KR20090029281A - Combinations of active ingredients with pesticidal and acaricide - Google Patents

Abstract

Combinations of novel active compounds are provided comprising the compounds of formula (I) or (II) which are very good in pesticidal and acaricidal properties and the active compounds (1) to (23) listed in the specification.

Description

ACTIVE INGREDIENT COMBINATIONS WITH INSECTICIDAL AND ACARICIDAL PROPERTIES}

The present invention relates primarily to combinations of novel active compounds comprising known cyclic ketoenols and then further known pesticidal active compounds and which are very suitable for controlling animal pests such as insects and unwanted mites.

It is already known that certain cyclic ketoenols have herbicides, insecticides and acaricides. The activity of these compounds is good but often unsatisfactory at low application rates.

It is known that the 1H-3-arylpyrrolidine-2,4-dione derivative (WO 98/05638) and its cis isomer (WO 04/007448) have pesticidal and / or acaricide activity.

Other mixtures of compounds known from WO 98/05638 with other pesticides and / or acaricides are known: WO 01/89300, WO 02/00025, WO 02/05648, WO 02/17715, WO 02/19824, WO 02 / 30199, WO 02/37963, WO 05/004603, WO 05/053405, WO 06/089665, DE-A-10342673. However, the activity of these mixtures is not always satisfactory.

It has been found according to the invention that the combination of the active compound comprising a compound of formula (I) or (II) with a compound of formula A) has very good insecticidal and / or acaricide:

A) pyrethroids, preferably

1. Acrinatrin

(Known from EP-A-048 186)

 And / or

2. Alpha-cypermethrin

(Known from EP-A-067 461)

 And / or

3. Betacyflutrin

(Known from EP-A-206 149)

 And / or

4. sihalothrin

(Known from DE-A-2 802 962)

 And / or

5. Cypermethrin

(Known from DE-A-2 326 077)

 And / or

6. Deltamethrin

(Known from DE-A-2 326 077)

 And / or

7. Espenalerate

(Known from DE-A-2 737 297)

 And / or

8. Etofenprox

 (Known from DE-A-3 117 510)

 And / or

9. Penpropartlin

 (Known from DE-A-2 231 312)

 And / or

10. penvalerate

 (Known from DE-A-2 335 347)

 And / or

11. Flucytinate

 (Known from DE-A-2 757 066)

 And / or

12 a. Lambda-Saihalothrin

(Known from EP-A-106 469)

 And / or

12 b. Gamma-Saihalothrin

(Known from GB-A-02143823)

 And / or

13. Permethrin

(Known from DE-A-2 326 077)

 And / or

14. Taupluvalinate

(Known from EP-A-038 617)

 And / or

15. Tralomethrin

(Known from DE-A-2 742 546)

And / or

16. Zeta-cypermethrin

(Known from EP-A-026 542)

 And / or

17. Cyflutrin

(Known from DE-A-27 09 264)

 And / or

18. Bifenthrin

(Known from EP-A-049 977)

 And / or

19. Cycloprotrin

(Known from DE-A-2653189)

 And / or

20. Eflusylanate

(Known from DE-A-36 04 781)

 And / or

21.Pubpen Prox

(Known from DE-A-37 08 231)

 And / or

22. Pyrethrin

(Wherein

R = -CH ₃ or -CO ₂ CH ₃

R ₁ = -CH = CH ₂ , -CH ₃ or -CH ₂ CH ₃

The Pesticide Manual, 1997, 11th Edition, p. 1056).

 And / or

23. Lesmetrin

(Known from GB-A-1 168 797)

Surprisingly, the pesticidal and / or acaricide activity of the active compound combinations according to the invention is known from the prior art known from WO 02/00025 consisting of a pyrethroid and a cis / trans isomeric mixture of formula (Ia) or (II-a). Much greater than the activity of the active compound combination.

Preferred are combinations of the active compounds of the formula (I) and the active compounds comprising at least one of the compounds 1 to 23.

Preferred are combinations of the active compounds of the formula (II) and the active compounds comprising at least one of the compounds 1 to 23.

In addition, the active compound combinations may also comprise further fungicidal, acaricide or pesticidal active additives.

Improved activity is evident when the active compounds are present in certain weight ratios in the active compound combinations according to the invention. However, the weight ratio of the active compound in the active compound combination can vary within a relatively wide range. In general, the active compound combinations according to the invention comprise the compounds of formula (I) or (II) and mixing partners in the preferred, particularly preferred mixing ratios listed in the table below.

