KR20230109637A - 알칼리성 하이드록사이드 용액으로부터 플루오라이드를 제거하는 방법 - Google Patents

알칼리성 하이드록사이드 용액으로부터 플루오라이드를 제거하는 방법 Download PDF

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Publication number: KR20230109637A
Authority: KR; South Korea
Prior art keywords: lithium; solution; hydroxide; alkaline; salt
Prior art date: 2020-11-20
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

KR1020237016851A

Other languages

English (en)

Korean (ko)

Inventor

닐스-올로프 요아힘 본

마티아 기아코미니

비르기트 게르케

파비안 젤러

볼프강 로데

커스틴 쉬를레-아른트

레기나 포겔장

Original Assignee

바스프 에스이

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2020-11-20

Filing date

2021-11-19

Publication date

2023-07-20

2021-11-19 Application filed by 바스프 에스이 filed Critical 바스프 에스이

2023-07-20 Publication of KR20230109637A publication Critical patent/KR20230109637A/ko

Status Pending legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 72
KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title claims abstract description 33
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 title claims abstract description 25
239000003463 adsorbent Substances 0.000 claims abstract description 55
-1 alkaline earth metal salt Chemical class 0.000 claims abstract description 52
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 44
239000011347 resin Substances 0.000 claims abstract description 38
229920005989 resin Polymers 0.000 claims abstract description 38
239000007788 liquid Substances 0.000 claims abstract description 37
239000007787 solid Substances 0.000 claims abstract description 36
239000002798 polar solvent Substances 0.000 claims abstract description 34
150000001768 cations Chemical class 0.000 claims abstract description 33
239000000203 mixture Substances 0.000 claims abstract description 31
150000001450 anions Chemical class 0.000 claims abstract description 17
229910052784 alkaline earth metal Inorganic materials 0.000 claims abstract description 15
229910052782 aluminium Inorganic materials 0.000 claims abstract description 9
150000001298 alcohols Chemical class 0.000 claims abstract description 8
229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 7
150000002602 lanthanoids Chemical class 0.000 claims abstract description 7
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 6
239000010452 phosphate Substances 0.000 claims abstract description 6
229910052804 chromium Inorganic materials 0.000 claims abstract description 4
229910052733 gallium Inorganic materials 0.000 claims abstract description 4
229910052738 indium Inorganic materials 0.000 claims abstract description 4
229910052742 iron Inorganic materials 0.000 claims abstract description 4
229910052746 lanthanum Inorganic materials 0.000 claims abstract description 4
229910052706 scandium Inorganic materials 0.000 claims abstract description 4
229910052727 yttrium Inorganic materials 0.000 claims abstract description 4
WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical group [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims description 147
239000000243 solution Substances 0.000 claims description 65
229910052744 lithium Inorganic materials 0.000 claims description 57
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 54
239000000463 material Substances 0.000 claims description 44
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 31
229910003002 lithium salt Inorganic materials 0.000 claims description 28
159000000002 lithium salts Chemical class 0.000 claims description 28
230000008569 process Effects 0.000 claims description 28
229910001416 lithium ion Inorganic materials 0.000 claims description 27
HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 25
229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims description 18
238000004519 manufacturing process Methods 0.000 claims description 13
239000000843 powder Substances 0.000 claims description 13
239000012670 alkaline solution Substances 0.000 claims description 12
238000000605 extraction Methods 0.000 claims description 12
238000002386 leaching Methods 0.000 claims description 12
QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 9
239000011324 bead Substances 0.000 claims description 9
239000001506 calcium phosphate Substances 0.000 claims description 8
238000010438 heat treatment Methods 0.000 claims description 7
239000002351 wastewater Substances 0.000 claims description 7
OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
238000009835 boiling Methods 0.000 claims description 5
XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical group [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims description 5
229910052808 lithium carbonate Inorganic materials 0.000 claims description 5
239000012266 salt solution Substances 0.000 claims description 5
229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
235000011010 calcium phosphates Nutrition 0.000 claims description 4
239000007772 electrode material Substances 0.000 claims description 4
239000010881 fly ash Substances 0.000 claims description 4
NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 claims description 4
