KR102058263B1 - 광학 부품용 활성 에너지선 경화성 조성물, 경화물 및 그 경화물을 사용한 광학 렌즈, 광학 렌즈용 시트 또는 필름 - Google Patents
광학 부품용 활성 에너지선 경화성 조성물, 경화물 및 그 경화물을 사용한 광학 렌즈, 광학 렌즈용 시트 또는 필름 Download PDFInfo
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- KR102058263B1 KR102058263B1 KR1020157023433A KR20157023433A KR102058263B1 KR 102058263 B1 KR102058263 B1 KR 102058263B1 KR 1020157023433 A KR1020157023433 A KR 1020157023433A KR 20157023433 A KR20157023433 A KR 20157023433A KR 102058263 B1 KR102058263 B1 KR 102058263B1
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- acrylate
- radical polymerization
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- 239000000203 mixture Substances 0.000 title claims abstract description 53
- 230000003287 optical effect Effects 0.000 title claims description 50
- 239000000178 monomer Substances 0.000 claims abstract description 76
- 238000010526 radical polymerization reaction Methods 0.000 claims abstract description 38
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- -1 acryloyloxy group Chemical group 0.000 claims description 53
- 239000000463 material Substances 0.000 claims description 34
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
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- 125000006353 oxyethylene group Chemical group 0.000 description 1
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- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
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Abstract
Description
Claims (19)
- (I) 그 호모 폴리머의 유리 전이 온도가 200 ℃ 를 초과하는 라디칼 중합 반응성 기 (x1) 을 2 개 이상 갖는 모노머 (A), 그 호모 폴리머의 유리 전이 온도가 -15 ℃ 미만인 라디칼 중합 반응성 기 (x2) 를 2 개 이상 갖는 모노머 (C), 그 호모 폴리머의 유리 전이 온도가 -15 ℃ 이상 100 ℃ 이하인 라디칼 중합 반응성 기 (x3) 을 2 개 이상 갖는 모노머 (B) 및 광 중합 개시제 (E) 를 필수 성분으로서 함유하고,
모노머 (A), 모노머 (B) 및 모노머 (C) 의 합계 중량에 기초하여, (B) 를 5 ∼ 40 중량% 함유하고,
모노머 (A) 및 모노머 (C) 의 합계 중량에 기초하여, (A) 를 3 ~ 50 중량% 함유하는, 또는,
(II) 그 호모 폴리머의 유리 전이 온도가 200 ℃ 를 초과하는 라디칼 중합 반응성 기 (x1) 을 2 개 이상 갖는 모노머 (A), 그 호모 폴리머의 유리 전이 온도가 -15 ℃ 미만인 라디칼 중합 반응성 기 (x2) 를 2 개 이상 갖는 모노머 (C), 및 광 중합 개시제 (E) 를 필수 성분으로서 함유하고,
상기 모노머 (C) 가 하기 일반식 (1) 로 나타내는 다관능 (메트)아크릴레이트 및 하기 일반식 (4) 로 나타내는 2 관능 (메트)아크릴레이트를 함유하고,
모노머 (A) 및 모노머 (C) 의 합계 중량에 기초하여, (A) 를 3 ~ 50 중량% 함유하는
것을 특징으로 하는 광학 부품용 활성 에너지선 경화성 조성물.
[화학식 1]
[화학식 2]
[화학식 3]
[일반식 (1) 중, X 는 수산기, 메틸기, (메트)아크릴로일옥시기, 일반식 (2) 로 나타내는 기, 또는 일반식 (3) 으로 나타내는 기를 나타낸다. R1 ∼ R3 및 R 은 수소 원자 또는 메틸기로서, 동일하거나 상이하여도 된다. Y1 ∼ Y5 는 탄소수 2 ∼ 4 의 옥시알킬렌기로서, 동일하거나 상이하여도 된다. a, b, c, d 및 e 는 각각 독립적으로 0 ∼ 10 의 정수를 나타낸다. 단 a + b + c + d + e 는 6 ∼ 40 이다.]
[화학식 4]
(일반식 (4) 중, R4, R5 는 각각 독립적으로 수소 원자 또는 메틸기, m 및 n 은 각각 독립적으로 3 ∼ 10 의 정수를 나타낸다.) - 제 1 항에 있어서,
모노머 (A) 가 라디칼 중합 반응성 기 (x1) 을 4 개 이상 갖는 조성물. - 제 1 항 또는 제 2 항에 있어서,
라디칼 중합 반응성 기 (x1) ∼ (x2) 가 아크릴레이트기, 메타크릴레이트기, 비닐옥시기, 프로페닐옥시기 및 알릴옥시기로 이루어지는 군에서 선택되는 적어도 1 종의 기인 조성물. - 제 1 항 또는 제 2 항에 있어서,
모노머 (A) 가 라디칼 중합 반응성 기 (x1) 을 4 ∼ 6 개 갖고, 옥시알킬렌기를 0 ∼ 5 개 갖는 조성물. - 제 1 항 또는 제 2 항에 있어서,
상기 (I) 에 있어서의 모노머 (C) 가 옥시알킬렌기를 6 ∼ 40 개 갖는 조성물. - 제 1 항 또는 제 2 항에 있어서,
상기 (I) 에 있어서의 모노머 (C) 가 상기 일반식 (1) 로 나타내는 다관능 (메트)아크릴레이트인 조성물. - 제 1 항 또는 제 2 항에 있어서,
상기 (I) 에 있어서의 모노머 (C) 가 상기 일반식 (4) 로 나타내는 2 관능 (메트)아크릴레이트인 조성물. - 삭제
- 제 1 항 또는 제 2 항에 있어서,
추가로 슬립제 (D) 를 함유하는 조성물. - 제 9 항에 있어서,
슬립제 (D) 가 실리콘계 슬립제 (D1) 및/또는 불소계 슬립제 (D2) 인 조성물. - 제 9 항에 있어서,
슬립제 (D) 가 분자 내에 2 ∼ 100 개의 옥시알킬렌기를 갖는 조성물. - 삭제
- 삭제
- 제 1 항 또는 제 2 항에 있어서,
라디칼 중합 반응성 기 (x3) 이 아크릴레이트기, 메타크릴레이트기, 비닐옥시기, 프로페닐옥시기 및 알릴옥시기로 이루어지는 군에서 선택되는 적어도 1 종의 기인 조성물. - 제 1 항 또는 제 2 항에 기재된 광학 부품용 활성 에너지선 경화성 조성물이 활성 에너지선에 의해서 경화되어 이루어지는 경화물.
