KR102554929B1 - 엔진 피스톤 및 그 제조방법 - Google Patents
엔진 피스톤 및 그 제조방법 Download PDFInfo
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- KR102554929B1 KR102554929B1 KR1020180125496A KR20180125496A KR102554929B1 KR 102554929 B1 KR102554929 B1 KR 102554929B1 KR 1020180125496 A KR1020180125496 A KR 1020180125496A KR 20180125496 A KR20180125496 A KR 20180125496A KR 102554929 B1 KR102554929 B1 KR 102554929B1
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 27
- 238000010438 heat treatment Methods 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 42
- 238000005219 brazing Methods 0.000 claims abstract description 31
- 238000002161 passivation Methods 0.000 claims abstract description 28
- 239000000843 powder Substances 0.000 claims abstract description 19
- 230000003647 oxidation Effects 0.000 claims abstract description 18
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 18
- 239000011148 porous material Substances 0.000 claims abstract description 18
- 238000005121 nitriding Methods 0.000 claims abstract description 16
- 238000005245 sintering Methods 0.000 claims abstract description 11
- 238000005304 joining Methods 0.000 claims abstract description 4
- 238000003825 pressing Methods 0.000 claims abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 25
- 150000004767 nitrides Chemical class 0.000 claims description 25
- 229910052748 manganese Inorganic materials 0.000 claims description 16
- 229910052717 sulfur Inorganic materials 0.000 claims description 13
- 229910052804 chromium Inorganic materials 0.000 claims description 12
- 229910052750 molybdenum Inorganic materials 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 10
- 229910001337 iron nitride Inorganic materials 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052698 phosphorus Inorganic materials 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000011651 chromium Substances 0.000 description 14
- 239000011572 manganese Substances 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 7
- 229910000838 Al alloy Inorganic materials 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 238000000748 compression moulding Methods 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 229910001563 bainite Inorganic materials 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000009702 powder compression Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
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- C22C38/60—Ferrous alloys, e.g. steel alloys containing lead, selenium, tellurium, or antimony, or more than 0.04% by weight of sulfur
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- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
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- F41B11/642—Compressed-gas guns, e.g. air guns; Steam guns characterised by the supply of compressed gas having a piston effecting a compressor stroke during the firing of each shot the piston being spring operated
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Abstract
Description
도 2는 상부체와 하부체가 브레이징 접합되는 모습을 나타내는 단면도이고,
도 3은 상부체와 하부체가 결합되어 피스톤 본체를 이루는 모습과, 피스톤 본체가 최종적인 피스톤 형상으로 가공된 모습을 나타낸 사시도이고,
도 4는 피스톤 본체의 표면을 가공하여 표면에 노출된 기공을 제거하는 모습을 나타낸 개략도이고,
