KR20190068204A - Hydrogelmask composition - Google Patents
Hydrogelmask composition Download PDFInfo
- Publication number
- KR20190068204A KR20190068204A KR1020170168369A KR20170168369A KR20190068204A KR 20190068204 A KR20190068204 A KR 20190068204A KR 1020170168369 A KR1020170168369 A KR 1020170168369A KR 20170168369 A KR20170168369 A KR 20170168369A KR 20190068204 A KR20190068204 A KR 20190068204A
- Authority
- KR
- South Korea
- Prior art keywords
- oil
- water
- weight
- composition
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 239000000203 mixture Substances 0.000 title claims abstract description 97
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 67
- 239000000017 hydrogel Substances 0.000 claims abstract description 37
- 239000000284 extract Substances 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 15
- 239000002736 nonionic surfactant Substances 0.000 claims description 15
- 229920000642 polymer Polymers 0.000 claims description 11
- -1 polyoxyethylene Polymers 0.000 claims description 11
- 239000004094 surface-active agent Substances 0.000 claims description 11
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- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 230000003020 moisturizing effect Effects 0.000 claims description 8
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 7
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- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 150000005846 sugar alcohols Polymers 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 5
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- 125000001931 aliphatic group Chemical group 0.000 claims description 3
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- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
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- DEXFNLNNUZKHNO-UHFFFAOYSA-N 6-[3-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperidin-1-yl]-3-oxopropyl]-3H-1,3-benzoxazol-2-one Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1CCN(CC1)C(CCC1=CC2=C(NC(O2)=O)C=C1)=O DEXFNLNNUZKHNO-UHFFFAOYSA-N 0.000 description 2
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- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
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- 238000003912 environmental pollution Methods 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- MMKRHZKQPFCLLS-UHFFFAOYSA-N ethyl myristate Chemical compound CCCCCCCCCCCCCC(=O)OCC MMKRHZKQPFCLLS-UHFFFAOYSA-N 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
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- 238000005191 phase separation Methods 0.000 description 2
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- LADGBHLMCUINGV-UHFFFAOYSA-N tricaprin Chemical compound CCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCC)COC(=O)CCCCCCCCC LADGBHLMCUINGV-UHFFFAOYSA-N 0.000 description 2
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical class OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
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- A—HUMAN NECESSITIES
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- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
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- A—HUMAN NECESSITIES
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- A61K8/04—Dispersions; Emulsions
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- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/26—Optical properties
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- A—HUMAN NECESSITIES
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- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/82—Preparation or application process involves sonication or ultrasonication
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- Cosmetics (AREA)
Abstract
본 발명은 울릉도 삼나물 뿌리 추출물을 함유한 항산화 및 항염증 효능을 가진 가변적 투명도를 갖는 수중유 형태의 하이드로겔마스크 조성물에 관한 것으로, 보다 구체적으로는 울릉도산 삼나물 추출하여 항산화 및 항염증 효능을 가진 유상부 및 수상부를 포함하는 수중유(oil in water, O/W) 형태의 하이드로겔 마스크 조성물로서, 유상부와 수상부의 굴절률 차의 변화를 통해 사용자의 피부 컨디션, 온도 및 습도 등에 따라 조성물의 최상의 적용시간을 육안으로 확인할 수 있도록 하는 하이드로겔 마스크 조성물에 관한 것이다. The present invention relates to an oil-in-water type hydrogel mask composition having variable transparency with antioxidative and anti-inflammatory effects containing Ulleungdo's trilobinate root extract. More specifically, the present invention relates to a hydrogel mask composition having an antioxidative and anti- The present invention relates to a hydrogel mask composition in the form of an oil in water (O / W) including an oil-in-water and a water-in-oil portion. The composition of the hydrogel mask is superior in terms of skin condition, temperature and humidity, Thereby allowing the time to be visually confirmed.
Description
본 발명은 울릉도 삼나물 뿌리 추출물을 함유한 항산화 및 항염증 효능을 가진 가변적 투명도를 갖는 수중유 형태의 하이드로겔마스크 조성물에 관한 것으로, 보다 구체적으로는 울릉도산 삼나물 추출하여 항산화 및 항염증 효능을 가진 유상부 및 수상부를 포함하는 수중유(oil in water, O/W) 형태의 하이드로겔 마스크 조성물로서, 유상부와 수상부의 굴절률 차의 변화를 통해 사용자의 피부 컨디션, 온도 및 습도 등에 따라 조성물의 최상의 적용시간을 육안으로 확인할 수 있도록 하는 하이드로겔 마스크 조성물에 관한 것이다. The present invention relates to an oil-in-water type hydrogel mask composition having variable transparency with antioxidative and anti-inflammatory effects containing Ulleungdo's trilobinate root extract. More specifically, the present invention relates to a hydrogel mask composition having an antioxidative and anti- The present invention relates to a hydrogel mask composition in the form of an oil in water (O / W) including an oil-in-water and a water-in-oil portion. The composition of the hydrogel mask is superior in terms of skin condition, temperature and humidity, Thereby allowing the time to be visually confirmed.
소비자들의 피부 미용에 대한 관심이 높아지면서 보건의료기술에 의존하기 보다 기능성을 가진 화장품에 대한 요구가 증가하고 있는 추세이다. 노화, 스트레스 및 환경오염 등으로 피부 트러블의 발생이 증가하고 있어 항산화 효능 및 항염증 효능에 대한 관심도가 높아지고 있다.As consumers are increasingly interested in skin care, there is a growing demand for functional cosmetics rather than relying on health care technology. Aging, stress, and environmental pollution, skin troubles are increasing, and the interest in antioxidant efficacy and anti-inflammatory efficacy is increasing.
울릉도 청정 지역의 약용식물인 삼나물은 혹한 환경에서 생존을 위하여 여러 가지 방어 물질(파이토카인)을 만들어 내며, 특히 항산화 및 항염증 효능이 뛰어난 사포닌 성분이 다량 함유되어 있다. 울릉도의 특성상 토양 및 재배환경이 좋아 뿌리부분에 대한 효능이 뛰어날 것으로 예상된다. The medicinal herb of Ulleungdo is a medicinal plant in Ulleungdo, which produces various defense substances (phytocaine) for survival in a harsh environment. Especially, it contains a large amount of saponin, which has excellent antioxidant and anti-inflammatory effects. Due to the nature of Ulleungdo, soil and cultivation environment is good, and it is expected that the efficacy will be excellent.
팩은 스킨, 로션 및 크림과 같은 일반적인 기초 화장료 제품 유형의 하나로서, 피부에 단시간 적용하여 흡수시키는 다른 제품 유형들과 달리 장시간의 적용을 통해 수분 및 영양분 공급을 극대화시킬 수 있는 기능성 화장료 유형이다. 이러한 팩의 종류로는 부직포에 에센스 액을 충진하거나 하이드로겔 타입으로 제조하여 피부에 부착 후 떼어낼 수 있는 마스크 타입, 또는 피부에 고르게 도포한 후 일정 시간이 지난 후에 물 등으로 씻어내거나 고형화된 화장료를 떼어낼 수 있는 크림 타입 등이 시판되고 있으며, 소비자의 기호에 따라 다양하게 선택하여 사용할 수 있다.The pack is one of the most common cosmetic product types, such as skins, lotions and creams, and is a type of functional cosmetic that can maximize the supply of moisture and nutrients through prolonged application, unlike other product types that absorb and apply to the skin in a short time. Examples of such packs include a mask type in which a nonwoven fabric is filled with an essence liquid or made into a hydrogel type and attached to the skin and then peeled off, or a mask type in which the skin is evenly applied and then washed with water or a solidified cosmetic And a cream type which can be peeled off are commercially available and can be selected and used variously according to the taste of the consumer.
