[go: up one dir, main page]

KR100639201B1 - Titanium Silicide Formation Method of Semiconductor Device - Google Patents

Titanium Silicide Formation Method of Semiconductor Device Download PDF

Info

Publication number
KR100639201B1
KR100639201B1 KR1020000037123A KR20000037123A KR100639201B1 KR 100639201 B1 KR100639201 B1 KR 100639201B1 KR 1020000037123 A KR1020000037123 A KR 1020000037123A KR 20000037123 A KR20000037123 A KR 20000037123A KR 100639201 B1 KR100639201 B1 KR 100639201B1
Authority
KR
South Korea
Prior art keywords
forming
titanium silicide
semiconductor device
thin film
titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020000037123A
Other languages
Korean (ko)
Other versions
KR20020002812A (en
Inventor
서유석
박대규
차태호
조흥재
Original Assignee
주식회사 하이닉스반도체
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 하이닉스반도체 filed Critical 주식회사 하이닉스반도체
Priority to KR1020000037123A priority Critical patent/KR100639201B1/en
Publication of KR20020002812A publication Critical patent/KR20020002812A/en
Application granted granted Critical
Publication of KR100639201B1 publication Critical patent/KR100639201B1/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
    • H01L21/28518Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table the conductive layers comprising silicides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/283Deposition of conductive or insulating materials for electrodes conducting electric current
    • H01L21/285Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
    • H01L21/28506Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
    • H01L21/28512Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
    • H01L21/28556Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table by chemical means, e.g. CVD, LPCVD, PECVD, laser CVD
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/71Manufacture of specific parts of devices defined in group H01L21/70
    • H01L21/768Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
    • H01L21/76838Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
    • H01L21/76886Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances
    • H01L21/76889Modifying permanently or temporarily the pattern or the conductivity of conductive members, e.g. formation of alloys, reduction of contact resistances by forming silicides of refractory metals

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Power Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrodes Of Semiconductors (AREA)
  • Chemical Vapour Deposition (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)

Abstract

반도체소자의 티타늄실리사이드 형성방법은, 실리콘기판과 금속간의 오믹(ohmic) 콘택 및 금속배선을 형성시키기 위한 티타늄실리사이드(TiSi2)의 형성방법에 관한 것이다.The method for forming titanium silicide of a semiconductor device relates to a method of forming titanium silicide (TiSi 2 ) for forming ohmic contacts and metal wiring between a silicon substrate and a metal.

본 형성방법은 기판 상부에 절연층을 형성하는 단계, 이 상부에 티타늄실리사이드박막을 형성하는 단계 및, 티타늄박막을 형성하는 단계를 포함하고 있다.The present method includes forming an insulating layer on the substrate, forming a titanium silicide thin film on the substrate, and forming a titanium thin film.

따라서 본 발명은 ALE 화학기상증착법에 따라 원하는 조성과 두께로 조절함으로써 금속배선을 위한 티타늄실리사이드를 형성하는 효과가 있다.Therefore, the present invention has the effect of forming titanium silicide for metal wiring by controlling to a desired composition and thickness according to the ALE chemical vapor deposition method.

Description

반도체소자의 티타늄실리사이드 형성방법{METHOD OF FABRICATING TITANUM SILYCIDE IN SEMICONDUCTOR DEVICE}Titanium silicide formation method of semiconductor device {METHOD OF FABRICATING TITANUM SILYCIDE IN SEMICONDUCTOR DEVICE}

도 1a 내지 도 1c는 본 발명의 일실시예에 따른 반도체소자의 티타늄실리사이드 형성방법을 설명하기 위한 도면.1A to 1C illustrate a method of forming titanium silicide of a semiconductor device according to an embodiment of the present invention.

