JPH01294799A - Creamy detergent composition - Google Patents
Creamy detergent compositionInfo
- Publication number
- JPH01294799A JPH01294799A JP12334288A JP12334288A JPH01294799A JP H01294799 A JPH01294799 A JP H01294799A JP 12334288 A JP12334288 A JP 12334288A JP 12334288 A JP12334288 A JP 12334288A JP H01294799 A JPH01294799 A JP H01294799A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- alkyl
- component
- creamy
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims description 38
- 239000003599 detergent Substances 0.000 title claims description 23
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 12
- -1 amino acid salt Chemical class 0.000 claims description 35
- 230000002378 acidificating effect Effects 0.000 claims description 15
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 9
- 229960003237 betaine Drugs 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 150000003839 salts Chemical class 0.000 abstract description 5
- 239000002202 Polyethylene glycol Substances 0.000 abstract description 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 4
- 229920001223 polyethylene glycol Polymers 0.000 abstract description 4
- 150000001340 alkali metals Chemical class 0.000 abstract description 2
- 125000003342 alkenyl group Chemical group 0.000 abstract description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- IWIUXJGIDSGWDN-UQKRIMTDSA-M sodium;(2s)-2-(dodecanoylamino)pentanedioate;hydron Chemical compound [Na+].CCCCCCCCCCCC(=O)N[C@H](C([O-])=O)CCC(O)=O IWIUXJGIDSGWDN-UQKRIMTDSA-M 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 18
- 239000000194 fatty acid Substances 0.000 description 18
- 229930195729 fatty acid Natural products 0.000 description 18
- 235000001014 amino acid Nutrition 0.000 description 17
- 239000002253 acid Substances 0.000 description 12
- 150000004665 fatty acids Chemical class 0.000 description 12
- 239000006260 foam Substances 0.000 description 10
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 125000002252 acyl group Chemical group 0.000 description 6
- 150000001413 amino acids Chemical class 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 6
- 239000006071 cream Substances 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 235000015278 beef Nutrition 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- FFDGPVCHZBVARC-UHFFFAOYSA-N N,N-dimethylglycine Chemical compound CN(C)CC(O)=O FFDGPVCHZBVARC-UHFFFAOYSA-N 0.000 description 2
- ZXFQDPHJZVBMJZ-UHFFFAOYSA-N OCC[N+]1(CC([O-])=O)CCN=C1 Chemical compound OCC[N+]1(CC([O-])=O)CCN=C1 ZXFQDPHJZVBMJZ-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- GPLKUOGWSMYDNE-QHCPKHFHSA-N (2s)-2-(docosanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CC(O)=O GPLKUOGWSMYDNE-QHCPKHFHSA-N 0.000 description 1
- AVBJHQDHVYGQLS-AWEZNQCLSA-N (2s)-2-(dodecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O AVBJHQDHVYGQLS-AWEZNQCLSA-N 0.000 description 1
- XWECHXDFKBPXQY-IBGZPJMESA-N (2s)-2-(octadecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CC(O)=O XWECHXDFKBPXQY-IBGZPJMESA-N 0.000 description 1
- JCQLZKNHLVROBO-JTQLQIEISA-N (2s)-2-(octanoylamino)pentanedioic acid Chemical compound CCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O JCQLZKNHLVROBO-JTQLQIEISA-N 0.000 description 1
- MTJZWYHTZFVEGI-INIZCTEOSA-N (2s)-2-(tetradecanoylamino)pentanedioic acid Chemical compound CCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O MTJZWYHTZFVEGI-INIZCTEOSA-N 0.000 description 1
- VCRXMSMANOGRCM-UHFFFAOYSA-N 2-(dodecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CC(O)=O VCRXMSMANOGRCM-UHFFFAOYSA-N 0.000 description 1
- CYDQOEWLBCCFJZ-UHFFFAOYSA-N 4-(4-fluorophenyl)oxane-4-carboxylic acid Chemical compound C=1C=C(F)C=CC=1C1(C(=O)O)CCOCC1 CYDQOEWLBCCFJZ-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- ATFFFUXLAJBBDE-FQEVSTJZSA-N N-Stearoyl glutamic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O ATFFFUXLAJBBDE-FQEVSTJZSA-N 0.000 description 1
- UUFVSGRELDGPGL-QJRAZLAKSA-N N-oleoyl-L-glutamic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N[C@H](C(O)=O)CCC(O)=O UUFVSGRELDGPGL-QJRAZLAKSA-N 0.000 description 1
- 235000021314 Palmitic acid Nutrition 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- ZOJBYZNEUISWFT-UHFFFAOYSA-N allyl isothiocyanate Chemical compound C=CCN=C=S ZOJBYZNEUISWFT-UHFFFAOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- LHIJANUOQQMGNT-UHFFFAOYSA-N aminoethylethanolamine Chemical compound NCCNCCO LHIJANUOQQMGNT-UHFFFAOYSA-N 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 125000003910 behenoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- BHRMYIADWWJEBW-UHFFFAOYSA-L disodium;2-oxopyrrolidine-1-carboxylate Chemical compound [Na+].[Na+].[O-]C(=O)N1CCCC1=O.[O-]C(=O)N1CCCC1=O BHRMYIADWWJEBW-UHFFFAOYSA-L 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 239000008164 mustard oil Substances 0.000 description 1
- 125000001419 myristoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 1
- 125000002811 oleoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は、Ｎ−アシル酸性アミノ酸塩と２−アルキル−
Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾ
リニウムベタインと多価アルコールとを特定の比率で含
有してなる、クリーム状洗浄剤組成物に関する。Detailed Description of the Invention [Industrial Field of Application] The present invention provides an N-acyl acidic amino acid salt and a 2-alkyl-
The present invention relates to a cream detergent composition containing N-carboxymethyl-N-hydroxyethylimidazolinium betaine and a polyhydric alcohol in a specific ratio.
