KR0142602B1 - Method for manufacturing a flash Y pyrom device - Google Patents
Method for manufacturing a flash Y pyrom deviceInfo
- Publication number
- KR0142602B1 KR0142602B1 KR1019950006087A KR19950006087A KR0142602B1 KR 0142602 B1 KR0142602 B1 KR 0142602B1 KR 1019950006087 A KR1019950006087 A KR 1019950006087A KR 19950006087 A KR19950006087 A KR 19950006087A KR 0142602 B1 KR0142602 B1 KR 0142602B1
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- South Korea
- Prior art keywords
- oxide film
- voltage transistor
- film
- region
- forming
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 239000010410 layer Substances 0.000 claims description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 25
- 229910052710 silicon Inorganic materials 0.000 claims description 25
- 239000010703 silicon Substances 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 23
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims description 18
- 229920005591 polysilicon Polymers 0.000 claims description 18
- 150000004767 nitrides Chemical class 0.000 claims description 12
- 238000005530 etching Methods 0.000 claims description 11
- 238000000059 patterning Methods 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 9
- 239000011229 interlayer Substances 0.000 claims description 9
- 238000000206 photolithography Methods 0.000 claims description 9
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 238000005468 ion implantation Methods 0.000 claims description 5
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 3
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims 1
- 230000002093 peripheral effect Effects 0.000 abstract description 3
- 229920002120 photoresistant polymer Polymers 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
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- Non-Volatile Memory (AREA)
- Semiconductor Memories (AREA)
Abstract
본 발명은 플래쉬 이이피롬(FLASH EEPROM) 소자의 제조방법에 관한 것으로, 메모리셀(Cell)의 유전체막의 ONO(하부산화막-질화막-상부산화막)구조로 이루어지는 플래쉬 이이피롬 소자의 제조에 있어, 고전압용 트랜지스터의 게이트산화막특성을 향상시키기 위하여 주변지역에 형성되는 고전압용 트랜지스터의 게이트산화막을 유전체막의 상부산화막을 이용하여 형성하므로써 소자의 신뢰성을 향상시키며 공정을 단순화시킬 수 있도록 한 플래쉬 이이피롬 소자의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a method for manufacturing a flash EEPROM device. The present invention relates to a method for manufacturing a flash easy pyrom device comprising an ONO (lower oxide film-nitride film-top oxide film) structure of a dielectric film of a memory cell. A method of manufacturing a flash Y pyrom device in which a gate oxide film of a high voltage transistor formed in a peripheral region is formed by using an upper oxide film of a dielectric film to improve the gate oxide film characteristics of the transistor, thereby improving the reliability of the device and simplifying the process. It is about.
Description
제1a 내지 제1d도는 종래 플래쉬 이이피롬 소자의 제조방법을 설명하기 위한 소자의 단면도.1A to 1D are cross-sectional views of a device for explaining a method of manufacturing a conventional flash ypyrom device.
제2a 내지 제2e도는 본 발명에 따른 플래쉬 이이피롬 소자의 제조방법을 설명하기 위한 소자의 단면도.2A through 2E are cross-sectional views of a device for explaining a method of manufacturing a flash y-pyrom device according to the present invention.
