KR101834491B1 - Diffuser formulation containing natural essential oils and hydrosols of Artemisia - Google Patents

Abstract

The present invention relates to a fragrance composition comprising an extract of mugwort, and more specifically, to a fragrance composition containing mugwort natural essential oil and a hydrolyzate of mugwort including at least one selected from the group consisting of dog mugwort, mugwort, mugwort yellow mugwort, Sol. ≪ / RTI > The perfume composition of the present invention contains a natural essential oil and a hydrosol of mugwort to provide a natural natural fragrance which is stably excellent in flavor preference to a user. In addition, the fragrance composition containing mugwort in the present invention is remarkably excellent in aromatherapy efficacy, antibacterial effect, and air cleaning effect, and also has excellent odoriness, flavor persistence and odor.

Description

[0001] The present invention relates to a diffuser aerosol composition containing natural essential oils and hydrosols of Artemisia sp.

FIELD OF THE INVENTION The present invention relates to a perfume composition, and more particularly to a perfume composition comprising natural essential oils and hydrosols of mugwort.

As the economy develops and the standard of living improves, the desire for well-being or healing is increasing. Accordingly, in order to improve the quality of life, a demand for a product such as a fragrance or a diffuser which spreads a good fragrance in the room is increasing. Among these, the fragrance usually fills the space at the moment of opening, but disappears quickly, while the diffuser has a feature that the fragrance of the fragrance lasts from the beginning to the end.

The fragrance, which is a main component of the fragrance or diffuser, can be classified into natural fragrance and chemically synthesized fragrance. Most fragrance compositions currently use chemically synthesized fragrance. However, the chemical synthetic perfume does not give a lasting affinity to the user, and the additive used for long lasting fragrance may cause side effects such as allergic reaction, and recently, interest in perfumes using natural essential oils obtained from plants is increasing.

Natural essential oils and natural hydrosols are widely used in the world. Especially, they are the main ingredients of fragrance, and they are used for skin, lotion, cosmetics, lotion, perfume, aromatherapy, Deodorant, daily necessities, or raw materials for food and beverage, which is very valuable in industrial value. Hydrogels have an antiseptic and germicidal effect. They control the pH of the skin and moisturize the skin, thereby preventing or reducing skin diseases and allergic reactions. Accordingly, hydrogels become important raw materials for raw materials of cosmetics since they become main raw materials such as skins, lotions, skin moisturizers and the like of natural cosmetics.

Furthermore, recent trends in the consumption of fragrance or diffuser products are not limited to simple fragrance emission, but also products with additional functionality.

Accordingly, a problem to be solved by the present invention is to provide a fragrance composition excellent in fragrance, flavor, and flavor persistency using natural plants.

Another object of the present invention is to provide a method for producing a fragrance composition having excellent flavor, flavor, and flavor persistency using natural plants.

In order to accomplish the above object, the present invention provides a fragrance composition comprising an extract of mugwort comprising at least one selected from the group consisting of dog mugwort, mugwort, mugwort yellow mugwort, and mugwort mugwort. The present invention also provides a perfume composition comprising the perfume composition and a perfume composition comprising such a combination perfume composition in an oil phase.

The inventors of the present invention have made intensive researches to solve the problems of the prior art, and as a result, they found that a combination perfume containing a natural essential oil of mugwort at a constant weight ratio has excellent perfume quality and palatability. Further, the inventors of the present invention have found that the fragrance composition, flavor, and flavor persistence of the fragrance composition containing the combined fragrance as an oil phase and containing mugwort hydrosol or purified water in the water phase are remarkably excellent.

The extract of mugwort may be a natural essential oil of mugwort, a hydrosol, or a mixture thereof. The extract of the mugwort may be prepared by conventional extraction, distillation, or compression, and may be produced according to each part of the mugwort, for example, root, stem, leaf, flower, fruit, seed, and skin.

Generally, the method of extracting natural essential oil of mugwort is steam distillation, which can break the cell wall of plant and extract natural essential oil by using hot water or steam. That is, when the temperature exceeds a certain temperature, the cell wall of the plant is broken and the fragrance material evaporates. When the evaporated fragrance material is cooled again, a liquid essential oil can be obtained. At this time, the water evaporated together contains soluble active ingredients of natural plant ingredients dissolved and contained. Such extracted water is called hydrosol. Hydrosol is a term derived from the word "water" (hydro) and "decomposition" (sol), also called directional distilled water. Particularly, the above-mentioned hydroose contains a large amount of water-soluble components soluble in water among the mugwort extract obtained through steam distillation. In this way, water-insoluble components can be floated on water with natural essential oil after extraction to extract the hydrosol and natural essential oil. Hydrosol is a highly industrial distillate extract that can extract essential oils from distillation and produce a large amount of by-products. The name of the hydrosol varies depending on the sample to be extracted. Floral water is an aqueous solution obtained by distilling only flowers, and Herbal water is an aqueous solution obtained by distilling a herb.

