epoxidharzen
JPS59146024U (ja) * 1983-12-13 1984-09-29 松下電器産業株式会社 空気清浄器
DD223456A1 (de) * 1984-01-18 1985-06-12 Leuna Werke Veb Verfahren zur herstellung von epoxidharzen mit niedrigem chlorgehalt
JPS60244321A (ja) * 1984-05-21 1985-12-04 Hitachi Ltd 空気清浄機

Also Published As

Publication number Publication date
EP0233843A2 (de) 1987-08-26
JPS62205069A (ja) 1987-09-09
BR8700777A (pt) 1987-12-15
EP0233843A3 (de) 1988-09-07

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Patent event code: PA01091R01D

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Patent event date: 19870219

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