이러한 팩 화장료 조성물의 경우 통상적으로 피부에 일정시간 적용하여 수분 및 성분 흡수를 극대화한 후 제거하는 방법으로 사용하게 되는데, 사용자의 피부 컨디션, 피부의 온도 및 습도 등에 따라 최적의 적용시간이 달라질 수 있으므로 이를 육안으로 확인할 수 있도록 하는 화장료 조성물에 대한 연구가 당 분야에 요구되고 있다.In the case of such a packaged cosmetic composition, usually, it is applied to the skin for a certain period of time to maximize the absorption of moisture and components, and then used as a method for removing the cosmetic composition. However, the optimum application time may vary depending on the skin condition of the user, There is a need in the art for a cosmetic composition that can be visually confirmed.
따라서, 스트레스 및 외부자극으로 인해 예민해진 피부를 개선시켜줄 수 있는 항산화 효능 및 항염증 효능을 갖는 사용자의 피부 컨디션, 피부의 온도 및 습도 정도 등에 따라 최상의 적용시간을 육안으로 확인할 수 있도록 하는 하이드로겔 마스크 조성물에 대한 연구가 당 분야에 요구되고 있는 것이다.Therefore, the hydrogel mask which can visually confirm the best application time according to the skin condition of the user, the temperature of the skin and the humidity level of the user having the antioxidant effect and the anti-inflammatory effect which can improve the skin which is sensitive due to stress and external stimulation Research on the composition is required in the art.
이에 본 발명이 해결하고자 하는 과제는, 외부자극(스트레스, 환경오염 등)으로 예민해진 피부를 개선시켜줄 수 있는 항산화 효능 및 항염증 효능의 화장료 조성물을 개발하고 이를 함유한 사용자의 피부 컨디션, 온도 및 습도 등에 따라 하이드로겔마스크의 최상의 적용시간을 육안으로 확인할 수 있도록 하는 하이드로겔마스크 조성물 개발하기 위한 것이다.SUMMARY OF THE INVENTION Accordingly, it is an object of the present invention to provide a cosmetic composition having antioxidative and anti-inflammatory properties capable of improving the skin sensitive to external stimuli (stress, environmental pollution, etc.) Humidity and the like of the hydrogel mask so that the best application time of the hydrogel mask can be visually confirmed.
본 발명은 상기와 같은 과제를 해결하기 위하여, 총 중량 대비 0.05 내지 50.00 중량%의 유상부와 50 내지 99.95 중량%의 수상부로 이루어지고, 상기 수상부는 울릉도 삼나물 뿌리 추출물이 총 중량대비 1.00 내지 10.00 중량%를 함유하고 있으며, 상기 유상부와 수상부의 굴절률 차는 0.02 내지 0.15인 것을 특징으로 한다.In order to solve the above-mentioned problems, the present invention provides a method for producing a water-borne water-borne fruit, which comprises 0.05 to 50.00% by weight of an oil-in-water portion and 50 to 99.95% %, And a difference in refractive index between the oil phase part and the water phase part is 0.02 to 0.15.
또한, 본 발명은 울릉도 삼나물 뿌리 추출물을 유효성분으로 함유하고 있으며, 초음파 추출법을 사용하여 추출하고 용매로 1,3-부틸렌글라이콜을 30 중량% 사용한 것을 특징으로 한다.In addition, the present invention is characterized in that Ulleungdo triangular root root extract is contained as an active ingredient and is extracted using an ultrasonic extraction method and 30 wt% of 1,3-butyleneglycol is used as a solvent.
또한, 본 발명의 일실시예에 따르면, 상기 하이드로겔 마스크 조성물은 총 중량 대비 5 내지 20 중량%의 유상부 및 80 내지 95 중량%의 수상부로 이루어지고, 상기 수상부는 1 내지 10 중량%의 울릉도 삼나물 뿌리 추출물을 함유하고 있는 것을 특징으로 한다.According to an embodiment of the present invention, the hydrogel mask composition comprises 5 to 20% by weight of an oil phase and 80 to 95% by weight of a water phase, and the water phase comprises 1 to 10% And a root extract of the herb.
또한, 본 발명의 일실시예에 따르면, 상기 유상부 또는 수상부의 굴절률은 각각 1.350 내지 1.550 범위인 것을 특징으로 한다.According to an embodiment of the present invention, the refractive indexes of the oil phase portion and the water phase portion are respectively in the range of 1.350 to 1.550.
또한, 본 발명의 일실시예에 따르면, 상기 수상부는 보습제, 겔화 고분자 및 정제수, 울릉도 삼나물 뿌리 추출물을 포함하여 이루어지는 것을 특징으로 한다.In addition, according to an embodiment of the present invention, the water receiving unit comprises a moisturizing agent, a gelled polymer, purified water, and Ulleungdo's trilobate root extract.
또한, 본 발명의 일실시예에 따르면, 상기 보습제는 다가알코올류, 글리세린류, 당류 또는 이들의 혼합물로서, 조성물 총 중량 대비 1 내지 70 중량%로 이루어진 것을 특징으로 한다.According to an embodiment of the present invention, the humectant may be a polyhydric alcohol, a glycerin, a saccharide, or a mixture thereof, and is composed of 1 to 70% by weight based on the total weight of the composition.
또한, 본 발명의 일실시예에 따르면, 상기 겔화 고분자로는 천연 당류, 친수성 겔화제 또는 이들의 혼합물로서, 조성물 총 중량 대비 0.1 내지 10 중량%로 이루어진 것을 특징으로 한다.According to an embodiment of the present invention, the gelled polymer is a natural saccharide, a hydrophilic gelling agent, or a mixture thereof, and is composed of 0.1 to 10% by weight based on the total weight of the composition.
또한, 본 발명의 일실시예에 따르면, 상기 유상부는 통상적인 오일 및 계면활성제(유화제)로 이루어진 것을 특징으로 한다.In addition, according to one embodiment of the present invention, the oily phase is characterized by being composed of conventional oils and surfactants (emulsifiers).
또한, 본 발명의 일실시예에 따르면, 상기 오일은 에스테르계 오일, 탄화수소계 오일, 왁스류, 천연오일, 실리콘 오일 또는 이들의 혼합물로서, 조성물 총 중량 대비 0.05 내지 50.00 중량%로 이루어진 것을 특징으로 한다.According to an embodiment of the present invention, the oil is an ester-based oil, a hydrocarbon-based oil, a wax, a natural oil, a silicone oil, or a mixture thereof and is 0.05 to 50.00% do.