도 5는 피스톤 본체의 표면에 부동태 피막을 형성시킨 모습을 나타낸 개략도이다.
110: 상부체
120: 하부체
130: 부동태 피막
200: 브레이징재
P: 기공
Claims (18)
- 분말 형태의 소결재를 가압하여 피스톤 본체의 상부 형상인 상부체를 성형하는 상부체성형단계;
분말 형태의 소결재를 가압하여 피스톤 본체의 하부 형상인 하부체를 성형하는 하부체성형단계;
상기 상부체와 상기 하부체의 사이에 브레이징재를 배치하고, 소결재를 소결시킴과 동시에 상부체와 하부체를 브레이징 접합시켜 피스톤 본체를 제조하는 접합단계;
상기 피스톤 본체의 표면을 가공하여 표면에 노출된 기공을 제거하는 가공단계; 및
상기 피스톤 본체의 표면에 질화 열처리 및 산화 열처리 중 선택된 어느 하나 이상을 수행하여 부동태 피막을 형성시키는 열처리단계;를 포함하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 열처리단계는 상기 피스톤 본체의 표면에 질화 열처리 이후 산화 열처리를 수행하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 소결재는 중량%로, C: 0.45~0.6%, Cr: 1.3~1.7%, Mo: 0.15~0.35%, Mn: 0.25~0.40%, S: 0.1~0.2%, 잔부 Fe 및 불가피한 불순물을 포함하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 소결재는 중량%로, C: 0.5~0.8%, Mo: 0.8~0.9%, Mn: 0.25~0.40%, S: 0.1~0.2%, 잔부 Fe 및 불가피한 불순물을 포함하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 접합단계에서 사용되는 상기 브레이징재는 중량%로, Cu: 35~45%, Si, Mn, B, P, C, Fe의 군 중 선택된 어느 하나 또는 둘 이상의 총량을 5~30% 및 잔부 Ni을 포함하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 접합단계는 1100~1170℃ 조건에서 20~40분간 소결 및 브레이징을 수행하고, 0.8~1.2℃/s 속도로 상온까지 냉각하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 접합단계는 상기 상부체와 상기 하부체 사이를 0.05~0.15mm 이격시킨 후 그 사이에 상기 브레이징재를 배치하여 수행하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 가공단계는 상기 피스톤 본체의 표면을 0.1~0.2mm 깊이로 가공하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 열처리단계에서는 540~570℃ 조건에서 20~120분간 산화 열처리를 수행하여 상기 부동태 피막을 형성하되,
상기 부동태 피막은 Fe3O4 를 포함하여 상기 피스톤 본체의 표면에 2~8㎛ 두께로 형성되는 제1산화물층을 포함하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 청구항 1에 있어서,
상기 열처리단계에서는 450~540℃ 조건에서 1~4시간 질화 열처리를 수행하여 질화물층을 형성시킨 후, 540~570℃ 조건에서 산화 열처리를 수행하여 상기 부동태 피막을 형성하되,
부동태 피막은 철 질화물을 포함하여 상기 피스톤 본체의 표면에 4~20㎛ 두께로 형성되는 질화물층과, Fe3O4 를 포함하여 질화물층의 표면에 1~3㎛ 두께로 형성되는 제2산화물층을 포함하는 것을 특징으로 하는 엔진 피스톤 제조방법.
- 분말을 압축 성형한 상부체 및 분말을 압축 성형한 하부체를 소결시킴과 동시에 상부체와 하부체를 브레이징 접합시켜 제조된 후 표면이 가공되어 표면에 기공이 노출되지 않는 피스톤 본체; 및
상기 피스톤 본체의 표면에 형성된 산화물 및 질화물 중 선택된 어느 하나 이상을 포함하는 부동태 피막;을 포함하는 엔진 피스톤.
- 청구항 11에 있어서,
상기 피스톤 본체의 밀도는 6.9~7.3g/cm3인 것을 특징으로 하는 엔진 피스톤.
- 삭제
- 청구항 11에 있어서,
상기 부동태 피막은 Fe3O4 를 포함하여 상기 피스톤 본체의 표면에 2~8㎛ 두께로 형성되는 제1산화물층을 포함하는 것을 특징으로 하는 엔진 피스톤.
- 청구항 11에 있어서,
상기 부동태 피막은 철 질화물을 포함하여 상기 피스톤 본체의 표면에 4~20㎛ 두께로 형성되는 질화물층을 포함하는 엔진 피스톤.
- 청구항 11에 있어서,
상기 부동태 피막은 철 질화물을 포함하여 상기 피스톤 본체의 표면에 4~20㎛ 두께로 형성되는 질화물층과, Fe3O4 를 포함하여 질화물층의 표면에 1~3㎛ 두께로 형성되는 제2산화물층을 포함하는 엔진 피스톤.
- 청구항 11에 있어서,
상기 피스톤 본체를 형성하는 분말은 중량%로, C: 0.45~0.6%, Cr: 1.3~1.7%, Mo: 0.15~0.35%, Mn: 0.25~0.40%, S: 0.1~0.2%, 잔부 Fe 및 불가피한 불순물을 포함하는 것을 특징으로 하는 엔진 피스톤.
- 청구항 11에 있어서,
상기 피스톤 본체를 형성하는 분말은 중량%로, C: 0.5~0.8%, Mo: 0.8~0.9%, Mn: 0.25~0.40%, S: 0.1~0.2%, 잔부 Fe 및 불가피한 불순물을 포함하는 것을 특징으로 하는 엔진 피스톤.
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US16/352,392 US10871126B2 (en) | 2018-10-19 | 2019-03-13 | Engine piston and method of manufacturing the same |
CN201910270377.1A CN111074176A (zh) | 2018-10-19 | 2019-04-04 | 发动机活塞及其制造方法 |
US17/097,204 US20210062752A1 (en) | 2018-10-19 | 2020-11-13 | Engine piston and method of manufacturing the same |
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US20200123997A1 (en) | 2020-04-23 |
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