［従来の技術及び問題点〕
従来、シャンプー、洗顔石鹸、台所用洗剤等の各種洗浄
剤にはアルキルベンゼンスルホン酸塩、高級アルコール
硫酸エステル塩、ポリオキシエチレンアルキルエーテル
硫酸塩、高級脂肪酸塩等の起泡性、洗浄性に優れたアニ
オン界面活性剤が配合されていたが、これらのアニオン
界面活性剤は手あれなど皮膚に対する刺激性が懸念され
ている。[Prior Art and Problems] Conventionally, various cleaning agents such as shampoos, facial soaps, and kitchen detergents contain ingredients such as alkylbenzene sulfonates, higher alcohol sulfate ester salts, polyoxyethylene alkyl ether sulfates, and higher fatty acid salts. Anionic surfactants with excellent foaming and cleansing properties were included, but there are concerns that these anionic surfactants may irritate the skin, such as causing rough hands.
近年、Ｎ−アシル酸性アミノ酸塩が人体、特に皮膚に対
して安全性が高く、また使用感にも優れることから、固
形石鹸、液体洗浄剤をはじめ、クレンジングフオームな
どのクリーム状洗浄剤にも利用されている。In recent years, N-acyl acidic amino acid salts have been used in bar soaps, liquid detergents, and cream-like detergents such as cleansing foams because they are highly safe for the human body, especially the skin, and are also comfortable to use. has been done.
ところで、クリーム状洗浄剤にＮ−アシル酸性アミノ酸
塩を利用する場合、Ｎ−アシル酸性アミノ酸アルカリ金
属塩が用いられるが、クリーム状のなめらかな形態にす
るためには、ポリエチレングリコール、グリセリン、プ
ロピレングリコール、１．３−ブチレングリコール、ソ
ルビット等の多価アルコール成分が必須である。しかし
ながら、この様な組成のクリーム状洗浄剤は低温では固
くなりやすく、高温では多価アルコールが分離しやすい
という問題がある。また−最に、Ｎ−アシル酸性アミノ
酸塩は泡の質が軽いためクリーミーな泡の感触を出すた
めには、脂肪酸ジェタノールアミドの添加が行われてい
るが、クリーム状洗浄剤の場合には脂肪酸ジェタノール
アミドの添加量を多くすると高温での安定性が低下しや
すいという問題がある。By the way, when using an N-acyl acidic amino acid salt in a cream-like cleaning agent, an N-acyl acidic amino acid alkali metal salt is used, but in order to make it into a cream-like smooth form, polyethylene glycol, glycerin, propylene glycol is used. , 1,3-butylene glycol, sorbitol, and other polyhydric alcohol components are essential. However, creamy detergents with such a composition tend to become hard at low temperatures, and polyhydric alcohols tend to separate at high temperatures. Furthermore, since N-acyl acidic amino acid salts produce light foam, fatty acid jetanolamide is added to create a creamy foam feel; There is a problem in that when the amount of fatty acid jetanolamide added is increased, stability at high temperatures tends to decrease.
［発明が解決しようとする課題］
即ち、本発明の目的は、使用感及び、温度安定性に優れ
たクリーム状洗浄剤組成物を提供することにある。[Problems to be Solved by the Invention] That is, an object of the present invention is to provide a creamy detergent composition that has excellent usability and temperature stability.