*도면의 주요부분에 대한 부호의 설명* Explanation of symbols for main parts of the drawings
1:실리콘기판기2:필드산화막1: Silicon substrate 2: Field oxide film
3 및 13:터널산화막4 및 14:제1폴리실리콘층3 and 13: tunnel oxide 4 and 14: first polysilicon layer
4A 및 14A:플로팅게이트5 및 12:유전체막4A and 14A: Floating gates 5 and 12: Dielectric film
6 및 18:제2폴리실리콘층6A 및 18A:콘트롤게이트6 and 18: second polysilicon layer 6A and 18A: control gate
7:절연막8 및 20:층간절연막7: insulating film 8 and 20: interlayer insulating film
9 및 19:소오스 및 드레인영역10 및 10A:1차 및 2차 게이트산화막9 and 19: source and drain regions 10 and 10A: primary and secondary gate oxides
11 및 21:게이트산화막15 및 17:하부 및 상부산화막11 and 21: gate oxide 15 and 17: lower and upper oxide
16:질화막18B:게이트전극16: Nitride film 18B: Gate electrode
본 발명은 플래쉬 아이피롬(FLASH EEPROM) 소자의 제조방법에 관한 것으로, 특히 메모리셀(Cell)의 유전체막이 ONO(하부산화막-질화막-상부산화막)구조로 이루어지는 플래쉬 이이피롬 소자의 제조에 있어, 주변지역에 형성되는 고전압용 트랜지스터의 게이트산화막을 유전체막의 상부산화막을 이용하여 형성하므로써 게이트산화막의 특성을 향상시키며 공정을 단순화시킬 수 있도록 한 플래쉬 이이피롬 소자의 제조방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a flash EEPROM device, and more particularly, in the manufacture of a flash Y pyrom device in which a dielectric film of a memory cell has an ONO (lower oxide film-nitride film-top oxide film) structure. The present invention relates to a method for manufacturing a flash Y pyrom device in which a gate oxide film of a high voltage transistor formed in a region is formed by using an upper oxide film of a dielectric film to improve the characteristics of the gate oxide film and simplify the process.
일반적으로 반도체 소자의 제조공정에서 전기적인 프로그램(Program) 및 소거(Erase) 기능을 함께 가지는 플래쉬 이이피롬(Electrically Erasable Read Only Memory; EEPROM) 소자는 고전압(High Voltage)을 요구하는 동작원리 때문에, 주변회로에 고전압용 트랜지스터 및 저전압용 트랜지스터가 각각 필요하다.In general, an electrically erasable read only memory (EEPROM) device having both an electric program and an erase function in a semiconductor device manufacturing process has a high voltage. The circuit requires a high voltage transistor and a low voltage transistor, respectively.
그러면 종래 플래쉬 이이피롬 소자의 제조방법을 제1A 내지 제1D도를 통해 설명하면 다음과 같다.A method of manufacturing a conventional flash ypyrom device will now be described with reference to FIGS. 1A to 1D.
제1a 내지 제1d도는 종래 플래쉬 이이피롬 소자의 제조방법을 설명하기 위한 소자의 단면도로서,1A to 1D are cross-sectional views of a device for describing a method of manufacturing a conventional flash ypyrom device.
제1a도는 메모리셀지역(MC), 고전압용 트랜지스터지역(HV) 및 저전압용 트랜지스터지역(LV)을 전기적으로 각각 분리시키기 위하여 실리콘기판(1)의 필드영역(F)에 필드산화막(2)을 형성한 후 전체 상부면에 터널산화막(3), 제1폴리실리콘층(4), 유전체막(5) 및 제2폴리실리콘층(6)을 순차적으로 형성하고 그 상부에 TEOS을 증착하여 절연막(7)을 형성한 상태의 단면도이다.FIG. 1A shows a field oxide film 2 in the field region F of the silicon substrate 1 to electrically separate the memory cell region MC, the high voltage transistor region HV and the low voltage transistor region LV, respectively. After the formation, the tunnel oxide film 3, the first polysilicon layer 4, the dielectric film 5, and the second polysilicon layer 6 are sequentially formed on the entire upper surface, and TEOS is deposited thereon to form an insulating film ( It is sectional drawing of the state which formed 7).