Water-steam distillation extract methods extract plant essential oil efficiently because it extracts plant raw materials only with water vapor without contacting with water, and because it does not use organic solvent, it is environment-friendly and stable. There is an advantage that it can be used for medicine or aromatherapy.

The steam distillation extraction target can be mainly used for plant parts such as seed, fruit, peel, some flower, outpost, or lobe. The directional refinery water vapor distillation apparatus used in the water-steam distillation extraction method can be used as water-distillation or water and steam distillation as a generally used method. The steam distillation apparatus does not require removal of solvent which is a disadvantage of solvent extraction and can obtain a highly directional essential oil and is suitable for the production of a large-scale aromatic natural essential oil.

In the present invention, Artemisia annua ) is also called Leaf mugwort or dog mugwort. It is about 1m in height. It has no hairs on the whole grass and has a strange smell. Its stem is green and its branches are split a lot. Leaves are alternate and 2-3 times thin and diverged deeply. Flowers bloom in June-September with greenish-yellow bloom. In one room, it is used for the treatment of fever and cold, school, pediatrics, indigestion, or dysentery.

In the present invention, Artemisia selengensis Turcz. ex Besser is a perennial plant that grows in rivers and wetlands. Its stem is 1 ~ 2m in height and grows straight and has a red color and vertical wrinkles. Root leaves are seeded when flowers are bloomed, stem leaves are alternate, and 3 to 5 branches are deeply cracked. Flowers bloom from August to September, and hair-like flowers hang on cones.

In the present invention, Artemisia argyi Lev. Et Vnt grows with a marine climate unique to the Rhodope and a sea breeze mixed with the base of the south coast of the clean sea. It is rich in vitamin A and contains minerals, calcium, sodium and the like There is a wealth of features. In addition, Artemisia argyi Lev. Et Vnt from Geomundo is rich in various minerals due to sea breeze and seawater because of its soft texture and geographical characteristics such as abundant sunshine and granitic soil.

In the present invention, the mugwort may include any one or more selected from the group consisting of dog mugwort, mugwort, mugwort yellow mugwort, and mugwort mugwort, and other mugwort may be included in the mugwort. In the case of the perfume composition containing the mugwort extract, the perfume composition has excellent flavor, flavor, and flavor persistence. More preferably, the perfume composition of the present invention may include all of the extracts of the above-mentioned Cryptosporidium sp., Cryptosporidium sp., Cryptosporidium sp., And Geomundo sp., And in this case, the fragrance composition, flavor, Most excellent.

The present invention provides the combined perfume composition comprising the perfume composition, wherein the perfume composition comprises 3 to 20% by weight, more preferably 5 to 15% by weight, of natural essential oil of mugwort, based on the total weight of the combined perfume composition. When the natural essential oil of mugwort is less than 3% by weight, the natural fragrance of mugwort rarely appears and the quality of the fragrance is poor. When the natural essential oil is more than 20% by weight, the mugwort flavor is too strong.

According to an embodiment of the present invention, the combined fragrance includes a fragrance of a floral series, and the natural essential oil of mugwort includes 3 to 15 wt%, preferably 4 to 10 wt% ≪ / RTI > When the natural essential oil is less than 3% by weight, the natural scent of mugwort does not appear. When the natural essential oil is more than 15% by weight, the flavor of the natural wormwood is too strong and the degree of preference is lowered. The composition of the present invention is harmonized with floral fragrance of floral fragrance by adding a natural herb flavor to the fragrance of the floral fragrance to provide excellent perfume palatability. The fragrance of the floral series may include aldehyde C11 undecylenic 10%, bergamot oil FFC, gamma-undecalactone 10%, phenylacetaldehyde 50% (Phenylacetaldehyde 50%), or Helional and the like, which are more specifically shown in Table 8 below.

According to another embodiment of the present invention, the combined fragrance includes green fragrance, and the natural essential oil of mugwort is 5 to 30% by weight, preferably 10 to 20% by weight, To provide the combined perfume composition. When the natural essential oil is less than 5% by weight, the natural scent of mugwort does not appear. When the natural essential oil is more than 30% by weight, the smell of mugwort is too strong and the balance of fragrance is collapsed. The composition of the present invention is excellent in flavor and palatability due to the natural flavor of leaves and grasses and the mushroom as an accent. The fragrance of the green series may include Bergamot, Green note, Lemon, Fresh herb (Rosmarry, Rose marry), Rose, etc., Respectively.

The present invention also provides a perfume composition comprising the combined perfume composition in oil phase. The perfume composition may be formulated into a liquid gel containing oil and water to fill the diffuser and act as a perfume, although the formulation is not particularly limited. The water phase may be prepared containing purified water, a hydrosol of wormwood, or a mixture thereof.

The perfume composition may contain 5 to 25% by weight, preferably 10 to 20% by weight, more preferably 12 to 16% by weight based on the total weight of the perfume composition. When the combined perfume composition is less than 5% by weight, the perfume and fragrance strength are decreased. When the combined perfume composition is more than 25% by weight, fragrance is too strong and there is a concern that the degree of preference may decrease.