또한, 본 발명의 일실시예에 따르면, 상기 계면활성제는 다가 알코올과 지방산의 에스테르계 비이온계면활성제, 지방족 폴리옥시에틸렌 중합계의 비이온계면활성제, 솔비탄 에스테르의 폴리옥시에틸렌 에테르계의 비이온계면활성제, 천연유의 폴리옥시에틸렌 에테르계 비이온계면활성제, 폴리옥시에틸렌 에테르계 비이온계면활성제, 알칼리성 음이온계면활성제, 중성 음이온계면활성제 또는 이들의 혼합물로서, 조성물 총 중량 대비 0 내지 15 중량%로 이루어진 것을 특징으로 한다.According to one embodiment of the present invention, the surfactant is selected from the group consisting of an ester type nonionic surfactant of polyhydric alcohol and fatty acid, a nonionic surfactant of aliphatic polyoxyethylene polymerization type, a polyoxyethylene ether type surfactant of sorbitan ester A polyoxyethylene ether nonionic surfactant, a polyoxyethylene ether nonionic surfactant, an alkaline anionic surfactant, a neutral anionic surfactant or a mixture thereof, in an amount of 0 to 15% by weight, based on the total weight of the composition, of anionic surfactant, natural polyoxyethylene ether nonionic surfactant, .
본 발명에 따른 유상부 및 수상부를 포함하는 수중유(oil in water, O/W) 형태의 하이드로겔 마스크 조성물로서, 총 중량 대비 0.05 내지 50 중량%의 유상부 및 50 내지 99.95 중량%의 수상부를 포함할 수 있고 수상부에 1 내지 10 중량%의 울릉도 삼나물 뿌리 추출물을 포함하며 유상부와 수상부의 굴절률 차가 0.02 내지 0.15인 것을 특징으로 하는 항산화 및 항염증 효능을 가진 가변적 투명도를 갖는 하이드로겔 마스크 조성물은, i)항산화 및 항염증 효능을 가지고, 온도 및 시간에 따른 ⅱ) 제형 안정성이 우수할 뿐 아니라 ⅲ) 수상부 및 유상부 내 함유 성분의 함량 조절을 통해 피부에 적용되었을 때 불투명한 유백색에서 투명하게 변화되어 적용 최적 시간을 육안으로 용이하게 식별할 수 있으므로, 일정 적용시간을 필요로 하는 하이드로겔 마스크 제품 개발에 유용하게 활용될 수 있다.An oil in water (O / W) type hydrogel mask composition comprising an oil phase part and a water phase part according to the present invention, which comprises 0.05 to 50% by weight of an oil phase part and 50 to 99.95% And a hydrogel mask composition having variable transparency having an antioxidant and anti-inflammatory effect, wherein the hydrogel mask composition comprises 1 to 10% by weight of Ulleungdo's trilobate root extract on the top of the water and has a refractive index difference of 0.02 to 0.15 between the oil- i) has antioxidant and anti-inflammatory properties, and ii) is excellent in formulation stability according to temperature and time, iii) transparently changes in opaque milky white when applied to skin through control of the contents of components contained in water and oil Therefore, it is necessary to develop a hydrogel mask product that requires a certain time for application It can be used.
이하, 본 발명의 실시 예에 의거하여 상세히 설명하기로 한다.Hereinafter, embodiments of the present invention will be described in detail.
먼저, 본 발명의 울릉도 삼나물 뿌리 추출물을 함유한 항산화 및 항염증 효능을 가진 유상부 및 수상부를 포함하는 수중유(oil in water, O/W) 형태의 하이드로겔 마스크 조성물로서, 총 중량 대비 0.05 내지 50.00 중량%의 유상부 및 50 내지 99.95 중량%의 수상부를 포함하며 First, an oil in water (O / W) type hydrogel mask composition comprising an oil portion and a water portion having an antioxidant and anti-inflammatory effect containing Ulleungdo's trilobate root extract of the present invention, 50.00% by weight of an oily phase and 50% to 99.95% by weight of a water-
상기 수상부에는 총중량대비 1.00 내지 10.00 중량%의 울릉도 삼나물 뿌리 추출물을 함유하고 있으며,The upper part of the water contains Ulleungdo trilobal root extract of 1.00 to 10.00% by weight based on the total weight,
상기 유상부와 수상부의 굴절률 차는 0.02 내지 0.15인 것을 특징으로 한다. And the refractive index difference between the oil phase portion and the water phase portion is 0.02 to 0.15.
따라서, 항산화 및 항염증 효능으로 인해 외부자극으로 예민해진 피부를 개선시키고 피부에 적용하는 경우 피부온도에서 수분이 증발함에 따라 수상부와 유상부간의 굴절률차가 줄어들어 투명하게 변색됨으로써 개인차에 따른 최상의 제품 적용시간을 육안으로 쉽게 확인할 수 있는 장점이 있다.Therefore, when the skin is sensitized by external stimuli due to the antioxidant and anti-inflammatory effect, the refractive index difference between the upper part and the upper part is reduced as the water is evaporated at the skin temperature, so that it is discolored transparently so that the best application time Can be easily confirmed with the naked eye.
울릉도 삼나물 뿌리 추출물에는 사포닌이 다량 함유되어 있어 항산화 및 항염증 효능이 뛰어나다.Ulleungdo's three-root root extract contains a large amount of saponin, so it has excellent antioxidant and anti-inflammatory effects.
본 발명의 화장료 조성물은 유상부가 수상부에 용해된 수중유 형태의 하이드로겔 마스크 조성물로서 보습감과 유분감이 우수하다. The cosmetic composition of the present invention is an oil-in-water type hydrogel mask composition in which an oily portion is dissolved in water, and has excellent moisturizing and oiliness.
본 발명의 조성물에서 상기 유상부는 조성물 총 중량 대비 0.05 내지 50.00 중량%, 바람직하게는 5 내지 20 중량%로 포함될 수 있으며, 이때 0.05 중량% 미만인 경우에는 함량이 미비하여 불투명한 유백색을 구현하는 것이 어렵고, 50.00 중량% 초과인 경우에는 수중유 형태의 제형 안정성이 떨어질 수 있다.In the composition of the present invention, the oily portion may be contained in an amount of 0.05 to 50.00% by weight, preferably 5 to 20% by weight based on the total weight of the composition. When the content is less than 0.05% by weight, it is difficult to realize opaque milky white , And if it is more than 50.00% by weight, the formulation stability of the oil-in-water type may be deteriorated.
또한, 상기 수상부는 조성물 총 중량 대비 50 내지 99.95 중량%, 바람직하게는 80 내지 95 중량%로 포함될 수 있으며, 이때 50 중량% 미만인 경우에는 수중유 형태의 에멀젼 형성이 어렵고, 99.5 중량% 초과인 경우에는 불투명한 유백색 구현이 어렵다.The water phase may be contained in an amount of 50 to 99.95% by weight, preferably 80 to 95% by weight based on the total weight of the composition. When the weight fraction is less than 50% by weight, emulsion formation in oil- It is difficult to implement opaque milky white.
또한, 본 발명의 수중유 형태의 하이드로겔 마스크 조성물은 상기 수상부와 유상부 간의 굴절률 차가 0.02 내지 0.15으로 불투명한 유백색을 나타내며, 피부에 적용하는 경우 피부온도에 의해 수분이 증발함으로써 수상부와 유상부 간의 굴절률 차가 줄어들어 투명하게 변화되는 것을 특징으로 한다. In addition, the hydrogel mask composition of the present invention has an opaque milky white color with a refractive index difference of 0.02 to 0.15 between the upper part and the upper part of the water. When applied to the skin, moisture is evaporated by the skin temperature, And the refractive index difference is reduced so as to be transparently changed.