^* Mixing ratio is based on weight ratio. This ratio is to be understood as meaning the ratio of active compound of formula (I): active compound of formula (II): mixing partner.

 Mixed partners Preferred Mixing Ratio Especially preferred mixing ratio Very particularly preferred mixing ratio  Akrinathrin 125: 1-1:50 25: 1-1:10 10: 1-1: 1  Alpha-cypermethrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Beta-cyflutrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Sihalothrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Cypermethrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Deltamethrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Espenvalerate 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Etofenprox 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Phenpropatrine 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Penvalerate 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Flusitelinate 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Lambda-Saihalothrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Gamma-Saihalothrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Permethrin 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Taufluvalinate 25: 1-1: 5 10: 1-1: 5 5: 1-1: 2  Tralomethrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Zeta-cypermethrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 2  Cyfluthrin 125: 1-1: 5 25: 1-1: 3 10: 1-1: 1  Bifenthrin 125: 1-1:10 10: 1-1: 5 5: 1-1: 1  Cycloprotrin 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Eflusylanate 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Pufenfenrox 25: 1-1:10 10: 1-1: 5 5: 1-1: 3  Pyrethrin 125: 1-1:10 25: 1-1: 5 5: 1-1: 1  Resmetrin 125: 1-1:10 25: 1-1: 5 5: 1-1: 1

Combinations of the active compounds according to the invention can be found in animal pests, preferably arthropods and nematodes, particularly those encountered in the fields of grape cultivation, fruit farming, horticulture, agriculture, animal hygiene, forestry, storage products and materials, and hygiene. It is suitable for controlling insects and / or arachnids. They are active for normal or sensitive species and for all or some stages of development. The pests mentioned above include:

The order of Isopoda , for example Oniscus asellus , Armadillidium vulgare and Porcellio scaber .

Millipedes (Diplopoda) tree, for example Blast niul loose obtain Tula tooth (Blaniulus guttulatus).

From the genus Chilopoda , for example Geophilus carpophagus and Scutigera spec .

From the order of Symphyla , for example Scutigerella immaculata .

Thysanura , for example Lepisma saccharina .

From the order of Collembola , for example Onychiurus armatus .

Orthoptera , for example, Acheta domesticus , Gryllotalpa spp. , Locusta migratoria migratorioides , Melanofluus species ( Melanoplus spp.) And Schistocerca gregaria .

From the tree of Blattaria , for example Blatta orientalis , Periplaneta americana , Leucophaea maderae , Blattella germanica .

Dermaptera , for example Forficula auricularia .

Termite Isoptera , for example Reticulitermes spp .

Phthiraptera , for example Pediculus humanus corporis , Haematopinus spp ., Linognathus spp ., Trichodectes spp. .) And damalinia spp .

From the order of the Thysanoptera , for example Hercinothrips femoralis , Thrips tabaci , Thrips palmi and Frankliniella occidentalis ).

From the order of Heteroptera , for example Eurygaster spp ., Dysdercus intermedius , Piesma quadrata , Cimex lectularius , Rodney Rhodnius prolixus and Triatoma spp .

Cicadas (Homoptera) tree, for example, waters right Death in Brassica (Aleurodes brassicae), bemi cyano other dedicate (Bemisia tabaci), the tree Valley right des bar Fora Rio room (Trialeurodes vaporariorum), Apis notice blood (Aphis gossypii), the breather Vico Rhine Brassica (Brevicoryne brassicae), the creep Tommy juice Leavis (Cryptomyzus ribis), Apis wave bar (Aphis fabae), Apis breech (Aphis pomi), Erie O Soma Raney gerum (Eriosoma lanigerum), hyaluronic rope Teruel's Arun Dinis ( Hyalopterus arundinis ), Phylloxera vastatrix , Pemphigus spp. , Macrosiphum avenae , Myzus spp ., Phorodon humulley humuli), a Palo sipum Fadi (Rhopalosiphum padi), empo Empoasca (Asuka kind spp.), yusel lease Biloba tooth (Euscelis bilobatus), four Forte Athletics new Sancti Joseph's (Nephotettix cincticeps), Recaro nium corset you (Lecanium cor ni), the poinsettia Ole Ah between (Saissetia oleae), Lao del Parks Austria Tel Ruth (Laodelphax striatellus), Neela Parque Bata Lou Regensburg (Nilaparvata lugens), Oh sludge de Ella Augusta is T (Aonidiella aurantii), Oh Speedy Aspidiotus hederae , Pseudococcus spp . And Psylla spp .

