JPS6366103A - Insecticide - Google Patents
InsecticideInfo
- Publication number
- JPS6366103A JPS6366103A JP21035386A JP21035386A JPS6366103A JP S6366103 A JPS6366103 A JP S6366103A JP 21035386 A JP21035386 A JP 21035386A JP 21035386 A JP21035386 A JP 21035386A JP S6366103 A JPS6366103 A JP S6366103A
- Authority
- JP
- Japan
- Prior art keywords
- pinene
- active ingredient
- insecticide
- alpha
- insecticidal properties
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002917 insecticide Substances 0.000 title abstract description 6
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004480 active ingredient Substances 0.000 claims abstract 4
- 239000000077 insect repellent Substances 0.000 claims description 14
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 abstract description 17
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000011148 porous material Substances 0.000 abstract description 2
- OTTZHAVKAVGASB-UHFFFAOYSA-N hept-2-ene Chemical compound CCCCC=CC OTTZHAVKAVGASB-UHFFFAOYSA-N 0.000 abstract 2
- 241000130771 Tinea pellionella Species 0.000 abstract 1
- 229940000425 combination drug Drugs 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 150000003505 terpenes Chemical class 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は新規な防虫剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a novel insect repellent.
従来防虫剤、殺虫剤として使用されているものは数多い
が、一般的農園芸用殺虫剤と異なり家庭内等の衣類収納
用家具、容器内で使用する衣類用防虫剤は多くはない。There are many insect repellents and insecticides that have been used in the past, but unlike general agricultural and horticultural insecticides, there are not many insect repellents for clothing that are used in clothing storage furniture and containers in the home.
それは人畜に対する毒性が低く、衣類等に対し汚染、損
傷を与えずに、イガ当特定の虫頻に有効であること等の
制約を受けるためである。This is because it has low toxicity to humans and livestock, does not contaminate or damage clothing, etc., and is effective against specific insects such as burrs.
従ってナフタリン、樟脳、パラ−ジクロロベンゼン等の
古くから使用されている防虫剤が、それらが有する上記
特性の良さから今でも相当量使用されている。Therefore, insect repellents that have been used for a long time, such as naphthalene, camphor, and para-dichlorobenzene, are still used in considerable quantities because of their good properties.
しかしこれらの防虫剤は効力は弱く、比較的短時間で気
散するため長期間効果を持続できず、頻繁に薬剤の補充
が必要であり、従って使用量が多くなる。However, these insect repellents have low efficacy and are dispersed in a relatively short period of time, so they cannot maintain their effectiveness over a long period of time, require frequent replenishment, and therefore require a large amount of use.
比較的少量で効果が長期間持続し、且つ安全な新しい防
虫剤の開発が望まれていた。It has been desired to develop a new insect repellent that is safe and effective for a long period of time with a relatively small amount.
本発明者は防虫剤として使用されている化合物の類縁あ
るいは周縁の化合物について種々研究した結果、２，６
．６−トリメチルビシクロ［３，１゜１］ヘプト−２−
エン（以下これをα−ピネンと呼ぶ。）が気散性を有し
、その気散ガスにによる殺虫性が優れていることを見出
し本発明に到達した。As a result of various studies on compounds related to or peripheral to compounds used as insect repellents, the present inventor found that 2,6
．． 6-trimethylbicyclo[3,1゜1]hept-2-
The present invention was achieved by discovering that ene (hereinafter referred to as α-pinene) has a vaporizing property and that the vaporized gas has excellent insecticidal properties.
α−ピネンは沸点１５５℃〜１５６℃の液体で天然に得
られる精油に含まれる極めて安全性の高いテルペンであ
る。α-Pinene is a liquid with a boiling point of 155°C to 156°C and is an extremely safe terpene contained in naturally obtained essential oils.
α−ピネンをＩＱのビーカーに少量とり、イガの幼虫数
頭をいれて蓋をし数日放置したところ、α−ピネンから
気散した蒸気によりその殆どが死滅した。A small amount of α-pinene was placed in an IQ beaker, several burr larvae were placed in the beaker, the beaker was covered with a lid, and the beaker was left for several days. Most of the larvae were killed by the vapor released from the α-pinene.
α−ピネンは常温で液体であるから適当な保持剤、例え
ば厚紙、織布、多孔性素材に含浸させ、またはゲル化剤
等で固形化して使用する。これはα−ピネン単独でも、
他の防虫剤との複合の場合でも適用することができる。Since α-pinene is liquid at room temperature, it is used by impregnating it into a suitable holding agent, such as cardboard, woven cloth, or porous material, or by solidifying it with a gelling agent. This is true even for α-pinene alone.
It can also be applied in combination with other insect repellents.
内容積約１０の硝子製有蓋容器の底部に、薬剤１ｇを含
浸させた厚紙を置き、さらに羊毛と一緒にイガ幼虫１０
頭を約０．１２ｆｌの硝子容器に納めて、２０℃（７５
％Ｒ，Ｈ）の恒温恒湿槽に１週間放置した。Place a piece of cardboard impregnated with 1 g of the drug at the bottom of a glass container with an internal volume of about 10 g, and add 10 g of bur larvae along with the wool.
Place the head in an approximately 0.12 fl glass container and heat at 20°C (75°C).
%R,H) for one week in a constant temperature and humidity chamber.
試験結果は試験数５個の食害量と致死数の平均をもって
結果とした。The test results were taken as the average of the amount of feeding damage and the number of deaths for the five tested specimens.
試験結果を第１表に示す。The test results are shown in Table 1.
第１表
〔発明の効果〕
本発明のα−ピネンは強力な防虫剤で少量でも優れた防
虫性を有し、しかも長期に亘って効果は持続する。Table 1 [Effects of the Invention] The α-pinene of the present invention is a strong insect repellent and has excellent insect repellent properties even in small amounts, and the effect persists for a long period of time.
その他衣類用の防虫剤としての特性を有するので従来の
防虫剤にとって代る優れた防虫剤となるものと期待され
る。Since it also has properties as an insect repellent for clothing, it is expected to be an excellent insect repellent to replace conventional insect repellents.
Claims (1)
−２−エンを有効成分として含有する防虫剤。An insect repellent containing 2,6,6-trimethylbicyclo[3,1,1]hept-2-ene as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21035386A JPS6366103A (en) | 1986-09-06 | 1986-09-06 | Insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21035386A JPS6366103A (en) | 1986-09-06 | 1986-09-06 | Insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6366103A true JPS6366103A (en) | 1988-03-24 |
Family
ID=16587986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21035386A Pending JPS6366103A (en) | 1986-09-06 | 1986-09-06 | Insecticide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6366103A (en) |
-
1986
- 1986-09-06 JP JP21035386A patent/JPS6366103A/en active Pending
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