［課題を解決するための手段］
本発明者らは、クリーム状洗浄剤における上記の欠点に
鑑み、使用感及び、温度安定性を改善すべく、Ｎ−アシ
ル酸性アミノ酸塩を用いたクリーム状洗浄剤に関して鋭
意検討した結果、Ｎ−アシル酸性アミノ酸塩と２−アル
キル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイ
ミダゾリニウムベタインと多価アルコールとを後述の如
き特定割合にて配合した場合には、使用感及び、温度安
定性に優れたクリーム状洗浄剤組成物が得られることを
見いだし、本発明を完成するに至った。[Means for Solving the Problems] In view of the above-mentioned drawbacks of cream-like detergents, the present inventors developed a cream-like detergent using an N-acyl acidic amino acid salt in order to improve the feeling of use and temperature stability. As a result of intensive studies regarding the agent, we found that when N-acyl acidic amino acid salt, 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, and polyhydric alcohol are blended in specific proportions as described below, It was discovered that a cream-like cleaning composition with excellent usability and temperature stability can be obtained, and the present invention was completed.
［発明の構成］
即ち、本発明は、 （Ａ）−ｆｆｉ式（１）で表される
Ｎ−アシル酸性アミノ酸塩と、
Ｍｌ ＯＯＣ−（ＣＨ２） ｎ−ＣＨ−Ｃ００Ｍ２
（１）Ｒ，Ｃ０ＮＨ
（但ｉ、、Ｒ１は炭素数７〜２１のアルキル基またはア
ルケニル基、Ｍｌ、Ｍ２は各々水素またはアルカリ金属
、ｎは１または２の整数を示す）（Ｂ）２−アルキル−
Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミダゾ
リニウムベタインと、（Ｃ）多価アルコールとを含有す
ることを特徴とするクリーム状洗浄剤組成物において、
（Ｂ）成分と（Ａ）成分との組成重量比（Ｂ）／（Ａ
）が１／２０以上ないし、１１５未満であり、かつ組成
物中の（Ａ＞成分と（Ｂ）成分の合計含有量が１０〜４
０重量％の範囲であり、かつ（Ｃ）多価アルコールの含
有量が１０〜４０重量％であるクリーム状洗浄剤組成物
である。[Configuration of the Invention] That is, the present invention provides an N-acyl acidic amino acid salt represented by (A)-ffi formula (1), and Ml OOC-(CH2) n-CH-C00M2
(1) R, C0NH (However, R1 is an alkyl group or alkenyl group having 7 to 21 carbon atoms, Ml and M2 are each hydrogen or an alkali metal, n is an integer of 1 or 2) (B) 2- Alkyl-
A cream-like cleaning composition characterized by containing N-carboxymethyl-N-hydroxyethylimidazolinium betaine and (C) a polyhydric alcohol,
Compositional weight ratio of component (B) and component (A) (B)/(A
) is 1/20 or more and less than 115, and the total content of (A>component and (B) component in the composition is 10 to 4
0% by weight, and the content of (C) polyhydric alcohol is 10 to 40% by weight.
［構成の具体的な説明］
本発明に用いられる上記一般式（Ｉ）で表されるＮ−ア
シル酸性アミノ酸塩において、Ｎ−アシル酸性アミノ酸
の構成成分である酸性アミノ酸としては、グルタミン酸
、アスパラギン酸が挙げられ、これらは光学活性体、ラ
セミ体のいずれでも良い、また、アシル基としては、炭
素数８ないし２２の脂肪族アシル基が用いられ、具体的
には、カプリロイル、カプロイル、ラウロイル、ミリス
トイル、バルミトイル、ステアロイル、ベヘノイル、オ
レオイル、ココイル（ヤシ油脂肪酸アシル）、硬化牛脂
脂肪酸アシル、牛脂脂肪酸アシル等が挙げられる。更に
これらのアシル基の混合したものであってもよい。[Specific explanation of the structure] In the N-acyl acidic amino acid salt represented by the above general formula (I) used in the present invention, the acidic amino acids that are constituents of the N-acyl acidic amino acid include glutamic acid and aspartic acid. These may be either optically active or racemic. As the acyl group, an aliphatic acyl group having 8 to 22 carbon atoms is used, specifically capryloyl, caproyl, lauroyl, myristoyl. , valmitoyl, stearoyl, behenoyl, oleoyl, cocoyl (coconut oil fatty acid acyl), hydrogenated beef tallow fatty acid acyl, beef tallow fatty acid acyl, and the like. Furthermore, a mixture of these acyl groups may be used.