150000003839 salts Chemical group 0.000 claims description 4
229910000391 tricalcium phosphate Inorganic materials 0.000 claims description 4
235000019731 tricalcium phosphate Nutrition 0.000 claims description 4
229940078499 tricalcium phosphate Drugs 0.000 claims description 4
239000012267 brine Substances 0.000 claims description 3
CADZRPOVAQTAME-UHFFFAOYSA-L calcium;hydroxy phosphate Chemical compound [Ca+2].OOP([O-])([O-])=O CADZRPOVAQTAME-UHFFFAOYSA-L 0.000 claims description 3
FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 3
ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 3
239000001095 magnesium carbonate Substances 0.000 claims description 3
229910000021 magnesium carbonate Inorganic materials 0.000 claims description 3
239000000395 magnesium oxide Substances 0.000 claims description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 3
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 3
238000002844 melting Methods 0.000 claims description 3
230000008018 melting Effects 0.000 claims description 3
239000002893 slag Substances 0.000 claims description 3
HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 3
239000003513 alkali Substances 0.000 claims description 2
239000008187 granular material Substances 0.000 claims description 2
HQRPHMAXFVUBJX-UHFFFAOYSA-M lithium;hydrogen carbonate Chemical compound [Li+].OC([O-])=O HQRPHMAXFVUBJX-UHFFFAOYSA-M 0.000 claims description 2
239000008188 pellet Substances 0.000 claims description 2
230000001376 precipitating effect Effects 0.000 claims description 2
238000002156 mixing Methods 0.000 abstract description 3
XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 abstract 1
239000013618 particulate matter Substances 0.000 description 28
239000011575 calcium Substances 0.000 description 26
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 19
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
239000012530 fluid Substances 0.000 description 15
238000001179 sorption measurement Methods 0.000 description 15
239000002699 waste material Substances 0.000 description 13
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
239000000706 filtrate Substances 0.000 description 12
229910052731 fluorine Inorganic materials 0.000 description 12
235000019000 fluorine Nutrition 0.000 description 12
229910002804 graphite Inorganic materials 0.000 description 12
239000010439 graphite Substances 0.000 description 12
239000012535 impurity Substances 0.000 description 12
239000003456 ion exchange resin Substances 0.000 description 12
229920003303 ion-exchange polymer Polymers 0.000 description 12
239000000523 sample Substances 0.000 description 12
YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 11
239000000284 extract Substances 0.000 description 11
239000011737 fluorine Substances 0.000 description 11
150000002500 ions Chemical class 0.000 description 11
239000011734 sodium Substances 0.000 description 11
238000005342 ion exchange Methods 0.000 description 10
PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical compound [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 10
239000011572 manganese Substances 0.000 description 10
230000008929 regeneration Effects 0.000 description 10
238000011069 regeneration method Methods 0.000 description 10
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 9
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
238000011068 loading method Methods 0.000 description 9
239000000047 product Substances 0.000 description 9
AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 8
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
229910052748 manganese Inorganic materials 0.000 description 8
229910052759 nickel Inorganic materials 0.000 description 8
229910052791 calcium Inorganic materials 0.000 description 7
229910052799 carbon Inorganic materials 0.000 description 7
229910052751 metal Inorganic materials 0.000 description 7
239000002184 metal Substances 0.000 description 7
239000012071 phase Substances 0.000 description 7
238000000634 powder X-ray diffraction Methods 0.000 description 7
238000000926 separation method Methods 0.000 description 7
229910017052 cobalt Inorganic materials 0.000 description 6
239000010941 cobalt Substances 0.000 description 6
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
238000010586 diagram Methods 0.000 description 6
238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 6
229920000642 polymer Polymers 0.000 description 6
230000005855 radiation Effects 0.000 description 6
230000009467 reduction Effects 0.000 description 6
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 5
239000008367 deionised water Substances 0.000 description 5
229910021641 deionized water Inorganic materials 0.000 description 5
238000000921 elemental analysis Methods 0.000 description 5
238000002474 experimental method Methods 0.000 description 5
238000001914 filtration Methods 0.000 description 5
239000001257 hydrogen Substances 0.000 description 5
229910052739 hydrogen Inorganic materials 0.000 description 5
150000004679 hydroxides Chemical class 0.000 description 5
238000009616 inductively coupled plasma Methods 0.000 description 5