제1b도는 전체 상부면에 감광막(도시않됨)을 도포한 후 메모리셀의 게이트전극용 마스크를 이용한 사진 및 식각공정을 통해 상기 감광막을 패터닝하고, 패터닝된 감광막을 마스크로 이용한 자기정렬(Self-Align)식각 방법으로 상기 절연막(7), 제2폴리실리콘층(6), 유전체막(5), 제1폴리실리콘층(4) 및 터널산화막(3)을 순차적으로 패터닝하여 상기 메모리셀지역(MC)에 터널산화막(3), 플로팅게이트(4A), 유전체막(5), 콘트롤게이트(6A) 및 절연막(7)이 적층된 구조의 게이트전극을 형성한다.FIG. 1B is a photosensitive film (not shown) applied to the entire upper surface, and the photoresist is patterned through a photolithography and etching process using a gate electrode mask of a memory cell, and self-aligned using the patterned photoresist as a mask. The memory cell region MC by sequentially patterning the insulating film 7, the second polysilicon layer 6, the dielectric film 5, the first polysilicon layer 4, and the tunnel oxide film 3 by an etching method. ), A gate electrode having a structure in which the tunnel oxide film 3, the floating gate 4A, the dielectric film 5, the control gate 6A, and the insulating film 7 are stacked.
이후 불순물이온주입공정을 실시하여 상기 메모리셀지역(MC)의 노출된 실리콘기판(1)에 소오스 및 드레인영역(9)을 형성한 상태의 단면도이다.After that, the source and drain regions 9 are formed in the exposed silicon substrate 1 in the memory cell region MC by performing an impurity ion implantation process.
제1c도는 고전압용 트랜지스터지역(HV) 및 저전압용 트랜지스터지역(LV)의 노출된 실리콘기판(1)에 문턱전압조절용 불순물이온주입을 실시한 후 전체 상부면에 고온산화막과 질화막을 순차적으로 형성하여 층간절연막(8)을 형성하고 상기 고전압용 트랜지스터지역(HV)의 실리콘기판(1)이 노출되도록 상기 층간절연막(8)을 패터닝한 다음 산화공정을 실시하여 상기 노출된 실리콘기판(1)에 고전압용 트랜지스터의 1차 게이트산화막(10)을 형성한 상태의 단면도이다.FIG. 1C shows a high-temperature oxide film and a nitride film sequentially formed on the entire upper surface after impurity ion implantation for the threshold voltage is applied to the exposed silicon substrate 1 of the high voltage transistor region HV and the low voltage transistor region LV. The insulating film 8 is formed and the interlayer insulating film 8 is patterned so that the silicon substrate 1 of the high voltage transistor region HV is exposed, and then an oxidation process is performed to apply the high voltage to the exposed silicon substrate 1. It is sectional drawing of the state which formed the primary gate oxide film 10 of a transistor.
제1d도는 제1C도의 상태에서 상기 저전압용 트랜지스터지역(LV)의 실리콘기판(1)이 노출되도록 상기 층간절연막(8)을 패터닝한 다음 산화공정을 실시하여 상기 노출된 실리콘기판(1)에 저전압용 트랜지스터의 게이트산화막(11)을 형성한 상태의 단면도인데, 이때 상기 고전압용 트랜지스터의 1차 게이트산화막(10)도 같이 성장되어 두꺼운 2차 게이트산화막(10A)이 형성된다.In FIG. 1D, the interlayer insulating film 8 is patterned so that the silicon substrate 1 of the low voltage transistor region LV is exposed in the state of FIG. 1C and then subjected to an oxidation process to perform a low voltage on the exposed silicon substrate 1. A cross-sectional view of the gate oxide film 11 of the transistor for forming is shown, wherein the primary gate oxide film 10 of the high voltage transistor is also grown to form a thick secondary gate oxide film 10A.
그런데 상기와 같이 형성되는 고전압용 트랜지스터의 게이트산화막은 두차례의 산화공정을 거치기 때문에 그 두께조절이 어려우며 처음의 산화공정과 두 번째의 산화공정사이에 불순물이 첨가되고 사진공정시 감광막에 의한 오염도 발생되어 게이트산화막의 특성이 저하된다.However, since the gate oxide film of the high voltage transistor formed as described above undergoes two oxidation processes, it is difficult to control its thickness, and impurities are added between the first oxidation process and the second oxidation process and contamination by the photoresist film occurs during the photo process. As a result, the gate oxide film is degraded.