본 발명의 일실시예에 따르면, 상기 유상부 또는 수상부의 굴절률은 각각 1.250 내지 1.450 범위일 수 있고, 상기 굴절률 차는 0.02 내지 0.15내외로 이루어지며 바람직하게는 0.08일 수 있다. 이때 굴절률의 차가 0.02 미만인 경우에는 불투명한 유백색 구현이 어렵고, 0.15을 초과하는 경우에는 굴절률 차가 너무 커져 피부온도에서의 수분 증발 정도로 효과적인 투명 변색을 기대하기 어려울 수 있다.According to an embodiment of the present invention, the refractive indexes of the oil phase portion and the water phase portion may be in the range of 1.250 to 1.450, and the refractive index difference may be 0.02 to 0.15, preferably 0.08. At this time, when the refractive index difference is less than 0.02, opaque milky white color is difficult to implement. When the refractive index difference is more than 0.15, the refractive index difference becomes too large, and it may be difficult to expect an effective transparent discoloration at the degree of moisture evaporation at skin temperature.
따라서 본 발명은 이러한 수상부와 유상부 간의 굴절률 차를 이용한 가변적 투명도를 가짐으로써 개인차에 따른 최상의 적용시간을 육안으로 쉽게 확인할 수 있는 장점이 있다.Therefore, the present invention has an advantage that it is easy to visually confirm the best application time according to the individual difference by having the variable transparency using the refractive index difference between the water top and the oil part.
또한, 본 발명의 조성물에서 수상부와 유상부 간의 굴절률 차는 화장료 조성물의 필수 성분, 적용 대상, 목적하는 적정 시간 등에 따라 상기 범위 내에서 적절히 조절할 수 있다. 이때, 유상부와 수상부의 굴절률의 차를 조절하기 위해, 수상부에 포함되는 보습제나 유상부에 첨가되는 오일 등의 함량을 조절할 수 있으며, 보다 구체적으로는 굴절률 차를 낮추기 위해서는 수상부에 포함되는 다가알코올류, 글리세린류 또는 당류 등의 함량을 높이거나 유상부에 포함되는 오일 등의 함량을 낮추거나 굴절률이 낮은 오일을 사용하는 방법을 채택할 수 있으며, 반대로 굴절률 차를 높이기 위해서는 수상부의 다가알코올류, 글리세린류 또는 당류 등의 함량을 낮추거나 유상부 오일의 함량 또는 굴절률을 높이는 방법을 채택할 수 있다.In the composition of the present invention, the difference in the refractive index between the upper aqueous layer and the upper aqueous layer can be appropriately controlled within the above range depending on the essential components of the cosmetic composition, the application purpose, the desired time, and the like. At this time, in order to control the refractive index difference between the oil phase part and the water phase part, it is possible to control the content of the moisturizing agent included in the water phase and the oil added to the oil phase part. More specifically, in order to lower the refractive index difference, A method in which the content of oil, glycerin or saccharides is increased, the content of oil contained in the oil phase is lowered or the oil having a low refractive index is used. On the other hand, in order to increase the difference in refractive index, a polyhydric alcohol, A method of lowering the content of oils or saccharides or raising the content or refractive index of the oil phase oil may be adopted.
본 발명의 하이드로겔 마스크 조성물에서, 상기 수상부는 통상적인 보습제, 겔화 고분자 및 정제수, 울릉도 삼나물 추출물 등을 포함할 수 있다.In the hydrogel mask composition of the present invention, the water receiving portion may include a conventional humectant, a gelling polymer and purified water, Ulleungdo Trilobal Extract, and the like.
이때, 상기 보습제로는 피부에 수분을 공급하기 위한 통상적인 화장료 보습제 성분이라면 어느 것이든 사용할 수 있으며, 예를 들면 부틸렌글리콜, 프로필렌글리콜, 펜틸렌글리콜, 헥실렌글리콜, 폴리에틸렌글리콜 등의 다가알코올류; 글리세린, 디글리세린, 폴리글리세린 등의 글리세린류; 및 솔비톨 멀티톨, 자당, 전분당, 라쿠치톨 등의 당류 등을 포함하는 군으로부터 하나 이상 선택하여 사용할 수 있으나, 이에 제한되는 것은 아니다. 상기 보습제의 함량은 조성물 총 중량 대비 1 내지 70 중량%, 바람직하게는 5 내지 45 중량%일 수 있으며, 이때 1 중량% 미만인 경우에는 수상부와 유상부 간의 굴절률 차가 너무 커져 투명도 변화가 일어나기 어려우며, 70 중량% 초과인 경우에는 수상부와 유상부의 굴절률의 차가 너무 낮아져 유백색 구현이 어려워질 수 있다.As the moisturizing agent, any conventional cosmetic moisturizing agent for supplying moisture to the skin may be used. Examples of the moisturizing agent include polyhydric alcohols such as butylene glycol, propylene glycol, pentylene glycol, hexylene glycol, and polyethylene glycol Ryu; Glycerin such as glycerin, diglycerin and polyglycerin; And saccharides such as sorbitol multitol, sucrose, starch sugar, and racquitol, but the present invention is not limited thereto. The amount of the moisturizing agent may be 1 to 70% by weight, preferably 5 to 45% by weight based on the total weight of the composition. If the amount is less than 1% by weight, the difference in refractive index between the upper part and the upper part becomes too large, If it is more than 10% by weight, the difference between the refractive indexes of the upper part and the upper part becomes too low, and it becomes difficult to realize the milky white color.
또한, 상기 겔화 고분자로는 화장료 조성물의 하이드로겔 마스크 형태 구현을 위해 사용되는 통상적인 겔화 고분자라면 어느 것이든 사용할 수 있으며, 예를 들면 갈락토만난, 글루코만난, 구아껌, 로카스트 빈 껌, 플루로닉, 아가, 알긴, 카라기난, 잔탄, 겔란, 젤라틴, 메틸셀룰로오스, 셀룰로오스, 카르복시메틸셀룰로오스,히드록시에틸셀룰로오스 등의 천연 당류; 및 폴리아크릴레이트 또는 그의 염, 폴리메타크릴산, 카르복시비닐폴리머, 폴리비닐알코올, 폴리아크릴아미드, 폴리에틸렌옥시드, 폴리에틸렌이민, 폴리비닐피롤리돈 등의 친수성 겔화제를 포함하는 군으로부터 하나 이상 선택하여 사용할 수 있으나, 이에 제한되는 것은 아니다.상기 겔화고분자는 조성물 총 중량 대비 0.1 내지 10 중량%, 바람직하게는 0.5 내지 5 중량%로 포함될 수 있으며, 이때 0.1 중량% 미만의 경우에는 겔의 경화로 인해 유연성이 떨어져 피부에 적용 시 밀착성이 떨어질 수 있고, 10 중량% 초과의 경우에는 겔의 연화가 심해져 형태 유지가 어렵고 탄력성이 떨어질 수 있다.The gelling polymer may be any conventional gelling polymer used in the form of a hydrogel mask of the cosmetic composition. Examples of the gelling polymer include galactomannan, glucomannan, guar gum, rocastine gum, Natural saccharides such as nickel, agar, algin, carrageenan, xanthan, gellan, gelatin, methylcellulose, cellulose, carboxymethylcellulose and hydroxyethylcellulose; And a hydrophilic gelling agent such as polyacrylate or its salt, polymethacrylic acid, carboxyvinyl polymer, polyvinyl alcohol, polyacrylamide, polyethylene oxide, polyethyleneimine, polyvinylpyrrolidone and the like. The gelation polymer may be contained in an amount of 0.1 to 10% by weight, preferably 0.5 to 5% by weight, based on the total weight of the composition. When the gelation polymer is less than 0.1% by weight, It may be difficult to maintain the shape and the elasticity may be deteriorated because the softness of the gel is increased when the content is more than 10% by weight.