Lepidoptera , for example Pectinophora gossypiella , Bupalus piniarius , Cheimatobia brumata , Lithocolletis blancardella , Hyponomeuta padella , Plutella xylostella , Malacosoma neustria , Euproctis chrysorrhoea , Lymantria spp. , the unit Kula matrix Tour Barry Ella (Bucculatrix thurberiella), Philo greatest seutiseu sheet mozzarella (Phyllocnistis citrella), Agrobacterium-Tees species (Agrotis spp.), six pediatric species (Euxoa spp.), Pell Tia species (Feltia spp.), Earias insulana , Heliothis spp ., Mamestra brassicae , Panolis flammea , Spodoptera sp p .), Trichoplusia ni , Carpocapsa pomonella , Pieris spp. , Chilo spp ., Pyrausta nubilalis , Ephestia kuehniella , Galleria mellonella , Tineola bisselliella , Tinea pellionella , Hofmannophila pseudospretella ), Cacoecia podana , Capua reticulana , Choristoneura fumiferana , Clysia ambiguella , Homona magnanima magnanima ), Tortrix viridana , Cnaphalocerus spp . and Oulema oryzae .

Coleoptera , for example, Anobium punctatum , Rhizopertha dominica , Bruchidius obtectus , Acanthoscelides obtectus , Hylotrupes bajulus , Agelastica alni , Leptinotarsa decemlineata , Phaedon cochleariae , Diabrotica spp ), peusil Rio des Creative sose Palacio (Psylliodes chrysocephala), epilra keuna Bari Betsy's (Epilachna varivestis), Ato Maria kinds (Atomaria spp.), duck chair Phil Ruth repairs namen system (Oryzaephilus surinamensis), St labor's servants (Anthonomus spp.), Citrus peel loose species (Sitophilus spp.), cut out ot kusu sulka tooth (Otiorrhynchus sulcatus), poly Cosmo test sorbitan di Douce (Cosmopolites sordidus), establish Torin Scotland know Millie's (Ceuthorrhynchus assimilis), Hebrews Blow Force Galactica (Hypera postica), no scalpel test species (Dermestes spp.), Tree logo Dumaguete species (Trogoderma spp.), No trail pandanus species (Anthrenus spp.), Oh ride Attagenus spp ., Lyctus spp ., Meligethes aeneus , Ptinus spp ., Niptus hololeucus , Gibiumuf Gibbium psylloides , Tribolium spp ., Tenebrio molitor , Agriotes spp ., Conoderus spp ., Melonta Melonta ( Melolontha melolontha ), Amphimallon solstitialis , Costelytra zealandica and Lissorhoptus oryzophilus .

Hymenopera species, for example Diprion spp ., Hoplocampa spp ., Lasius spp ., Monomorium pharaonis and Vespa species Vespa spp .

Diptera , for example Aedes spp ., Anopheles spp ., Culex spp ., Drosophila melanogaster , Musca species. Musca spp .), Fannia spp ., Calliphora erythrocephala , Lucilia spp ., Chrysomyia spp ., Cuterebra spp . ), Gastrophilus spp ., Hyppobosca spp ., Stomoxys spp ., Oestrus spp ., Hypoderma spp . , Tabanus spp. , Tannia spp ., Bibio hortulanus , Oscinella frit , Phorbia spp ., Pegomia hyosquiami ( Pegomyia hyoscyami ), Ceratitis capitata , Dacus oleae , Tifula paludosa ( Tipula paludosa ), Hylemyia spp . And Liriomyza spp .

From the order of Siphonaptera , for example Xenopsylla cheopis and Ceratophyllus spp .

Arachnida , for example, Scorpio maurus , Latrodectus mactans , Acarus siro , Argas spp ., Ornitodoros species ( Ornithodoros spp .), Dermanyssus gallinae , Eriophyes ribis , Phyllocoptruta oleivora , Boophilus spp ., Rhipicephalu sp. ., Amblyomma spp. , Hyalomma spp ., Ixodes spp ., Psoroptes spp ., Coriooptes spp . Chorioptes spp. ), Sarcoptes spp ., Tarsonemus spp ., Bryobia praetiosa , Panonychus spp ., Tetranicus spp . ( Tetranychus spp. ), Hemitarsonemus spp . And Brevipalpus species ( Br evipalpus spp .).