The present invention also relates to a perfume composition comprising a combined fragrance composition comprising natural essential oil of mugwort in an oil phase and comprising purified water, a hydrosol of a mugwort or a mixture thereof in an aqueous phase, wherein the composition is a liquid gel type, To 25% by weight, preferably 27% to 33% by weight, based on the total weight of the gel base. When the water phase is less than 25% by weight, the flavor is strong but the incense persistence is low. When the water phase is more than 35% by weight, the flavor persistency is good but the flavor is decreased.

In the present invention, the perfume composition may contain at least one selected from the group consisting of water, dipropylene glycol, ethanol, etc., in the gel base. Preferably, in order to form a stable liquid gel type, Glycol, and ethanol. The weight ratio of the water phase, dipropylene glycol, and ethanol may be 2.5 to 3.5: 4.5 to 5.5: 1.5 to 2.5 (water: dipropylene glycol: ethanol). The liquid gel type composition containing water, dipropylene glycol, and ethanol in the above-mentioned weight ratio is generally most excellent for the purpose of the present invention because it has excellent perfume, fragrance strength, flavor, odor, and flavor persistence .

In the present invention, the above-described perfume composition may be prepared by being contained in a liquid gel-type diffuser. For the purpose of the present invention, the perfume composition including the combination fragrance and the weight ratio of water and oil phase as described above is remarkably excellent in perfume, fragrance strength, odor, flavor, and flavor persistence and is used in a liquid gel type diffuser The best effect can be obtained. The perfume composition may further include, but is not limited to, an indoor perfume, a spray perfume, an indoor perfume spray, an oriental candle, an air purifier, an air freshener, a deodorant, or a deodorizing agent.

(S1) mixing natural essential oil of wormwood with the combination fragrance; (s2) introducing the hydrosol of wormwood into an aqueous base; And (s3) adding the combined fragrance to the water base to mix the fragrance. The content of the perfume composition may be applied equally to the preparation method.

The perfume composition of the present invention contains a natural essential oil and a hydrosol of mugwort to provide a natural natural fragrance which is stably excellent in flavor preference to a user.

In addition, the fragrance composition containing mugwort in the present invention is remarkably excellent in aromatherapy efficacy, antibacterial effect, and air cleaning effect, and also has excellent odoriness, flavor persistence and odor.

BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 shows a flow chart of a process for preparing the diffuser perfume composition of the present invention.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

Experimental Example  1: Fragrance characteristics of mugwort essential oil, which is the main ingredient of aromatic fragrance composition

The volatile flavor components and major components of mugwort natural essential oil, which is the main ingredient of aromatic fragrance composition, were investigated to confirm the directional characteristics.

1) Artemisia argyi Lev . et Vnt )

The main ingredients of natural essential oils are Caryophyllene 15.35%, 1R-.alpha.-Pinene 11.13%, L (-) Borneol 8.52%, Limonene 6.59%, beta.- Pinene 6.41%, 1,4,7, -Cycloundecatriene 5.85% , 1,8-Cineole 4.40%, Camphene 3.79%, and Copaene 3.26, among which Caryophyllene and Pinene occupied an area ratio of 32.89% of the total content.

The efficacy of volatile fragrance components and major components of natural essential oil from Geomundo Mountain Yellow Mugwort is as follows: air purification efficacy (phytoncide, forest), air purification (antibacterial, anti-inflammatory, insecticidal), aromatherapy efficacy (anti-stress, respiratory disease prevention, ), Fragrance (deodorizing function), and the like.

The major fragrance components of natural essential oil from Geomunso Mountain Yellow Mugwort were analyzed by GC-mass spectrometry and the results are shown in Table 1 below.

Volatile fragrance component of natural essential oil from geomunso mountain yellow wormwood No. RT Compound name Area Pct (%) One 4.952 2-ethyl-Furan 0.0367 2 6.964 Nonane 0.0845 3 8.470 1R-.alpha.-Pinene 11.135 4 8.935 Camphene 3.7927 5 9.759 beta.-Pinene 6.4164 6 10.364 beta.-Myrcene 1.3326 7 10.947 (+) - 2-Carene 0.7173 8 11.441 Limonene 6.5936 9 11.612 1,8-Cineole 4.4015 10 12.741 1-methyl-4- (1-methylethylidene) -Cyclohexene 0.9203 11 14.118 2,4,6-Octatriene 0.7748 12 14.647 1-methyl-4- (1-methylethenyl) -Benzene 0.7145 13 14.959 1,4-Cyclohexadiene 0.6234 14 16,000 3-Cyclopentene-1-acetaldehyde 0.4226 15 16.589 3-Carene 0.3455 16 16.759 Camphor ( 0.5936 17 17.195 1,4-Cyclohexadiene 0.2335 18 17.854 2 (10) -Pinene-3-one 0.6306 19 18.501 3-Cyclohexen-1-ol 2.2072 20 19.118 Acetic acid 0.7494 21 19.389 3-Cyclohexene-1-methanol 2.9196 22 19.989 1,3,8-p-Menthatriene 1.4766 23 20.683 L (-) - Borneol 8.5223 24 21.601 Caryophyllene 15.3488 25 22.972 1,4,7, -Cycloundecatriene 5.8548 26 23.537 gamma-cadinene 1.2705 27 23.960 Bicyclo [4.4.0] dec-1-ene 2.2212 28 24.201 Copaene 3.2626 29 25.243 -Muurolene 2.6628 30 27.296 1H-Benzocycloheptene 0.1713 31 28.290 alpha.-Calacorene 0.1101 32 28.943 Bicyclo [3.3.1] non-3-en-2-ol 0.2391 33 29.449 1H-Benzocycloheptene 0.0887 34 29.761 trans-Z-.alpha.-Bisabolene epoxide 0.0501 35 30.349 Caryophyllene oxide 0.5506 36 32.043 1H-Cycloprop [e] azulene 0.1459 37 32.738 Humulen- (v1) 0.0491 38 33.2146 1H-Cycloprop [e] azulen-7-ol 0.1149 39 33.8618 1H-Indene 0.1748 41 34.6266 Naphthalene 0.3847 42 37.4975 3-Methylene-bicyclo [3.2.1] oct-6-en-8-ol 0.1411