- 제 16 항에 있어서,
동마찰 계수가 0.05 ∼ 0.5 인 경화물. - 제 16 항에 있어서,
손실 탄성률 E”가 5 × 107 ㎩ 이하인 경화물. - 제 16 항에 기재된 경화물을 사용한 광학 렌즈, 광학 렌즈용 시트 또는 필름.
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012116923A (ja) * | 2010-11-30 | 2012-06-21 | Sanyo Chem Ind Ltd | 紫外線硬化型樹脂組成物 |
JP2012242464A (ja) * | 2011-05-17 | 2012-12-10 | Nippon Kayaku Co Ltd | 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 |
JP2013008825A (ja) * | 2011-06-24 | 2013-01-10 | Mitsubishi Rayon Co Ltd | ナノ凹凸構造用樹脂組成物、およびそれを用いた自動車メータカバー用透明部材とカーナビゲーション用透明部材 |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05214044A (ja) * | 1992-02-05 | 1993-08-24 | Kuraray Co Ltd | 組成物 |
JPH05255462A (ja) * | 1992-03-10 | 1993-10-05 | Kuraray Co Ltd | 組成物 |
JPH0770219A (ja) | 1993-09-03 | 1995-03-14 | Dainippon Ink & Chem Inc | 紫外線硬化性組成物の硬化方法 |
JPH10241206A (ja) * | 1997-02-28 | 1998-09-11 | Toray Ind Inc | 光記録媒体および光記録媒体の製造方法 |
JP3826145B2 (ja) * | 2004-07-16 | 2006-09-27 | 株式会社クラレ | 集光フィルム、液晶パネルおよびバックライト並びに集光フィルムの製造方法 |
JP3904027B2 (ja) * | 2004-12-24 | 2007-04-11 | Jsr株式会社 | 光学部材用放射線硬化性樹脂組成物及び光学部材 |
JP4703180B2 (ja) * | 2004-12-28 | 2011-06-15 | リンテック株式会社 | コーティング用組成物、ハードコートフィルムおよび光記録媒体 |
JP4831464B2 (ja) * | 2005-08-26 | 2011-12-07 | 大日本印刷株式会社 | 高屈折率ハードコート層 |
JP4376848B2 (ja) | 2005-10-06 | 2009-12-02 | 日産自動車株式会社 | 硬化型溶剤系クリア塗料 |
JP2006309248A (ja) | 2006-05-08 | 2006-11-09 | Mitsubishi Rayon Co Ltd | レンズシートおよびそれを用いた面光源素子ならびに液晶表示装置 |
JP2008094987A (ja) | 2006-10-13 | 2008-04-24 | Nippon Kayaku Co Ltd | 光学材料用高屈折率樹脂組成物およびその硬化物 |
KR101496481B1 (ko) * | 2007-03-27 | 2015-02-26 | 다이니폰 인사츠 가부시키가이샤 | 시트 형상 광학 부재 |
JP2008286845A (ja) * | 2007-05-15 | 2008-11-27 | Konica Minolta Opto Inc | 防眩性光学フィルム、防眩性光学フィルムの製造方法、偏光板及び表示装置 |
JP5155018B2 (ja) | 2007-05-31 | 2013-02-27 | 三洋化成工業株式会社 | 活性エネルギー線硬化型樹脂組成物 |
JP2011063698A (ja) * | 2009-09-16 | 2011-03-31 | Idemitsu Kosan Co Ltd | 光学部品用樹脂原料組成物および光学部品 |
JP5710356B2 (ja) | 2011-04-18 | 2015-04-30 | 日本化薬株式会社 | 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 |
JP5930758B2 (ja) * | 2012-02-15 | 2016-06-08 | 三洋化成工業株式会社 | 感光性組成物 |
JP2013228729A (ja) * | 2012-03-30 | 2013-11-07 | Sanyo Chem Ind Ltd | 光学部品用活性エネルギー線硬化性組成物 |
WO2013151119A1 (ja) | 2012-04-06 | 2013-10-10 | 東亞合成株式会社 | 光学層形成用活性エネルギー線硬化型組成物 |
JP2014114402A (ja) * | 2012-12-11 | 2014-06-26 | Taiyo Ink Mfg Ltd | 光硬化性組成物および成型品 |
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Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012116923A (ja) * | 2010-11-30 | 2012-06-21 | Sanyo Chem Ind Ltd | 紫外線硬化型樹脂組成物 |
JP2012242464A (ja) * | 2011-05-17 | 2012-12-10 | Nippon Kayaku Co Ltd | 光学レンズシート用エネルギー線硬化型樹脂組成物及びその硬化物 |
JP2013008825A (ja) * | 2011-06-24 | 2013-01-10 | Mitsubishi Rayon Co Ltd | ナノ凹凸構造用樹脂組成物、およびそれを用いた自動車メータカバー用透明部材とカーナビゲーション用透明部材 |
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