229920011301 perfluoro alkoxyl alkane Polymers 0.000 description 5
235000021317 phosphate Nutrition 0.000 description 5
229910052708 sodium Inorganic materials 0.000 description 5
238000003756 stirring Methods 0.000 description 5
239000000126 substance Substances 0.000 description 5
238000012360 testing method Methods 0.000 description 5
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
230000002378 acidificating effect Effects 0.000 description 4
239000012736 aqueous medium Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
229910052588 hydroxylapatite Inorganic materials 0.000 description 4
230000003993 interaction Effects 0.000 description 4
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238000004375 physisorption Methods 0.000 description 4
238000012545 processing Methods 0.000 description 4
239000004071 soot Substances 0.000 description 4
239000000725 suspension Substances 0.000 description 4
229910052723 transition metal Inorganic materials 0.000 description 4
150000003624 transition metals Chemical group 0.000 description 4
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
239000004812 Fluorinated ethylene propylene Substances 0.000 description 3
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
229910010093 LiAlO Inorganic materials 0.000 description 3
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
239000002156 adsorbate Substances 0.000 description 3
238000005054 agglomeration Methods 0.000 description 3
230000002776 aggregation Effects 0.000 description 3
239000003957 anion exchange resin Substances 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
238000001636 atomic emission spectroscopy Methods 0.000 description 3
239000011230 binding agent Substances 0.000 description 3
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
238000005341 cation exchange Methods 0.000 description 3
239000003729 cation exchange resin Substances 0.000 description 3
229940023913 cation exchange resins Drugs 0.000 description 3
239000012153 distilled water Substances 0.000 description 3
230000000694 effects Effects 0.000 description 3
238000001704 evaporation Methods 0.000 description 3
230000008020 evaporation Effects 0.000 description 3
239000012527 feed solution Substances 0.000 description 3
150000002222 fluorine compounds Chemical class 0.000 description 3
125000000524 functional group Chemical group 0.000 description 3
239000007789 gas Substances 0.000 description 3
229920001903 high density polyethylene Polymers 0.000 description 3
239000004700 high-density polyethylene Substances 0.000 description 3
238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 3
229910052500 inorganic mineral Inorganic materials 0.000 description 3
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
229910021645 metal ion Inorganic materials 0.000 description 3
238000003801 milling Methods 0.000 description 3
239000011707 mineral Substances 0.000 description 3
235000010755 mineral Nutrition 0.000 description 3
VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 3
229920009441 perflouroethylene propylene Polymers 0.000 description 3
229910052698 phosphorus Inorganic materials 0.000 description 3
239000011574 phosphorus Substances 0.000 description 3
229910052700 potassium Inorganic materials 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000000746 purification Methods 0.000 description 3
238000004064 recycling Methods 0.000 description 3
230000027756 respiratory electron transport chain Effects 0.000 description 3
239000002904 solvent Substances 0.000 description 3
239000008399 tap water Substances 0.000 description 3
235000020679 tap water Nutrition 0.000 description 3
MGRVRXRGTBOSHW-UHFFFAOYSA-N (aminomethyl)phosphonic acid Chemical group NCP(O)(O)=O MGRVRXRGTBOSHW-UHFFFAOYSA-N 0.000 description 2
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
229910002483 Cu Ka Inorganic materials 0.000 description 2
229910018119 Li 3 PO 4 Inorganic materials 0.000 description 2
239000004698 Polyethylene Substances 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
229910045601 alloy Inorganic materials 0.000 description 2
239000000956 alloy Substances 0.000 description 2
229910000147 aluminium phosphate Inorganic materials 0.000 description 2
238000004458 analytical method Methods 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
229910052586 apatite Inorganic materials 0.000 description 2
239000002585 base Substances 0.000 description 2
229910052792 caesium Inorganic materials 0.000 description 2
TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical group [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
239000000920 calcium hydroxide Substances 0.000 description 2
229910001861 calcium hydroxide Inorganic materials 0.000 description 2
229910002091 carbon monoxide Inorganic materials 0.000 description 2
125000002843 carboxylic acid group Chemical group 0.000 description 2
239000006182 cathode active material Substances 0.000 description 2
125000002091 cationic group Chemical group 0.000 description 2
239000003153 chemical reaction reagent Substances 0.000 description 2