The efficacy of the major fragrance components of the mugwort mugwort is shown in Table 2 below.

Fragrance characteristics and efficacy on the main ingredients of natural essential oil Compounds Odorant description and efficacy Caryophyllene Air purification (phytoncide), medicinal Pinene Air purification (phytoncide), antibacterial, anti-inflammation Borneol Pepper flavor, poultice, cosmetic perfume Limonene Cosmetics fragrances, food fragrances, antibacterials, air purification (phytoncide), anti-inflammation 1,8-Cineole Fresh camphor odor, antibacterial, respiratory disease prevention, inflammation, fatigue, pain relief cosmetic perfume, perfume, food fragrance, oral cleaning, cough suppression, Camphene Medicines, spices, insecticides and pesticides Copaene Perfume, cosmetic perfume

2) Artemisia argyi Lev . et Vnt )

The major fragrance components of the natural essential oils of Codophyllum yellow mugwort were 12.19% of Caryophyllene, 11.14% of 1R-alpha-Pinene, 9.35% of Bicyclo [3.1.1] heptane, 7.30% of D-Limonene, 7.30% of 1,8-Cineole. -Caryophyllene 3.91%, Camphene 3.51%, Borneol 3.54%, and Isoborneol 2.442%. Among these components, Caryophyllene and alpha-Pinene were 27.24 %%, showing similar aroma components and contents to Geomundo mugwort. Especially Pinene and Limonene are the main components of phytoncide which is an air purification substance of green forest. It is known that it has strong anxiolytic effect because it relieves stress and provides comfort. In the case of Jojodosan mugwort and Geomundo mugwort, these components are 17.72 ~ 18.17 %, Indicating the content of a lot of area ratio, so that it has the effect of refreshing the mugwort fragrance and clearing the hair.

The major fragrance components of the natural essential oil of Jojobo mugwort were analyzed by GC-mass spectrometry and the results are shown in Table 3 below.

Volatile flavor component of natural essential oil from Jodosan Yellow Sea Mugwort No. RT Compound name Area Pct (%) One 3.00 2,3-Dichloro-1,4,5,8-tetraaza-phenanthrene 0.0056 2 3.19 (1,2-Dichlorovinyl) trichlorosilane 0.0032 3 5.22 1-Cyclopentenecarbonitrile 0.0044 4 6.23 Furan 0.0041 5 7.61 Pyridine 0.0029 6 8.56 Naphtho [1,2-b] furan-2,8 (3H, 4H) -dione 0.0025 7 9.76 3- (2-Hydroxy-6-methylphenyl) -4 (3H) -quinazolinone 0.0122 8 9.80 Cyclohexanone, 0.0044 9 10.20 Dimethyl (1-methylvinyl) chlorosilane 0.1486 10 10.37 beta.-Myrcene 0.1723 11 11.45 Naphtho [1,2-b] furan-2,8 (3H, 4H) -dione 0.0023 12 14.28 D-Limonene 2.4511 13 15.85 1,8-Cineole 3.0025 14 17.83 1,3,6-Octatriene 0.5908 15 18.84 1,4-Cyclohexadiene 1.6932 16 23.30 1,7-Octadien-3-one 0.6044 17 24.98 Naphtho [1,2-b] furan-2,8 (3H, 4H) -dione 0.0049 18 25.65 3- (2-Hydroxy-6-methylphenyl) -4 (3H) -quinazolinone 0.0097 19 28.81 acetate 0.0098 20 29.01 Indan-1,3-dione 0.0538 21 31.31 Benzene 0.3029 22 32.21 1R-alpha-Pinene 19.6197 23 33.00 Camphene 3.5124 24 34.08 Bicyclo [3.1.1] heptane 9.3501 25 35.07 2-Cyclohexen-1-ol 0.6721 26 35.46 1,3,8-p-Menthatriene 0.8027 27 36.02 D-Limonene 4.8492 28 36.52 Eucalyptol 4.2986 29 38.69 1,7-Octadien-3-one 1.0674 30 39.25 4-Cyclopropylnorcarane 0.0264 31 39.35 1,4-Octadiene 0.1473 32 40.05 N-Furfuryl-N ' - (benzyl) oxamide 0.2370 33 42.05 1,3,6,10-Dodecatetraene 0.5046 34 42.40 Cedran-13-ol 0.1145 35 42.63 (E) -3 (10) -Caren-4-ol 0.0548 36 43.12 Camphene 0.6124 37 43.22 cis-.alpha.-Bisabolene 0.5756 38 43.55 1,3,6,10-Dodecatetraene 0.4875 39 44.26 Isoborneol 2.4397 40 45.69 Humulen- (v1) 1.4660 41 46.29 3-Cyclohexene-1-ethanol 0.0576 42 46.40 (Z, Z) -. Alpha.-Farnesene 0.0484 43 47.18 2,6-Octadien-1-ol 1.2260 44 47.95 Borneol 3.5417 45 49.43 Caryophyllene 6.2315 46 50.35 Caryophyllene oxide 0.7202 47 51.02 Acetic acid 0.4708 48 51.99 Caryophyllene 5.9609 49 52.72 1,6-Cyclodecadiene, 0.0805 50 52.91 1H-3a, 7-Methanoazulene (blue) 0.2639 51 53.05 Di-epi-.alpha.-cedrene 0.1138 52 53.91 alpha.-Caryophyllene 3.9071 53 55.14 γ-Muurolene 1.0251