Plant parasitic nematodes include, for example, Pratylenchus spp ., Radopholus similis , Ditylenchus dipsaci , Tylenchulus semipenetrans . , Heterodera spp ., Globodera spp ., Meloidogyne spp ., Apelenchoides spp ., Longidorus spp . , Xiphinema spp. , Trichodorus spp . And Bursaphelenchus spp .

Combinations of active compounds include conventional solutions such as solutions, emulsions, hydrating agents, suspensions, powders, powders, pastes, soluble powders, granules, suspension-emulsion concentrates, natural and synthetic materials in which the active compound has been injected, and microcapsules in polymeric materials. Can be converted to a formulation.

These formulations are prepared by known methods, for example by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, optionally using surfactants, ie emulsifiers and / or dispersants and / or foam formers.

If the extender used is water, for example an organic solvent can also be used as co-solvent. Suitable liquid solvents are mainly aromatic compounds such as xylene, toluene or alkylnaphthalene, chlorinated aromatic or chlorinated aliphatic hydrocarbons such as chlorobenzene, chloroethylene or methylene chloride, cyclohexane or paraffins, for example mineral oil fractions, mineral oils and vegetable oils. Strong polar solvents such as aliphatic hydrocarbons, alcohols such as butanol or glycol and ethers and esters thereof, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, dimethylformamide and dimethyl sulfoxide and also water .

Suitable solid carriers are, for example, ammonium salts and ground natural minerals such as kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground powders such as highly dispersed silica, alumina and silicates. It is a synthetic mineral. Suitable granular carriers for granules are, for example, pulverized and classified natural rocks such as calcite, marble, pumice, calcite and dolomite, or synthetic granules of inorganic and organic flours, and sawdust, coconut husks, corn cobs and tobacco It is a granule of the same organic matter.

Suitable emulsifiers and / or foam formers are for example nonionic and anionic emulsifiers, for example polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example alkylaryl polyglycol ethers, alkylsulfonates, alkylsulfates , Arylsulfonates or protein hydrolysates.

Suitable dispersants are, for example, lignosulphite waste liquors and methylcellulose.

Tackifiers such as carboxymethylcellulose, and natural and synthetic polymers in the form of powders, granules or latex, such as gum arabic, polyvinyl alcohol and polyvinyl acetate, and also natural phospholipids such as cephalin and lecithin, and synthetic phospholipids It can be used in this formulation. Other possible additives are mineral and vegetable oils.

Colorants such as inorganic pigments such as iron oxide, titanium oxide and prussian blue, and organic colorants such as alizarin colorants, azo colorants and metal phthalocyanine colorants and salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc. Micronutrients may also be used.

The formulations generally contain 0.1 to 95% by weight, preferably 0.5 to 90% by weight of active compound.

Combinations of the active compounds according to the invention can be carried out in commercially available preparations and in the form of use prepared from these preparations, for example other pesticides, attractants, sterilizers, fungicides, acaricides, nematicides, fungicides, growths. It may be present in a mixture with modulators or herbicides. Pesticides include, for example, phosphates, carbamates, carboxylates, chlorinated hydrocarbons, phenylurea, materials produced by microorganisms, and the like.

Other known active compounds such as herbicides or mixtures with fertilizers and growth regulators are also possible.

When used as pesticides, the active compound combinations according to the invention may also be present in their commercially available formulations and in the applications prepared from these formulations as a mixture with synergists. Synergists are compounds that increase the action of the active compound without the need for the synergist added itself to be activated.

The active compound content of the use forms prepared from commercially available formulations can vary within wide ranges. The active compound concentration of the use forms can be 0.0000001 to 95% by weight, preferably 0.0001 to 1% by weight of active compound.

The compound is used in a conventional manner suitable for the use form.

According to the invention, all plants and some treatment of plants are possible. Plant is to be understood here as meaning all plants and plant populations, such as desired or unwanted wild plants or crops (including naturally occurring crops). Crops include plant varieties and transgenic plants that may or may not be protected by plant breeders' assurances, by conventional breeding and optimization methods, by biotechnological and genetic engineering methods, or by combining these methods It may be a plant obtainable by. Some of the plants are to be understood as meaning all the above-ground and underground parts and organs of the plant, for example, shoots, leaves, flowers and roots, examples of which are leaves, needles, stems and trunks. ), Flowers, fruits, fruits, seeds, roots, tubers and rhizomes may be mentioned. Some of the plants also include harvesting materials, and nutritional and reproductive materials, such as seedlings, tubers, rhizomes, cuttings and seeds.

