KR870003061A - 디페닐 메탄 디칼바민산 에스텔류의 제조 방법 - Google Patents
디페닐 메탄 디칼바민산 에스텔류의 제조 방법 Download PDFInfo
- Publication number
- KR870003061A KR870003061A KR1019860007291A KR860007291A KR870003061A KR 870003061 A KR870003061 A KR 870003061A KR 1019860007291 A KR1019860007291 A KR 1019860007291A KR 860007291 A KR860007291 A KR 860007291A KR 870003061 A KR870003061 A KR 870003061A
- Authority
- KR
- South Korea
- Prior art keywords
- acid
- manufacturing
- acid ester
- reaction temperature
- solution
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 4
- -1 diphenyl methane dicarbamic acid ester Chemical class 0.000 title claims 2
- 239000002253 acid Substances 0.000 claims 4
- 239000000243 solution Substances 0.000 claims 4
- 150000007522 mineralic acids Chemical class 0.000 claims 3
- PWXJULSLLONQHY-UHFFFAOYSA-N phenylcarbamic acid Chemical class OC(=O)NC1=CC=CC=C1 PWXJULSLLONQHY-UHFFFAOYSA-N 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- UOSDGLNNKSPWEE-UHFFFAOYSA-N [(carboxyamino)-diphenylmethyl]carbamic acid Chemical compound C=1C=CC=CC=1C(NC(O)=O)(NC(=O)O)C1=CC=CC=C1 UOSDGLNNKSPWEE-UHFFFAOYSA-N 0.000 claims 1
- OTSJRHVZRARHBC-UHFFFAOYSA-N benzylbenzene;carbamic acid Chemical compound NC(O)=O.NC(O)=O.C=1C=CC=CC=1CC1=CC=CC=C1 OTSJRHVZRARHBC-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 claims 1
- 239000002994 raw material Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C269/00—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C269/06—Preparation of derivatives of carbamic acid, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups by reactions not involving the formation of carbamate groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C271/00—Derivatives of carbamic acids, i.e. compounds containing any of the groups, the nitrogen atom not being part of nitro or nitroso groups
- C07C271/06—Esters of carbamic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
Claims (5)
- N-페닐칼바민산에스텔류를 산수용액중에서 메틸렌화제와 반응시켜서 디페닐 메탄 디칼바민산에 스텔류를 제조할때에, 산수용액으로 무기산 수용액을 사용하며, 또 산수용액 중의 N-페닐 칼바민산에스텔류의 농도를 그 반응 온도에 있어서의 용해도 이하로 하는 디페닐메탄 디칼바민산에스텔류의 제조 방법.
- 무기산수용액은, 원료 N-페닐 칼바민산 에스텔의 용해도에 대한 제품 디페닐 메탄디칼바민산에 스텔의 용해도는 비는 반응온도에 있어서, 0.1 이하의 것인 제1항 기재의 제조 방법.
- 무기산 수용액의 산 농도는 1-80중량%인 제1항 기재의 제조 방법.
- 반응온도는 20-150℃인 제1항 기재의 제조 방법.
- 반응온도는 50-120℃인 제1항 기재의 제조 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP204361 | 1985-09-18 | ||
JP60204361A JPS6267059A (ja) | 1985-09-18 | 1985-09-18 | ジフエニルメタンジカルバミン酸エステル類の製造方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR870003061A true KR870003061A (ko) | 1987-04-14 |
KR890005037B1 KR890005037B1 (ko) | 1989-12-08 |
Family
ID=16489237
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019860007291A KR890005037B1 (ko) | 1985-09-18 | 1986-09-01 | 디페닐 메탄디칼바민산 에스테르류의 제조방법 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4699994A (ko) |
EP (1) | EP0216273B1 (ko) |
JP (1) | JPS6267059A (ko) |
KR (1) | KR890005037B1 (ko) |
CA (1) | CA1249297A (ko) |
DE (1) | DE3675866D1 (ko) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2649103B1 (ko) * | 1989-06-29 | 1991-09-27 | Rhone Poulenc Chimie | |
JPH0358965A (ja) * | 1989-07-27 | 1991-03-14 | Mitsui Petrochem Ind Ltd | N―フェニルカルバメート類の縮合方法 |
EP0520377B1 (en) * | 1991-06-26 | 1998-02-25 | Lucky Ltd. | A process for the selective preparation of 4,4-methylene-bis-(N-phenylalkylcarbamate) |
EP2457602A1 (en) | 2010-11-25 | 2012-05-30 | F. Hoffmann-La Roche AG | Infusion pump having dosing unit with safety valve |
JP5968568B1 (ja) * | 2016-02-08 | 2016-08-10 | 株式会社神鋼環境ソリューション | リグノフェノールの製造方法、及び、リグノフェノールの製造装置 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT1126563B (it) * | 1978-12-14 | 1986-05-21 | Mitsui Toatsu Chemicals | Processo per preparare polimetilen polifenil policarbammati |
DE2931554A1 (de) * | 1979-08-03 | 1981-02-26 | Basf Ag | Verfahren zur herstellung von methylen-bis-phenyl-carbaminsaeureestern und polymethylen-polyphenylcarbaminsaeureestern |
DE3370152D1 (en) * | 1982-12-07 | 1987-04-16 | Asahi Chemical Ind | Process for producing diphenylmethane dicarbamates |
-
1985
- 1985-09-18 JP JP60204361A patent/JPS6267059A/ja active Granted
-
1986
- 1986-09-01 KR KR1019860007291A patent/KR890005037B1/ko not_active IP Right Cessation
- 1986-09-08 US US06/905,067 patent/US4699994A/en not_active Expired - Fee Related
- 1986-09-10 CA CA000517877A patent/CA1249297A/en not_active Expired
- 1986-09-12 EP EP86112651A patent/EP0216273B1/en not_active Expired - Lifetime
- 1986-09-12 DE DE8686112651T patent/DE3675866D1/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US4699994A (en) | 1987-10-13 |
JPH0329785B2 (ko) | 1991-04-25 |
JPS6267059A (ja) | 1987-03-26 |
DE3675866D1 (de) | 1991-01-10 |
CA1249297A (en) | 1989-01-24 |
EP0216273A3 (en) | 1987-12-16 |
EP0216273A2 (en) | 1987-04-01 |
KR890005037B1 (ko) | 1989-12-08 |
EP0216273B1 (en) | 1990-11-28 |
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