The efficacy of the major fragrance components of Jodosan Yellow Sea Mugwort is shown in Table 4 below.

A rtemisia argyi H. Lev . & Vaniot ) Surface composition of natural essential oil Compounds Odorant description and efficacy Caryophyllene Air purification (phytoncide), medicinal Pinene Air purification (phytoncide), antibacterial, anti-inflammation Borneol Pepper flavor, poultice, cosmetic perfume Bicyclo [3.1.1] heptane Food fragrance, perfume, antibacterial, anti-inflammatory, antitumor, seasoning, insecticide Limonene Cosmetics fragrances, food fragrances, antibacterials, air purification (phytoncide), anti-inflammation 1,8-Cineole, Eucalyptol Fresh camphor odor, antibacterial, respiratory disease prevention, inflammation fatigue, pain relief cosmetic perfume, perfume, food fragrance, oral cleaning, cough suppression, Camphene Medicines, spices, insecticides and pesticides .alpha.-Bisabolene Sweet aromatic direction, blue anti-inflammatory, antibacterial, immune control, anti-cancer effect, fragrance

3) Artemisia annua Linne

[4aR- (4a.alpha., 7.alpha., 8a.beta.)] - Naphthalene 4.05%, Beta-beta-cyclodecadiene 4.72% -Eudesmene 4.06%, Bicyclo [2.2.1] heptan-2-one 2.70%, 1,6,10-Dodecatriene 2.69%, (e) -? - FARNESENE 2.69%, Caryophyllene oxide 1.78%, alpha.- , 1.42% of 3,3,6-trimethyl-1,5-heptadien-4-ol, and 1.39% of caryophyllene. It was confirmed that the mugwort was composed of various fragrance components, unlike the mugwort of Choodosan and Geomundo, and especially fragrant components such as Estragole, beta.-Phellandrene, beta.-Myrcene, 2-Butyl-1,2-azaborolidine, ) -β-Farnesene are used as fragrances for perfume raw materials and cosmetics. These ingredients are mainly known to contain a lot of herbs and ripe fruits, and since they contain these various fragrance ingredients, And flavor.

Antioxidants such as Santolina trien, S-alpha.-Pinene (anti-inflammatory component), Camphen, Artemisia alcohol, and Caryophyllene were found to contain antimicrobial components such as anti-inflammatory and insecticide.

The main fragrance components of the natural essential oil of C. pentruculus were analyzed by GC-mass spectrometry and the results are shown in Table 5 below.

