JPS614800A - Body detergent composition - Google Patents
Body detergent compositionInfo
- Publication number
- JPS614800A JPS614800A JP12484284A JP12484284A JPS614800A JP S614800 A JPS614800 A JP S614800A JP 12484284 A JP12484284 A JP 12484284A JP 12484284 A JP12484284 A JP 12484284A JP S614800 A JPS614800 A JP S614800A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- formula
- formulas
- carbon atoms
- alkyl group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Detergent Compositions (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、低刺戟性界面活性剤と脂肪酸石鹸の組み合せ
による外観透明性に優れ、起泡性が良好で且つ皮膚に対
して温和な水性液体状身体用洗浄剤組成物に関する。Detailed Description of the Invention (Field of Industrial Application) The present invention provides an aqueous soap that has excellent appearance transparency, good foaming properties, and is mild to the skin due to the combination of a low-irritation surfactant and a fatty acid soap. The present invention relates to a liquid body cleansing composition.
(従来の技術)
従来、低刺戟性身体用洗浄剤としては、アルキルイミダ
ゾリニウムベタイン、アシルグルタミン酸アルカリ塩、
ジメチル高級アルキルベタイン、スルホベタイン等の界
面活性剤を主配合する処方のものが知られているが、こ
れ等は一般に泡立ちが悪く、そのため使用に際してはス
ポンジ等で泡立てて使用しなければならない。しかも、
使用後の濯ぎ効果も悪くて身にぬるぬるした感じが残枳
清涼感に欠ける嫌いがあった。(Prior Art) Conventionally, as low-irritation body cleansers, alkylimidazolinium betaine, acylglutamic acid alkali salt,
Formulations mainly containing surfactants such as dimethyl higher alkyl betaine and sulfobetaine are known, but these generally have poor foaming properties and must be lathered with a sponge or the like before use. Moreover,
I didn't like the rinsing effect after use, which left a slimy feeling on my skin and lacked a refreshing feeling.
また、石鹸を主成分とするシャンプーも、例えば、特公
昭57−57080号公報に示される如く、知られては
いるが、この種のものは、低温時における透明性が悪く
、エタノールやプロピレングリコール等のアルコール類
の多量添加を必要とし、加えて、石鹸によるアルカリ性
のために使用後の皮膚につっばった感じが残る欠点があ
った。In addition, shampoos whose main ingredient is soap are also known, for example, as shown in Japanese Patent Publication No. 57-57080, but this kind of shampoo has poor transparency at low temperatures and does not contain ethanol or propylene glycol. It requires the addition of a large amount of alcohol such as alcohol, and in addition, the alkalinity of the soap leaves the skin with a tight feeling after use.
(発明が解決しようとする問題点)
したがって、本発明では、従来の低刺戟洗浄剤としての
アルキルイミダゾリニウムベタイン系における泡立ち不
良及び清涼感欠如、また、N−アシルグルタミン酸系に
おける洗浄後のぬるつきの残シ、さらには、石鹸系にお
ける高いアルカリ性および多量に添加された可溶化剤に
よる刺戟などの諸欠点をなくし、低刺戟性界面活性剤と
脂肪酸石鹸との組み合せによって気泡性に優れ安定性の
良い改良された身体用洗浄剤組成物を得ることにある〇
(問題を解決するだめの手段)
本発明は、前記問題点に鑑み、低刺戟性の身体用洗浄剤
組成物として、脂肪酸加水分解コラ−rンアルカリ塩類
(Na HK + NH4+アルカノールア(前記式中
、R1は炭素原子数8〜22個のアルキル基または一般
式
原子数8〜22個のアルキル基またはアルケニル基、R
3はHまたはCH,5、MはNa + K * NH4
またはアルカノールアミンのようなカチオン、Nは2〜
でahされるスルホコハク酸系の陰イオン界面活性剤お
よび、
(前記式中、R4は、炭素原子数7〜21個のアルキル
基またはアルケニル基、R5、R6は炭素原子数1〜3
個のアルキル基)
で表わされるベタインにおいて、
前記成分(、)が40〜60重量%、(b)が0〜30
重量%、(C)が20〜45重量%である混合物および
、
一般式 R7C00M ・・
・(d)(前記式中、R7は炭素原子数7〜21個のア
ルキル基またはアルケニル基、MはNa 、 K 、
NH4tたはアルカノ−ルアはン)
で表わされる石鹸を、前記混合物に対して5〜25重量
%添加して得られるものを提供することにある。(Problems to be Solved by the Invention) Therefore, the present invention solves the problem of poor foaming and lack of cooling sensation in conventional alkylimidazolinium betaine-based detergents as low irritation detergents, and the slimy feeling after washing in N-acylglutamic acid-based detergents. The combination of a low-irritant surfactant and a fatty acid soap eliminates various disadvantages such as the irritation caused by the high alkalinity of soap systems and the addition of a large amount of solubilizer, and provides excellent foaming properties and stability. An object of the present invention is to obtain an improved body cleansing composition (means for solving the problem). Choran alkali salts (Na HK + NH4 + alkanolia (in the above formula, R1 is an alkyl group having 8 to 22 carbon atoms or an alkyl group or alkenyl group having general formula 8 to 22 atoms, R
3 is H or CH, 5, M is Na + K * NH4
or a cation such as an alkanolamine, where N is 2 to
a sulfosuccinic acid-based anionic surfactant, and (in the above formula, R4 is an alkyl group or alkenyl group having 7 to 21 carbon atoms, R5 and R6 are 1 to 3 carbon atoms
In the betaine represented by the following alkyl group), the component (, ) is 40 to 60% by weight, and (b) is 0 to 30% by weight.