本発明で用いられるＮ−アシル酸性アミノ酸を例示する
ならば、Ｎ−カプリロイルグルタミン酸、Ｎ−ラウロイ
ルグルタミン酸、Ｎ−ミリストイルグルタミン酸、Ｎ−
バルミトイルグルタミン酸、Ｎ−ステアロイルグルタミ
ン酸、Ｎ−ベベノイルグルタミン酸、Ｎ−オレオイルグ
ルタミン酸、Ｎ−ココイルグルタミン酸、Ｎ−硬化牛脂
脂肪酸アシルグルタミン酸、Ｎ−カプロイルアスパラギ
ン酸、Ｎ−ラウロイルアスパラギン酸、Ｎ−バルミトイ
ルアスパラギン酸、Ｎ−ステアロイルアスパラギン酸、
Ｎ−ベヘノイルアスパラギン酸、Ｎ−牛脂脂肪酸アシル
アスパラギン酸等及びこれらの混合物が挙げられる。Examples of N-acyl acidic amino acids used in the present invention include N-capryloylglutamic acid, N-lauroylglutamic acid, N-myristoylglutamic acid, N-
Valmitoylglutamic acid, N-stearoylglutamic acid, N-bebenoylglutamic acid, N-oleoylglutamic acid, N-cocoylglutamic acid, N-hydrogenated beef tallow fatty acid acylglutamic acid, N-caproyl aspartic acid, N-lauroyl aspartic acid, N- Valmitoylaspartic acid, N-stearoyl aspartic acid,
Examples include N-behenoylaspartic acid, N-tallow fatty acid acylaspartic acid, and mixtures thereof.
本発明で用いられるＮ−アシル酸性アミノ酸の塩の種類
としては、ナトリウム、カリウム、リチウム等のアルカ
リ金属塩が挙げられるが、これらを単独または混合して
使用できる。Examples of the salts of N-acyl acidic amino acids used in the present invention include alkali metal salts such as sodium, potassium, and lithium salts, which can be used alone or in combination.
本発明に用いられる２−アルキル−Ｎ−カルボキシメチ
ル−Ｎ−ヒドロキシエチルイミダゾリニウムベタインは
化粧品原料基準にも収載されている公知の物質であり、
通常は、脂肪酸とアミノエチルエタノールアミンとを脱
水環化し、次いでモノクロル酢酸ナトリウム及び水酸化
ナトリウムでベタイン化して得られるものであり、シャ
ンプー用界面活性剤として使用されている。２−アルキ
ル−Ｎ−カルボキシメチル−Ｎ−ヒドロキシエチルイミ
ダゾリニウムベタインの製造に使用される脂肪酸として
は、ラウリン酸、ミリスチン酸、パルミチン酸、ステア
リン酸、ヤシ油脂肪酸、硬化牛脂脂肪酸等が挙げられる
０本発明においては、これらの２−アルキル−Ｎ−カル
ボキシメチル−Ｎ−ヒドロキシエチルイミダゾリニウム
ベタインを単独または混合して使用できる。2-Alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine used in the present invention is a known substance that is also listed in the Cosmetic Raw Materials Standards.
It is usually obtained by cyclodehydrating a fatty acid and aminoethylethanolamine, followed by betaineization with sodium monochloroacetate and sodium hydroxide, and is used as a surfactant for shampoos. Fatty acids used in the production of 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine include lauric acid, myristic acid, palmitic acid, stearic acid, coconut oil fatty acid, hydrogenated tallow fatty acid, etc. In the present invention, these 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaines can be used alone or in combination.
本発明に用いられる多価アルコールとしては、ポリエチ
レングリコール、グリセリン、プロピレングリコール、
１，３−ブチレングリコール、ソルビット等が例示され
、これらを単独または混合して使用できる。Polyhydric alcohols used in the present invention include polyethylene glycol, glycerin, propylene glycol,
Examples include 1,3-butylene glycol and sorbitol, which can be used alone or in combination.
本発明のクリーム状洗浄剤組成物においては、（Ａ）Ｎ
−アシル酸性アミノ酸塩と（Ｂ）２−アルキル−
エチルイミダゾリニウムベタインとの組成重量比（Ｂ）
／（Ａ）は１／２０以上ないし、１１５未満であり、か
つ組成物中の（Ａ）成分と（Ｂ）成分の合計含有量は１
０〜４０重量％の範囲である。In the creamy detergent composition of the present invention, (A)N
-Composition weight ratio (B) of acyl acidic amino acid salt and (B) 2-alkyl-ethylimidazolinium betaine
/(A) is 1/20 or more and less than 115, and the total content of components (A) and (B) in the composition is 1/20 or more and less than 115.
It ranges from 0 to 40% by weight.