Volatile Flavor Components for Natural Essential Oil of Dogwood Mugwort PK RT Compound name Area Pct (%) One 4.7642 Ethyl ether 0.1673 2 7.7881 Santolina triene 0.3166 3 8.4705 1S-alpha.-Pinene 0.2229 4 8.8941 1,3,6-Heptatriene 0.0881 5 9.253 Camphene 0.7250 6 10.4884 beta.-Phellandrene 0.9819 7 11.3827 beta.-Myrcene 0.3230 8 13.1064 Santolina trien 5.0748 9 14.0536 1,4-Cyclohexadiene 0.2436 10 16.6303 2-Butyl-1,2-azaborolidine 0.2058 11 16.9951 2,6-Octadienal 0.2800 12 17.7775 Artemisia alcohol 1.4212 13 18.2423 Copaene 0.2990 14 18.5011 1,6-Octadien-3-ol 0.3922 15 19.2365 Bicyclo [2.2.1] heptan-2-one 2.7029 16 20.0837 Bicyclo [2.2.1] heptan-3-one 0.1747 17 21.172 Caryophyllene 1.3872 18 21.7603 Estragole 0.8510 19 22.2251 1,5,7-Octatrien-3-ol 0.3733 20 22.7369 (e) - [beta] -FARNESENE 0.4020 21 23.6665 1,5-Cyclodecadiene 0.0235 22 24.1136 Tricyclo [5.4.0.0 (2,8)] undec-9-ene 0.5457 23 24.3371  (-) - Germacrene 0.4647 24.6371 decahydro-4a-methyl-1-methylene-7- (1-methylethenyl) -Naphthalene 0.7555 24 25 25.0548 alpha.-Cubebene 1.7440 26 25.5902  (-) - Germacrene 0.2407 27 25.9079 1H-Cycloprop [e] azulene 0.0963 28 26.5256 α-Cedrene 0.1254 29 27.1198 Caryophyllene 6.2754 30 27.4492 Propanoic acid 0.8047 31 27.8081 Naphthalene 0.0849 32 28.2493 (e) - [beta] -FARNESENE 2.2918 33 28.5847 Naphthalene 0.1101 34 29.673 D-Germacrene 4.7237 35 29.9378 beta-Eudesmene 4.0560 36 33.4205 alpha.-Farnesene 0.2661 37 34.8501 Caryophyllene oxide 1.7783

Table 6 shows the efficacy for the major fragrance components of dog mugwort.

Flavor characteristics and efficacy on the major components of natural essential oil Compounds Odorant description and efficacy Caryophyllene Air purification (phytoncide), medicinal Santolinatrien Inflammation, pain, atopy, arthritis, antibacterial activity (-) - Germacrene Antimicrobial, insecticide Bicyclo [3.1.1] heptane Food flavor, perfume, antibacterial, lobular agent, antitumor, seasoning, insecticide [4aR- (4a.alpha., 7.alpha., 8a.beta.)] - Naphthalene Cosmetics fragrances, food fragrances, antibacterials, air purification (phytoncide), anti-inflammation beta-Eudesmene, Conflict, Tonic, Anti-inflammatory, Anti-itch Bicyclo [2.2.1] heptan-2-one, Moxibustion odor, medicines, spices, insecticides and pesticides (e) -β-FARNESENE, Herb fragrance, blueprint smell, perfume, fragrance, aphid remover beta.-Phellandrene, Odor reducing agent, fragrance raw material Artemisia alcohol, Mugwort, anti-malaria, anthelmintic, anticancer, insecticidal action Estragole, Herbal fragrances, cosmetics fragrances, fragrances 1H-Cycloprop [e] azulene Blue anti-inflammatory, antibacterial, anti-inflammatory

Experimental Example 2: Development of a steering formulation base for fragrance addition for the development of indoor gel fragrance

The first steering formulation base for the development of indoor gel fragrance was selected and shown in Table 7 below.

A method of manufacturing the steering formulation bases is as follows. Firstly, natural essential oil was extracted from water-steam distillation methods from mud wormwood, mudosan yellow mugwort, geomundo mud wormwood, and wormwood. Then, each natural essential oil was mixed with 25 wt% each to prepare a wormwood flavor base. The prepared wormwood flavor base was added to each of the steering formulation bases in an amount of 10% by weight and mixed.

Developed a steering-purpose parabolic base for in-vivo function and aromatherapy efficacy division Flavor compatibility (added 10% by weight of wormwood flavoring base) Remarks Green fragrance Floral bouquet fragrance
(joy) Carnation Perfume
(Single flower) Herbal Perfume compatibility ○ ○ × × - Mugwort base: mugwort, mugwort mugwort, mugwort mugwort, mugwort Scent
evaluation A nostalgic perfume that emphasizes the natural fragrance of leaves, grasses, and meadows. It features a green herb blend of wild herbs, mousse, as an accent. Soft floral bouquet fragrance with a soft floral effect Spicy carnation scent mixed with strong camouflaged scent of wormwood, incompatible with fragrance of tobacco smell of weak tobacco dry leaf tobacco and medicinal smell Herbal flavor and notes added with mugwort flavor, and a rough and spicy,

The carnation perfume and herbal perfume were unsuitable for the reason shown in Table 7 above, so the green perfume, the floral bouquet perfume, and the mugwort base were firstly selected. A steering formula base was constructed centering on the first selected steering perfume. The components of the formula base prepared in Table 8 below are specifically shown.