또한 상기 층간절연막으로 이용되는 질화막은 결함(Particle)생성의 원인으로 착용한다.In addition, the nitride film used as the interlayer insulating film is worn as a cause of defect generation.
따라서 본 발명은 메모리셀의 유전체막이 ONO(하부산화막-질화막-상부산화막)구조로 이루어지는 플래쉬 이이피롬 소자의 제조에 있어, 주변지역에 형성되는 고전압용 트랜지스터의 게이트산화막을 유전체막의 상부산화막을 이용하여 형성하므로써 상기한 단점을 해소할 수 있는 플래쉬 이이피롬 소자의 제조방법을 제공하는데 그 목적이 있다.Accordingly, in the manufacture of a flash Y pyrom device in which a dielectric film of a memory cell is formed of an ONO (lower oxide film-nitride film-top oxide film) structure, a gate oxide film of a high voltage transistor formed in a peripheral region is formed by using an upper oxide film of a dielectric film. It is an object of the present invention to provide a method for manufacturing a flash Y pyrom device that can solve the above-mentioned disadvantages by forming.
상기한 목적을 달성하기 위한 본 발명은 메모리셀지역, 고전압용 트랜지스터지역 및 저전압용 트랜지스터지역을 전기적으로 각각 분리시키기 위하여 실리콘기판의 필드영역에 필드산화막을 형성한 후 전체상부면에 터널산화막, 제1폴리실리콘층, 하부산화막 및 질화막을 순차적으로 형성하는 단계와, 상기 단계로부터 플로팅게이트전극용 마스크를 이용한 사진 및 식각공정을 통해 상기 질화막, 하부산화막, 제1폴리실리콘층 및 터널산화막을 순차적으로 패터닝하여 메모리셀지역에 터널산화막, 플로팅게이트, 하부산화막 및 질화막이 적층된 구조를 형성하는 단계와, 상기 단계로부터 상기 고전압용 트랜지스터지역 및 저전압용 트랜지스터지역의 노출된 실리콘기판에 문턱전압조절용 불순물이온주입을 실시한 후 전체 상부면에 상부산화막 및 제2폴리실리콘층을 순차적으로 형성하는 단계와, 상기 단계로부터 콘트롤게이트전극용 마스크를 이용한 사진 및 식각공정을 통해 메모리셀지역의 제2폴리실리콘층 및 상부산화막을 순차적으로 패터닝하여 상기 질화막상에 상부산화막 및 콘트롤게이트가 적층된 구조의 게이트전극을 형성하는 단계와, 상기 단계로부터 고전압용 트랜지스터의 게이트전극용 마스크를 이용한 사진 및 식각공정으로 잔류된 제2폴리실리콘층 및 상부산화막을 순차적으로 패터닝하여 고전압용 트랜지스터지역에 게이트전극을 형성하는 단계와, 상기 단계로부터 불순물이온주입공정을 실시하여 상기 메모리셀지역의 노출된 실리콘기판에 소오스 및 드레인영역을 형성하는 단게와, 상기 단계로부터 전체상부면에 층간절연막을 형성한 후 상기 저전압용 트랜지스터지역의 실리콘기판이 노출되도록 상기 층간절연막을 패터닝하고 산화공정을 실시하여 상기 노출된 실리콘기판에 저전압용 트랜지스터의 게이트산화막을 형성하는 단계로 이루어지는 것을 특징으로 한다.In order to achieve the above object, the present invention provides a field oxide film in a field region of a silicon substrate to electrically separate a memory cell region, a high voltage transistor region, and a low voltage transistor region, respectively. Sequentially forming the polysilicon layer, the lower oxide film, and the nitride film, and sequentially forming the nitride film, the lower oxide film, the first polysilicon layer, and the tunnel oxide film through a photolithography and an etching process using a mask for the floating gate electrode from the step. Forming a structure in which a tunnel oxide film, a floating gate, a lower oxide film, and a nitride film are stacked in a memory cell region by patterning, and from the step, an impurity ion for adjusting a threshold voltage on an exposed silicon substrate of the high voltage transistor region and the low voltage transistor region; After the injection, the upper oxide film and the second upper surface Sequentially forming the silicon layer, patterning the second polysilicon layer and the upper oxide layer in the memory cell region sequentially through the photolithography and etching process using the mask for the control gate electrode. And forming a gate electrode having a structure in which the control gates are stacked, and sequentially patterning the second polysilicon layer and the upper oxide layer remaining in the photo and etching process using the gate electrode mask of the high voltage transistor. Forming a gate electrode in the semiconductor transistor region, and performing source impurity ion implantation from the step to form source and drain regions on the exposed silicon substrate of the memory cell region; After forming the insulating film, seal in the transistor region for low voltage Patterning the interlayer insulating film so that the cones substrate is exposed and is characterized in that by performing an oxidation process comprising a step of forming a gate oxide film of low-voltage transistor on the exposed silicon substrate.