% by weight, a mixture in which (C) is 20 to 45% by weight, and a general formula R7C00M...
・(d) (In the above formula, R7 is an alkyl group or alkenyl group having 7 to 21 carbon atoms, M is Na, K,
The object of the present invention is to provide a soap obtained by adding 5 to 25% by weight of a soap represented by NH4t or alkanolamine to the above mixture.
(作用)
本発明組成物に用いる脂肪酸加水分解コラーゲンアルカ
リ塩類(&)は、=ラーrンタンパク質を加水分解した
ものと、脂肪酸を縮合したものをNa。(Function) The fatty acid hydrolyzed collagen alkali salts (&) used in the composition of the present invention are Na.
K 、 NH4またはアルカノールアミンで中和した界
面活性剤でアシ、非常に低刺戟で且つ皮膚保護作用があ
る。It is a surfactant neutralized with K, NH4 or alkanolamine, and has a very low irritation and skin protective effect.
また、前記一般式伽)で表わされるスルホコハク酸系の
陰イオン界面活性剤も非常に刺戟性の低い界面活性剤で
ある。Furthermore, the sulfosuccinic acid-based anionic surfactant represented by the general formula (a) is also a surfactant with very low irritating properties.
さらに、前記一般式(、)で表わされるベタインも非常
に低刺戟な界面活性剤である。Furthermore, betaine represented by the above general formula (,) is also a very mildly irritating surfactant.
加えて、前記一般式(d)で表わされる石鹸は、炭素原
子数7ないし21個のアルキル基またはアルケニル基の
脂肪酸(例えば、カプリル酸、カブリン酸、ラウリン酸
、ミリスチン酸、ノぐルミチン酸、ステアリン酸、イン
ステアリン酸、オレイン酸、竺ヘニン酸等)の二種以上
の組み合せのN&またはに、NH5r アルカノール
アミン石鹸でアシ、脂肪酸は一種よシニ種以上組み合せ
る方が刺戟を低減できる。In addition, the soap represented by the general formula (d) may contain alkyl or alkenyl fatty acids having 7 to 21 carbon atoms (for example, caprylic acid, cabric acid, lauric acid, myristic acid, noglumitic acid, Irritation can be reduced by combining two or more types of fatty acids (stearic acid, instearic acid, oleic acid, henic acid, etc.) with NH5r alkanolamine soap.
本発明組成物の構成において、成分(a) 、 (b)
および(C)の成分比が、成分(a)40ないし60重
量%、成分(b)0ないし30重量%、(c)20ない
し45重量%である混合物と、これに対して成分(d)
を5ないし25重量%混合して得られる最終混合物が声
6ないし8程度で低刺戟であって、かつ泡立ちが良くて
洗い上がシの感触も良い。In the composition of the present invention, components (a) and (b)
and (C) in a proportion of 40 to 60% by weight of component (a), 0 to 30% by weight of component (b), and 20 to 45% by weight of component (c), with respect to which component (d)
The final mixture obtained by mixing 5 to 25 wt.
