KR101518571B1 - 고강도 및 고인성 비조질 선재 및 그 제조방법 - Google Patents
고강도 및 고인성 비조질 선재 및 그 제조방법 Download PDFInfo
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- KR101518571B1 KR101518571B1 KR1020130100456A KR20130100456A KR101518571B1 KR 101518571 B1 KR101518571 B1 KR 101518571B1 KR 1020130100456 A KR1020130100456 A KR 1020130100456A KR 20130100456 A KR20130100456 A KR 20130100456A KR 101518571 B1 KR101518571 B1 KR 101518571B1
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- 238000000034 method Methods 0.000 title claims description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 33
- 238000001816 cooling Methods 0.000 claims description 32
- 238000005096 rolling process Methods 0.000 claims description 20
- 239000010936 titanium Substances 0.000 claims description 19
- 229910000859 α-Fe Inorganic materials 0.000 claims description 19
- 239000010955 niobium Substances 0.000 claims description 16
- 239000011572 manganese Substances 0.000 claims description 15
- 239000011651 chromium Substances 0.000 claims description 12
- 229910001562 pearlite Inorganic materials 0.000 claims description 11
- 229910052758 niobium Inorganic materials 0.000 claims description 7
- 238000010622 cold drawing Methods 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 6
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000002902 bimodal effect Effects 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 15
- 239000000463 material Substances 0.000 description 29
- 229910000831 Steel Inorganic materials 0.000 description 11
- 239000000203 mixture Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- 239000010959 steel Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 238000001953 recrystallisation Methods 0.000 description 10
- 238000005204 segregation Methods 0.000 description 9
- 239000002244 precipitate Substances 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000013078 crystal Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 229910001566 austenite Inorganic materials 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 238000010791 quenching Methods 0.000 description 4
- 230000000171 quenching effect Effects 0.000 description 4
- 230000002829 reductive effect Effects 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- 230000009466 transformation Effects 0.000 description 4
- 229910001563 bainite Inorganic materials 0.000 description 3
- 238000005098 hot rolling Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 230000035939 shock Effects 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000003303 reheating Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 229910001341 Crude steel Inorganic materials 0.000 description 1
- 229910000742 Microalloyed steel Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 1
- 229910000734 martensite Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/16—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling wire rods, bars, merchant bars, rounds wire or material of like small cross-section
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
- C21D8/065—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires of ferrous alloys
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/24—Ferrous alloys, e.g. steel alloys containing chromium with vanadium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/26—Ferrous alloys, e.g. steel alloys containing chromium with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/28—Ferrous alloys, e.g. steel alloys containing chromium with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
이를 위해, 본 발명에서는 연화 열처리를 실시하지 않고서도 고강도 및 고인성을 확보할 수 있는 비조질 선재 및 이의 제조방법을 제공하고자 한다.
Description
구분 |
성분조성 (중량%) | ||||||
C | Si | Mn | Cr | Nb | Ti | V | |
발명재 1 | 0.12 | 0.21 | 0.71 | 0.42 | 0.03 | 0.005 | - |
발명재 2 | 0.11 | 0.25 | 1.40 | 0.47 | 0.02 | 0.005 | - |
발명재 3 | 0.19 | 0.19 | 1.20 | 0.71 | 0.03 | 0.006 | 0.2 |
비교재 1 | 0.41 | 0.21 | 0.73 | 0.32 | 0.03 | 0.003 | - |
비교재 2 | 0.12 | 0.30 | 0.75 | 0.44 | 0.06 | 0.005 | - |
비교재 3 | 0.13 | 0.25 | 1.40 | 0.47 | 0.02 | 0.002 | - |
구분 |
제조조건 | 물성 | |||||
가열온도 (℃) |
압연온도 (℃) |
냉각속도 (℃/s) |
저온조직 유무 |
FGS (㎛) |
인장강도 (MPa) |
충격치 (J) |
|
발명재 1 | 1120 | 750 | 12 | × | 8 | 690 | 90 |
발명재 2 | 1150 | 770 | 13 | × | 7 | 715 | 93 |
발명재 3 | 1130 | 780 | 21 | × | 8 | 740 | 100 |
비교재 1 | 1100 | 830 | 13 | ○ | 27 | 820 | 13 |
비교재 2 | 1110 | 800 | 10 | × | 23 | 671 | 21 |
비교재 3 |
1120 | 900 | 5 | × | 33 | 662 | 38 |
1010 | 850 | 8 | × | 28 | 693 | 33 |
구분 |
선재 | 신선가공 | |||
인장강도(MPa) | 충격치(J) | 신선량(%) | 인장강도(MPa) | 충격치(J) | |
발명재 1 | 690 | 90 | 60 | 1000 | 89 |
발명재 2 | 715 | 93 | 30 | 860 | 90 |
발명재 3 | 740 | 100 | 70 | 1100 | 93 |
비교재 1 | 820 | 13 | (단선) | - | - |
비교재 2 | 671 | 21 | 40 | 870 | 15 |
비교재 3 |
662 | 38 | 60 | 943 | 22 |
693 | 33 | 60 | 870 | 23 |
Claims (8)
- 중량%로, 탄소(C): 0.05~0.30%, 실리콘(Si): 0.1~0.4%, 망간(Mn): 0.3~1.5%, 크롬(Cr): 0.3~2.0%, 니오븀(Nb): 0.005~0.040%를 포함하고, 티타늄(Ti): 0.005~0.040% 및 바나듐(V): 0.05~0.50% 중 1종 이상, 잔부 Fe 및 불가피한 불순물을 포함하고, 미세조직으로 페라이트 단상 또는 페라이트 및 펄라이트 복합조직으로 이루어지고, 상기 펄라이트는 면적분율로 20% 이하로 포함하는 고강도 및 고인성 비조질 선재.