이하, 첨부된 도면을 참조하여 본 발명을 상세히 설명하기로 한다.Hereinafter, with reference to the accompanying drawings will be described in detail the present invention.
제2a 내지 제2e도는 본 발명에 따른 플래쉬 이이피롬 소자의 제조방법을 설명하기 위한 소자의 단면도로서,2A through 2E are cross-sectional views of a device for describing a method of manufacturing a flash y-pyrom device according to the present invention.
제2a도는 메모리셀지역(MC), 고전압용 트랜지스터지역(HV) 및 저전압용 트랜지스터지역(LV)을 전기적으로 각각 분리시키기 위하여 실리콘기판(1)의 필드영역(F)에 필드산화막(2)을 형성한 후 전체 상부면에 터널산화막(3), 제1폴리실리콘층(4), 하부산화막(15) 및 질화막(16)을 순차적으로 형성한 상태의 단면도이다.2A shows a field oxide film 2 in the field region F of the silicon substrate 1 to electrically separate the memory cell region MC, the high voltage transistor region HV, and the low voltage transistor region LV, respectively. After formation, it is sectional drawing of the state which formed the tunnel oxide film 3, the 1st polysilicon layer 4, the lower oxide film 15, and the nitride film 16 sequentially on the whole upper surface.
제2b도는 플로팅게이트전극용 마스크를 이용한 사진 및 식각공정을 통해 상기 질화막(16), 하부산화막(15), 제1폴리실리콘층(14) 및 터널산화막(13)을 순차적으로 패터닝하여 상기 메모리셀지역(MC)에 터널산화막(13), 플로팅게이트(14A), 하부산화막(15) 및 질화막(16)이 적층된 구조를 형성한 상태의 단면도이다.FIG. 2B illustrates the nitride cell 16, the lower oxide layer 15, the first polysilicon layer 14 and the tunnel oxide layer 13 by sequentially patterning the photolithography and etching processes using a mask for a floating gate electrode. It is sectional drawing of the state which formed the structure in which the tunnel oxide film 13, the floating gate 14A, the lower oxide film 15, and the nitride film 16 were laminated | stacked in the area | region MC.
제2c도는 상기 고전압용 트랜지스터지역(HV) 및 저전압용 트랜지스터지역(LV)의 노출된 실리콘기판(1)에 문턱전압조절용 불순물이온주입을 실시한 후 전체 상부면에 상부산화막(17) 및 제2폴리실리콘층(18)을 순차적으로 형성한 상태의 단면도이다.FIG. 2C shows the upper oxide film 17 and the second poly on the entire upper surface of the silicon substrate 1 of the high voltage transistor region HV and the low voltage transistor region LV. It is sectional drawing of the state which formed the silicon layer 18 sequentially.