さらに、 （Ｃ）多価アルコールの含有量は１０〜４０
重量％の範囲である．かかる配合割合をはずれた場合に
は、使用感及び、温度安定性の向上が得られない。Furthermore, (C) the content of polyhydric alcohol is 10 to 40
It is in the range of % by weight. If the blending ratio is outside of this range, the feeling of use and temperature stability cannot be improved.
本発明のクリーム状洗浄剤組成物には、上記の必須成分
の他に、ｄｉ−ピロリドンカルボン酸ナトリウム、乳酸
ナトリウム、尿素、アミノ酸、プロティン、カチオン化
ポリマー、ラノリンまたはその誘導体、クエン酸ナトリ
ウム、硫酸ナトリウム、ヒドロキシエチルセルロース、
カルボキシビニルポリマー、ポリエチレングリコール脂
肪酸エステル等の種々の湿潤剤、コンデイショニング剤
、ビルダー、増粘剤あるいは香料、着色料、防腐剤等の
通常の洗浄剤用原料を適宜配合することができる。In addition to the above-mentioned essential ingredients, the cream detergent composition of the present invention contains sodium di-pyrrolidone carboxylate, sodium lactate, urea, amino acids, proteins, cationized polymers, lanolin or derivatives thereof, sodium citrate, sulfuric acid, etc. sodium, hydroxyethyl cellulose,
Various humectants such as carboxyvinyl polymers and polyethylene glycol fatty acid esters, conditioning agents, builders, thickeners, and common raw materials for cleaning agents such as perfumes, colorants, and preservatives can be appropriately blended.
更に、洗浄時あるいは洗浄後の感触や風合いを調整する
目的で他のアニオン界面活性剤、カチオン界面活性剤、
両性界面活性剤、非イオン界面活性剤を本発明の目的を
達成する範囲で適宜添加することは何等差し支えない．
これらのものには、例えば長鎖脂肪酸塩、アルキル硫酸
塩、ポリオキシエチレンアルキルエーテル硫酸塩、ポリ
オキシエチレンアルキルスルホコハク酸塩、アシルモノ
エタノールアミドポリオキシエチレンスルホコハク酸モ
ノエステル塩、モノアルキルリン酸塩、ポリオキシエチ
レンアルキルエーテルリン酸塩、Ｎ−アシル中性アミノ
酸及びその塩、第四級アンモニウム塩、Ｎ−長鎖アシル
塩基性アミノ酸アルキルエステル塩、高級脂肪酸アミド
プロビルジメチルアミノ酢酸ベタイン、ポリオキシエチ
レンソルビタン脂肪酸部分エステル、ポリオキシエチレ
ングリセリン脂肪酸部分エステル、ポリオキシエチレン
モノ脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油
、ショ糖脂肪酸エステル、Ｎ−アシルグルタミン酸ポリ
オキシエチレンアルキルエーテルジエステル、モノピロ
グルタミン酸モノ脂肪酸ポリオキシエチレン硬化しマシ
油、モノピログルタミン酸モノ脂肪酸ポリオキシエチレ
ングリセリン、脂肪酸アルキロールアミド、アルキルア
ミンオキシド等が挙げられる。Furthermore, other anionic surfactants, cationic surfactants,
There is no problem in adding amphoteric surfactants and nonionic surfactants as appropriate to the extent that the purpose of the present invention is achieved.
These include, for example, long-chain fatty acid salts, alkyl sulfates, polyoxyethylene alkyl ether sulfates, polyoxyethylene alkyl sulfosuccinates, acyl monoethanolamide polyoxyethylene sulfosuccinate monoester salts, monoalkyl phosphates. , polyoxyethylene alkyl ether phosphate, N-acyl neutral amino acid and its salt, quaternary ammonium salt, N-long chain acyl basic amino acid alkyl ester salt, higher fatty acid amidoprobyl dimethylamino acetic acid betaine, polyoxy Ethylene sorbitan fatty acid partial ester, polyoxyethylene glycerin fatty acid partial ester, polyoxyethylene monofatty acid ester, polyoxyethylene hydrogenated castor oil, sucrose fatty acid ester, N-acylglutamic acid polyoxyethylene alkyl ether diester, monopyroglutamic acid monofatty acid polyester Examples include oxyethylene hardened mustard oil, monopyroglutamic acid monofatty acid polyoxyethylene glycerin, fatty acid alkylolamides, and alkylamine oxides.