The first fragrance formula basic formula for developing mugwort combination fragrance Formula 1: floral bouquet Formula 2: green flavor Formula 3: naturally mushroom Fragrance characteristic Raw material name  Raw material name Raw material name Aldehyde Aldehyde C11 Undecylenic 10% Bergamot Shag Caryophyllene Citrus Bergamot Oil FFC green note Worm Santolinatrien Dairy gamma-Undecalactone 10% Lemon 1,6-Cyclodecadiene Green Phenylacetaldehyde 50% Fresh Herb (Rose marry) [4aR- (4a.alpha., 7.alpha., 8a.beta.)] - Naphthalene Helional Rose beta-Eudesmene Iris alpha-Damascone 10% Muguet Bicyclo [2.2.1] heptan-2-one Jasmine Benzyl acetate Geranium 1,6,10-Dodecatriene Methyl Dihydro Jasmonate Hyacinth Estragole cis- Jasmone 10% Musk (e) - [beta] -FARNESENE HCA Iris Mud wormwood Caryophyllene Jasmin Absolute 10% Vetiver Geomundo mugwort 1R-alpha-Pinene Muge Hydroxycitronellal Moss beta.-Pinene Narcotics Aurantiol Bicyclo [3.1.1] heptane Ylang ylang oil D-Limonene Oriental Benzon Resinoid Light 1,8-Cineole rose Rose Oxide 10% alpha.-Caryophyllene Geranium oil Camphene Phenyl ethyl alcohol Borneol Rosalve 10% Isoborneol Rose absolute 10% Copaene Spicy Eugenol alcohol Animal Indolene 10% Civer Cat Oil Woody Sandalwood Musk Ethylene Brassylate Exaltolide 50% Sum 100 100 100 Fidelity characteristics Fidelity characteristics Fidelity characteristics Jasmine, Bulgarian rose, classic and elegant romantic fragrance Natural fragrances emphasize the images of leaves, grasses and meadows The strong aroma of herbaceous camphor, cariophyllene and fresh pine scent of the wild mugwort

Two types of combined fragrances for the addition of a gel fragrance were prepared by combining the formula bases described in Table 8 above, and their content and finessing characteristics are shown in Table 9 below.

Developed two kinds of combined fragrance for adding aromatic fragrance Combination Spice 1: Herbal Floral Bouquet Combination Spices 2: Herb Green Flavor Formula Content (% by weight) Formula Content (% by weight) Formula 1 95 Formula 2 85 Formula 3 5 Formula 3 15 Sum 100 Sum 100 Fidelity characteristics Fidelity characteristics Jasmine, Bulgarian rose, floral bouquet with natural herbal fragrance in a classical and elegant romantic fragrance An image of a green grassland with an emphasis on the natural fragrance of leaves, grasses, grasses,

Experimental Example 3: Liquid Gel Base for Diffuser [

95% by weight of Formula 1 and 5% by weight of Formula 3 described in Experimental Example 2 were mixed to prepare a combined perfume. Dipropylene glycol, and ethanol were mixed at the weight ratios shown in Table 10 below and the combined flavor was added at 14 wt% to prepare a liquid gel base. The water phase was prepared from distilled water or a hydrosol of mugwort, and the mugwort hydrosol was prepared from hydrogens by a mixing method of 1: 1: 1: 1, respectively, , 20, 30, and 40 wt%.

Dustiness investigation according to the mixing ratio of liquid base for diffuser Gel base mixing ratio
(14% by weight addition of fragrance) The fragrance strength (A.U., 2 투 injection / 3 ℓ) Fragrance
Degree Fragrance
speed Incense continuity Perfume Fragrance strength Smell Award layer Award layer: DPG: Ethanol Air (control) - 3 711 One Odorless - - Distilled water 10: 50: 40 26 3039 4 Strong speed lowness 20: 50: 30 24 2707 4 Strong usually Slightly low 30: 50: 20 24 2560 3 usually usually Slightly low 40: 50: 10 22 2124 3 usually usually usually Hydrosol
(Mugwort + mugwort + mugwort) 10: 50: 40 24 2882 4 Strong usually Slightly low 20: 50: 30 25 2750 4 Strong usually Slightly low 30: 50: 20 24 2577 3 usually usually Slightly low 40: 50: 10 22 2217 3 usually usually usually

The fragrance intensity was measured as the fragrance intensity indicating the strong degree of smell of the sample to be measured, For example, the same numerical value of the perfume quality indicates that the fractions of the same series and the numerical values adjacent to each other, such as 3 and 4, have similar scents.

The strength of fragrance was measured at a very low concentration to compare the strength of fragrance relatively. The intensity of fragrance was measured by using air (odorless) as a control and the degree of fragrance of the developed sample to be measured was measured . As a method of measuring the fragrance strength, 5 ~ 20 ㎕ of fragrance stock solution was put into a sampling bag (3liter), and the developed product was put into an envelope to measure the fragrance strength. At this time, the fragrance intensity measuring instrument is e-nose (Futaba, Made in Japan) with dual sensitivity sensor for measurement of various gases such as odor and odor, and the fragrance intensity indicator shows the odorless air as the control value (AU = Arbitrary Unit) value as an arbitrary notation value.

≪ Method for evaluating flavor and flavor persistence >

The fragrance intensity is proportional to the value of the fragrance intensity of the measured sample, and the fragrance diffusivity is gradually diffused. The distance to detect the odor of the nose was used. That is, the higher the fragrance intensity value of the measured sample, the more the fragrance spreads far away, and the range (distance + space) that can be detected by the nose is numerically expressed.