또한, 상기 정제수는 화장품에 사용되는 정제수로써, 총 중량 대비 5 내지 90 중량%를 함유할 수 있으며, 바람직하게는 10 내지 60 중량%이다. 이때 상기 정제수는 10 중량% 미만인 경우에는 겔의 경화로 인해 유연성이 떨어져 피부에 적용 시 밀착성이 떨어질 수 있고, 수상부와 유상부 간의 굴절률 차가 너무 커져 투명도 변화가 일어나기 어려우며, 60 중량% 초과인 경우에는 수상부와 유상부의 굴절률의 차가 너무 낮아져 유백색 구현이 어려워지고, 겔의 연화가 심해져 형태 유지가 어렵고 탄력성이 떨어질 수 있다.The purified water is purified water used for cosmetics, and may contain 5 to 90% by weight, preferably 10 to 60% by weight based on the total weight of the cosmetic. When the purified water is less than 10% by weight, the gel is hardened due to the curing of the gel. Therefore, when it is applied to the skin, the adhesiveness may deteriorate and the difference in refractive index between the water layer and the oil layer becomes too large to change the transparency. The difference in the refractive index between the water layer and the oil phase becomes too low to make the milky white color difficult, and the softening of the gel becomes severe, so that it is difficult to maintain the shape and the elasticity may be deteriorated.
또한, 본 발명의 화장료 조성물에서, 상기 유상부는 통상적인 오일 및 계면활성제 등을 포함할 수 있다.Further, in the cosmetic composition of the present invention, the oily portion may contain conventional oils and surfactants.
이때, 상기 오일로는 화장료 조성물에 통상적으로 사용될 수 있는 오일이라면 어느 것이든 사용할 수 있으며, 예를 들면 이소프로필미리스테이트, 에틸라우레이트, 에틸미리스테이트, 이소프로필팔미테이트, 부틸라우레이트, 헥실라우레이트, 카프릴릭/카프릭트리글리세라이드, 부틸렌글라이콜디카프릴레이트/디카프레이트, 이소프로필미리스테이트, 트리에틸헥사노인, 세틸에틸헥사노에이트, 옥틸도데칸올, 폴리올에스테르 등의 에스테르계 오일; 시클로도데칸, 이소옥탄, 리퀴드파라핀, 바세린, 하이드로제네이티드폴리데센, 시클로옥탄, 시클로펜탄 및 스쿠알렌 등의 탄화수소계 오일; 마이크로리스탈린왁스, 비즈왁즈, 라놀린왁스, 오조케라이트왁스, 칸데릴라왁스, 카르나우바왁스, 합성왁스 등의 왁스류; 호호바오일, 아보카도오일, 아몬드오일, 올리브오일, 참기름, 밀배아유, 사플라워오일, 동백기름, 피마자유, 포도씨오일, 녹차씨오일, 마카다미아넛츠오일, 야자유, 로즈힙오일, 경화유, 아르간오일, 산자나무오일, 아르간트리커넬오일 및 라벤더오일 등의 천연오일;및 사이클로메치콘, 페닐트리메치콘, 사이클로펜타실록산, 디메치콘 등의 실리콘 오일을 포함하는 군으로부터 하나 이상 선택하여 사용할 수 있으나, 이에 제한되는 것은 아니다. 본 발명의 바람직한 일실시예에 따르면, 올리브오일, 디메치콘, 카프릴릭/카프릭트리글리세라이드, 세틸에틸헥사노에이트, 리퀴드파라핀 또는 이들의 혼합물 등을 사용할 수 있다. 상기 오일은 본 발명의 조성물 총 중량 대비 0.05 내지 50.00 중량%, 바람직하게는 5 내지 20 중량%로 포함될 수 있으며, 이때 0.05 중량% 미만인 경우에는 하이드로겔 마스크의 유백색 구현이 어렵고, 50.00 중량%초과의 경우에는 수중유 타입의 에멀젼 형성이 어려워 제형 안정성이 떨어질 수 있다.The oil may be any oil conventionally used in cosmetic compositions. Examples of the oil include isopropyl myristate, ethyl laurate, ethyl myristate, isopropyl palmitate, butyl laurate, Ester oils such as lactose, caprylic / capric triglyceride, butyleneglycolic dicaprylate / dicaprate, isopropyl myristate, triethylhexanoin, cetyl ethylhexanoate, octyldodecanol and polyol esters ; Hydrocarbon oils such as cyclododecane, isooctane, liquid paraffin, vaseline, hydrogenated polydecene, cyclooctane, cyclopentane and squalene; Waxes such as microcrystalline wax, beeswax, lanolin wax, ozokerite wax, candelilla wax, carnauba wax and synthetic wax; Jojoba Oil, Avocado Oil, Almond Oil, Olive Oil, Sesame Oil, Wheat Germ Oil, Four Flower Oil, Camellia Oil, Castor Oil, Grape Seed Oil, Green Tea Seed Oil, Macadamia Nut Oil, Palm Oil, Rosehip Oil, Natural oils such as wood oil, argan tree trunk oil and lavender oil, and silicone oils such as cyclomethicone, phenyltrimethicone, cyclopentasiloxane and dimethicone. It is not. According to one preferred embodiment of the present invention, olive oil, dimethicone, caprylic / capric triglyceride, cetyl ethylhexanoate, liquid paraffin or mixtures thereof can be used. The oil may be contained in an amount of 0.05 to 50.00% by weight, preferably 5 to 20% by weight based on the total weight of the composition of the present invention. When the oil is less than 0.05% by weight, it is difficult to implement the milky white color of the hydrogel mask. It is difficult to form an oil-in-water type emulsion, which may result in poor formulation stability.