本発明のクリーム状洗浄剤組成物は、従来のりリーム状
洗浄剤組成物の製造の場合と同様に容易に製造すること
ができる０例えば、各成分を水とともに加熱混合して溶
解した後、攪拌しながら室温まで冷却すればよく、従来
の製造装置で容易に製造できる。The cream-like detergent composition of the present invention can be easily produced in the same manner as in the production of conventional cream-like detergent compositions. For example, after heating and mixing each component with water to dissolve it, stirring It can be easily manufactured using conventional manufacturing equipment.
本発明のクリーム状洗浄剤組成物は、クレンジングフオ
ーム（クリーム状洗顔料）、シャンプー、浴用洗浄剤、
台所用洗剤、その他多くのクリーム状の洗浄剤に適用さ
れる。The creamy cleansing composition of the present invention includes cleansing foam (creamy face wash), shampoo, bath cleansing agent,
Applies to kitchen detergents and many other creamy cleaning products.
［実施例］
以下、実施例にて本発明を更に詳細に説明するが、本発
明はこれに限定されるものではない、尚、各実施例及び
比較例において組成は重量％で示されている。[Example] Hereinafter, the present invention will be explained in more detail with reference to Examples, but the present invention is not limited thereto. In each Example and Comparative Example, the composition is expressed in weight%. .
実施例１
本発明に基づき第１表に示す種々の組成のクリーム状洗
浄剤組成物を調製し、性能を評価した。Example 1 Based on the present invention, creamy detergent compositions having various compositions shown in Table 1 were prepared and their performance was evaluated.
尚、効果の測定は、以下の試験法と評価法によって行っ
た。The effects were measured using the following test methods and evaluation methods.
使」Ｌ怒
調製した液体洗浄剤組成物について、泡の感触、起泡性
、しっとり感について、下記の基準により評価し、その
結果を第１表に示した。The prepared liquid detergent composition was evaluated in terms of foam feel, foaming properties, and moist feeling according to the following criteria, and the results are shown in Table 1.
Ｕ皿五ヱ１
比較例１の組成物を標準品として、１２名のパネラ−を
用いて洗顔による官能試験を行い、泡の感触を評価した
。Using the composition of Comparative Example 1 as a standard product, a sensory test was conducted by washing the face of 12 panelists to evaluate the feel of the foam.
○：標準品よりもクリーミーな泡
Δ：標準品と同程度
×：標準品よりも劣る
ｕと且主上
比較例１の組成物を標準品として、１５名のパネラ−を
用いて洗髪による官能試験を行い、起泡性を評価した。○: Creamier foam than the standard product Δ: Same level as the standard product ×: Inferior to the standard product A test was conducted to evaluate foaming properties.
Ｏ：標準品よりも起泡性が良い
Δ：標準品と同程度
×：標準品よりも劣る
ｆｆｉユ上ユｊ
比較例１の組成物を標準品として、１５名のパネラ−を
用いて洗顔による官能試験を行い、洗顔後のしっとり感
を評価した。O: Better foaming properties than the standard product Δ: Same level as the standard product A sensory test was conducted to evaluate the moist feeling after washing the face.
Ｏ：標準品よりもしっとりしている
Δ：標準品と同程度
×：標準品よりも劣る
ｌヱ安淀ヱ
調製したクリーム状洗浄剤組成物を各々０°Ｃ１４０°
Ｃに２週間放置し、色相、匂いの変化、及び分離、固化
等の形態の変化の有無を観察した。O: Moister than the standard product Δ: Same level as the standard product ×: Inferior to the standard product Each of the creamy detergent compositions prepared by Yasudai was heated at 0°C and 140°C.
C for two weeks, and the presence or absence of changes in hue, odor, and changes in morphology such as separation and solidification was observed.
Ｏ：色相、匂いの変化または形態の変化が殆ど認められ
ない。O: Almost no change in hue, odor, or morphology is observed.
Δ：色相、匂いの変化または形態の変化が若干比められ
る。Δ: Changes in hue, odor, or form are slightly comparable.
×：色相、匂いの変化または形態の変化がかなり認めら
れる。×: Significant changes in hue, odor, or morphology are observed.
（結果）
第１表に示すように本発明のクリーム状洗浄剤組成物は
使用感、温度安定性に優れていた。(Results) As shown in Table 1, the creamy detergent composition of the present invention was excellent in feel and temperature stability.
実施例２
本発明に基づき第２表に示すクレンジングフオーム（ク
リーム状洗顔料）組成物を調製し、実施例１に準じて試
験した。Example 2 Based on the present invention, cleansing foam (creamy facial cleansing) compositions shown in Table 2 were prepared and tested according to Example 1.
第 ２ 表 クレンジングフオーム組成物（結果）
第２表のクレンジングフオーム組成物は使用域、温度安
定性に優れていた。Table 2 Cleansing Foam Compositions (Results) The cleansing foam compositions shown in Table 2 were excellent in use range and temperature stability.