- 삭제
- 제 1항에 있어서,
상기 페라이트는 평균 결정립 크기가 15㎛ 이하인 고강도 및 고인성 비조질 선재.
- 제 1항에 있어서,
상기 선재의 인장강도는 400~700MPa인 고강도 및 고인성 비조질 선재.
- 제 1항에 있어서,
상기 선재는 냉간신선 후 800~1400MPa의 인장강도와 80J 이상의 V-충격인성을 갖는 고강도 및 고인성 비조질 선재.
- 중량%로, 탄소(C): 0.05~0.30%, 실리콘(Si): 0.1~0.4%, 망간(Mn): 0.3~1.5%, 크롬(Cr): 0.3~2.0%, 니오븀(Nb): 0.005~0.040%를 포함하고, 티타늄(Ti): 0.005~0.040% 및 바나듐(V): 0.05~0.50% 중 1종 이상, 잔부 Fe 및 불가피한 불순물을 포함하는 빌렛을 얻는 단계;
상기 빌렛을 1100~1250℃에서 60분 이하로 가열하는 단계;
상기 가열된 빌렛을 Ar1~Ar3의 2상역 온도구간에서 선재압연하는 단계;
상기 선재압연 후 10~40℃/s의 냉각속도로 냉각하는 단계; 및
상기 냉각 후 공냉하는 단계
를 포함하는 고강도 및 고인성 비조질 선재의 제조방법.
- 제 6항에 있어서,
상기 Ar1~Ar3의 2상역 온도구간은 650~850℃인 고강도 및 고인성 비조질 선재의 제조방법.
- 제 6항에 있어서,
상기 냉각 단계는 400~650℃에서 냉각을 종료하는 것인 고강도 및 고인성 비조질 선재의 제조방법.
Priority Applications (1)
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KR1020130100456A KR101518571B1 (ko) | 2013-08-23 | 2013-08-23 | 고강도 및 고인성 비조질 선재 및 그 제조방법 |
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KR1020130100456A KR101518571B1 (ko) | 2013-08-23 | 2013-08-23 | 고강도 및 고인성 비조질 선재 및 그 제조방법 |
Publications (2)
Publication Number | Publication Date |
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KR20150022492A KR20150022492A (ko) | 2015-03-04 |
KR101518571B1 true KR101518571B1 (ko) | 2015-05-07 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019132195A1 (ko) * | 2017-12-26 | 2019-07-04 | 주식회사 포스코 | 냉간압조용 선재, 이를 이용한 가공품 및 이들의 제조방법 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101758470B1 (ko) | 2015-11-12 | 2017-07-17 | 주식회사 포스코 | 냉간가공성이 우수한 비조질 선재 및 그 제조방법 |
KR101839240B1 (ko) * | 2016-11-16 | 2018-03-16 | 주식회사 포스코 | 냉간 가공성이 우수한 고성형 저탄소 선재 및 이의 제조방법 |
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2013
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019132195A1 (ko) * | 2017-12-26 | 2019-07-04 | 주식회사 포스코 | 냉간압조용 선재, 이를 이용한 가공품 및 이들의 제조방법 |
US11441202B2 (en) | 2017-12-26 | 2022-09-13 | Posco | Wire rod for cold heading, processed product using same, and manufacturing method therefor |
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