一方、前記成分(d)の添加量が成分(a) 、 (b
)および(c)の前記混合物に対して5重量%未満であ
ると泡立ち機能が低下して、この点に関する改良目的が
達せられず、また、この添加量が20重量%よシも多い
と、泡立ちは良好ではあるが、液の声がアルカリ性にな
シ、加えて、最終混合物を5ないし30重量%含有する
水性液状組成物にしたときの低温安定性が悪くて、沈殿
等を生じ易くなシ、これを防ぐためにエタノール等の可
溶化剤を添加しなければならないこととなル、この添加
による別の刺戟作用が発生するので、本発明組成物の目
的とする低刺戟性に反し好ましくない。On the other hand, the amount of the component (d) added is the same as that of the components (a) and (b).
If the amount is less than 5% by weight based on the mixture of () and (c), the foaming function will deteriorate and the improvement objective in this regard will not be achieved, and if the amount added is more than 20% by weight, Although the foaming is good, the texture of the liquid is not alkaline, and in addition, when the final mixture is made into an aqueous liquid composition containing 5 to 30% by weight, the low temperature stability is poor and precipitation etc. easily occur. However, in order to prevent this, it is necessary to add a solubilizing agent such as ethanol, and this addition causes other stimulatory effects, which is undesirable as it goes against the low irritating properties that are aimed at by the composition of the present invention. .
なお、この本発明組成物の構成に低刺戟性の香料、防腐
剤、金属イオン封鎖剤および着色料などを適量添加して
、本発明組成物からなるボディーシャンプーなどの商品
価値を上げることができることは勿論である。It should be noted that by adding appropriate amounts of low-irritating fragrances, preservatives, sequestrants, colorants, etc. to the composition of the present invention, it is possible to increase the commercial value of body shampoos and the like made of the composition of the present invention. Of course.
(実施例)
次に、本発明組成物の好ましい実施例を比較例と共に表
1に示す。なお、表中の数値は重量%を示す。(Example) Next, preferred examples of the composition of the present invention are shown in Table 1 along with comparative examples. Note that the numerical values in the table indicate weight %.
(発明の効果)
前記実施例における結果からも明らかな如く、本発明組
成物は、低刺戟性の界面活性剤を組み合せたことによシ
、泡立ちが良好で使用感に優れ、かつ、低温での安定性
が良くて、特に、皮膚に温和な低刺戟性の洗浄剤を得る
ことができる◎しかも、本発明組成物における低刺戟性
から、これをベビー用全身洗浄剤に用いて極めて有効で
ある他に、一般洗顔料および全身用洗浄剤に利用するこ
とができ、その効果が極めて顕著なるものである。(Effects of the Invention) As is clear from the results in the above examples, the composition of the present invention has good foaming properties, excellent feeling of use, and is effective at low temperatures due to the combination of a low-irritant surfactant. The composition of the present invention has good stability, making it possible to obtain a low-irritation cleansing agent that is particularly gentle on the skin.Moreover, due to the low-irritancy of the composition of the present invention, it is extremely effective when used as a whole-body cleanser for babies. In addition, it can be used in general facial cleansers and whole body cleansers, and its effects are extremely remarkable.
Claims (2)
K、NH_4、アルカノールアミン)・・・(a)一般
式▲数式、化学式、表等があります▼・・・(b) (前記式中、R_1は炭素原子数8〜22個のアルキル
基または一般式▲数式、化学式、表等があります▼で表
わされる アミド基、R_2は炭素原子数8〜22個のアルキル基
またはアルケニル基、R_3はHまたはCH_3、Mは
Na、K、NH_4またはアルカノールアミンのような
カチオン、Nは2〜5) で表わされるスルホコハク酸系の陰イオン界面活性剤お
よび、 一般式▲数式、化学式、表等があります▼ (前記式中、R_4は、炭素原子数7〜21個のアルキ
ル基またはアルケニル基、R_5、R_6は炭素原子数
1〜3個のアルキル基) で表わされるベタインにおいて、 前記成分(a)が40〜60重量%、(b)が0〜30
重量%、(c)が20〜45重量%である混合物および
、 一般式R_7COOM・・・(d) (前記式中、R_7は炭素原子数7〜21個のアルキル
基またはアルケニル基、MはNa、K、NH_4または
アルカノールアミン) で表わされる石鹸を、前記混合物に対して5〜25重量
%添加して得られることを特徴とする身体洗浄剤組成物
。(1) Fatty acid hydrolyzed collagen alkaline salts (Na,
K, NH_4, alkanolamine)... (a) General formula▲ Numerical formula, chemical formula, table, etc.▼...(b) (In the above formula, R_1 is an alkyl group having 8 to 22 carbon atoms or a general An amide group represented by the formula ▲ There are mathematical formulas, chemical formulas, tables, etc. There are sulfosuccinic acid-based anionic surfactants represented by the following cations, N is 2 to 5), and general formulas, numerical formulas, chemical formulas, tables, etc. (In the above formula, R_4 is a carbon atom number of 7 to 21) (alkyl group or alkenyl group, R_5 and R_6 are alkyl groups having 1 to 3 carbon atoms), the component (a) is 40 to 60% by weight, and the component (b) is 0 to 30% by weight.