実施例３
本発明に基づき第３表に示すクリーム状シャンプー組成
物を調製した。Example 3 Cream shampoo compositions shown in Table 3 were prepared according to the present invention.
第 ３ 表 クリーム状シャンプー組成物（結果）
第３表のクリーム状シャンプー組成物は使用感、温度安
定性に優れていた。Table 3 Cream Shampoo Compositions (Results) The cream shampoo compositions shown in Table 3 were excellent in feel and temperature stability.
実施例４
本発明に基づき第４表に示すクリーム状浴用洗浄剤組成
物を調製した。Example 4 Based on the present invention, creamy bath cleaning compositions shown in Table 4 were prepared.
第 ４ 表 クリーム状浴用洗浄剤組成物（結果）
第４表のクリーム状浴用洗浄剤組成物は使用感、温度安
定性に優れていた。Table 4 Creamy Bath Cleaning Composition (Results) The creamy bath cleaning composition shown in Table 4 was excellent in feel and temperature stability.
実施例５
本発明に基づき第５表に示すクリーム状台所用洗剤組成
物を調製した。Example 5 Based on the present invention, creamy kitchen detergent compositions shown in Table 5 were prepared.
（結果）
第５表のクリーム状台所用洗剤組成物は使用感、温度安
定性に優れていた。(Results) The creamy kitchen detergent compositions shown in Table 5 were excellent in feel and temperature stability.
［発明の効果］
以上記載のごとく、本発明は、使用感及び、温度安定性
に優れたクリーム状洗浄剤組成物を提供することは明ら
かである。[Effects of the Invention] As described above, it is clear that the present invention provides a creamy detergent composition with excellent usability and temperature stability.
Claims (1)
酸塩と、 ▲数式、化学式、表等があります▼（ I ） （但し、Ｒ＿１は炭素数７〜２１のアルキル基またはア
ルケニル基、Ｍ＿１、Ｍ＿２は各々水素またはアルカリ
金属、ｎは１または２の整数を示す） （Ｂ）２−アルキル−Ｎ−カルボキシメチル−Ｎ−ヒド
ロキシエチルイミダゾリニウムベタインと、 （Ｃ）多価アルコールとを含有することを特徴とするク
リーム状洗浄剤組成物において、（Ｂ）成分と（Ａ）成
分との組成重量比（Ｂ）／（Ａ）が１／２０以上ないし
、１／５未満であり、かつ組成物中の（Ａ）成分と（Ｂ
）成分の合計含有量が１０〜４０重量％の範囲であり、
かつ（Ｃ）多価アルコールの含有量が１０〜４０重量％
であるクリーム状洗浄剤組成物。[Scope of Claims] (A) N-acyl acidic amino acid salt represented by the general formula (I), ▲There are numerical formulas, chemical formulas, tables, etc.▼(I) (However, R_1 is a carbon number of 7 to 21 (B) 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, (C ) A cream-like detergent composition characterized by containing a polyhydric alcohol, wherein the composition weight ratio (B)/(A) of the component (B) and the component (A) is 1/20 or more, or 1 /5, and component (A) and (B
) The total content of the components is in the range of 10 to 40% by weight,
and (C) the content of polyhydric alcohol is 10 to 40% by weight
A creamy cleaning composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12334288A JPH0823036B2 (en) | 1988-05-20 | 1988-05-20 | Creamy cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12334288A JPH0823036B2 (en) | 1988-05-20 | 1988-05-20 | Creamy cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01294799A true JPH01294799A (en) | 1989-11-28 |
| JPH0823036B2 JPH0823036B2 (en) | 1996-03-06 |
Family
ID=14858194
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12334288A Expired - Lifetime JPH0823036B2 (en) | 1988-05-20 | 1988-05-20 | Creamy cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0823036B2 (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000143497A (en) * | 1998-11-13 | 2000-05-23 | Ajinomoto Co Inc | Creamy detergent composition |
| FR2839078A1 (en) * | 2002-04-24 | 2003-10-31 | Ajinomoto Kk | Detergent composition, useful as skin and hair detergent, comprises surfactant(s), N-(long-chain acyl) acidic amino acid(s) and cationic polymer compound(s) |
| US6656892B2 (en) | 2001-04-24 | 2003-12-02 | Ajinomoto Co., Inc. | Detergent composition |
| JP2005325243A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Cleaning composition |
| JP2005350645A (en) * | 2004-05-13 | 2005-12-22 | Asahi Kasei Chemicals Corp | Cleaning composition |
| JP2010215577A (en) * | 2009-03-18 | 2010-09-30 | Nof Corp | Hair shampoo composition |
| US7947260B2 (en) | 2006-07-07 | 2011-05-24 | Ajinomoto Co., Inc. | Low temperature-stable creamy wash composition |