또한, 상기 계면활성제로는 화장료 조성물의 수중유 형태 구현 및 유지를 위해 통상적으로 사용되는 계면활성제라면 어느 것이든 사용할 수 있으며, 예를 들면 솔비탄 스테아레이트, 솔비탄 라우레이트, 솔비탄 팔미테이트, 글리세릴 스테아레이트, 폴리글리세릴 스테아레이트 등의 다가 알코올과 지방산의 에스테르계의 비이온계면활성제; 폴리옥시에틸렌 스테아릴에테르, 폴리옥시에틸렌 올리에이트 등의 지방족 폴리옥시에틸렌 중합계의 비이온계면활성제; 폴리옥시에틸렌 솔비탄 스테아레이트, 폴리옥시에틸렌 솔비탄 라우레이트, 폴리옥시에틸렌 솔비탄 올리에이트, 폴리옥시에틸렌 솔비톨 헥사올레이트 등의 솔비탄 에스테르의 폴리옥시에틸렌 에테르계의 비이온계면활성제; 폴리옥시에틸렌 하이드로제네이티드 캐스터오일 등의 천연유의 폴리옥시에틸렌 에테르계 비이온계면활성제; 폴록사머 168, 폴록사머 407등의 폴리옥시 프로필렌의 폴리옥시에틸렌 에테르계 비이온계면활성제; 소듐스테아레이트, 포타슘스테아레이트, 소듐 라우레이트 등의 알칼리성 음이온계면활성제;및 소듐라우릴설페이트, 소듐라우레스설페이트, 암모늄라우레스설페이트, 포타슘세틸포스페이트 등의 중성 음이온계면활성제로 이루어진 군으로부터 하나 이상을 선택하여 사용할 수 있으나, 이에 제한되는 것은 아니다. 상기 계면활성제는 조성물 총 중량 대비 0 내지 10 중량%, 바람직하게는 0 내지 5 중량%로 포함될 수 있으며, 이때 10.00 중량% 초과의 경우에는 피부자극을 유발할 수 있을 뿐 아니라 겔화 고분자의 겔화 형성을 저해할 수 있어 적절치 않다. The surfactant may be any surfactant conventionally used for the implementation and maintenance of the oil-in-water type of cosmetic composition. Examples of the surfactant include sorbitan stearate, sorbitan laurate, sorbitan palmitate, Ester-based nonionic surfactants of polyhydric alcohols such as glyceryl stearate and polyglyceryl stearate and fatty acids; Nonionic surfactants of aliphatic polyoxyethylene polymerization type such as polyoxyethylene stearyl ether and polyoxyethylene oleate; Polyoxyethylene ether nonionic surfactants of sorbitan esters such as polyoxyethylene sorbitan stearate, polyoxyethylene sorbitan laurate, polyoxyethylene sorbitan oleate, and polyoxyethylene sorbitol hexaoleate; Polyoxyethylene ether nonionic surfactants such as polyoxyethylene hydrogenated castor oil and the like; Polyoxyethylene ether nonionic surfactants of polyoxypropylene such as Poloxamer 168 and Poloxamer 407; Alkaline anionic surfactants such as sodium stearate, potassium stearate and sodium laurate, and neutral anionic surfactants such as sodium lauryl sulfate, sodium laureth sulfate, ammonium laureth sulfate, and potassium cetyl phosphate. But it is not limited thereto. The surfactant may be included in an amount of 0 to 10% by weight, preferably 0 to 5% by weight, based on the total weight of the composition. If the surfactant is used in an amount of more than 10.00% by weight, skin irritation may be induced and the gelation of the gelation polymer may be inhibited It is not appropriate to do it.
본 발명에 따른 수중유 형태의 하이드로겔 마스크 조성물은 상기 성분들 외에도 조성물의 효과를 떨어트리지 않는 범위 내에서 통상적인 pH조절제, 보존제, 향료, 색소, 살균제, 산화안정화제 또는 펄제 등을 추가로 포함할 수 있다. The hydrogel mask composition according to the present invention further comprises, in addition to the above components, conventional pH adjusting agents, preservatives, perfumes, pigments, bactericides, oxidative stabilizers, pearlescent agents and the like within the range not deteriorating the effect of the composition can do.
본 발명의 수중유 형태의 하이드로겔 마스크 조성물은 통상적인 수중유 형태의 하이드로겔 마스크 조성물의 제조방법에 따라 제조할 수 있으며, 구체적으로 해당 성분들을 실온 또는 가열 혼합하는 방법을 통해 각각 수상부 혼합물 및 유상부 혼합물을 수득한 후 이들의 굴절률을 측정하고, 수득한 수상부 혼합물과 유상부 혼합물을 가열 혼합 후 냉각시키는 공정을 통해 제조할 수 있다. The water-in-oil type hydrogel mask composition of the present invention can be prepared according to a conventional method for producing a hydrogel mask composition in oil-in-water type, and specifically, A method in which the refractive index of the oil phase mixture is obtained, the refractive index of the oil phase mixture is measured, and the resultant aqueous mixture is heated and mixed and cooled.
본 발명의 바람직한 일실시예에 따르면, 유상부의 각 성분들을 혼합 후 80℃로 가열하여 용해하여 유상부 혼합물을 수득하고 수상부의 각 성분들을 실온에서 혼합 용해시켜 수상부 혼합물을 수득할 수 있었으며, 각 혼합물의 굴절률을 측정한 후 이들 수상부 및 유상부 혼합물들을 호모믹서를 이용하여 70~90℃ 및 3,000~3,500 rpm 조건에서 15~20분간 교반 혼합시키고 감압 탈포 후 35℃로 냉각하는 공정을 통해 본 발명의 하이드로겔 마스크 조성물을 제조할 수 있었다.According to one preferred embodiment of the present invention, the components of the oil phase are mixed and heated to 80 DEG C to obtain an oil phase mixture, and the components of the water phase are mixed and dissolved at room temperature to obtain an aqueous mixture, And then the mixture of the water and the oil phase is stirred using a homomixer at 70 to 90 ° C and 3,000 to 3,500 rpm for 15 to 20 minutes, and the mixture is cooled to 35 ° C by vacuum degassing. A hydrogel mask composition could be prepared.
본 발명의 일실시예에 따르면, 본 발명에 따른 하이드로겔 조성물은 i) 온도 및 시간에 따른 제형 안정성이 우수할 뿐 아니라 ii) 수상부 및 유상부 내 함유 성분들의 함량을 조절하여 적합한 적용시간에 투명도를 나타낼 수 있도록 조절할 수 있음을 알 수 있었으며, 따라서 본 발명의 화장료 조성물을 피부에 적용하는 경우 적용 화장료가 불투명한 유백색에서 투명하게 변화되어 개인차에 따른 최적의 적용 시간을 육안으로 용이하게 식별할 수 있으므로 필수 성분 흡수의 극대화를 실현할 수 있다.According to one embodiment of the present invention, the hydrogel composition according to the present invention is excellent in formulation stability with respect to temperature and time, ii) can control the content of components contained in the water and oil phase, Therefore, when the cosmetic composition of the present invention is applied to the skin, the applied cosmetic material changes transparently from an opaque milky white, so that the optimum application time according to individual differences can be easily visually recognized Therefore, it is possible to maximize absorption of essential components.
이하, 실시예를 통하여 본 발명을 더욱 상세히 설명하고자 한다. 이들 실시예는 오로지 본 발명을 예시하기 위한 것으로서, 본 발명의 범위가 이들 실시예에 의해 제한되는 것으로 해석되지 않는 것은 당 업계에서 통상의 지식을 가진 자에게 있어서 자명할 것이다.Hereinafter, the present invention will be described in more detail with reference to Examples. It is to be understood by those skilled in the art that these embodiments are merely illustrative of the present invention and that the scope of the present invention is not construed as being limited by these embodiments.