Treatment of plants and parts of plants with the active compound combinations according to the invention is carried out by conventional treatment methods, for example by dipping, spraying, evaporating, spraying, spraying, brushing, and in the case of propagating materials, in particular seed It is also carried out by applying one or multiple coatings, either directly or by applying the compound to its environment, habitat or storage space.

As mentioned above, treatment of all plants and plant parts is possible according to the invention. In a preferred embodiment, wild plant species and plant cultivars, or plant species and plant cultivars obtained by conventional biological breeding methods such as hybrid breeding or protoplast fusion, as well as parts thereof, are treated. In another preferred embodiment, transgenic plants and plant cultivars (genetically modified variants) and parts thereof obtained genetically, if appropriate, are treated in combination with conventional methods, if appropriate. The terms "part", "part of the plant" or "plant part" are described above.

Particularly preferably, the plants of the plant cultivars which are commercially available or in use in each case are treated according to the invention.

Depending on the plant species or plant cultivars, their location and growing conditions (soil, climate, growing season, nutrients), an additive (“raising”) effect may also be produced by treatment according to the invention. Thus, for example, reduction in the application rate of substances and compositions which can be used according to the invention and / or broadening the activity spectrum and / or increasing activity, improving plant growth, increasing hot or cold resistance, drought, or water or soil salinity Effects such as increased resistance to plants, increased blooms, easier harvesting, increased maturity, increased crop yields, improved quality and / or nutritional value of harvested products, and improved storage stability and / or processability of harvested products May appear more than

Preferred transgenic plants or plant cultivars treated in accordance with the present invention (ie, those obtained genetically) include all plants that accept genetic material that confers particularly advantageous and useful properties to these plants upon genetic modification. Examples of such properties include improved plant growth, increased high or low temperature resistance, drought, or increased resistance to water or soil salts, increased flowering, ease of harvest, increased maturity, increased crop yields, improved quality of harvested products, and / or Increased nutritional value, and increased storage stability and / or processability of the harvested product. Further particularly important examples of such properties include increased plant defense against animal and microbial pests such as insects, mites, phytopathogenic fungi, bacteria and / or viruses and also increased plant resistance to certain herbicidally active compounds. Examples of transgenic plants may include important crops such as cereals (wheat, rice), corn, soybeans, potatoes, cotton, oilseed rape, and also fruit trees (opening apples, pears, citrus fruits and grape fruits), Of particular interest are corn, soybeans, potatoes, cotton and oilseed rape. Highlighted properties are in particular genetic material derived from toxins formed in plants, in particular Bacillus thuringiensis (eg genes CryIA (a), CryIA (b), CryIA (c), CryIIA, CryIIIA, CryIIIB2, Cry9c) , Cry2Ab, Cry3Bb and CryIF and combinations thereof) is an increase in the plant's defense against insects due to toxins formed in plants (hereinafter referred to as "Bt plants"). Particularly emphasized properties are also increased plant tolerability to certain herbicidal active compounds such as imidazolinone, sulfonylurea, glyphosate or phosphinothricin (eg the "PAT" gene). Genes that confer the desired properties of interest can also be present in a transgenic combination in a transgenic plant. Examples of "Bt plants" include YIELD GARD ^® (e.g. corn, cotton, soybean), KnockOut ^® (e.g. corn), StarLink ^® (e.g. corn), Bollgard ^® (e.g. cotton), Nucotn ^® (e.g. cotton) And corn varieties, cotton varieties, soybean varieties and potato varieties which are commercially available under the NewLeaf ^® (eg potato) brand name. Examples of herbicide-tolerant plants include Roundup Ready ^® (glyphosate tolerant, eg corn, cotton, soybean), Liberty Link ^® (phosphinothricin tolerant, e.g. oilseed rape), IMI ^® (imidazolinone tolerant) And corn varieties, cotton varieties and soybean varieties available under the trade name STS ^® (sulfonylurea tolerant such as corn). Examples of herbicide-tolerant plants (plants bred by conventional methods for herbicide tolerability) may also be mentioned varieties sold under the name Clearfield ^® (eg corn). Of course, the above description also applies to plant cultivars which are to be developed and / or marketed in the future, having the above-described properties or in which future genetic properties will be developed.