| JP2017066048A (en) * | 2015-09-28 | 2017-04-06 | 味の素株式会社 | Creamy detergent composition and method for producing the same |
| JP2019001724A (en) * | 2017-06-12 | 2019-01-10 | ちふれホールディングス株式会社 | Cleaning composition |
| CN111263803A (en) * | 2017-11-06 | 2020-06-09 | 味之素株式会社 | Cleaning agent composition |
| US10736826B2 (en) | 2016-07-08 | 2020-08-11 | Ajinomoto Co., Inc. | Cream-like composition |
| JP2022023822A (en) * | 2020-07-27 | 2022-02-08 | 三洋化成工業株式会社 | Cleanser composition |
-
1988
- 1988-05-20 JP JP12334288A patent/JPH0823036B2/en not_active Expired - Lifetime
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000143497A (en) * | 1998-11-13 | 2000-05-23 | Ajinomoto Co Inc | Creamy detergent composition |
| US6656892B2 (en) | 2001-04-24 | 2003-12-02 | Ajinomoto Co., Inc. | Detergent composition |
| FR2839078A1 (en) * | 2002-04-24 | 2003-10-31 | Ajinomoto Kk | Detergent composition, useful as skin and hair detergent, comprises surfactant(s), N-(long-chain acyl) acidic amino acid(s) and cationic polymer compound(s) |
| JP2005350645A (en) * | 2004-05-13 | 2005-12-22 | Asahi Kasei Chemicals Corp | Cleaning composition |
| JP2005325243A (en) * | 2004-05-14 | 2005-11-24 | Asahi Kasei Chemicals Corp | Cleaning composition |
| US7947260B2 (en) | 2006-07-07 | 2011-05-24 | Ajinomoto Co., Inc. | Low temperature-stable creamy wash composition |
| CN101100630B (en) | 2006-07-07 | 2012-02-29 | 味之素株式会社 | Low temperature stable milky detergent composition |
| JP2010215577A (en) * | 2009-03-18 | 2010-09-30 | Nof Corp | Hair shampoo composition |
| JP2017066048A (en) * | 2015-09-28 | 2017-04-06 | 味の素株式会社 | Creamy detergent composition and method for producing the same |
| US10736826B2 (en) | 2016-07-08 | 2020-08-11 | Ajinomoto Co., Inc. | Cream-like composition |
| JP2019001724A (en) * | 2017-06-12 | 2019-01-10 | ちふれホールディングス株式会社 | Cleaning composition |
| CN111263803A (en) * | 2017-11-06 | 2020-06-09 | 味之素株式会社 | Cleaning agent composition |
| JP2022023822A (en) * | 2020-07-27 | 2022-02-08 | 三洋化成工業株式会社 | Cleanser composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0823036B2 (en) | 1996-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1163563A (en) | Liquid surfactant skin cleanser with lather boosters | |
| JPS6159283B2 (en) | ||
| JPH06172156A (en) | Lowly stimulative body detergent composition containing sodium alcohol ethoxyglycelyl sulfonate | |
| JPH01294799A (en) | Creamy detergent composition | |
| AU716758B2 (en) | Body soap composition | |
| JP3545372B2 (en) | Skin cleansing composition | |
| JPH0226676B2 (en) | ||
| KR100346315B1 (en) | Cleaning composition | |
| JPH01272697A (en) | Liquid detergent composition | |
| JPH0561259B2 (en) | ||
| JPH083585A (en) | Detergent composition | |
| JPH08134494A (en) | Detergent composition | |
| JPH01135714A (en) | Creamy skin cleaning agent | |
| JPS6023156B2 (en) | Creamy cleaning composition | |
| JPH02212598A (en) | Liquid detergent composition | |
| JPH07309742A (en) | Creamy skin detergent | |
| JPH01294798A (en) | Liquid detergent composition | |
| JP3376687B2 (en) | Detergent composition | |
| JPS6375096A (en) | Detergent composition | |
| JPS59138298A (en) | Transparent gel detergent composition | |
| JP2844495B2 (en) | Detergent composition | |
| JPH01294800A (en) | Liquid detergent composition | |
| JPH0436223A (en) | Low irritation detergent composition | |
| JP3362149B2 (en) | Detergent composition | |
| JPH0226674B2 (en) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080306 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090306 Year of fee payment: 13 |
|
| EXPY | Cancellation because of completion of term | ||
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090306 Year of fee payment: 13 |