% by weight, (c) is 20 to 45% by weight, and the general formula R_7COOM...(d) (In the above formula, R_7 is an alkyl group or alkenyl group having 7 to 21 carbon atoms, M is Na , K, NH_4 or alkanolamine) in an amount of 5 to 25% by weight based on the mixture.
体状物からなる特許請求の範囲第1項記載の身体洗浄剤
組成物。(2) The body cleansing composition according to claim 1, which comprises an aqueous liquid containing 5 to 30% by weight of the final mixture.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12484284A JPS614800A (en) | 1984-06-18 | 1984-06-18 | Body detergent composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12484284A JPS614800A (en) | 1984-06-18 | 1984-06-18 | Body detergent composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS614800A true JPS614800A (en) | 1986-01-10 |
JPH0361720B2 JPH0361720B2 (en) | 1991-09-20 |
Family
ID=14895440
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP12484284A Granted JPS614800A (en) | 1984-06-18 | 1984-06-18 | Body detergent composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS614800A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62109897A (en) * | 1985-11-06 | 1987-05-21 | ライオン株式会社 | Liquid detergent composition |
JPH01146814A (en) * | 1987-12-02 | 1989-06-08 | Sunstar Inc | Cleaning agent composition |
CN106281744A (en) * | 2016-08-16 | 2017-01-04 | 薛常莲 | A kind of infantile clothes concentrated cleaning and preparation method thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5130205A (en) * | 1974-05-06 | 1976-03-15 | Procter & Gamble | KESHOSETSUKENBO |
JPS5173505A (en) * | 1974-12-23 | 1976-06-25 | Kao Corp | Tomeisetsukenno seizoho |
JPS52148507A (en) * | 1976-06-04 | 1977-12-09 | Colgate Palmolive Co | Solid toilet soap |
JPS55151096A (en) * | 1979-05-14 | 1980-11-25 | Nippon Catalytic Chem Ind | Secondary alcohol type anionic surface active agent |
JPS57159897A (en) * | 1981-03-09 | 1982-10-02 | Johnson & Johnson Baby Prod | Detergent and cleaner composition |
JPS5825396A (en) * | 1981-07-24 | 1983-02-15 | ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ | Detergent composition |
-
1984
- 1984-06-18 JP JP12484284A patent/JPS614800A/en active Granted
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5130205A (en) * | 1974-05-06 | 1976-03-15 | Procter & Gamble | KESHOSETSUKENBO |
JPS5173505A (en) * | 1974-12-23 | 1976-06-25 | Kao Corp | Tomeisetsukenno seizoho |
JPS52148507A (en) * | 1976-06-04 | 1977-12-09 | Colgate Palmolive Co | Solid toilet soap |
JPS55151096A (en) * | 1979-05-14 | 1980-11-25 | Nippon Catalytic Chem Ind | Secondary alcohol type anionic surface active agent |
JPS57159897A (en) * | 1981-03-09 | 1982-10-02 | Johnson & Johnson Baby Prod | Detergent and cleaner composition |
JPS5825396A (en) * | 1981-07-24 | 1983-02-15 | ユニリ−バ−・ナ−ムロ−ゼ・ベンノ−トシヤ−プ | Detergent composition |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62109897A (en) * | 1985-11-06 | 1987-05-21 | ライオン株式会社 | Liquid detergent composition |
JPH01146814A (en) * | 1987-12-02 | 1989-06-08 | Sunstar Inc | Cleaning agent composition |
CN106281744A (en) * | 2016-08-16 | 2017-01-04 | 薛常莲 | A kind of infantile clothes concentrated cleaning and preparation method thereof |
CN106281744B (en) * | 2016-08-16 | 2019-02-26 | 苏雨江 | A kind of infantile clothes concentrated cleaning and preparation method thereof |
Also Published As
Publication number | Publication date |
---|---|
JPH0361720B2 (en) | 1991-09-20 |
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