- - 실시예Example 1 내지 5 - 1 to 5 -
하기 표 1의 조성에 따라, 유상부의 각 성분들을 혼합 후 80℃로 가열하여 용해하였으며, 수상부의 각 성분들을 실온에서 혼합 용해시켰다. 이렇게 혼합된 수상부 및 유상부의 각 굴절률을 Abbe refractometers(A. KRUSS Optronic, Japan)를 이용하여 측정하였으며, 측정 후 각 실시예에 해당하는 수상부 및 유상부를 70~90℃ 및 3,000~3,500 rpm 조건에서 호모믹서를 이용하여 15~20분간 교반 혼합하였다. 교반된 수중유 유화물을 감압 탈포 후 35℃로 냉각하여 실시예 1 내지 5의 하이드로겔 마스크 조성물을 수득하였다.According to the composition shown in the following Table 1, the respective components of the oily phase were mixed and heated to 80 DEG C to dissolve them, and the components of the water phase were mixed and dissolved at room temperature. The refractive indexes of the mixed water and oil phase were measured using Abbe refractometers (KRUSS Optronic, Japan), and the water and oil phase corresponding to each example were measured at 70 to 90 ° C and 3,000 to 3,500 rpm Using a homomixer for 15 to 20 minutes. The stirred oil-in-water emulsion was degassed under reduced pressure and then cooled to 35 DEG C to obtain the hydrogel mask compositions of Examples 1 to 5.
유상부
Floating
수상부
Water top
상기 실시예 1 내지 5의 화장료 조성물들의 유상부 및 수상부의 굴절률, 이들의 굴절률 차 및 중량비를 하기 표 2에 나타내었다.The refractive indexes of the oil phase and the water phase of the cosmetic compositions of Examples 1 to 5, the refractive index difference and the weight ratio thereof are shown in Table 2 below.
- - 비교예Comparative Example 1 내지 4 - 1 to 4 -
상기 실시예 1 내지 5에서와 동일한 방법으로, 하기 표 3의 조성에 따라 비교예 1 내지 4의 화장료 조성물을 수득하였다.The cosmetic compositions of Comparative Examples 1 to 4 were obtained in the same manner as in Examples 1 to 5, according to the composition shown in Table 3 below.
유상부
Floating
수상부
Water top
상기 비교예 1 내지 4의 화장료 조성물들의 유상부 및 수상부의 굴절률, 이들의 굴절률 차 및 중량비를 하기 표 4에 나타내었다. The refractive indexes of the oil phase part and the water phase part of the cosmetic compositions of comparative examples 1 to 4, the difference in refractive index and weight ratio thereof are shown in Table 4 below.
시험예Test Example
상기 실시예 1 내지 5 및 비교예 1 내지 4에서 제조된 울릉도 삼나물 뿌리 추출물을 함유한 항산화 및 항염증 효능을 가진 하이드로겔 마스크 조성물들의 안정성 및 백색에서 투명으로 변화되는 시간을 다음과 같이 평가하였다. The stability of the hydrogel mask compositions with antioxidant and antiinflammatory activity and the change from white to clear in the Ulleungdo trilobal root extracts prepared in Examples 1 to 5 and Comparative Examples 1 to 4 were evaluated as follows .
1)안정성 평가1) Evaluation of stability
각 화장료 조성물을 5℃, 실온, 45℃ 조건에서 1주일, 2주일, 1개월, 2개월 또는 3개월 단위로 보관한 후,각 조건에서의 제형의 안정성을 육안으로 관찰하여 하기 평가기준에 따라 평가하였으며, 그 결과를 표 5 및 표 6에 나타내었다. After each cosmetic composition was stored for 1 week, 2 weeks, 1 month, 2 months or 3 months at 5 ° C, room temperature and 45 ° C, the stability of the formulation under each condition was visually observed, And the results are shown in Tables 5 and 6.
[평가기준][Evaluation standard]
◎: 분리현상 발생 없음◎: No separation phenomenon occurred
△: 일부 분리현상 발생Δ: Partial separation occurred
×: 분리현상 발생 심함×: Severe separation occurs
그 결과, 상기 표 5 및 6에서 볼 수 있는 바와 같이, 실시예 1 내지 5의 하이드로겔 마스크 조성물 및 비교예 1 내지3의 조성물은 모두 5℃, 실온, 45℃ 조건에서 유상부와 수상부의 상 분리 현상이 발견되지 않았으며 안정성을 유지하는 것으로 확인하였다. 반면, 비교예 4의 화장료 조성물의 경우에는 수상부와 유상부의 상분리 현상이 확인되었으며, 제형 안정성이 현저히 떨어지는 것을 확인하였다.As a result, as shown in Tables 5 and 6, the hydrogel mask compositions of Examples 1 to 5 and the compositions of Comparative Examples 1 to 3 all exhibited phase separation at the temperature of 5 ° C, room temperature, and 45 ° C No phenomenon was found and it was confirmed that stability was maintained. On the other hand, in the case of the cosmetic composition of Comparative Example 4, a phase separation phenomenon between an aqueous phase and an oil phase was confirmed, and it was confirmed that the formulation stability was remarkably inferior.
2)투명도 변화 평가 2) Evaluation of Transparency Change
건강한 성인 남녀 50명을 대상으로 실시예 1 내지 5 및 비교예 1 내지 4의 하이드로겔 마스크 조성물을 각각 피부에 도포하여 1, 5, 10, 15, 20, 30, 40, 50 또는 60 분 후에 유백색에서 투명으로 변화된 정도를 육안으로 관찰하여 투명도 변화 평가기준(평가값: 1- 불투명, 2 - 약간 불투명, 3 - 보통, 4 - 우수, 5 - 매우 우수)에 따라 평가하게 하였으며, 각 평가 결과들의 평균값을 산출하여 하기 표 7에 나타내었다.The hydrogel mask compositions of Examples 1 to 5 and Comparative Examples 1 to 4 were applied to 50 healthy adult males and females, respectively, and skin was applied to the skin after 1, 5, 10, 15, 20, 30, 40, The degree of transparency change was visually observed and evaluated according to the transparency change evaluation criteria (evaluation value: 1 - opaque, 2 - slightly opaque, 3 - normal, 4 - excellent, 5 - excellent) The average values are shown in Table 7 below.
그 결과, 상기 표 7에서 볼 수 있는 바와 같이, 본 발명에 따른 실시예 1 내지 5의 하이드로겔 마스크 조성물들은 배합 한도에 따라 변화 시간에 차이는 있었으나 시간이 지남에 따라 유백색 불투명에서 투명으로 변화하는 것을 확인한 반면, 비교예 1 내지 4의 경우 처음부터 투명하거나(비교예 1 및 3), 불투명이어도 투명으로의 변화가 거의 일어나지 않거나(비교예 2), 일어나더라도 안정성이 떨어지는 것을 확인하였다(비교예 4).As a result, as can be seen from Table 7, the hydrogel mask compositions of Examples 1 to 5 according to the present invention had time-varying time depending on the mixing limit, but they changed from milky opaque to transparent On the other hand, it was confirmed that Comparative Examples 1 to 4 were transparent from the beginning (Comparative Examples 1 and 3), little change in transparency even when opaque was observed (Comparative Example 2) 4).
이로써, 본 발명에 따른 하이드로겔 마스크 조성물은 수상부 및 유상부 내 함유 성분의 함량 조절을 통해 적합한 적용시간에 투명도를 나타낼 수 있도록 조절할 수 있음을 알 수 있었으며, 온도 및 시간에 따른 제형 안정성이 우수한 것을 알 수 있다.Thus, it was found that the hydrogel mask composition according to the present invention can be adjusted so as to exhibit transparency at a suitable application time by controlling the content of the components contained in the water and oil phase, and has excellent formulation stability according to temperature and time Able to know.