제2d도는 콘트롤게이트전극용 마스크를 이용한 사진 및 식각공정을 통해 상기 메모리셀지역(MC)의 제2폴리실리콘층(18) 및 상부산화막(15)을 순차적으로 패터닝하여 상기 질화막(16)상에 상부산화막(17) 및 콘트롤게이트(18A)가 적층된 구조의 게이트전극을 형성한다.FIG. 2D illustrates a pattern of the second polysilicon layer 18 and the upper oxide layer 15 of the memory cell region MC sequentially and through the photolithography and etching process using a mask for a control gate electrode on the nitride layer 16. A gate electrode having a structure in which the upper oxide film 17 and the control gate 18A are stacked is formed.
이후 고전압용 트랜지스터의 게이트전극용 마스크를 이용한 사진 및 식각공정으로 잔류된 제2폴리실리콘층(18) 및 상부산화막(17)을 순차적으로 패터닝하여 고전압용 트랜지스터지역(HV)에 게이트전극(18B)을 형성한 상태의 단면도인데, 상기 상부산화막(17)이 고전압용 트랜지스터의 게이트산화막으로 이용된다.Subsequently, the second polysilicon layer 18 and the upper oxide layer 17 remaining in the photolithography and etching processes using the gate electrode mask of the high voltage transistor are sequentially patterned to form the gate electrode 18B in the high voltage transistor region HV. The upper oxide film 17 is used as a gate oxide film of a high voltage transistor.
제2e도는 불순물이온주입공정을 실시하여 상기 메모리셀지역(MC)의 노출된 실리콘기판(1)에 소오스 및 드레인영역(19)을 형성하고 전체상부면에 TEOS을 증착하여 층간절연막(20)을 형성한 후 상기 저전압용 트랜지스터지역(LV)의 실리콘기판(1)이 노출되도록 상기 층간절연막(20)을 패터닝하고 산화공정을 실시하여 상기 노출된 실리콘기판(1)에 저전압용 트랜지스터의 게이트산화막(21)을 형성한 상태의 단면도이다.FIG. 2E illustrates an impurity ion implantation process to form a source and a drain region 19 on the exposed silicon substrate 1 of the memory cell region MC, and deposit TEOS on the entire upper surface to form the interlayer insulating layer 20. After the formation, the interlayer insulating layer 20 is patterned so that the silicon substrate 1 of the low voltage transistor region LV is exposed and subjected to an oxidation process, thereby forming a gate oxide layer of the low voltage transistor on the exposed silicon substrate 1. It is sectional drawing of the state which formed 21).
상술한 바와같이 본 발명에 의하면 메모리셀의 유전체막이 ONO(하부산화막-질화막-상부산화막)구조로 이루어지는 플래쉬 이이피롬 소자의 제조에 있어, 주변지역에 형성되는 고전압용 트랜지스터의 게이트산화막을 유전체막의 상부산화막을 이용하여 형성하므로써 두께의 조절이 용이하며 불순물의 침투 및 감광막의 이용으로 인한 오염을 방지할 수 있어 게이트산화막의 특성을 향상시킬 수 있으며, 공정을 단순화시키므로써 소자의 수율을 증대시킬 수 있는 탁월한 효과가 있다.As described above, according to the present invention, in the fabrication of a flash Y pyrom device in which a dielectric film of a memory cell has an ONO (lower oxide film-nitride film-top oxide film) structure, a gate oxide film of a high voltage transistor formed in a peripheral region is formed on top of a dielectric film. It is easy to control the thickness by using the oxide film, and it is possible to prevent contamination due to the penetration of impurities and the use of the photoresist film, so that the characteristics of the gate oxide film can be improved, and the process yield can be increased by simplifying the process. Excellent effect
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US7320920B2 (en) | 2004-06-17 | 2008-01-22 | Samsung Electronics Co., Ltd. | Non-volatile flash memory device having at least two different channel concentrations and method of fabricating the same |
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US7320920B2 (en) | 2004-06-17 | 2008-01-22 | Samsung Electronics Co., Ltd. | Non-volatile flash memory device having at least two different channel concentrations and method of fabricating the same |
US7932154B2 (en) | 2004-06-17 | 2011-04-26 | Samsung Electronics Co., Ltd. | Method of fabricating non-volatile flash memory device having at least two different channel concentrations |
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