The plants listed can be particularly advantageously treated according to the invention using mixtures of the active compounds according to the invention. The preferred ranges mentioned above for the mixtures also apply to the treatment of these plants. Particular emphasis is given to the treatment of plants with the mixtures specifically mentioned in the present text.

The expected action for a given combination of two active compounds can be calculated using the Colby equation as follows (SR, Colby, Weeds 15 (1967), 20-22):

Where

X is the rescue rate expressed as% of untreated control when active compound A is applied at an application rate of m g / dL or at a concentration of m ppm,

Y is the rescue rate expressed as% of untreated control when active compound B is used at an application rate of n g / dL or at a concentration of n ppm,

E is the rescue rate expressed in% relative to untreated control when active compounds A and B are applied at an application rate of m and n g / dL or at concentrations of m and n ppm.

If the actual rescue rate exceeds the calculated value, the action of the formulation is superadditive, ie there is a synergistic effect. In this case, the actual observed rescue rate should be greater than the value of the expected rescue rate (E) calculated using the above formula.

Example A

Missoise Persia ( Myzus persicae ) exam

Solvent: 78 parts by weight of acetone

         Dimethylformamide 1.5 parts by weight

Emulsifier: 0.5 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvents and emulsifiers in the amounts mentioned above and diluting the concentrate with water containing the emulsifier to the desired concentration.

Cabbage leaves ( Brassica oleracea ) heavily infected with peach hump aphids ( Misso Pacifica ) were sprayed with the active compound formulation at the desired concentration.

After a certain period of time, the relief rate was determined in%. 100% means that all aphids have been killed; 0% means that the aphid has not been killed at all. The determined rescue rate was substituted into Colby's formula.

In this test, for example, combinations of the following active compounds according to the present application showed synergistically improved activity compared to the active compounds applied alone:

TABLE A-1

Insects that damage plants

Exam in misso persia

Table A-2

Example B

Phaedon Cocicleier ( Phaedon cochleariae Larval test

Solvent: 78 parts by weight of acetone

         Dimethylformamide 1.5 parts by weight

Emulsifier: 0.5 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvents and emulsifiers in the amounts mentioned above and diluting the concentrate with water containing the emulsifier to the desired concentration.

Cabbage (brassica oleracea) leaves were spray treated with the active compound formulation at the desired concentration and infected with mustard worms (Phaedon cocleariae) larvae while the leaves were moist.

After a certain period of time, the relief rate was determined in%. 100% means that all larvae have been killed; 0% means that none of the larvae have been killed. The determined rescue rate was substituted into Colby's formula.

In this test, for example, combinations of the following active compounds according to the present application showed synergistically improved activity compared to the active compounds applied alone:

TABLE B

Insects that damage plants

Peddon Coclearie Larva Test

Example C

Spodoptera prugiferda Spodoptera frugiperda Larval test

Solvent: 78 parts by weight of acetone

         Dimethylformamide 1.5 parts by weight

Emulsifier: 0.5 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvents and emulsifiers in the amounts mentioned above and diluting the concentrate with water containing the emulsifier to the desired concentration.

Cabbage (brassica oleracea) leaves were spray treated with the active compound formulation of the desired concentration and infected with the larvae (Spodoftera prugiferda) larva while the leaves were moist.

After a certain period of time, the relief rate was determined in%. 100% means that all larvae have been killed; 0% means that none of the larvae have been killed. The determined rescue rate was substituted into Colby's formula.

In this test, for example, combinations of the following active compounds according to the present application showed synergistically improved activity compared to the active compounds applied alone:

Table C

Insects that damage plants

Spodoptera prugiferda larval test

Example D

Tetranicus test (OP-resistant / spray treated)

Solvent: 78 parts by weight of acetone

         Dimethylformamide 1.5 parts by weight

Emulsifier: 0.5 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvents and emulsifiers in the amounts mentioned above and diluting the concentrate with water containing the emulsifier to the desired concentration.

Soybean (Paceolus vulgaris ) plant disks infected with the previous stage of spotted mite ( Tetranychus urticae ) were sprayed with the active compound formulation of the desired concentration.

After a certain period of time, the relief rate was determined in%. 100% means that all mites have been killed; 0% means that none of the mites have been killed. The determined rescue rate was substituted into Colby's formula.