< 도면의 주요 부분에 대한 부호의 설명 ><Description of Symbols for Main Parts of Drawings>

10 : 기판 12 : 절연층10 substrate 12 insulating layer

14 : TiSi2박막 16 : Ti박막14 TiSi 2 thin film 16 Ti thin film

본 발명은 반도체 제조공정에 관한 것으로, 자세하게는 실리콘기판과 금속간의 오믹(ohmic) 콘택 및 금속배선을 형성시키기 위한, 반도체소자의 티타늄실리사이드 형성방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a semiconductor manufacturing process, and more particularly, to a method for forming titanium silicide in a semiconductor device for forming ohmic contacts and metal wiring between a silicon substrate and a metal.

반도체소자의 제작에는 많은 콘택방법이 사용된다. 이러한 콘택은 완성된 반도체소자의 동작 전류 및 안정성 등에 관련된다. 따라서 보다 안정적이고 간단한 방법으로 콘택을 실시하기 위한 연구가 활발히 진행되고 있다. Many contact methods are used to fabricate semiconductor devices. This contact is related to the operating current and stability of the completed semiconductor device. Therefore, researches for conducting contacts in a more stable and simple manner have been actively conducted.                         

콘택을 실시함에 있어서, 종래에는 먼저 실리콘기판상에 이온주입방법에 의해 원하는 종류의 이온을 도핑한다. 이 후 적당한 두께의 티타늄(Ti)박막을 증착한다. 다음, RTP 방식으로 짧은 시간 동안 열처리를 수행하여 확산시킴으로써 티타늄실리사이드(이하 'TiSi2'라 함)에 의한 콘택을 형성하였다.In carrying out the contact, conventionally, a desired type of ions are first doped by an ion implantation method on a silicon substrate. After that, a titanium (Ti) thin film of a suitable thickness is deposited. Next, a contact by titanium silicide (hereinafter referred to as 'TiSi 2 ') was formed by diffusion by performing heat treatment for a short time in the RTP method.

그러나, 전술한 종래 RTP공정의 확산에 의한 콘택방법은 다음과 같은 문제점이 있다. 즉 RTP공정의 확산에 의해서는 정확한 두께조절이 어렵기 때문에 티타늄실리사이드(TiSi2)를 균일한 두께로 형성시키기 어렵다. 또한 RTP 공정시 티타늄(Ti)원소가 이온주입된 이온들과 반응을 일으키기도 한다. 이 때문에 콘택저항이 불안정하고 누설전류가 증가해 반도체소자의 전반적인 동작특성을 저해하는 문제점이 있다.However, the above-described contact method by the diffusion of the conventional RTP process has the following problems. That is, it is difficult to form a titanium silicide (TiSi 2 ) to a uniform thickness because it is difficult to precisely control the thickness by the diffusion of the RTP process. In addition, during the RTP process, titanium (Ti) elements react with the ions implanted. For this reason, there is a problem that the contact resistance is unstable and the leakage current increases, which hinders the overall operating characteristics of the semiconductor device.

따라서 전술한 문제점을 해결하기 위한 본 발명의 목적은, 티타늄실리사이드(TiSi2)를 ALE(Atomic Layer Epitaxy) 화학기상증착(CVD; Chemical Vapor Deposition) 방법에 따라 원하는 조성과 두께로 조절함으로써 금속배선 형성하기 위한, 반도체소자의 티타늄실리사이드 형성방법을 제공하는 데 있다.Accordingly, an object of the present invention for solving the above-described problems is to form a metal wiring by adjusting titanium silicide (TiSi 2 ) to a desired composition and thickness according to ALE (Atomic Layer Epitaxy) Chemical Vapor Deposition (CVD) method. The present invention provides a method for forming titanium silicide of a semiconductor device.