239000003795 chemical substances by application Substances 0.000 description 2
229910000428 cobalt oxide Inorganic materials 0.000 description 2
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 2
230000006835 compression Effects 0.000 description 2
238000007906 compression Methods 0.000 description 2
238000010411 cooking Methods 0.000 description 2
239000010949 copper Substances 0.000 description 2
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238000009826 distribution Methods 0.000 description 2
235000020188 drinking water Nutrition 0.000 description 2
239000003651 drinking water Substances 0.000 description 2
239000003792 electrolyte Substances 0.000 description 2
238000011049 filling Methods 0.000 description 2
239000011521 glass Substances 0.000 description 2
159000000011 group IA salts Chemical class 0.000 description 2
AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
229910052629 lepidolite Inorganic materials 0.000 description 2
YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 description 2
KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
239000011777 magnesium Substances 0.000 description 2
PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 2
VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 2
150000002739 metals Chemical class 0.000 description 2
229910052757 nitrogen Inorganic materials 0.000 description 2
ABLZXFCXXLZCGV-UHFFFAOYSA-N phosphonic acid group Chemical group P(O)(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
230000010287 polarization Effects 0.000 description 2
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239000011148 porous material Substances 0.000 description 2
239000011591 potassium Substances 0.000 description 2
239000002994 raw material Substances 0.000 description 2
238000011084 recovery Methods 0.000 description 2
230000001172 regenerating effect Effects 0.000 description 2
239000012508 resin bead Substances 0.000 description 2
230000002441 reversible effect Effects 0.000 description 2
239000008237 rinsing water Substances 0.000 description 2
229910052701 rubidium Inorganic materials 0.000 description 2
IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 2
238000010008 shearing Methods 0.000 description 2
229910001415 sodium ion Inorganic materials 0.000 description 2
239000007790 solid phase Substances 0.000 description 2
238000004611 spectroscopical analysis Methods 0.000 description 2
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229910000314 transition metal oxide Inorganic materials 0.000 description 2
229910052725 zinc Inorganic materials 0.000 description 2
239000011701 zinc Substances 0.000 description 2
229910000851 Alloy steel Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910000531 Co alloy Inorganic materials 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229910010092 LiAlO2 Inorganic materials 0.000 description 1
229910012851 LiCoO 2 Inorganic materials 0.000 description 1
229910013870 LiPF 6 Inorganic materials 0.000 description 1
235000019738 Limestone Nutrition 0.000 description 1
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
229910000990 Ni alloy Inorganic materials 0.000 description 1
229910016401 Ni0.34Co0.33Mn0.33 Inorganic materials 0.000 description 1
NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
239000002033 PVDF binder Substances 0.000 description 1
229920001774 Perfluoroether Polymers 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
238000005411 Van der Waals force Methods 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
WQHONKDTTOGZPR-UHFFFAOYSA-N [O-2].[O-2].[Mn+2].[Fe+2] Chemical compound [O-2].[O-2].[Mn+2].[Fe+2] WQHONKDTTOGZPR-UHFFFAOYSA-N 0.000 description 1
230000004913 activation Effects 0.000 description 1
239000013543 active substance Substances 0.000 description 1
230000001476 alcoholic effect Effects 0.000 description 1
229910052783 alkali metal Inorganic materials 0.000 description 1
150000001340 alkali metals Chemical class 0.000 description 1
150000001342 alkaline earth metals Chemical class 0.000 description 1
AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 1
125000003277 amino group Chemical group 0.000 description 1
150000008064 anhydrides Chemical class 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
239000003125 aqueous solvent Substances 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
239000002956 ash Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
229910001863 barium hydroxide Inorganic materials 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
238000010923 batch production Methods 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
239000012496 blank sample Substances 0.000 description 1
239000008280 blood Substances 0.000 description 1
210000004369 blood Anatomy 0.000 description 1
238000001354 calcination Methods 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
230000008859 change Effects 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
239000004927 clay Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000012790 confirmation Methods 0.000 description 1
238000010276 construction Methods 0.000 description 1