The fragrance persistence was evaluated by adding 0.5 ml of the sample to be measured in an open circular cell (3 cm x h1 cm), leaving it at room temperature for a certain period of time and having a perfume remaining. The evaluation scale and the evaluation score for each item are shown in Table 11 below.

Experimental Example 4: Evaluation of directional quality of gel fragrance for diffuser

The combined fragrance 1 and 2 in Table 9 were added according to the weight ratios shown in Table 12 below to prepare a gel fragrance, and then the directional quality (perfume and fragrance strength) according to the amount of fragrance added was evaluated. The evaluation criteria of the perfume and fragrance strength were the same as those of the flavor evaluation method of Experimental Example 3 above.

Measurement of aromatic strength for indoor diffuser Combination fragrance Award layer Incense Amount
(weight%) Perfume
(AU) Fragrance strength
(AU) Remarks Herbal
Floral Bouquets Distilled water 5 13 2286  - Measured quantity: Measured by putting 2 ㎕ of sample into 3ℓ capacity tetra-odor envelope 8 15 2496 11 20 3059 14 24 3560 Hydrosol 5 14 2246 8 19 2373 11 22 2895 14 24 3494 Hub Green Distilled water 5 16 2246 8 21 2788 11 24 3295 14 27 4558 Hydrosol 5 15 2349 8 22 2669 11 25 3244 14 28 4771

In addition, quality such as flavor, fragrance diffusion, spreading distance, and skin irritancy were evaluated, and the results are shown in Table 13 below.

The directional characteristics and the quality evaluation evaluation method are shown in Table 14 below.

Claims (10)

Mugwort, mugwort, mugwort, jodosan yellow mugwort, and mugwort mugwort; And
Bergamot, Green note, Lemon, Rose marry, Rose, Muguet, Geranium, Hyacinth, Musk, Green series flavor consisting of Iris, Vetiver, and Moss; Or aldehyde C11 undecylenic, Bergamot oil FFC, gamma-Undecalactone, Phenylacetaldehyde, Helional, alpha-damascone alpha-Damascone, benzyl acetate, Methyl Dihydro Jasmonate, cis-Jasmone, Hydrocitrate (HCA), Jasmin Absolute, Hydroxyseat It can be used in the form of hydroxycitronellal, aurantiol, ylang ylang oil, benzoin resinoid light, rose oxide, geranium oil, phenylethyl alcohol Phenyl ethyl alcohol, Rosalve, Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Bracelet, Ethylene Brassylate, And a fragrance of floral bouquets made of Exaltolide
≪ / RTI > The perfume composition according to claim 1, wherein the extract of mugwort is a natural essential oil of mugwort, a hydrosol, or a mixture thereof. A perfume composition comprising the perfume composition of claim 1,
Characterized in that it comprises 3 to 20% by weight of natural essential oil of mugwort, based on the total weight of the combined perfume composition. A perfume composition comprising the combined perfume composition of claim 3 in an oil phase. 5. The perfume composition according to claim 4, wherein the perfume composition comprises a hydrosol of mugwort in an aqueous phase. 5. The perfume composition according to claim 4, wherein the combined perfume composition is 5 to 25% by weight based on the total weight of the perfume composition. 5. The composition according to claim 4, wherein the perfume composition is a liquid gel type,
Wherein the water base is 25 to 35% by weight based on the total weight of the gel base. 8. The composition of claim 7, wherein the perfume composition comprises a water base, a dipropylene glycol, and ethanol in a gel base,
Wherein the weight ratio of the water phase, the dipropylene glycol, and the ethanol is 2.5 to 3.5: 4.5 to 5.5: 1.5 to 2.5 (water: dipropylene glycol: ethanol). A liquid gel-type diffuser comprising the perfume composition of claim 4. (s1) mixing natural essential oil of mugwort with the combination fragrance;
(s2) mixing the hydrosol of mugwort into an aqueous base; And
(s3) adding the combined fragrance to the water base and mixing
/ RTI >
The mugwort includes mugwort mugwort, mugwort mugwort, mugwort mugwort mugwort, and mugwort mugwort mugwort,
The combined fragrance may be selected from the group consisting of Bergamot, Green note, Lemon, Rose marry, Rose, Muguet, Geranium, Hyacinth, Green flavor consisting of musk, iris, vetiver, and moss; Or aldehyde C11 undecylenic, Bergamot oil FFC, gamma-Undecalactone, Phenylacetaldehyde, Helional, alpha-damascone alpha-Damascone, benzyl acetate, Methyl Dihydro Jasmonate, cis-Jasmone, Hydrocitrate (HCA), Jasmin Absolute, Hydroxyseat It can be used in the form of hydroxycitronellal, aurantiol, ylang ylang oil, benzoin resinoid light, rose oxide, geranium oil, phenylethyl alcohol Phenyl ethyl alcohol, Rosalve, Rose absolute, Eugenol alcohol, Indolene, Civet Cat Oil, Sandalwood, Ethylene Bracelet, Ethylene Brassylate, And a fragrance of floral bouquets made of Exaltolide
≪ / RTI >

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