본 발명에 따른 반도체소자의 티타늄실리사이드 형성방법은, 반도체소자의 제조공정에 있어서, Titanium silicide forming method of a semiconductor device according to the present invention, in the manufacturing process of the semiconductor device,

도전층이 형성된 기판 상부에 절연층을 형성하고 상기 도전층이 노출되도록 패터닝하여 콘택홀을 형성하는 제1단계; 상기 절연층의 상부에 상기 콘택홀을 통해 상기 노출된 도전층과 접촉되게 티타늄실리사이드박막을 ALE CVD방법에 의해 형성하는 제2단계; 및, 상기 형성된 티타늄실리사이드 박막 상부에 티타늄박막을 형성하는 제3단계를 포함한다.Forming a contact hole by forming an insulating layer on the substrate on which the conductive layer is formed and patterning the conductive layer to expose the conductive layer; Forming a titanium silicide thin film by an ALE CVD method on the insulating layer to be in contact with the exposed conductive layer through the contact hole; And a third step of forming a titanium thin film on the formed titanium silicide thin film.

이하 도면들을 참조하여 본 발명의 바람직한 실시예를 자세히 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.

도 1a 내지 도 1c는 본 발명의 일실시예에 따른 반도체소자의 티타늄실리사이드 형성방법을 설명하기 위한 도면이다.1A to 1C are diagrams for describing a method of forming titanium silicide of a semiconductor device according to an embodiment of the present invention.

본 발명은 반도체소자의 금속배선방법 중 종래의 물리기상증착법이나 화학기상증착법이 아닌 ALE CVD를 이용하여, 금속배선의 결함이 적고 두께 조절이 가능한 티타늄실리사이드(TiSi2) 형성방법에 관한 것이다. The present invention relates to a method for forming titanium silicide (TiSi 2 ) with less defects in metal wiring and controlling thickness by using ALE CVD rather than the conventional physical vapor deposition or chemical vapor deposition among the metal wiring methods of semiconductor devices.

도 1a에 도시한 바와 같이, 본 발명에 따른 일실시예는 먼저 금속배선을 형성하고자 하는 기판(10) 상부에 절연층(12)을 증착한다. 그리고 패턴 및 식각공정에 따라 콘택홀을 형성한다. As shown in FIG. 1A, an embodiment according to the present invention first deposits an insulating layer 12 on an upper portion of a substrate 10 on which metal wiring is to be formed. Then, contact holes are formed according to patterns and etching processes.

이후 도 1b와 같이, 이 상부에 TiSi2박막(14)을 형성하기 위한 공정을 실시한다. 이 공정은 먼저 ALE CVD방법의 순환소스공급방식에 따라 소스로 티타늄클로라이드(이하 'TiCl4'라 함)를 0.1∼1분간 10∼1000sccm의 유량만큼 한정적으로 공급하여 200∼700℃의 기판상에 흡착시킨다. 다음 아르곤(Ar)가스를 10∼1000sccm만큼 흘려 소스퍼지(source purge)를 0.1∼2분간 실시한다. 이 후 이미 흡착된 TiCl4 상부에 반응가스로 SiH4를 약 0.1∼1분 동안 10∼1000 sccm 정도 흘려 흡착시킴으로써 [화학식 1]과 같은 반응을 일으킨다. Thereafter, as shown in FIG. 1B, a process for forming the TiSi 2 thin film 14 is performed thereon. This process first supplies titanium chloride (hereinafter referred to as 'TiCl 4 ') to the source in a limited flow rate of 10 to 1000 sccm for 0.1 to 1 minute according to the circulating source supply method of the ALE CVD method. Adsorb. Next, argon (Ar) gas is flowed by 10 to 1000 sccm, and source purge is performed for 0.1 to 2 minutes. Thereafter, SiH 4 is adsorbed by flowing about 10 to 1000 sccm for about 0.1 to 1 minute on the TiCl 4 adsorbed to the reaction gas to generate a reaction as shown in [Formula 1].