239000000356 contaminant Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
238000004132 cross linking Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000000354 decomposition reaction Methods 0.000 description 1
230000007547 defect Effects 0.000 description 1
230000002950 deficient Effects 0.000 description 1
238000006115 defluorination reaction Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
238000002242 deionisation method Methods 0.000 description 1
238000001514 detection method Methods 0.000 description 1
238000009792 diffusion process Methods 0.000 description 1
230000029087 digestion Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
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229910001039 duplex stainless steel Inorganic materials 0.000 description 1
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238000000909 electrodialysis Methods 0.000 description 1
238000005868 electrolysis reaction Methods 0.000 description 1
230000009881 electrostatic interaction Effects 0.000 description 1
238000011067 equilibration Methods 0.000 description 1
HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 description 1
230000005294 ferromagnetic effect Effects 0.000 description 1
239000003337 fertilizer Substances 0.000 description 1
229910052587 fluorapatite Inorganic materials 0.000 description 1
150000004673 fluoride salts Chemical class 0.000 description 1
125000001153 fluoro group Chemical group F* 0.000 description 1
230000004927 fusion Effects 0.000 description 1
230000014509 gene expression Effects 0.000 description 1
239000000383 hazardous chemical Substances 0.000 description 1
HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
230000000415 inactivating effect Effects 0.000 description 1
229910001506 inorganic fluoride Inorganic materials 0.000 description 1
229910003480 inorganic solid Inorganic materials 0.000 description 1
238000009413 insulation Methods 0.000 description 1
ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
239000006028 limestone Substances 0.000 description 1
GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium hydroxide monohydrate Substances [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 description 1
229940040692 lithium hydroxide monohydrate Drugs 0.000 description 1
JILPJDVXYVTZDQ-UHFFFAOYSA-N lithium methoxide Chemical compound [Li+].[O-]C JILPJDVXYVTZDQ-UHFFFAOYSA-N 0.000 description 1
229910001760 lithium mineral Inorganic materials 0.000 description 1
INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
210000004072 lung Anatomy 0.000 description 1
229910001425 magnesium ion Inorganic materials 0.000 description 1
239000000696 magnetic material Substances 0.000 description 1
238000007885 magnetic separation Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000002609 medium Substances 0.000 description 1
239000012528 membrane Substances 0.000 description 1
229910000000 metal hydroxide Inorganic materials 0.000 description 1
239000007769 metal material Substances 0.000 description 1
238000001465 metallisation Methods 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052750 molybdenum Inorganic materials 0.000 description 1
238000012544 monitoring process Methods 0.000 description 1
150000004682 monohydrates Chemical class 0.000 description 1
229910017604 nitric acid Inorganic materials 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
239000005486 organic electrolyte Substances 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
239000012254 powdered material Substances 0.000 description 1
238000004886 process control Methods 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
239000003586 protic polar solvent Substances 0.000 description 1
238000005086 pumping Methods 0.000 description 1
239000012264 purified product Substances 0.000 description 1
239000010453 quartz Substances 0.000 description 1
239000012492 regenerant Substances 0.000 description 1
230000003716 rejuvenation Effects 0.000 description 1
238000005070 sampling Methods 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
230000001568 sexual effect Effects 0.000 description 1
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
235000020374 simple syrup Nutrition 0.000 description 1
239000002002 slurry Substances 0.000 description 1
239000011877 solvent mixture Substances 0.000 description 1
239000007921 spray Substances 0.000 description 1
238000010561 standard procedure Methods 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003860 storage Methods 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
125000000542 sulfonic acid group Chemical group 0.000 description 1
RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
238000007669 thermal treatment Methods 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
238000012546 transfer Methods 0.000 description 1
150000003623 transition metal compounds Chemical class 0.000 description 1
238000005406 washing Methods 0.000 description 1
239000010926 waste battery Substances 0.000 description 1
238000005303 weighing Methods 0.000 description 1
150000003751 zinc Chemical class 0.000 description 1