이제까지 본 발명에 대하여 그 바람직한 실시예들을 중심으로 살펴보았다. 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자는 본 발명이 본 발명의 본질적인 특성에서 벗어나지 않는 범위에서 변형된 형태로 구현될 수 있음을 이해할 수 있을 것이다. 그러므로 개시된 실시예들은 한정적인 관점이 아니라 설명적인 관점에서 고려되어야 한다. 본 발명의 범위는 전술한 설명이 아니라 특허청구범위에 나타나 있으며, 그와 동등한 범위 내에 있는 모든 차이점은 본 발명에 포함된 것으로 해석되어야 할 것이다. The present invention has been described with reference to the preferred embodiments. It will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. Therefore, the disclosed embodiments should be considered in an illustrative rather than a restrictive sense. The scope of the present invention is defined by the appended claims rather than by the foregoing description, and all differences within the scope of equivalents thereof should be construed as being included in the present invention.
Claims (12)
50 내지 99.95 중량%의 수상부로 이루어지고,
상기 수상부는 총 중량대비 1.00 내지 10.00 중량%의 울릉도 삼나물 뿌리 추출물을 함유하고 있으며,
상기 유상부와 수상부의 굴절률 차는 0.02 내지 0.15인 것을 특징으로 하는 하이드로겔마스크 조성물.0.05 to 50.00% by weight of the oil phase and
50 to 99.95% by weight of a water-
The water receiving part contains Ulleungdo trilobal root extract of 1.00 to 10.00% by weight based on the total weight,
Wherein the refractive index difference between the oil phase portion and the water phase portion is 0.02 to 0.15.
80 내지 95 중량%의 수상부로 이루어지고,
상기 수상부는 총 중량대비 1.00 내지 10.00 중량%의 울릉도 삼나물 뿌리 추출물을 함유하고 있으며,
상기 유상부와 수상부의 굴절률 차는 0.02 내지 0.15인 것을 특징으로 하는 하이드로겔마스크 조성물.5 to 20.00% by weight of the oily phase and
80 to 95% by weight of the water phase,
The water receiving part contains Ulleungdo trilobal root extract of 1.00 to 10.00% by weight based on the total weight,
Wherein the refractive index difference between the oil phase portion and the water phase portion is 0.02 to 0.15.
상기 수상부의 울릉도 삼나물 뿌리 추출물은 초음파 추출법을 사용하여 추출하고 용매로 1,3-부틸렌글라이콜을 30 중량% 사용한 것을 특징으로 하는 하이드로겔마스크 조성물.3. The method according to claim 1 or 2,
The hydrogel mask composition according to claim 1, wherein the root extract of Ulleungdo triticale extract is extracted by using an ultrasonic extraction method and 30 wt% of 1,3-butyleneglycol is used as a solvent.
상기 유상부와 수상부의 굴절률은 각각 1.350 내지 1.550 범위인 것을 특징으로 하는 하이드로겔마스크 조성물.3. The method according to claim 1 or 2,
Wherein the refractive indexes of the oil phase portion and the water phase portion are in the range of 1.350 to 1.550, respectively.
상기 수상부는 보습제와, 겔화 고분자와, 정제수와, 울릉도 삼나물 뿌리 추출물을 포함하여 이루어지는 것을 특징으로 하는 하이드로겔마스크 조성물.3. The method according to claim 1 or 2,
Wherein the water receiving part comprises a moisturizing agent, a gelled polymer, purified water, and an extract of a root of Ulleungdo trilobal root.
상기 보습제는 다가알코올류, 글리세린류, 당류 또는 이들의 혼합물로서, 총 중량 대비 1 내지 70 중량%로 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물6. The method of claim 5,
Wherein the humectant is selected from the group consisting of polyhydric alcohols, glycerol, saccharides, and mixtures thereof in an amount of 1 to 70% by weight based on the total weight of the composition.
상기 겔화 고분자로는 천연 당류, 친수성 겔화제 또는 이들의 혼합물로서, 총 중량 대비 0.1 내지 10 중량%로 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물.6. The method of claim 5,
The hydrogel mask composition according to claim 1, wherein the gelled polymer is a natural saccharide, a hydrophilic gelling agent or a mixture thereof in an amount of 0.1 to 10% by weight based on the total weight of the composition.
상기 정제수는 총 중량 대비 5 내지 90 중량%로 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물.6. The method of claim 5,
Wherein the purified water comprises 5 to 90% by weight based on the total weight of the hydrogel mask composition.
상기 유상부는 통상적인 오일 및 계면활성제를 포함하여 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물.3. The method according to claim 1 or 2,
Wherein the oil phase portion comprises a conventional oil and a surfactant.
상기 오일은 에스테르계 오일, 탄화수소계 오일, 왁스류, 천연오일, 실리콘 오일 또는 이들의 혼합물로서, 총 중량 대비 0.05 내지 50.00 중량%으로 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물.10. The method of claim 9,
Wherein the oil is an ester-based oil, a hydrocarbon-based oil, a wax, a natural oil, a silicone oil or a mixture thereof in an amount of 0.05 to 50.00% by weight based on the total weight of the composition.
상기 계면활성제는 다가 알코올과 지방산의 에스테르계 비이온계면활성제, 지방족 폴리옥시에틸렌 중합계의 비이온계면활성제, 솔비탄 에스테르의 폴리옥시에틸렌 에테르계의 비이온계면활성제, 천연유의 폴리옥시에틸렌 에테르계 비이온계면활성제, 폴리옥시에틸렌 에테르계 비이온계면활성제, 알칼리성 음이온계면활성제, 중성 음이온계면활성제 또는 이들의 혼합물로서, 총 중량 대비 0 내지 15 중량%로 이루어진 것을 특징으로 하는 하이드로겔마스크 조성물.10. The method of claim 9,
The surfactant may be selected from the group consisting of an ester type nonionic surfactant of a polyhydric alcohol and a fatty acid, a nonionic surfactant of an aliphatic polyoxyethylene polymerization type, a polyoxyethylene ether nonionic surfactant of a sorbitan ester, a polyoxyethylene ether type A nonionic surfactant, a polyoxyethylene ether nonionic surfactant, an alkaline anionic surfactant, a neutral anionic surfactant, or a mixture thereof, in an amount of 0 to 15% by weight based on the total weight of the composition.
상기 유상부는 각 성분들을 혼합 후 80℃로 가열하여 용해하여 유상부 혼합물을 수득하는 한편, 상기 수상부의 각 성분들을 실온에서 혼합 용해시켜 수상부 혼합물을 수득하고, 각 혼합물의 굴절률을 측정한 후 이들 수상부 및 유상부 혼합물들을 호모믹서를 이용하여 70~90℃ 및 3,000~3,500 rpm 조건에서 15~20분간 교반 혼합시키고 감압 탈포 후 35℃로 냉각한 것을 특징으로 하는 하이드로겔마스크 조성물.10. The method according to claim 5 or 9,
The oily phase was prepared by mixing and melting the components at 80 DEG C to obtain an oil phase mixture, while mixing the components of the water phase mixture at room temperature to obtain an aqueous mixture, measuring the refractive index of each mixture, The upper and lower oil mixtures were mixed with stirring using a homomixer at 70 to 90 ° C and 3,000 to 3,500 rpm for 15 to 20 minutes, followed by degassing under reduced pressure and cooling to 35 ° C.
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