TiCl4 (g) + 2SiH4 (g) = TiSl2 (s) + 4HCl (g) + 2H2 (g) TiCl 4 (g) + 2 SiH 4 (g) = TiSl 2 (s) + 4HCl (g) + 2H 2 (g)

이 때 반응기의 압력은 0.1∼5 Torr 정도로 유지한다. 그 후 반응기체와 부산물 HCl에 아르곤(Ar)가스를 흘려 퍼지(purge) 시킨다. 그리고 위와 같은 과정을 5∼2000회 정도 반복하여, 10∼500Å두께의 TiSi2박막(14)을 형성한다.At this time, the pressure of the reactor is maintained at about 0.1 to 5 Torr. Thereafter, argon (Ar) gas is flowed into the reactor and by-product HCl to purge. Then, the above process is repeated about 5 to 2000 times to form a TiSi 2 thin film 14 having a thickness of 10 to 500 kHz.

이 후 도 1c와 같이, 형성된 TiSi2층(14) 상부에 Ti박막(16)을 형성한다. 이 공정에서는 반응가스로 SiH4대신 H2를 흘려준다. 이 경우에는 이미 형성된 TiSi2박막(14)표면에서 다시 TiCl4가 흡착되어 아래 [화학식 2]와 같은 반응을 일으킨다.Thereafter, as shown in FIG. 1C, the Ti thin film 16 is formed on the formed TiSi 2 layer 14. In this process, H 2 is flowed into the reaction gas instead of SiH 4 . In this case, TiCl 4 is adsorbed again on the surface of the already formed TiSi 2 thin film 14 to cause a reaction as shown in [Formula 2].

TiCl4 (g) + 2H2 (g) = Ti (s) + 4HCl (g)TiCl 4 (g) + 2H 2 (g) = Ti (s) + 4HCl (g)

이러한 과정을 약 5∼2000회 반복하여 10∼600Å정도의 Ti박막(16)을 형성한다. 그리고 반복을 끝낸 후에는 반응기체와 부산물을 퍼지시킴으로써, 본 발명에 따른 반도체소자의 티타늄실리사이드 형성한다.This process is repeated about 5 to 2000 times to form a Ti thin film 16 of about 10 to 600 mV. After the completion of the repetition, titanium silicide of the semiconductor device according to the present invention is formed by purging the reactant and by-products.

전술한 바와 같이, 본 발명은 ALE 화학기상증착법에 따라 원하는 조성과 두께로 조절함으로써 금속배선을 위한 티타늄실리사이드(TiSi2)를 형성하는 효과가 있다.As described above, the present invention has an effect of forming titanium silicide (TiSi 2 ) for metal wiring by controlling to a desired composition and thickness according to the ALE chemical vapor deposition method.

Claims (9)