Classifications

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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/041—Oxides or hydroxides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/045—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing sulfur, e.g. sulfates, thiosulfates, gypsum
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/048—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing phosphorus, e.g. phosphates, apatites, hydroxyapatites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28004—Sorbent size or size distribution, e.g. particle size
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/02—Oxides; Hydroxides
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/288—Treatment of water, waste water, or sewage by sorption using composite sorbents, e.g. coated, impregnated, multi-layered
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/58—Treatment of water, waste water, or sewage by removing specified dissolved compounds
- C02F1/583—Treatment of water, waste water, or sewage by removing specified dissolved compounds by removing fluoride or fluorine compounds
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/02—Roasting processes
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/006—Wet processes
- C22B7/007—Wet processes by acid leaching
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/54—Reclaiming serviceable parts of waste accumulators
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
- C02F2101/14—Fluorine or fluorine-containing compounds
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/20—Waste processing or separation

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Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Organic Chemistry (AREA)
Materials Engineering (AREA)
Environmental & Geological Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
Manufacturing & Machinery (AREA)
Mechanical Engineering (AREA)
Geology (AREA)
Metallurgy (AREA)
General Life Sciences & Earth Sciences (AREA)
Inorganic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Analytical Chemistry (AREA)
Geochemistry & Mineralogy (AREA)
Hydrology & Water Resources (AREA)
Water Supply & Treatment (AREA)
Electrochemistry (AREA)
General Chemical & Material Sciences (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Manufacture And Refinement Of Metals (AREA)
Removal Of Specific Substances (AREA)
Processing Of Solid Wastes (AREA)
Treatment Of Liquids With Adsorbents In General (AREA)
Water Treatment By Sorption (AREA)

KR1020237016851A 2020-11-20 2021-11-19 알칼리성 하이드록사이드 용액으로부터 플루오라이드를 제거하는 방법 Pending KR20230109637A (ko)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
EP20208982.7		2020-11-20
EP20208982		2020-11-20
PCT/EP2021/082377 WO2022106660A1 (en)	2020-11-20	2021-11-19	Process for the removal of fluoride from alkaline hydroxide solutions

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Publication Number	Publication Date
KR20230109637A true KR20230109637A (ko)	2023-07-20

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TWI877188B (zh) *	2019-07-26	2025-03-21	德商巴斯夫歐洲公司	自廢鋰離子電池中回收鋰之方法
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DE102023211159A1 (de) *	2023-11-10	2025-05-15	Volkswagen Aktiengesellschaft	Aufbereitung von Blackmass
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Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2014056609A1 (de)	2012-10-10	2014-04-17	Rockwood Lithium GmbH	Verfahren zur hydrometallurgischen rückgewinnung von lithium, nickel, kobalt aus der lithium-übergangsmetalloxid haltigen fraktion gebrauchter galvanischer zellen
RS61656B1 (sr)	2013-03-15	2021-04-29	Nemaska Lithium Inc	Postupak za dobijanje litijum hidroksida
WO2017136885A1 (en) *	2016-02-09	2017-08-17	Lithium Australia Nl	Processes for extracting and recovering lithium values from lithium bearing materials
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CA3199654A1 (en)	2022-05-27
AU2021384857A9 (en)	2024-07-11
MX2023005972A (es)	2023-06-07
AU2021384857A1 (en)	2023-06-22
EP4247988A1 (en)	2023-09-27
WO2022106660A1 (en)	2022-05-27
JP2023549966A (ja)	2023-11-29
CN116490465A (zh)	2023-07-25

Publication	Publication Date	Title
KR20230109637A (ko)	2023-07-20	알칼리성 하이드록사이드 용액으로부터 플루오라이드를 제거하는 방법
US10648090B2 (en)	2020-05-12	Integrated system for lithium extraction and conversion
JP7156322B2 (ja)	2022-10-19	水酸化リチウムの製造方法
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JP7462570B2 (ja)	2024-04-05	熱を用いたリチウム及び遷移金属を回収する方法
AU2018363879B2 (en)	2024-06-13	Production of high purity nickel sulfate
WO2019160982A1 (en)	2019-08-22	Integrated system for lithium extraction and conversion
KR20210093919A (ko)	2021-07-28	침출물에 수소 가스 주입에 의한 배터리 재활용
CN111727171A (zh)	2020-09-29	用于从盐水中回收锂的方法
US20060275191A1 (en)	2006-12-07	System and method for separating tellurium from cadmium waste
CA3172956A1 (en)	2011-08-25	Method of producing high purity lithium carbonate
Harrison	2014	Technologies for extracting valuable metals and compounds from geothermal fluids
WO2023205073A1 (en)	2023-10-26	Synthetic lithium solutions with controlled impurity profiles
JP2019044246A (ja)	2019-03-22	リチウムの回収方法
Xu et al.	2023	Removal of fluoride from the mixed Ni-Co-Mn sulfate leach solution of spent lithium ion batteries using polyaluminum sulfate
CN110106356B (zh)	2021-05-04	一种粉末型钛系离子交换剂分离盐湖卤水中锂的方法
Xu et al.	0	Mechanism and Application Study of Purifying Fluoride from the Leaching Mixed Ni-Co-Mn Sulfate Solution of Spent Libs by Polyaluminum Sulfate
MX2007015005A (en)	2008-09-02	System and method for separating tellurium waste

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