In this test, for example, combinations of the following active compounds according to the present application showed synergistically improved activity compared to the active compounds applied alone:

TABLE D-1

Insects that damage plants

Tetranicus Urticae Test

Table D-2

Insects that damage plants

Tetranicus Urticae Test

Example E

Apis Notice Aphis gossypii ) exam

Solvent: Dimethylformamide 7 parts by weight

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvents and emulsifiers in the amounts mentioned above and diluting the concentrate with water containing the emulsifier to the desired concentration.

Cotton leaves ( Gossypium hirsutum ) heavily infected with cotton aphid (Apis gopi) were immersed in the active compound preparation at the desired concentration.

After a certain period of time, the relief rate was determined in%. 100% means that all aphids have been killed; 0% means that none of the aphids have been killed. The determined rescue rate was substituted into Colby's formula.

In this test, for example, combinations of the following active compounds according to the present application showed synergistically improved activity compared to the active compounds applied alone:

Table E

Insects that damage plants

Apis Examination Exam

Example F

Critical Concentration Test / Soil Insect-Treatment of Transgenic Plants

Test insect: Diabrotica balteata -larvae in soil

Solvent: 7 parts by weight of acetone

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

A suitable formulation of the active compound is prepared by mixing 1 part by weight of the active compound with the solvent in the amounts mentioned above, adding the above mentioned amount of emulsifier and then diluting the concentrate with water to the desired concentration.

The active compound formulation is poured into the soil. At this time, the concentration of the active compound in the formulation is of no practical importance, only the weight of the active compound applied in volume (expressed in ppm (mg / L)) per soil volume is an important factor. The soil was charged to a 0.25 L pot and left at 20 ° C.

Immediately after preparation, five germinated corn kernels of YIELD GUARD varieties (registered trademark of Monsanto Comp., USA) were introduced into each pot. Two days later, appropriate test insects were introduced into the treated soil. After seven more days, the number of germinated corn plants was counted to determine the efficiency of the active compound (all plant germination = 100% activity).

Example G

Heliotis non-resense Heliothis virescens ) Test-Treatment of Transgenic Plants

Solvent: 7 parts by weight of acetone

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

One part by weight of the active compound is mixed with the aforementioned amount of solvent and the aforementioned amount of emulsifier, and then the concentrate is diluted with water to the desired concentration to prepare a suitable formulation of the active compound.

Soybean sprouts ( Glycine max ) from the Roundup Ready variety (Monsanto Comp., USA) are sprayed with the active compound formulation at the desired concentration and infected with tobacco shoots Heliotis viresense while the leaves are moist. I was.

After a certain period of time, insect control rates were determined.

Example H

Testing in Missouri Pacifica- Treatment of Transgenic Plants

Solvent: 7 parts by weight of acetone

Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

1 part by weight of the active compound is mixed with the solvents and emulsifiers in the amounts mentioned above, and the concentrate is diluted with water to the desired concentration to prepare a suitable formulation of the active compound.

A heavily infected transgenic cabbage plant (Brassica oleracea) with peach hump aphid (Misso Pacifica) was sprayed with the active compound formulation of the desired concentration.

After a period of time, insect control rates were determined.

Claims (7)

With a compound of formula (I) or (II) Akrinathrin Alpha-cypermethrin Beta-cyflutrin Sihalothrin Cypermethrin Deltamethrin Espenvalerate Etofenprox Phenpropatrine Penvalerate Flusitelinate Lambda-Saihalothrin Gamma-Saihalothrin Permethrin Tau-Fluvalinate Tralomethrin Zeta-cypermethrin Cyfluthrin Bifenthrin Cycloprotrin Eflusylanate Pufenfenrox Pyrethrin and Resmetrin Combinations of active compounds comprising at least one compound of:

2. Combination of active compounds according to claim 1, comprising the compound of formula (I). The combination of active compounds according to claim 1, comprising a compound of formula (II). Use of a combination of the active compounds according to claim 1 for controlling animal pests. A method for controlling animal pests, characterized in that the combination of the active compounds according to claim 1 is acted on animal pests and / or their habitats. A process for the preparation of the pesticidal and / or acaricide composition, characterized in that the combination of the active compound according to claim 1 is mixed with an extender and / or a surfactant. A composition comprising a combination of the active compounds according to claim 1 for controlling animal pests.