반도체소자의 제조공정에 있어서, In the manufacturing process of a semiconductor device, 도전층이 형성된 기판 상부에 절연층을 형성하고 상기 도전층이 노출되도록 패터닝하여 콘택홀을 형성하는 제1단계;Forming a contact hole by forming an insulating layer on the substrate on which the conductive layer is formed and patterning the conductive layer to expose the conductive layer; 상기 절연층의 상부에 상기 콘택홀을 통해 상기 노출된 도전층과 접촉되게 티타늄실리사이드박막을 ALE CVD방법에 의해 형성하는 제2단계; 및,Forming a titanium silicide thin film by an ALE CVD method on the insulating layer to be in contact with the exposed conductive layer through the contact hole; And, 상기 형성된 티타늄실리사이드 박막 상부에 티타늄박막을 형성하는 제3단계를 포함하는 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.And a third step of forming a titanium thin film on the formed titanium silicide thin film. 삭제delete 제 1항에 있어서, 상기 제2단계는The method of claim 1, wherein the second step 0.1∼1분간 10∼1000sccm의 유량만큼 한정적으로 공급하여, 200∼700℃의 기판상에 흡착시키는 단계인 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.A method of forming a titanium silicide of a semiconductor device, characterized in that the step of supplying a limited flow rate of 10 to 1000 sccm for 0.1 to 1 minute, adsorbed onto a substrate of 200 to 700 ℃. 제 1항에 있어서, 상기 제2단계는The method of claim 1, wherein the second step 0.1∼2분 동안, 아르곤(Ar)가스를 10∼1000sccm만큼 흘려 소스퍼지(source purge)를 실시하는 단계를 더 포함하는 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.A method of forming titanium silicide in a semiconductor device, the method comprising: performing source purge by flowing argon (Ar) gas by 10 to 1000 sccm for 0.1 to 2 minutes. 제 1항에 있어서, 상기 제2단계는The method of claim 1, wherein the second step 흡착된 TiCl4 상부에 반응가스로 SiH4를 약 0.1∼1분 동안 공정압력을 0.1∼5 Torr 정도로 유지한 상태에서, 10∼1000 sccm 정도 흘려 흡착시키는 단계인 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.Titanium of the semiconductor device characterized in that the step of adsorbing about 10 to 1000 sccm flowing SiH 4 with a reaction gas on the adsorbed TiCl 4 while maintaining a process pressure of about 0.1 to 5 Torr for about 0.1 to 1 minutes Silicide formation method. 제 1항에 있어서, 상기 제2단계는The method of claim 1, wherein the second step 아르곤(Ar)가스를 흘려 퍼지(purge)시키는 단계를 더 포함하는 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.A method of forming a titanium silicide of a semiconductor device, further comprising the step of purging argon (Ar) gas. 제 1항에 있어서, 상기 제2단계는The method of claim 1, wherein the second step 상기 제2단계를 5∼2000회 정도 반복적으로 실시하여 상기 티타늄실리사이드박막을 10∼500Å두께로 형성하는 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.And repeating the second step about 5 to 2000 times to form the titanium silicide thin film at a thickness of 10 to 500 microseconds. 제 1항에 있어서, 상기 제3단계는The method of claim 1, wherein the third step 반응가스로 H2를 이용하는 것을 특징으로 하는, 반도체소자의 티타늄실리사 이드 형성방법.A method of forming titanium silicide in a semiconductor device, characterized in that H 2 is used as the reaction gas. 제 1항에 있어서, 상기 제3단계는The method of claim 1, wherein the third step 상기 제3단계를 5∼2000회 정도 반복적으로 실시하여 상기 티타늄박막을 10∼600Å두께로 형성하는 것을 특징으로 하는, 반도체소자의 티타늄실리사이드 형성방법.And repeating the third step 5 to 2000 times to form the titanium thin film with a thickness of 10 to 600 microseconds.
KR1020000037123A 2000-06-30 2000-06-30 Titanium Silicide Formation Method of Semiconductor Device Expired - Fee Related KR100639201B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020000037123A KR100639201B1 (en) 2000-06-30 2000-06-30 Titanium Silicide Formation Method of Semiconductor Device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020000037123A KR100639201B1 (en) 2000-06-30 2000-06-30 Titanium Silicide Formation Method of Semiconductor Device

Publications (2)

Publication Number Publication Date
KR20020002812A KR20020002812A (en) 2002-01-10
KR100639201B1 true KR100639201B1 (en) 2006-10-31

Family

ID=19675377

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020000037123A Expired - Fee Related KR100639201B1 (en) 2000-06-30 2000-06-30 Titanium Silicide Formation Method of Semiconductor Device

Country Status (1)

Country Link
KR (1) KR100639201B1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10062567B2 (en) 2015-06-30 2018-08-28 International Business Machines Corporation Reducing autodoping of III-V semiconductors by atomic layer epitaxy (ALE)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100538806B1 (en) 2003-02-21 2005-12-26 주식회사 하이닉스반도체 SEMICONDUCTOR DEVICE WITH EPITAXIAL C49-TiSi2 LAYER AND METHOD FOR FABRICATING THE SAME

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05243179A (en) * 1992-02-29 1993-09-21 Sony Corp Method of forming barrier metal layer of semiconductor device
JPH08186173A (en) * 1994-12-28 1996-07-16 Nec Corp Manufacture of semiconductor device
KR19990015715A (en) * 1997-08-08 1999-03-05 윤종용 Metal wiring layer formation method
JP2000133617A (en) * 1998-10-23 2000-05-12 Oki Electric Ind Co Ltd TiSi2 LAYER FORMATION AND MANUFACTURE OF SEMICONDUCTOR DEVICE PROVIDED WITH THE LAYER

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05243179A (en) * 1992-02-29 1993-09-21 Sony Corp Method of forming barrier metal layer of semiconductor device
JPH08186173A (en) * 1994-12-28 1996-07-16 Nec Corp Manufacture of semiconductor device
KR19990015715A (en) * 1997-08-08 1999-03-05 윤종용 Metal wiring layer formation method
JP2000133617A (en) * 1998-10-23 2000-05-12 Oki Electric Ind Co Ltd TiSi2 LAYER FORMATION AND MANUFACTURE OF SEMICONDUCTOR DEVICE PROVIDED WITH THE LAYER

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10062567B2 (en) 2015-06-30 2018-08-28 International Business Machines Corporation Reducing autodoping of III-V semiconductors by atomic layer epitaxy (ALE)

Also Published As

Publication number Publication date
KR20020002812A (en) 2002-01-10

Similar Documents

Publication Publication Date Title
US7521379B2 (en) Deposition and densification process for titanium nitride barrier layers
JP2001303251A (en) Method of manufacturing barrier metal film using atomic layer deposition method
KR100519376B1 (en) Method for Forming Barrier Layer of Semiconductor Device
US7358188B2 (en) Method of forming conductive metal silicides by reaction of metal with silicon
KR100477816B1 (en) Method for forming titanium silicide contact of semiconductor device
KR20220044601A (en) Reduced line bending during metal filling process
KR101628843B1 (en) Method for forming ruthenium containing thin film by atomic layer deposition
KR100447031B1 (en) Method of forming tungsten silicide film
US7411254B2 (en) Semiconductor substrate
US6602785B1 (en) Method of forming a conductive contact on a substrate and method of processing a semiconductor substrate using an ozone treatment
KR100639201B1 (en) Titanium Silicide Formation Method of Semiconductor Device
KR0161889B1 (en) Formation method of wiring in semiconductor device
KR100615602B1 (en) Methods of forming a titanium nitride film having a smooth surface and methods of forming a semiconductor device using the same
KR100609049B1 (en) Metal wiring formation method of semiconductor device
KR20010007527A (en) Method of silicide formation in a semiconductor device and processor readable storage medium using the same
JP3801923B2 (en) Method for forming tungsten silicide
KR100248145B1 (en) Process for forming metal wire of semiconductor device
KR100513810B1 (en) FORMING METHOD OF Ti LAYER USING ATOMIC LAYER DEPOSITION BY CATALYST
KR100268791B1 (en) Metal wiring formation method of semiconductor device
KR20040051700A (en) Method for forming metal line of semiconductor device
KR20080057086A (en) Method for manufacturing bit line of semiconductor device
KR100524921B1 (en) Manufacturing method of barrier layer for semiconductor device
KR100273716B1 (en) Manufacturing method of semiconductor device
TW202447723A (en) Formation of silicon-and-metal-containing materials for hardmask applications
TW202503092A (en) Formation of silicon-and-metal-containing materials for hardmask applications

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 20000630

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20050308

Comment text: Request for Examination of Application

Patent event code: PA02011R01I

Patent event date: 20000630

Comment text: Patent Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20060426

Patent event code: PE09021S01D

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 20060926

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20061020

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20061023

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20090922

Start annual number: 4

End annual number: 4

FPAY Annual fee payment

Payment date: 20100920

Year of fee payment: 5

PR1001 Payment of annual fee

Payment date: 20100920

Start annual number: 5

End annual number: 5

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee